{"title":"Mathematical modelling of essential oil supercritical carbon dioxide extraction from chamomile flowers","authors":"Oliwer Sliczniuk, Pekka Oinas","doi":"10.1002/cjce.25557","DOIUrl":"https://doi.org/10.1002/cjce.25557","url":null,"abstract":"<p>This study investigates the supercritical extraction process of essential oil from chamomile flowers. Essential oils of chamomile are used extensively for medicinal purposes. Many different chamomile products have been developed, the most popular of which is herbal tea. In this study, a mathematical model is formulated that describes the governing mass transfer phenomena in a solid–fluid environment under supercritical conditions using carbon dioxide. The concept of quasi-one-dimensional flow is applied to reduce the number of spatial dimensions. The flow of carbon dioxide is assumed to be uniform across any cross-section, although the area available for the fluid phase can vary along the extractor. The physical properties of the solvent are estimated based on the Peng–Robinson equation of state. Model parameters, including the partition factor, internal diffusion coefficient, and decaying factor, were determined through maximum likelihood estimation based on experimental data assuming normally distributed errors. The model parameters were combined to obtain a set of correlations. The generalized process model is capable of reproducing the dataset with satisfactory accuracy.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2737-2750"},"PeriodicalIF":1.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://onlinelibrary.wiley.com/doi/epdf/10.1002/cjce.25557","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Prediction of SO2 concentration in WFGD system based on GWO optimized CNN-BiLSTM-attention","authors":"Minan Tang, Zhongcheng Bai, Jiandong Qiu, Chuntao Rao, Yude Jiang, Wenxin Sheng","doi":"10.1002/cjce.25559","DOIUrl":"https://doi.org/10.1002/cjce.25559","url":null,"abstract":"<p>Due to external disturbances, the parameters of the desulphurization system are uncertain, and their relationships are complex, which makes it difficult to predict the concentration of SO<sub>2</sub> at the desulphurization system outlet. In this paper, grey wolf optimization (GWO) optimized convolutional neural network (CNN)-bi-directional long short-term memory (BiLSTM)-Attention algorithm was used for prediction, and the problem of low SO<sub>2</sub> concentration prediction accuracy at outlet has been resolved. First, the outliers of the thermal power plant desulphurization data were processed using the local outlier factor (LOF) algorithm. Secondly, CNN-BiLSTM model was constructed using CNN and BiLSTM, and attention module was added to realize feature extraction and better capture the regularity of input data. Then, the CNN-BiLSTM-Attention model was optimized using GWO and its hyperparameters were improved. Finally, based on the Matlab R2023a platform, the prediction comparison as well as the error analysis of the desulphurization data were carried out. In the prediction of SO<sub>2</sub> concentration in low-flow continuous slurry supply mode, the error of the combined model decreased by 23.2% on average compared to the CNN-BiLSTM-Attention model. In the prediction of SO<sub>2</sub> concentration in the high-flow intermittent slurry supply mode, the error of the combined model decreased by 20.8% on average. According to the results, the combined model surpasses both the single model and several other algorithmic combination models in terms of performance metrics, and the predictions are more accurate.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 7","pages":"3153-3170"},"PeriodicalIF":1.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191213","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Urvashi K. Sarode, Hitesh D. Rawate, Prakash D. Vaidya
{"title":"Investigation on vapour–liquid equilibrium (VLE) solubility of CO2 in aqueous solutions of amino sugars","authors":"Urvashi K. Sarode, Hitesh D. Rawate, Prakash D. Vaidya","doi":"10.1002/cjce.25550","DOIUrl":"https://doi.org/10.1002/cjce.25550","url":null,"abstract":"<p>Amino sugars, which are candidate CO<sub>2</sub>-capturing solvents, react reversibly with CO<sub>2</sub>, thereby setting up vapour–liquid equilibrium (VLE). Knowing equilibrium data is useful for designing gas–liquid contactors for CO<sub>2</sub> absorption. In this work, VLE data for two amino sugars, glucosamine (GA) and N-methyl-D-glucamine (NMG), was measured and reported at 303, 308, and 313 K using a high-pressure VLE setup for the first time. The equilibrium CO<sub>2</sub> partial pressure <span></span><math>\u0000 <mrow>\u0000 <mfenced>\u0000 <msubsup>\u0000 <mi>P</mi>\u0000 <mrow>\u0000 <mi>C</mi>\u0000 <msub>\u0000 <mi>O</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <mo>*</mo>\u0000 </msubsup>\u0000 </mfenced>\u0000 </mrow></math> was high (up to 1500 kPa). The molarity of sugar in the aqueous solution was in the 0.5–1.25 M range. It was