Journal of hazardous materials最新文献

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Molecular imprinting electrochemical sensor based on hollow spherical PProDOT-2CH2OH and chitosan-derived carbon materials for highly sensitive detection of chloramphenicol. 基于中空球形 PProDOT-2CH2OH 和壳聚糖衍生碳材料的分子印迹电化学传感器,用于高灵敏度检测氯霉素。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-22 DOI: 10.1016/j.jhazmat.2024.135615
Qian Cheng, Cong Xue, Tursun Abdiryim, Ruxangul Jamal
{"title":"Molecular imprinting electrochemical sensor based on hollow spherical PProDOT-2CH<sub>2</sub>OH and chitosan-derived carbon materials for highly sensitive detection of chloramphenicol.","authors":"Qian Cheng, Cong Xue, Tursun Abdiryim, Ruxangul Jamal","doi":"10.1016/j.jhazmat.2024.135615","DOIUrl":"10.1016/j.jhazmat.2024.135615","url":null,"abstract":"<p><p>The misuse of chloramphenicol (CAP) has jeopardized environmental safety. It is critical to create an effective and sensitive CAP detection technique. In this paper, a composite of chitosan (CS)-derived carbon material modified hollow spherical hydroxylated poly(3,4-propylenedioxythiophene) (PProDOT-2CH<sub>2</sub>OH) was designed, which innovatively used o-phenylenediamine and p-aminobenzoic acid as bi-functional monomers to prepare molecular imprinting polymer (MIP) sensors for highly sensitive analysis and determination of CAP. It was found that the hollow spherical structure of PProDOT-2CH<sub>2</sub>OH significantly enhanced the rapid electron migration. When combined with the CS-derived carbon material, which has multi-functional sites, it improved the electrical activity and stability of the sensor. It also provided more active centers for the MIP layer to specifically recognize CAP. Therefore, this MIP sensor had a wide linear response (0.0001 ∼ 125 μM), a low limit of detection (LOD, 6.6 pM), excellent selectivity and stability. In addition, studies showed that the sensor has potential practical value. ENVIRONMENTAL IMPLICATION: Chloramphenicol (CAP) is one of the most widely used antibiotics with the highest dosage due to its low price and broad-spectrum antimicrobial properties. Due to its incomplete metabolism in living organisms and its difficulty in degrading in the environment, contamination caused by it can pose a threat to public health. In this study, a novel molecularly imprinted sensor (MIP/PC2C1/GCE) was designed to provide a new idea for rapid and precise removal of CAP by adsorption. The detection of CAP in pharmaceutical, water quality, and food fields was realized.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135615"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142057627","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Exploring alkali-treated corn cob for high-rate removal of NOX and SO2 from flue gas: Focus on carbon release capacity, removal performance, and comparison with conventional carbon sources. 探索碱处理玉米芯对烟道气中 NOX 和 SO2 的高去除率:重点关注碳释放能力、去除性能以及与传统碳源的比较。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-22 DOI: 10.1016/j.jhazmat.2024.135613
Yao Lu, Biaojun Zhang, Ying Cao, Yanling Wang, Yongqing Zhang, Shaobin Huang
{"title":"Exploring alkali-treated corn cob for high-rate removal of NO<sub>X</sub> and SO<sub>2</sub> from flue gas: Focus on carbon release capacity, removal performance, and comparison with conventional carbon sources.","authors":"Yao Lu, Biaojun Zhang, Ying Cao, Yanling Wang, Yongqing Zhang, Shaobin Huang","doi":"10.1016/j.jhazmat.2024.135613","DOIUrl":"10.1016/j.jhazmat.2024.135613","url":null,"abstract":"<p><p>This investigation explored the potential of utilizing alkali-treated corn cob (CC) as a solid carbon source to improve NO<sub>X</sub> and SO<sub>2</sub> removal from flue gas. Leaching experiments unveiled a hierarchy of chemical oxygen demand release capacity: 0.03 mol/L alkali-treated CC > 0.02 mol/L > 0.01 mol/L > 0.005 mol/L > control. In NO<sub>X</sub> and SO<sub>2</sub> removal experiments, as the inlet NO<sub>X</sub> concentration rose from 300 to 1000 mg/m<sup>3</sup>, the average NO<sub>X</sub> removal efficiency increased from 58.56 % to 80.00 %. Conversely, SO<sub>2</sub> removal efficiency decreased from 99.96 % to 91.05 %, but swiftly rebounded to 98.56 % by day 18. The accumulation of N intermediates (NH<sub>4</sub><sup>+</sup>, NO<sub>3</sub><sup>-</sup>, NO<sub>2</sub><sup>-</sup>) increased with escalating inlet NO<sub>X</sub> concentration, while the accumulation of S intermediates (SO<sub>4</sub><sup>2-</sup>, SO<sub>3</sub><sup>2-</sup>, S<sup>0</sup>) varied based on shifts in the population of functional bacteria. The elevation in inlet NO<sub>X</sub> concentration stimulated the growth of denitrifying bacteria, enhancing NO<sub>X</sub> removal efficiency. Concurrently, the population of nitrate-reducing sulfur-oxidizing bacteria and sulfate-reducing bacteria expanded, aiding in the accumulation of S<sup>0</sup> and the removal of SO<sub>2</sub>. The comparison experiments on carbon sources confirmed the comparable NO<sub>X</sub> and SO<sub>2</sub> removal efficiencies of alkali-treated CC and glucose, yet underscored differences in intermediates accumulation due to distinct genus structures.