ChemistryOpen最新文献

Facile and Practical Synthesis of Substituted Piperidine-2,6-Diones Under Transition-Metal Free Condition. 无过渡金属条件下取代哌啶-2,6-二酮的简易实用合成。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-27 DOI: 10.1002/open.202500067

Yue-Hua Liu, Zhang-Qin Xue, Kai-Wen Yang, Hao-Wen Yin, Bo Yang, Rui Zhang, Hao Zhong, Zhu-Shuang Bai

{"title":"Facile and Practical Synthesis of Substituted Piperidine-2,6-Diones Under Transition-Metal Free Condition.","authors":"Yue-Hua Liu, Zhang-Qin Xue, Kai-Wen Yang, Hao-Wen Yin, Bo Yang, Rui Zhang, Hao Zhong, Zhu-Shuang Bai","doi":"10.1002/open.202500067","DOIUrl":"https://doi.org/10.1002/open.202500067","url":null,"abstract":"Substituted piperidine-2,6-diones are privileged scaffolds in numerous bioactive molecules and their facile and practical preparation still remains unsolved. In this paper, a facile and practical approach for the construction of α-substituted and α,α-/α,β-disubstituted piperidine-2,6-diones from abundant methyl acetates and acrylamides under transition-metal free condition was disclosed. It features mild reaction condition, operational simplicity, and excellent functional group tolerance, delivering a wide range of piperidine-2,6-diones in moderate to good yield. Furthermore, the application potential was further demonstrated by reaction scale-up (5 kilo-gram scale) and bio-active molecule synthesis (Aminoglutethimide and Niraparib). Additional control experiments revealed that the radical process could be excluded from this reaction and a michael addition/intramolecular imidation cascade sequence was proposed based on the control experiments. All these results demonstrated its significant application potential both in academic and industrial production.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e202500067"},"PeriodicalIF":2.5,"publicationDate":"2025-06-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144504958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Ytterbium-Zinc Oxide Embedded on Hexagonal Boron Nitride Nanocomposite for Electro-Oxidation of Ciprofloxacin. 六方氮化硼纳米复合材料包埋氧化钇-氧化锌电氧化环丙沙星。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-26 DOI: 10.1002/open.202500246

Collen Nepfumbada, Christopher P Woodley, Bhekie B Mamba, Bart M Bartlett, Usisipho Feleni

{"title":"Ytterbium-Zinc Oxide Embedded on Hexagonal Boron Nitride Nanocomposite for Electro-Oxidation of Ciprofloxacin.","authors":"Collen Nepfumbada, Christopher P Woodley, Bhekie B Mamba, Bart M Bartlett, Usisipho Feleni","doi":"10.1002/open.202500246","DOIUrl":"https://doi.org/10.1002/open.202500246","url":null,"abstract":"Metal oxide-based electrocatalysts have become increasingly popular in the electrochemical field due to their outstanding electrocatalytic properties. Herein, a hydrothermal approach is used to synthesize the composite of ytterbium zinc oxide endorsed on 2D hexagonal boron nitride (YbZnO@h-BN). Different analytical methods, including Fourier transform infrared (FTIR), Raman spectroscopy, field emission scanning electron microscopy (FESEM), transmission electron microscopy (TEM), and X-ray diffraction (XRD), along with X-ray photoelectron spectroscopy (XPS), are used to interrogate the morphological and structural characteristics of the nanocomposite. FTIR analysis reveals Zn-O and Yb-O functionality, while SEM images shows the YbZnO@h-BN microspherical structure. Cyclic voltammetry (CV) and square-wave voltammetry (SWV) techniques are employed for the electrochemical analysis of Ciprofloxacin (CIP) on the YbZnO@h-BN/glassy carbon electrode (GCE)-modified electrode. The YbZnO@h-BN/GCE sensor demonstrates a broad linear range (0.05 μM to 100 μM) with a lower limit of detection (0.059 μM) and high sensitivity of 7.4441 μA μM-1 cm-2 under optimal conditions. Additionally, the sensor shows good responsiveness for CIP, along with notable reproducibility, stability, and selectivity. Furthermore, the genuine real wastewater sample and commercial CIP tablet are utilized to investigate the usefulness of the proposed YbZnO@h-BN/GCE sensor for CIP detection in real practice, revealing satisfactory recovery values of 94 to 105% and 95 to 112%, respectively.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500246"},"PeriodicalIF":2.5,"publicationDate":"2025-06-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144494912","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Comparative Photo-Induced Aging of Poly(Butylene Adipate-co-Terephthalate) and Polystyrene Microplastics and their Divergent Affinities for Tetracycline in Aquatic Environments. 聚己二酸丁二酯和聚苯乙烯微塑料的光致老化比较及其对四环素在水生环境中的不同亲和力。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-25 DOI: 10.1002/open.202500243