found that the CO<sub>2</sub> loading capacity of NMG was much higher than that of GA. For instance, 1.25 M NMG loaded 1.066 mol/mol at 303 K and 1500 kPa CO<sub>2</sub> partial pressure. Using regression, empirical equations were developed to predict VLE data for GA and NMG. To enable comparison, VLE trials were also performed using two amines, monoethanolamine (MEA) and 2-amino-2-methyl-1-propanol (AMP), and an amino acid salt potassium glycinate (PG). It was found that CO<sub>2</sub> solubility (α, mol/mol) in NMG was comparable to that in MEA and higher than that in PG. Besides, it was also found that CO<sub>2</sub> was most soluble in AMP. The effect of promoter addition on the loading capacity at <i>T</i> = 308 K was studied too. The value of CO<sub>2</sub> solubility in GA solution (1 M) at <span></span><math>\u0000 <mrow>\u0000 <msubsup>\u0000 <mi>P</mi>\u0000 <mrow>\u0000 <mi>C</mi>\u0000 <msub>\u0000 <mi>O</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <mo>*</mo>\u0000 </msubsup>\u0000 </mrow></math> = 1450 kPa was <i>α</i> = 0.298 mol CO<sub>2</sub>/mol amino sugar. It improved to <i>α</i> = 0.46 mol/mol in GA/NMG (1/0.5 M) mixtures. Similarly, the CO<sub>2</sub> solubility in NMG solution (0.75 M) at <span></span><math>\u0000 <mrow>\u0000 <msubsup>\u0000 <mi>P</mi>\u0000 <mrow>\u0000 <mi>C</mi>\u0000 <msub>\u0000 <mi>O</mi>\u0000 <mn>2</mn>\u0000 </msub>\u0000 </mrow>\u0000 <mo>*</mo>\u0000 </msubsup>\u0000 </mrow></math> = 250 kPa was <i>α</i> = 0.76 mol CO<sub>2</sub>/mol amino sugar. It improved to 0.94 and 0.93 mol/mol in NMG/PZ and NMG/AMP (0.75","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 7","pages":"3358-3367"},"PeriodicalIF":1.6,"publicationDate":"2024-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144191212","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ning Li, Zheng Guang Xu, Cheng Tao Zhao, Xiang Quan Li
{"title":"Pattern-moving-based dynamic description and optimal control for non-Newtonian mechanical systems with generalized cell mapping","authors":"Ning Li, Zheng Guang Xu, Cheng Tao Zhao, Xiang Quan Li","doi":"10.1002/cjce.25552","DOIUrl":"https://doi.org/10.1002/cjce.25552","url":null,"abstract":"<p>This article focuses on the problem of modelling and control for a non-Newtonian mechanical system that may be subject to the statistical law instead of the traditional Newtonian principles mechanics. A discrete method, synthesizing the generalized cell mapping (GCM) together with dynamic programming (DP), with inverse search strategy, using pattern moving theory (PMT) framework, was proposed. The basic idea is to describe and control the system's dynamic peculiarity utilizing pattern class variable in ‘pattern moving space’. First, a few prior concepts were reviewed, including PMT, cell mapping, and optimal control for this kind system. Then, we articulated a cross-mapping method to analyze the system dynamic behaviour, which takes into account the computational and statistical properties of pattern class variable simultaneously. For system optimal control, the improved GCM and cost function were performed to determine the discrete optimal control table (DOCT) in accordance with dynamic programming and inverse search. Finally, simulation results of two cases demonstrate the efficiency and practicality of the proposed approach. The study has resulted in a solution of describing and controlling based on pattern class variable for non-Newtonian mechanical systems, and its main objective was to give a different perspective in term of research into non mechanistic principles modelling and application of nonlinear systems.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 7","pages":"3208-3229"},"PeriodicalIF":1.6,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144190725","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nilkumar Laxmanbhai Radadiya, Abhay Kumar, Sarita Kalla
{"title":"Micro-nanobubbles assisted fouling reduction in membrane distillation for desalination","authors":"Nilkumar Laxmanbhai Radadiya, Abhay Kumar, Sarita Kalla","doi":"10.1002/cjce.25542","DOIUrl":"https://doi.org/10.1002/cjce.25542","url":null,"abstract":"<p>The present study describes the use of micro-nanobubbles (MNBs) as an easy-to-use method for delaying scaling in membrane distillation (MD) while treating highly concentrated saline feed (10 wt.%). The hydrodynamic flow conditions with MNBs are enhanced compared to the traditional gas bubbling in MD. Specifically, an air cushion is formed between the membrane surface and bulk, limiting the deposition of solid particles on the surface. Also, turbulence created by the MNBs reduces the membrane fouling. The findings of the MD performance analysis showed that, in the absence of nanobubbles, considerable membrane scaling occurred during the treatment of high-salinity feed, which significantly decreased the distillate flux to 70% after 20 h. The one-time incorporation of air NBs into the saline feed significantly reduced salt precipitation or fouling on the polyvinylidene fluoride (PVDF) membrane surface by delaying the start of flux drop and preventing membrane wetting, thus improving MD performance. For nanobubble-assisted MD, the only measured flux drop after 20 h of operation was 57% under similar input concentration and operating parameters.