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135613"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142057620","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Eco-friendly and highly efficient PM0.3 air filter made from nonwoven basalt fiber and electrospun nanocellulose fiber. 由无纺布玄武岩纤维和电纺纳米纤维素纤维制成的环保型高效 PM0.3 空气过滤器。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-22 DOI: 10.1016/j.jhazmat.2024.135608
Desalegn Atalie, Ze-Xin Chen, Hui Li, Cun-Guang Liang, Ming-Cheng Gao, Xiao-Xi Cheng, Peng-Cheng Ma
{"title":"Eco-friendly and highly efficient PM<sub>0.3</sub> air filter made from nonwoven basalt fiber and electrospun nanocellulose fiber.","authors":"Desalegn Atalie, Ze-Xin Chen, Hui Li, Cun-Guang Liang, Ming-Cheng Gao, Xiao-Xi Cheng, Peng-Cheng Ma","doi":"10.1016/j.jhazmat.2024.135608","DOIUrl":"10.1016/j.jhazmat.2024.135608","url":null,"abstract":"<p><p>This study addresses the need for high-performance and sustainable air filters by developing a bio-based, high-efficiency particulate air (HEPA) filter. Current HEPA filters often rely on non-biodegradable materials, creating environmental burdens. In this paper, we presented a HEPA filter fabricated from natural basalt fiber (BF) and nanocellulose fiber. The developed filter featured a sandwich structure with electrospun nanocellulose fiber deposited onto a base BF layer, followed by a second BF layer and heat treatment. Various techniques were employed to characterize the obtained sample, and the results showed that the nonwoven BF fabric significantly reduced the pressure drop of the filter by up to 60 %. The nanocellulose fiber played a crucial role in achieving a remarkable filtration efficiency of 99.99 % for PM<sub>0.3</sub>. BF-based filter demonstrated exceptional fire resistance, hydrophobia, durability, and ease of cleaning, maintaining its effectiveness at temperatures up to 150 °C. Notably, it exhibited significantly better biodegradability than commercially available HEPA filters. By employing a hierarchical structure of sustainable basalt and cellulose fibers, this study paved the way for the development of next-generation hazardous particulate matter filters with exceptional performance in harsh conditions and reduced environmental impact.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135608"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142057687","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Bacterial outer membrane vesicles increase polymyxin resistance in Pseudomonas aeruginosa while inhibiting its quorum sensing. 细菌外膜囊泡增加了铜绿假单胞菌对多粘菌素的抗性,同时抑制了其法定人数感应。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-22 DOI: 10.1016/j.jhazmat.2024.135588
Zhihui Chen, Yucheng Liu, Lan Jiang, Chao Zhang, Xun Qian, Jie Gu, Zilin Song
{"title":"Bacterial outer membrane vesicles increase polymyxin resistance in Pseudomonas aeruginosa while inhibiting its quorum sensing.","authors":"Zhihui Chen, Yucheng Liu, Lan Jiang, Chao Zhang, Xun Qian, Jie Gu, Zilin Song","doi":"10.1016/j.jhazmat.2024.135588","DOIUrl":"10.1016/j.jhazmat.2024.135588","url":null,"abstract":"<p><p>The persistent emergence of multidrug-resistant bacterial pathogens is leading to a decline in the therapeutic efficacy of antibiotics, with Pseudomonas aeruginosa (P. aeruginosa) emerging as a notable threat. We investigated the antibiotic resistance and quorum sensing (QS) system of P. aeruginosa, with a particular focused on outer membrane vesicles (OMVs) and polymyxin B as the last line of antibiotic defense. Our findings indicate that OMVs increase the resistance of P. aeruginosa to polymyxin B. The overall gene transcription levels within P. aeruginosa also reveal that OMVs can reduce the efficacy of polymyxin B. However, both OMVs and sublethal concentrations of polymyxin B suppressed the transcription levels of genes associated with the QS system. Furthermore, OMVs and polymyxin B acted in concert on the QS system of P. aeruginosa to produce a more potent inhibitory effect. This suppression was evidenced by a decrease in the secretion of virulence factors, impaired bacterial motility, and a notable decline in the ability to form biofilms. These results reveal that OMVs enhance the resistance of P. aeruginosa to polymyxin B, yet they collaborate with polymyxin B to inhibit the QS system. Our research contribute to a deeper understanding of the resistance mechanisms of P. aeruginosa in the environment, and provide new insights into the reduction of bacterial infections caused by P. aeruginosa through the QS system.