用于富硒大豆硒诊断的高选择性局部表面等离子体共振传感器。

Journal of hazardous materials Pub Date : 2024-10-05 Epub Date: 2024-08-22 DOI:10.1016/j.jhazmat.2024.135632
Suyan Qiu, Yifan Dong, Xiren Yu, Qiushuang Ai, Lijuan Yuan, Li Zhang, Dawen Zhang
{"title":"用于富硒大豆硒诊断的高选择性局部表面等离子体共振传感器。","authors":"Suyan Qiu, Yifan Dong, Xiren Yu, Qiushuang Ai, Lijuan Yuan, Li Zhang, Dawen Zhang","doi":"10.1016/j.jhazmat.2024.135632","DOIUrl":null,"url":null,"abstract":"<p><p>It is a challenge to determine selenium in acid aqueous for environmental monitoring and selenium-rich agricultural diagnosis. Herein, we developed a novel localized surface plasmon resonance (LSPR) sensor to detect Se(IV) ions based on the extraordinary laterals etching of gold nanorods (AuNRs). The etching started from the laterals in the low amount of Se(IV) ions, and accompanied by an apparent red shift of the longitudinal plasmon band (LPB), and then transformed to the tips etching with the upward of Se(IV) ions, the LPB band immediately shifted to the shorter wavelength. The red shift change (Δλ) of LPB band was utilized to quantitative analysis instead of blue shift or absorbance intensity, which gave a high selectivity for the proposed sensor. More importantly, this sensor could be performed in 0.1 mol/L of HCl solution, which achieved the seamlessly jointing with the pretreatment of complex samples, without time-consuming pH adjustment.Successful selenium detection was demonstrated in complex soybean samples that collected from the maturity after spraying organic chelated selenium at full flower period. The sensor provided a promising way to monitor and diagnose selenium in complex environmental samples and selenium-rich crops.</p>","PeriodicalId":94082,"journal":{"name":"Journal of hazardous materials","volume":null,"pages":null},"PeriodicalIF":0.0000,"publicationDate":"2024-10-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Highly selective localized surface plasmon resonance sensor for selenium diagnosis in selenium-rich soybeans.\",\"authors\":\"Suyan Qiu, Yifan Dong, Xiren Yu, Qiushuang Ai, Lijuan Yuan, Li Zhang, Dawen Zhang\",\"doi\":\"10.1016/j.jhazmat.2024.135632\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p><p>It is a challenge to determine selenium in acid aqueous for environmental monitoring and selenium-rich agricultural diagnosis. Herein, we developed a novel localized surface plasmon resonance (LSPR) sensor to detect Se(IV) ions based on the extraordinary laterals etching of gold nanorods (AuNRs). The etching started from the laterals in the low amount of Se(IV) ions, and accompanied by an apparent red shift of the longitudinal plasmon band (LPB), and then transformed to the tips etching with the upward of Se(IV) ions, the LPB band immediately shifted to the shorter wavelength. The red shift change (Δλ) of LPB band was utilized to quantitative analysis instead of blue shift or absorbance intensity, which gave a high selectivity for the proposed sensor. More importantly, this sensor could be performed in 0.1 mol/L of HCl solution, which achieved the seamlessly jointing with the pretreatment of complex samples, without time-consuming pH adjustment.Successful selenium detection was demonstrated in complex soybean samples that collected from the maturity after spraying organic chelated selenium at full flower period. The sensor provided a promising way to monitor and diagnose selenium in complex environmental samples and selenium-rich crops.</p>\",\"PeriodicalId\":94082,\"journal\":{\"name\":\"Journal of hazardous materials\",\"volume\":null,\"pages\":null},\"PeriodicalIF\":0.0000,\"publicationDate\":\"2024-10-05\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of hazardous materials\",\"FirstCategoryId\":\"1085\",\"ListUrlMain\":\"https://doi.org/10.1016/j.jhazmat.2024.135632\",\"RegionNum\":0,\"RegionCategory\":null,\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"2024/8/22 0:00:00\",\"PubModel\":\"Epub\",\"JCR\":\"\",\"JCRName\":\"\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of hazardous materials","FirstCategoryId":"1085","ListUrlMain":"https://doi.org/10.1016/j.jhazmat.2024.135632","RegionNum":0,"RegionCategory":null,"ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"2024/8/22 0:00:00","PubModel":"Epub","JCR":"","JCRName":"","Score":null,"Total":0}
引用次数: 0

摘要

如何测定酸性水体中的硒以进行环境监测和富硒农业诊断是一项挑战。在此,我们开发了一种新型局部表面等离子体共振(LSPR)传感器,利用金纳米棒(AuNRs)的非凡侧向刻蚀来检测硒(IV)离子。在Se(IV)离子含量较低时,刻蚀从侧面开始,伴随着纵向等离子体波段(LPB)的明显红移,然后随着Se(IV)离子含量的上升转变为尖端刻蚀,LPB波段立即向较短波长移动。利用 LPB 波段的红移变化(Δλ)进行定量分析,而不是蓝移或吸光度,这就为拟议的传感器提供了高选择性。更重要的是,该传感器可在 0.1 mol/L 的盐酸溶液中使用,实现了与复杂样品预处理的无缝对接,无需费时调节 pH 值。该传感器为监测和诊断复杂环境样品和富硒作物中的硒含量提供了一种可行的方法。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Highly selective localized surface plasmon resonance sensor for selenium diagnosis in selenium-rich soybeans.

It is a challenge to determine selenium in acid aqueous for environmental monitoring and selenium-rich agricultural diagnosis. Herein, we developed a novel localized surface plasmon resonance (LSPR) sensor to detect Se(IV) ions based on the extraordinary laterals etching of gold nanorods (AuNRs). The etching started from the laterals in the low amount of Se(IV) ions, and accompanied by an apparent red shift of the longitudinal plasmon band (LPB), and then transformed to the tips etching with the upward of Se(IV) ions, the LPB band immediately shifted to the shorter wavelength. The red shift change (Δλ) of LPB band was utilized to quantitative analysis instead of blue shift or absorbance intensity, which gave a high selectivity for the proposed sensor. More importantly, this sensor could be performed in 0.1 mol/L of HCl solution, which achieved the seamlessly jointing with the pretreatment of complex samples, without time-consuming pH adjustment.Successful selenium detection was demonstrated in complex soybean samples that collected from the maturity after spraying organic chelated selenium at full flower period. The sensor provided a promising way to monitor and diagnose selenium in complex environmental samples and selenium-rich crops.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
自引率
0.00%
发文量
0
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:481959085
Book学术官方微信