Sadam Hussain Tumrani, Zeenat Naz, Razium Ali Soomro, Mohamed E Khalifa, Gaber A M Mersal, Ahmed M Fallatah, Selcan Karakuş

{"title":"Comparative Photo-Induced Aging of Poly(Butylene Adipate-co-Terephthalate) and Polystyrene Microplastics and their Divergent Affinities for Tetracycline in Aquatic Environments.","authors":"Sadam Hussain Tumrani, Zeenat Naz, Razium Ali Soomro, Mohamed E Khalifa, Gaber A M Mersal, Ahmed M Fallatah, Selcan Karakuş","doi":"10.1002/open.202500243","DOIUrl":"https://doi.org/10.1002/open.202500243","url":null,"abstract":"Microplastics (MPs) experience photo-induced surface modification in sunlit waters, yet the implications for contaminant binding differ fundamentally for biodegradable and conventional MPs. To simulate submerged aging, biodegradable poly (butylene adipate-co-terephthalate) (PBAT) and nondegradable polystyrene (PS) are exposed to ultraviolet A irradiation and river water for 30 days. Aged PBAT shows significant surface oxidation, including a 16% decrease in carbonyl index, a reversal of ζ-potential from slightly positive to -50 mV, and an increase in tetracycline (TC) sorption kinetics. In contrast, the nondegradable analog (PS) displays only modest oxidation (ΔCI ≈ 6%), a smaller charge shift, and a lower capacity increase (qm ≈ 33 mg g-1). Maximum TC uptake occurs at pH ≈ 7, whereas modest salinity increments (0.010-0.0105 M) attenuate retention, confirming the controlling influence of electrostatic forces. Fluorescence quenching (86% vs 74% for PBAT and PS) and Akaike information criterion/Bayesian information criterion-ranked model fits indicate that hydrogen bonding and electrostatic attraction dominate on the biodegradable surface, whereas π-π and hydrophobic interactions on the PS. This work confirms that submerged photo-oxidation turns biodegradable MPs into reactive, salinity-sensitive antibiotic sinks while conventional MPs remain inert transport vectors, emphasizing the need for MP-specific risk assessment and antibiotic pollution mitigation in aquatic settings.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500243"},"PeriodicalIF":2.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144483356","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Impregnation of Melaleuca Family Essential Oil Nanoemulsions into Pectin:Polyvinyl Alcohol Patches to Provide an Antibacterial Environment for Infected Wounds. 千层树家族精油纳米乳浸渍于果胶聚乙烯醇贴剂中为感染伤口提供抗菌环境。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-25 DOI: 10.1002/open.202500117