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135588"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142057683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Childhood Helicobacter pylori infection: Impacts of environmental exposures and parental stress. 儿童幽门螺旋杆菌感染:环境暴露和父母压力的影响。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-24 DOI: 10.1016/j.jhazmat.2024.135584
Chan Lu, Wen Deng, Zipeng Qiao, Wenying Sun, Wenhui Yang, Zijing Liu, Faming Wang
{"title":"Childhood Helicobacter pylori infection: Impacts of environmental exposures and parental stress.","authors":"Chan Lu, Wen Deng, Zipeng Qiao, Wenying Sun, Wenhui Yang, Zijing Liu, Faming Wang","doi":"10.1016/j.jhazmat.2024.135584","DOIUrl":"10.1016/j.jhazmat.2024.135584","url":null,"abstract":"<p><strong>Background: </strong>Helicobacter pylori infection (HPI) is extremely common in the world, particularly in less developed areas, but the primary causes of childhood HPI are unspecified.</p><p><strong>Objectives: </strong>To determine the influences of exposure to home environmental factors (HEFs), outdoor air pollutants (OAPs), and parental stress (PS), as well as their interactions on children's HPI.</p><p><strong>Methods: </strong>We implemented a retrospective cohort study with 8689 preschoolers from nine districts at Changsha, China, was conducted using questionnaires to collect data of health and HEFs. Temperature and OAPs data were collected from ten and eight monitoring stations, individually. Temperature and OAPs exposures were calculated for all home addresses using the inversed distance weighted (IDW) model. Multiple logistic regression analysis was carried out to determine the separate and combined impacts of HEFs, OAPs, and PS on HPI.</p><p><strong>Results: </strong>Children's HPI was significantly associated with exposure to moisture-specific indoor allergens in one-year preceding conception, gestation, and first year, smoke-specific air pollution throughout life, and plant-specific allergens in previous year. Outdoor exposures to CO in the 7th-9th month before conception, as well as PM<sub>2.5</sub> in the second trimester and previous year, were associated with HPI, with ORs (95 % CIs) of 1.22 (1.05-1.41), 1.23 (1.03-1.46), and 1.33 (1.14-1.55). Parents' socioeconomic and psychological stress indicators were positively related to HPI. High socioeconomic indicators and psychological stresses increased the roles of indoor renovation and moisture indicators as well as outdoor SO<sub>2</sub>, PM<sub>2.5</sub> and O<sub>3</sub> on children's HPI over their entire lives. Parental psychological stress interacts with indoor renovation-specific air pollution, moisture- and plant-specific allergens, as well as outdoor traffic-related air pollution on HPI, during a critical time window in early life.</p><p><strong>Conclusions: </strong>Indoor and outdoor air pollutants, as well as allergens, separately and interactively exert important effects on childhood HPI, lending support to the \"(pre-) fetal origin of HPI\" hypothesis.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135584"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142057684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
In vivo visualization of environmentally relevant microplastics and evaluation of gut barrier damages in Artemia franciscana. 环境相关微塑料的活体可视化以及对法氏鲟肠道屏障损伤的评估。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-21 DOI: 10.1016/j.jhazmat.2024.135596
Jin Il Kwak, Hanju Rhee, Lia Kim, Youn-Joo An
{"title":"In vivo visualization of environmentally relevant microplastics and evaluation of gut barrier damages in Artemia franciscana.","authors":"Jin Il Kwak, Hanju Rhee, Lia Kim, Youn-Joo An","doi":"10.1016/j.jhazmat.2024.135596","DOIUrl":"10.1016/j.jhazmat.2024.135596","url":null,"abstract":"<p><p>Although irregularly-shaped label-free microplastics (MPs) are predominantly distributed in the environment, non-destructive analysis of environmentally relevant MPs in organisms is still challenging. The purpose of the study is to suggest in vivo visual evidence of the uptake and effect of environmentally relevant MPs in organism. Transparent irregularly-shaped high-density polyethylene was selected as an