Amir Detho, Aeslina Abdul Kadir, Zawawi Daud, Asif Ali Memon, Mohd Arif Rosli, Hesham Hussein Rassem
{"title":"Optimizing regeneration techniques and fixed-bed column application for leachate treatment utilizing carbon mineral composite","authors":"Amir Detho, Aeslina Abdul Kadir, Zawawi Daud, Asif Ali Memon, Mohd Arif Rosli, Hesham Hussein Rassem","doi":"10.1007/s13201-025-02370-z","DOIUrl":"10.1007/s13201-025-02370-z","url":null,"abstract":"<div><p>The performance of carbon mineral-combined adsorbents in a batch and fixed column study was examined for removing chemical oxygen demand (COD) and ammoniacal nitrogen (NH<sub>3</sub>-N), which typically found in landfill leachate. The batch experiment was carried out using various factors including adsorbent dosages and retention time, while column performance was evaluated by optimizing the influent flow rate. The surface of the composite adsorbent was examined using X-ray fluorescence (XRF), Fourier transform infrared (FTIR), and scanning electron microscopy (SEM) to determine any changes before and after column operations. The XRF analysis of the composite adsorbent reveals a high concentration of calcium oxide and silica oxide as the primary compounds. The main functional groups in the composite adsorbent included O–H, N–H, O–C, C–N, C–O, and Si–O–Si. The SEM analysis revealed that the composite adsorbent contains heterogeneous pores and a rough surface. The reduction rates achieved were 86% for COD, with an optimum adsorption capacity of 31.3 mgg<sup>−1</sup>, and 80% for NH<sub>3</sub>-N, with an optimum adsorption capacity of 29.8 mgg<sup>−1</sup>. The breakthrough capacities for COD and NH<sub>3</sub>-N adsorption were 6.55 and 4.24 mgg<sup>−1</sup>, respectively. However, optimal empty-bed contact times (EBCTs) in minutes were 480. The performance efficiency of the column for COD and NH<sub>3</sub>-N was 0.9978% and 0.9913%, by utilizing fresh composite adsorbent, and these number figures increased to (≥ 0.9998%) respectively after the regeneration process. The Adams–Bohart constant for COD from 5.30 × 10<sup>–6</sup> to 4.92 × 10<sup>–6</sup> mL/min-mg and NH<sub>3</sub>-N from 2.90 × 10<sup>–5</sup> to 4.52 × 10<sup>–5</sup> mL/min-mg respectively was found to increase with increasing flow rates from 1.5 to 3.0 mLmin<sup>−1</sup>. Therefore, COD and NH<sub>3</sub>-N adsorption on composite adsorbent at flow rates of 1.5 mLmin<sup>−1</sup> was considered appropriate from the context of this study. In summary, this research has successfully shown that the use of composites as an adsorbent is a viable and suitable for the removal of COD and NH<sub>3</sub>-N from leachate, indicating their potential for use in real-world industrial wastewater treatment could further enhance their practical applications.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-025-02370-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143027269","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Surface water quality evaluation of Mahanadi and its Tributary Katha Jodi River, Cuttack District, Odisha, using WQI, PLSR, SRI, and geospatial techniques","authors":"Abhijeet Das","doi":"10.1007/s13201-024-02357-2","DOIUrl":"10.1007/s13201-024-02357-2","url":null,"abstract":"<div><p>Surface water depletion in Odisha tract poses significant challenges for sustainable water management. An important part of the effort to satisfy the growing demand for water is surface water quality control. For that purpose, this study’s primary goal is to assess the surface water quality for drinking and irrigation at nine different locations, via the use of the innovative techniques. In this regard, Drinking Water Quality Index (DWQI), Partial Least Square Regression (PLSR) and Spatial reflectance (SR) Indices (I), were considered to determine water suitability for different people’s activities. The samples were collected in the study area during the pre-monsoon season of period 2023–2024. The parameters analyzed: pH, DO, Alkalinity, Conductivity, Nitrate, Phosphate and Hardness. The results were subsequently contrasted with the water quality requirements, as instructed by World Health Organizations (WHO). The major anionic trend is expressed in the subsequent order: NO<sub>3</sub><sup>−</sup> > PO<sub>4</sub><sup>3−</sup>. Finally, the analytical results were collected in order to produce the parameters’ numerical geographic distribution using the geographical information system (GIS) environment. According to the results of pH, the obtained average value is recorded as 8.0. This implies that the water is slight alkaline in nature. The results