Didem Demir, Seda Ceylan, Semih Latif İpek, Deren Aslan, Veli Özbolat

{"title":"Impregnation of Melaleuca Family Essential Oil Nanoemulsions into Pectin:Polyvinyl Alcohol Patches to Provide an Antibacterial Environment for Infected Wounds.","authors":"Didem Demir, Seda Ceylan, Semih Latif İpek, Deren Aslan, Veli Özbolat","doi":"10.1002/open.202500117","DOIUrl":"https://doi.org/10.1002/open.202500117","url":null,"abstract":"Essential oils have long been utilized in food, cosmetic, and medicinal applications. Recently, their biomedical use for wound healing, skin repair, and tissue regeneration has gained considerable attention. In this study, tea tree oil (TTO) and niaouli oil (NIO) were formulated into aqueous nanoemulsions (NEs) and incorporated into pectin/polyvinyl alcohol (PP) thin films to develop antibacterial wound dressing patches. The NEs were characterized by dynamic light scattering (DLS), and their morphological and chemical structures were also analyzed. The patches' morphology, hydrophilicity, swelling ratio, and mechanical properties were evaluated to assess the effect of NEs on material performance. Antibacterial activity assessed by plate count and agar diffusion methods against six bacteria commonly associated with infected wounds showed significant efficacy of NEs-loaded patches against Gram-negative strains and Escherichia coli. Direct and indirect cytotoxicity tests, using Mouse embryonic fibroblast (MEF) cells, confirmed that NEs incorporation maintained cell viability within acceptable limits and promoted their biocompatibility. These findings suggest that TTO and NIO-based nanoemulsion patches are promising candidates for antibacterial wound dressings.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500117"},"PeriodicalIF":2.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144483357","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Synthesis and Mechanistic Study of a Copolymer Demulsifier for Dehydration of Water-in-Oil Emulsion of Crude Oil. 原油油包水乳状液共聚物破乳剂的合成及机理研究。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-25 DOI: 10.1002/open.202500188

Xuezhi Li, Bin Ma, Liming Fu, Jing Bai, Qingbing Zhang, Baolu Yu

{"title":"Synthesis and Mechanistic Study of a Copolymer Demulsifier for Dehydration of Water-in-Oil Emulsion of Crude Oil.","authors":"Xuezhi Li, Bin Ma, Liming Fu, Jing Bai, Qingbing Zhang, Baolu Yu","doi":"10.1002/open.202500188","DOIUrl":"https://doi.org/10.1002/open.202500188","url":null,"abstract":"This study presents the synthesis and characterization of a novel polymeric demulsifier, P(AM-EHMA-VBS-VP), through emulsion polymerization for efficient separation of water-in-crude oil emulsions. The synthesis parameters are systematically optimized using orthogonal array design complemented by single-factor experiments. The demulsification performance is evaluated under simulated field conditions, with particular emphasis on dosage optimization and temperature effects. Comprehensive mechanistic investigations are conducted through dynamic interfacial tension measurements, interfacial dilational rheology analysis, and zeta potential characterization to elucidate the demulsification mechanism and the impact of inorganic salts on demulsification efficiency. The optimized synthesis conditions yield a copolymer with monomer mass ratios of AM:EHMA:VBS:VP = 1:4:4:1, achieved at 60 °C for 8 h with 30% monomer concentration and 0.15% initiator dosage. Optimal demulsification performance is observed at 80 °C with a demulsifier concentration of 300 mg L-1. The synthesized demulsifier demonstrates remarkable salt tolerance, maintaining effectiveness in environments containing up to 30 000 mg L-1 NaCl and 10 000 mg L-1 CaCl2. Mechanistic studies reveal that the demulsifier operates through interfacial adsorption, which simultaneously reduces the mechanical strength of the interfacial film and decreases the surface charge density of emulsion droplets. This dual mechanism effectively compromises the emulsion stability by diminishing both the film's resistance to deformation and the electrostatic repulsion between droplets.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500188"},"PeriodicalIF":2.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144483358","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Challenges in Mechanistic Investigation of a Flexible Aminocatalyst as Demonstrated through Enamine Formation. 通过烯胺形成证明的柔性氨基催化剂机理研究的挑战。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-25 DOI: 10.1002/open.202500116