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2804-2812"},"PeriodicalIF":1.6,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of trace oxygen on smelter off-gas reduction desulphurization process over FeSx/γ-Al2O3 catalysts","authors":"Tingting Ge, Hui Guo, Yuchao Li, Jinguo Hao, Yanxia Zheng, Lixi Yang, Haofei Huang, Ming Wang, Cuncun Zuo","doi":"10.1002/cjce.25551","DOIUrl":"https://doi.org/10.1002/cjce.25551","url":null,"abstract":"<p>Effects of trace oxygen on iron sulphides-supported catalysts (FeS<sub>x</sub>/γ-Al<sub>2</sub>O<sub>3</sub>) were evaluated through smelter off-gas reduction process for sulphur synthesis. Catalytic performance was evaluated under different oxygen content conditions. The properties of fresh and used catalysts were investigated by means of X-ray diffraction (XRD), thermogravimetry-differential thermal analysis (TG-DTA), X-ray photoelectron spectroscopy (XPS), and elemental analysis and relationships of active phases and activity were analyzed. The relationship between different active crystal crystals (FeS<sub>x</sub>, FeS<sub>2</sub>, Fe, FeO, γ-Fe<sub>2</sub>O<sub>3</sub>) and SO<sub>2</sub>/O<sub>2</sub> adsorption and conversion was investigated. The mechanism of oxygen influence on the FeS<sub>x</sub>/γ-Al<sub>2</sub>O<sub>3</sub> surface was given and the lifetime of the catalyst in the reaction atmosphere close to real smelter off-gas after dust and oxygen removal steps containing trace oxygen (0.5 O<sub>2</sub> v/v.%) was explored.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2729-2736"},"PeriodicalIF":1.6,"publicationDate":"2024-11-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919414","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sabreen M. El-Gamasy, Amal E. Mubark, Samar E. Abd-El Razek, Ahmed A. Eliwa
{"title":"A study on the adequacy of some actinides adsorption on a modified guanidine Schiff base from laboratory effluents","authors":"Sabreen M. El-Gamasy, Amal E. Mubark, Samar E. Abd-El Razek, Ahmed A. Eliwa","doi":"10.1002/cjce.25544","DOIUrl":"https://doi.org/10.1002/cjce.25544","url":null,"abstract":"<p>Besides the distinctive features and medicinal benefits of guanidine Schiff bases, the possibility of their use as a sorbent for radioactive contents of effluents was developed in the current study. A series of adsorption experiments were performed with 2,2-benzene-1,4-dildiguanidine di-salicylate synthesized sorbent from sulphate feed solutions containing UO<sub>2</sub><sup>2+</sup> and ThSO<sub>4</sub><sup>2+</sup> species each separately. Infrared studies demonstrated that the sorbent links to both actinides via the azomethine nitrogen atom and the hydroxyl groups on the sorbent. Thermal analyses were also performed. Using the greatest adsorption results, UO<sub>2</sub><sup>2+</sup> and ThSO<sub>4</sub><sup>2+</sup> were able to bind to modified guanidine Schiff base (MGSB) sorbent with uptake capacities of 98 and 54 mg/g respectively. The maximal uptake was achieved at pH 5.5 and 3.5 and 90 min contact time for UO<sub>2</sub><sup>2+</sup> and ThSO<sub>4</sub><sup>2+</sup>, respectively. The equilibrium adsorption results for UO<sub>2</sub><sup>2+</sup> and ThSO<sub>4</sub><sup>2+</sup> were in good agreement with Langmuir isotherm and the pseudo-second-order reaction model and demonstrated the endothermic nature and kinetic improvement by increasing temperatures. All kinetic and isotherm results demonstrated the chemical adsorption of both UO<sub>2</sub><sup>2+</sup> and ThSO<sub>4</sub><sup>2+</sup> at the MGSB active sites. Positive ∆<i>H</i> (40.54 and 40.16 kJ/mol for UO<sub>2</sub><sup>2+</sup> and ThSO<sub>4</sub><sup>2+</sup>, respectively) proved the endothermic nature of the adsorption process.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2864-2879"},"PeriodicalIF":1.6,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919757","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Byoung Chul Kim, Su Yeong Jeong, Cho Won Jin, Jeom-Soo Kim, Young Han Kim