of the DWQI showed that 44.44% shared investigated locations, were classified as excellent to good, and 11% as poor, 22.22% as very poor and, 22.22% is indicated as unsuitable for drinking purpose classes. In addition, the new SRIs that were taken out of the VIS and NIR regions demonstrated a substantial correlation with DWQI, according to the results. The new SRIs and DWQI had R<sup>2</sup> correlations with values ranging from 0.65 to 0.82. The results from DWQI and SRI depicts that Nitrate and Phosphate concentration were higher and exceeds the WHO standards. At five sites, which confers as poor water quality, these parameters were recorded very high. Additionally, the main factors causing variations in water quality were fertilizer, organic waste, and soil leaching. Based on the values of R<sup>2</sup>, the PLSR model generated an evaluation of DWQI that was more accurate. Furthermore, the PLSR model generated accurate predictions for DWQI, with an R<sup>2</sup> of 0.82 and 0.85, in the validation and calibration dataset. Hence, PLSR is efficient and provides us with a clear image for evaluating surface water’s fitness for drinking and its regulating elements. This study provides a quantitative framework for assessing surface water suitable potential zones in the chosen region. By identifying the hidden variables influencing water quality, the three approaches work together to maintain their advantages while also offering crucial information for water management. The results allow for the monitoring of restoration measures to be prioritized, the identification of the anthropogenic impact","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02357-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020676","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Aly Reda, Abdel-Ghafar El-Demerdash, Wagih Sadik, Essam El-Rafey, Tamer Shoeib
{"title":"Effectively eliminating lead and cadmium from industrial wastewater using a biowaste-based sorbent","authors":"Aly Reda, Abdel-Ghafar El-Demerdash, Wagih Sadik, Essam El-Rafey, Tamer Shoeib","doi":"10.1007/s13201-024-02343-8","DOIUrl":"10.1007/s13201-024-02343-8","url":null,"abstract":"<div><p>Toxic heavy metals, such as Pb(II) and Cd(II), pose serious environmental and health risks, stressing the urgent demand for innovative and sustainable techniques to reduce their adverse effects. This study investigates the use of sugar beet biowaste as an eco-friendly biosorbent for the removal of Pb(II) and Cd(II) from aqueous solutions, in both laboratory and industrial effluents. Characterization through scanning electron microscopy, X-ray diffraction, thermogravimetric analysis, Fourier-transform infrared spectroscopy, and energy-dispersive X-ray spectroscopy revealed the formation of stable hydrocerussite and otavite, confirming chemisorption. Approximately 95% of the employed biowaste is composed of calcium (Ca), carbon (C), and oxygen (O). The zeta potential was measured at − 17.5 mV with a point of zero charge at pH 8.0, and the total surface area of the biosorbent was approximately 7.72 m<sup>2</sup> g<sup>−1</sup>, with a Langmuir surface area of 11.563 m<sup>2</sup> g<sup>−1</sup> and a pore volume of 0.028 cm<sup>3</sup> g<sup>−1</sup>. Various parameters, such as the metal concentration, biosorbent dosage, pH, temperature, and contact time, were optimized, achieving maximum removal of Pb(II) and Cd(II) within 60 min at pH 12 and 328 K. Sorption followed a pseudo-second-order kinetic model (R<sup>2</sup> = 0.99) and the Freundlich isotherm (R<sup>2</sup> = 0.98), with high sorption capacities of 466.5 mg g<sup>−1</sup> for Pb(II) and 505.6 mg g<sup>−1</sup> for Cd(II). Thermodynamic analysis indicated that the sorption process is spontaneous, thermodynamically favorable, and endothermic. The biowaste effectively removed heavy metals and demonstrated removal efficiencies exceeding 85% for most heavy metals in industrial effluent samples from Alexandria and Ain Sokhna. Sorption capacity ratio values close to 1 indicate effective Pb(II) and Cd(II) uptake with minimal interference, even in the presence of methylene blue dye. Comparative analysis revealed that the untreated biosorbent was more efficient than typical biosorbents, and an economic cost evaluation revealed that processing the biosorbent costs 1.05 USD/kg, highlighting its potential as a sustainable and economically viable option for industrial effluent treatment and supporting broader environmental goals.