environmentally relevant model MP and exposed to brine shrimp (Artemia franciscana). As a result, we suggest the application of SEM/EDX and coherent anti-Stokes Raman scattering (CARS) microspectroscopy as complementary tools to secure in vivo visual evidence of irregularly-shaped unlabeled MPs in living organisms without chemical digestion for biodistribution observations. Biological transmission electron microscopy also provides how ingested MPs physically affects the digestive tract in the brine shrimp which is rarely reported. In terms of environmental implications, this study would advance ecotoxicological research on microplastic pollution by providing a cutting-edge tool for investigating the bioavailability and ecotoxicity of environmentally relevant MPs in ecosystems.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135596"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142047718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Daily exposure to chlordecone, an organochlorine pesticide, increases cardiac fibrosis and atrial fibrillation vulnerability. 每天接触十氯酮(一种有机氯杀虫剂)会增加心脏纤维化和心房颤动的可能性。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-14 DOI: 10.1016/j.jhazmat.2024.135533
Alexia Fundere, Andrew Rose, Feng Xiong, Kalai Mangai Muthukumarasamy, Yasemin Altuntas, Harika Dasari, Louis Villeneuve, Martin G Sirois, Jean-François Tanguay, Jean-Claude Tardif, Roddy Hiram
{"title":"Daily exposure to chlordecone, an organochlorine pesticide, increases cardiac fibrosis and atrial fibrillation vulnerability.","authors":"Alexia Fundere, Andrew Rose, Feng Xiong, Kalai Mangai Muthukumarasamy, Yasemin Altuntas, Harika Dasari, Louis Villeneuve, Martin G Sirois, Jean-François Tanguay, Jean-Claude Tardif, Roddy Hiram","doi":"10.1016/j.jhazmat.2024.135533","DOIUrl":"10.1016/j.jhazmat.2024.135533","url":null,"abstract":"<p><strong>Context: </strong>Chlordecone (CLD) is a carcinogenic organochlorine pesticide. CLD was shown to disturb the activity of cardiac Na<sup>+</sup>-K<sup>+</sup>-ATPase and Ca<sup>2+</sup>-Mg<sup>2+</sup>-ATPase. Conditions affecting these transmembrane pumps are often associated with cardiac arrhythmias (CA). However, little is known about the role of CLD on atrial fibrillation (AF) incidence, the most common type of CA.</p><p><strong>Hypotheses: </strong>1) Daily ingestion of CLD induces arrhythmogenic cardiac remodeling. 2) A phase of CLD withdrawal can reduce CLD-induced AF susceptibility.</p><p><strong>Methods: </strong>Adult male Wistar rats (250 g-275 g) ingested daily-doses of CLD (0 μg/L, 0.1 μg/L, or 1 μg/L) diluted in their quotidian water for 4 weeks. From day (D)29 to D56, all rats received CLD-free water. Vulnerability to AF and cardiac function were evaluated at D28 and D56 by electrophysiological study, echocardiography, and optical-mapping. Levels of genes and proteins related to inflammation, fibrosis, and senescence were quantified by qPCR and immunoassays.</p><p><strong>Results: </strong>Twenty-eight days of CLD exposure were associated with significantly increased AF vulnerability compared to CLD-free rats. Contamination with 1 μg/L CLD significantly reduced atrial conduction velocity (ERP, APD). CLD-weaning normalized food consumption and weight intake. However, after the CLD-withdrawal period of 28 days, AF inducibility, atrial inflammation (IL6, IL1β), and atrial fibrosis (Masson's trichrome staining) remained significantly higher in rats exposed to 1 μg/L CLD compared to 0 μg/L.</p><p><strong>Conclusions: </strong>Prolonged CLD ingestion provokes atrial conduction slowing and increased risk of AF. Although CLD-weaning, some persistent damages occurred in the atrium like atrial fibrosis and atrial senescence signals, which are accompanied by atrial inflammation and arrhythmogenicity.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135533"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142038102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of low-cost sludge-based highly porous biochar for efficient removal of refractory pollutants from agrochemical and pharmaceutical wastewater. 制备基于污泥的低成本高多孔生物炭,用于高效去除农用化学品和制药废水中的难降解污染物。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-17 DOI: 10.1016/j.jhazmat.2024.135572
Md Manik Mian, Wenya Ao, Lei Xiao, Jianzhong Xiao, Shubo Deng