{"title":"Vapour–liquid equilibrium using quantum chemical molecular dynamics simulation and radial distribution function analysis","authors":"Byoung Chul Kim, Su Yeong Jeong, Cho Won Jin, Jeom-Soo Kim, Young Han Kim","doi":"10.1002/cjce.25545","DOIUrl":"https://doi.org/10.1002/cjce.25545","url":null,"abstract":"<p>Instead of the classical molecular simulation widely implemented for estimating the vapour–liquid equilibrium (VLE), a quantum chemical (QC) molecular dynamics simulation was applied to the VLE estimation in three typical systems that include a deep eutectic solvent (DES) and an ionic liquid (IL). In addition, a radial distribution function (RDF) was derived from the QC simulation to examine the molecular behaviour in the liquid phase. A mean absolute error of 2.72% was obtained from the QC simulation compared to the experimental data. The RDF analysis explains the relative volatility increase of the acetic acid and water binary system with the propyl acetate solvent. This analysis indicated that the DES mixture comprising glycerol and choline chloride facilitated the separation of water and <i>i</i>-propanol. The interaction between water and ethyl sulphate pair with the help of 1-ethyl-3-methylimidazolium as an IL is stronger than that between ethanol and water, which explains how the IL improves ethanol and water separation in the vapour phase.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2790-2803"},"PeriodicalIF":1.6,"publicationDate":"2024-11-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919756","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Geetu P Paul, Virivinti Nagajyothi, Kishalay Mitra
{"title":"Computational approach for copolymerization of lactide with lactone (5HDON) inimer","authors":"Geetu P Paul, Virivinti Nagajyothi, Kishalay Mitra","doi":"10.1002/cjce.25548","DOIUrl":"https://doi.org/10.1002/cjce.25548","url":null,"abstract":"<p>Polylactide, a biodegradable polymer, has garnered significant attention due to its environmental sustainability and application versatility. The present study introduces a comprehensive mathematical model for the sustainable production of branched polylactide through ring-opening polymerization (ROP) of L-lactide with 5HDON (5-hydroxymethyl-1,4-dioxane-2-on), using Sn(Oct)<sub>2</sub>. The model incorporates a derived reaction mechanism, mass and population balance equations, and the method of moments to predict average molecular properties. Kinetic parameters are estimated through optimization techniques such as particle swarm optimization (PSO), simulated annealing (SA), and genetic algorithm (GA). The model effectively predicts the behaviour of different lactide/5HDON ratios (PLLH80, PLLH94, PLLH97, and PLLH99), revealing a positive correlation between monomer concentration and average molecular weight and an inverse correlation with degree of branching. Notably, PLLH80 exhibits superior branching compared to PLLH99, demonstrating the potential for tailoring polymer properties via controlled lactide/5HDON ratios. Moreover, this work offers a robust tool for optimizing copolymer synthesis for diverse industrial applications.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2708-2718"},"PeriodicalIF":1.6,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919829","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kamand Ghasemi, Ali Akbari, Shahriar Jahani, Yousef Kazemzadeh
{"title":"A critical review of life cycle assessment and environmental impact of the well drilling process","authors":"Kamand Ghasemi, Ali Akbari, Shahriar Jahani, Yousef Kazemzadeh","doi":"10.1002/cjce.25539","DOIUrl":"https://doi.org/10.1002/cjce.25539","url":null,"abstract":"<p>Life cycle assessment (LCA) is a robust tool for evaluating the environmental impacts of products, processes, and systems throughout their entire life cycle. This article presents a comprehensive investigation into the potential of LCA in drilling methods. The growing emphasis on sustainable and environmentally responsible drilling practices is becoming a critical concern in the drilling industry. As demand for natural resources continues to rise, the need for accurate assessments of the environmental impacts associated with various drilling methods becomes increasingly essential. LCA offers a holistic perspective on all key stages of the drilling industry, providing reliable data and serving as a valuable resource for informed decision-making aimed at promoting sustainable and optimized drilling techniques. This article delves into the challenges and complexities surrounding LCA evaluations in the context of drilling operations. It underscores the importance of LCA in enhancing the management of drilling cuttings, waste, and surplus materials generated during drilling activities, as well as the effective handling of drilling mud. Additionally, it highlights the critical issue of groundwater contamination resulting from drilling operations. By presenting a holistic view of the life cycle of drilling products and processes, the article offers practical insights into improving and optimizing drilling techniques and waste management strategies. Moreover, the article examines the challenges and potential solutions associated with implementing LCA in these areas. It aims to support responsible and informed decision-making, ultimately leading to improved drilling performance and enhanced environmental management.</p>","PeriodicalId":9400,"journal":{"name":"Canadian Journal of Chemical Engineering","volume":"103 6","pages":"2499-2526"},"PeriodicalIF":1.6,"publicationDate":"2024-11-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143919830","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}