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02343-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Visible light photocatalytic degradation of water-soluble organic pollutants in aqueous solution by thulium copper oxide nanostructures: sonochemical synthesis, characterization, optimization of conditions, and mechanisms","authors":"Fatemeh Yousefzadeh, Masoud Salavati-Niasari, Mojgan Ghanbari","doi":"10.1007/s13201-024-02349-2","DOIUrl":"10.1007/s13201-024-02349-2","url":null,"abstract":"<div><p>The problem of water contamination has grown significantly in recent years, and the development of novel materials capable of effectively removing these toxins is imperative. The Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> nanophotocatalyst for the decolorization of various organic pollutants that are soluble in water is presented in the current study. A quick and easy sonochemical process was used to create Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> nanostructures, which had an appropriate bandgap of 1.6 eV according to DRS spectroscopy. The BET result indicated type III isotherm with H3 hysteresis and the specific surface area of 5.9788 m<sup>2</sup> g<sup>−1</sup>. To get the maximum effectiveness, a number of variables were carefully examined, including the pH of the medium, the concentrations of organic pollutants, the types of organic contaminants, and the doses of Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub>. The outcomes demonstrated that Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> was very successful in eliminating various organic pollutants from water. For instance, 100% of the erythrosine was destroyed when 50 mg of Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> and 10 ppm dye were utilized under visible irradiation for 35 min. Subsequent analysis utilizing Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> as a photocatalyst showed that hydroxyl radicals were the main cause of pollutant photodegradation. The recyclability test showed that Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> is very stable and after five cycles, the degradation performance reduced by 7.8% from the first cycle (100.0%) to about 92.2%. According to this research, Tm<sub>2</sub>Cu<sub>2</sub>O<sub>5</sub> is a promising choice for creating novel materials that efficiently eliminate water pollutants.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02349-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941126","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Water quality and eutrophication status of the Zarivar Wetland (Iran)","authors":"Rasool Zamani-Ahmadmahmoodi, Samira Bayati, Khodayar Abdollahi, Davood Mafi-Gholami, Sharif Joorabian Shooshtari, Nasrin Gharahi, Arezou Raeisi-bidekani, Jose Antonio Rodríguez Martín, Seyedeh Samira Soleimanipour","doi":"10.1007/s13201-024-02354-5","DOIUrl":"10.1007/s13201-024-02354-5","url":null,"abstract":"<div><p>Wetlands are critically impacted by a variety of pollutants, primarily due to their position at the terminus of both surface and subsurface water flows. This study aims to assess the eutrophication status of Zarivar Wetland, situated in Kurdistan Province, Iran. To evaluate the eutrophication levels, the research employed the Iranian Water Quality Index for Surface Water Resources-Conventional Parameters (IRWQI<sub>SC</sub>) and the Carlson’s Trophic State Index (TSI) during two sampling periods in July and September 2021. The findings indicate that in July, the wetland exhibited an upper-mesotrophic condition, with an average Carlson index value of 52.2, while in September, it transitioned to both upper-mesotrophic and eutrophic conditions, reflected by an average Carlson index value of 60.17. The zoned map of the eutrophication index identified domestic sewage from Marivan city as a significant contributor to elevated eutrophication levels in the southeastern region. Additionally, runoff from irrigated agricultural lands, orchards, and domestic wastewater from surrounding villages contributed to heightened eutrophication in the northeastern and eastern areas of the wetland. A comparative analysis of water quality between July and September 2021 revealed IRWQI<sub>SC</sub> values ranging from 3.57 to 9.72 in July and from 2.63 to 4.72 in September, categorizing them as relatively good and good, respectively. To safeguard Zarivar Wetland, it is recommended to implement measures that prevent livestock waste discharge into the wetland, manage urban and rural sewage systems, control agricultural runoff, and optimize fertilizer application practices.