{"title":"Preparation of low-cost sludge-based highly porous biochar for efficient removal of refractory pollutants from agrochemical and pharmaceutical wastewater.","authors":"Md Manik Mian, Wenya Ao, Lei Xiao, Jianzhong Xiao, Shubo Deng","doi":"10.1016/j.jhazmat.2024.135572","DOIUrl":"10.1016/j.jhazmat.2024.135572","url":null,"abstract":"<p><p>Producing a high-performance sludge biochar through a feasible method is a great challenge and is crucial for practicability. Herein, we reported a highly porous sludge biochar synthesized from agrochemical-pharmaceutical and municipal sludge blends through a novel pyrolysis-acid treatment-post pyrolysis method. The optimized biochar named ASMS91 obtained interconnected pores with a total pore volume of 0.894 cm<sup>3</sup>/g and a surface area of 691.4 m<sup>2</sup>/g through extended acid wash and subsequent post-pyrolysis, which is superior to non-activated sludge biochar. ASMS91 removed 45.3 % of wastewater COD (156 mg/L) in 24 h, which was rapid and higher performance than commercial activated carbon (1000 iodine number). This outstanding performance is due to its high adsorption ability of long-chain aliphatic compounds (e.g., 2,4-Di-tert-butylphenol, neophytadiene and eicosane) into mesopores, which accounts for 71.8 % of pore filling. ASMS91 was highly recyclable, and adsorption was reduced by only 5.3 % after the 4th cycle. It also outperformed other sludge biochar in literature in removing perfluorooctanoic acid (PFOA), 6:2 fluorotelomer sulfonate (6:2 FTS), sulfamethoxazole, methylene blue, and methylene orange. Finally, the feasibility of our proposed method was validated by a brief techno-economic analysis. This feasible approach may support future research regarding sludge valorization and low-cost chemical wastewater treatment.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135572"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142019924","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Real time monitoring of nerve agent mimics: Novel solid state emitter for enhanced precision and reliability. 实时监测神经毒剂模拟物:新型固态发射器,提高精度和可靠性。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-13 DOI: 10.1016/j.jhazmat.2024.135508
Anju Ranolia, Kiran, Priyanka, Rahul Kumar Dhaka, Jayant Sindhu
{"title":"Real time monitoring of nerve agent mimics: Novel solid state emitter for enhanced precision and reliability.","authors":"Anju Ranolia, Kiran, Priyanka, Rahul Kumar Dhaka, Jayant Sindhu","doi":"10.1016/j.jhazmat.2024.135508","DOIUrl":"10.1016/j.jhazmat.2024.135508","url":null,"abstract":"<p><p>Chemical nerve agents are hazardous compounds that terrorists can exploit to pose a significant threat to public safety and national security. The nucleophilic behaviour of these agents enables their interaction with acetyl cholinesterase in the body, leading to paralysis and potentially fatal consequences. Therefore, developing robust and efficient detection methods for these agents is crucial for preventing their misuse. In this manuscript, (E)-12-(1-hydrazineylideneethyl)benzo[f]pyrido[1,2-a]indole-6,11-dione (HBID) is developed as a novel colorimetric and fluorometric probe for the detection of specific chemical nerve agent simulants in both liquid and vapor phase. HBID reacts rapidly with diethyl chlorophosphate (DCP), a common nerve agent simulant, leading to a significant increase in the fluorescence intensity. Under optimized conditions, HBID exhibits high sensitivity, good recyclability, fast response and low limit of detection (0.092 µM). NMR and mass spectral studies suggest that the reaction involves the nucleophilic addition of HBID to DCP, forming a phosphate ester. Additionally, the developed sensor demonstrates viscosity-sensitive AIE phenomena thus greatly expanding its potential applications in biological systems. This sensitivity enables precise detection and visualization of viscosity changes within cellular environments, making the sensor an invaluable tool for studying complex biological processes. The developed probe also detects pH within biologically relevant range (4-6). In practical applications, the probe-treated strips efficiently detected DCP vapor in real time, showing a noticeable fluorescence response. Further, the probe has a strong potential to detect the presence of DCP in the soil samples.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":"478 ","pages":"135508"},"PeriodicalIF":0.0,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142057693","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-efficiency removal of microcystis aeruginosa using Z-scheme AgBr/NH2-MIL-125(Ti) photocatalyst with superior visible-light absorption: Performance insights and mechanisms. 利用具有优异可见光吸收能力的 Z 型 AgBr/NH2-MIL-125(Ti) 光催化剂高效去除铜绿微囊藻:性能见解与机理。
Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-08 DOI: 10.1016/j.jhazmat.2024.135461
Xingfeng Cao, Gongduan Fan, Jing Luo, Ling Zhang, Shiyun Wu, Yixin Yao, Kai-Qin Xu
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