Irina Osadchuk, Tõnis Kanger

{"title":"Challenges in Mechanistic Investigation of a Flexible Aminocatalyst as Demonstrated through Enamine Formation.","authors":"Irina Osadchuk, Tõnis Kanger","doi":"10.1002/open.202500116","DOIUrl":"https://doi.org/10.1002/open.202500116","url":null,"abstract":"Asymmetric catalysis has become a prominent topic in synthesis over recent decades. Conformational changes in the catalyst core play a significant role in the reaction, determining both its rate and selectivity. This article presents computational studies of enamine formation from cyclohexanone and the tripeptide catalyst Phe-Lys-Phe and considers challenges related to conformational search and the selection of an appropriate level of theory for studying flexible catalysts. This also demonstrates the importance of selecting the initial model system and how reducing the system under study or including the entire system in the model can impact the study's outcome. Furthermore, incorporating a water molecule into the model system significantly reduces the energy of proton transfer. Finally, the catalyst's ability to reorganize plays an important role, since it allows the energy of the transition states to be reduced. Thus, this shows that an alternative reaction pathway is more favorable than the one initially found, and the catalyst's flexibility allows and contributes its conformations to vary at different stages of the reaction.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500116"},"PeriodicalIF":2.5,"publicationDate":"2025-06-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144483341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Essential Oil Profiles of Lippia turbinata (Verbenaceae) from Argentina: Insights from a Systematic Review and Meta-Analysis. 阿根廷马鞭草科（Lippia turbinata）精油谱：来自系统综述和荟萃分析的见解。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-24 DOI: 10.1002/open.202500203

Fernando Livio Corzo, Franco Emmanuel Calvo, Emilio Fernando Lizarraga, Guillermo Emilio Marcial, Maria Ines Mercado

{"title":"Essential Oil Profiles of Lippia turbinata (Verbenaceae) from Argentina: Insights from a Systematic Review and Meta-Analysis.","authors":"Fernando Livio Corzo, Franco Emmanuel Calvo, Emilio Fernando Lizarraga, Guillermo Emilio Marcial, Maria Ines Mercado","doi":"10.1002/open.202500203","DOIUrl":"https://doi.org/10.1002/open.202500203","url":null,"abstract":"Lippia turbinata (Verbenaceae), \"poleo,\" is an aromatic shrub native to Argentina, Chile, and Paraguay. Traditionally used as food and medicine, it exhibits a great polymorphism and essential oil (EO) variability. This study analyzes the EO profile of the different populations of L. turbinata distributed throughout Argentina through a meta-analysis comparing their chemical composition of EOs reported in the literature. The meta-analysis comparison with available literature suggests the existence of chemotypes within the species that may correlate with infraspecific genetic differences, geographical origin of the plants, phenological stage, soil, and stress conditions, among other factors. This analysis reveals that the most frequent and abundant compounds are limonene, carvone, β-caryophyllene, and its derivative oxide. This approach of multivariate statistical analyses enables to compare EO profiles of different populations and identify critical thresholds for selecting chemotypes to optimize the species' applications in the food, pharmacology, and agriculture industries.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500203"},"PeriodicalIF":2.5,"publicationDate":"2025-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144474080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The Atmospheric Pressure Capillary Plasma Jet Is Well-Suited to Supply H₂O₂ for Plasma-Driven Biocatalysis. 常压毛细管等离子体射流非常适合为等离子体驱动的生物催化提供H2O2。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-22 DOI: 10.1002/open.202500057

Tim Dirks, Davina Stoesser, Steffen Schüttler, Frank Hollmann, Judith Golda, Julia E Bandow

{"title":"The Atmospheric Pressure Capillary Plasma Jet Is Well-Suited to Supply H2O2 for Plasma-Driven Biocatalysis.","authors":"Tim Dirks, Davina Stoesser, Steffen Schüttler, Frank Hollmann, Judith Golda, Julia E Bandow","doi":"10.1002/open.202500057","DOIUrl":"https://doi.org/10.1002/open.202500057","url":null,"abstract":"Plasma-generated H2O2 can be used to fuel biocatalytic reactions that require H2O2 as a cosubstrate, such as the conversion of ethylbenzene to (R)-1-phenylethanol ((R)-1-PhOl) catalyzed by unspecific peroxygenase from Agrocybe aegerita (rAaeUPO). Immobilization is recently shown to protect biocatalysts from inactivation by highly reactive plasma-produced species; however, H2O2 supply by the employed plasma sources (μAPPJ and DBD) is limiting for rAaeUPO performance. This study evaluates a recently introduced capillary plasma jet for suitability to supply H2O2 in situ. H2O2 production is modulated by varying the water concentration in the feed gas, providing a greater operating window for applications in plasma-driven biocatalysis. In a static system after 80 min of biocatalysis, a turnover number of 44,199 mol(R)-1-PhOl mol-1 rAaeUPO is achieved without significant enzyme inactivation. By exchanging the reaction solution every 5 min, a total product yield of 122 μmol (R)-1-PhOl is achieved in 700 min run time, resulting in a total turnover number of 174,209 mol(R)-1-PhOl mol-1 rAaeUPO. This study concludes that the capillary plasma jet, due to its flexibility regarding feed gas, admixtures, and power input, is well suited for in situ H2O2 generation for plasma-driven biocatalysis tailoring to enzymes with high H2O2 turnover.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500057"},"PeriodicalIF":2.5,"publicationDate":"2025-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144367987","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Kinetic Investigation by Batch Processing of Film Growth during the Electrodeposition of Titanium from Ethaline. 间歇处理法制备钛电沉积过程中薄膜生长的动力学研究。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-20 DOI: 10.1002/open.202500311

Katarzyna Grubel, Diana B Horangic, Steven Livers, Christopher J Chancellor, Riah Burnett, Bailey Byrd, Bethany Lawler, Christina Arendt, Lance R Hubbard

引用次数: 0

Simple and Rapid Microwave-Assisted Suzuki-Miyaura Cross-coupling in Betaine/Glycerol Natural Eutectic Solvent. 甜菜碱/甘油天然共晶溶剂的简单快速微波辅助Suzuki-Miyaura交联。

IF 2.5 4区化学

ChemistryOpen Pub Date : 2025-06-17 DOI: 10.1002/open.202500138

Chefikou Salami, Leslie Boudesocque-Delaye, Pierre-Olivier Delaye, Emilie Thiery

{"title":"Simple and Rapid Microwave-Assisted Suzuki-Miyaura Cross-coupling in Betaine/Glycerol Natural Eutectic Solvent.","authors":"Chefikou Salami, Leslie Boudesocque-Delaye, Pierre-Olivier Delaye, Emilie Thiery","doi":"10.1002/open.202500138","DOIUrl":"https://doi.org/10.1002/open.202500138","url":null,"abstract":"For some years now, eutectic solvents have been seen as an alternative to conventional organic solvents and ionic liquids. When the components are of natural origin, they meet the challenges of green chemistry. Although eutectic solvents are used in many synthetic reactions today, few references reported their use in microwave-assisted reactions. To explore their potential and diversify their applications, Suzuki-Miyaura coupling was studied in eutectic solvents under microwave irradiation. After optimization using a design of experiment based on response surface methodology, the most efficient conditions were found to be betaine: glycerol (1:4, mol mol-1) as eutectic solvent, PdCl2dppf.CH2Cl2 as catalyst, Na2CO3 as base, and microwave heating at 129 °C for 15 min. The results showed an increase in reactivity with very rapid reaction kinetics. Furthermore, the catalyst in the eutectic solvent was recycled, and a gram-scale reaction was performed as an example. Finally, this new methodology was evaluated using CHEM21 metrics.","PeriodicalId":9831,"journal":{"name":"ChemistryOpen","volume":" ","pages":"e2500138"},"PeriodicalIF":2.5,"publicationDate":"2025-06-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144315980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0