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02354-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142941125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Enhancing water productivity of solar still using thermal energy storage material and flat plate solar collector","authors":"Waleed A. Abdelmaksoud","doi":"10.1007/s13201-024-02340-x","DOIUrl":"10.1007/s13201-024-02340-x","url":null,"abstract":"<div><p>In this research, the impact of integrating solar still with thermal energy storage material and flat plate solar collector (FPSC) on the freshwater productivity was experimentally investigated. The experiments were conducted on three types of similar-sized solar stills under climate conditions of Saudi Arabia. The first type was a conventional solar still (CSS), without any modifications. The second type was a modified solar still (MSS-1), CSS integrated with natural stones in the still basin. The third type was a modified solar still (MSS-2), CSS integrated with both natural stones and FPSC. Three types of natural stones with same quantity were selected and individually tested in the MSS-1 and MSS-2 simultaneously (each stone type on one day). The corresponding experimental results of MSS-1 showed a 11–32% increase in the daily freshwater yield, compared to CSS, indicating a minimal effect of natural stones utilization on the freshwater productivity. The MSS-2 showed a 155–183% increase in the daily freshwater yield, compared to CSS, indicating a significant effect of basin water heating on the freshwater productivity. The total dissolved solids (TDS) level was measured at 112 ppm, which complies with the permissible limits for drinking water quality standards. The economic analysis revealed that the cost to produce one liter of freshwater is 0.028, 0.022, and 0.027 $ from CSS, MSS-1, and MSS-2, respectively. Additionally, the benefit–cost ratio (BCR) analysis demonstrated the economic feasibility of the constructed solar still, with a BCR value of 2.1.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02340-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142937624","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Dynamic coupling of qualitative–quantitative models for operation of water resources based on environmental criteria","authors":"Saeid Farokhi, Mohsen Najarchi, Hosein Mazaheri, Saeid Shabanlou","doi":"10.1007/s13201-024-02356-3","DOIUrl":"10.1007/s13201-024-02356-3","url":null,"abstract":"<div><p>Concerning issues include the distribution of scarce water resources, the quality of utilized water, environmental repercussions, and regulations for the sustainable use of water resources. In the management of water resources, optimal qualitative–quantitative exploitation of surface water bodies is regarded as a desirable strategy. The Dez River surface water system from the Dez regulatory dam to Band-e-Ghir is selected in the current paper to create a qualitative–quantitative model that can determine the best exploitation strategies. A dynamic linkage between qualitative and quantitative models is built in order to simulate the current exploitation conditions under the umbrella of the best-case scenario. In this coupled system, hydraulic relationships are established between all of the system’s components. The available data are shared between two models in this structure to simulate the qualitative and quantitative effects of surface water. Then, a new structure is produced to derive the best policies for exploiting the dam and the river by connecting the multi-objective particle swarm optimization algorithm with the qualitative–quantitative coupled model body. The monthly river environmental demand is one of the decision variables in the ideal scenario, and the goals include boosting the percentage of supply demands and minimizing the violation of quality standards. The best-case scenario’s implementation increases the likelihood that all plain demands will be met, regardless of priority. Furthermore, in comparison with the reference scenario, the results of the optimal scenario show that not only are the concentrations of contaminants and qualitative parameters increased, but there are also only minimal violations of the quality and pollution standards of the river water in the majority of river points, particularly in the locations of agricultural withdrawals. The findings demonstrate that using the qualitative–quantitative dynamic relationship between water resources and the development of the coupled model using the NSGA-II algorithm allows us to better plan for the appropriate use of existing water resources by taking into account all stakeholders in such a way that, in addition to meeting needs, maintains the river quality close to standard limits throughout the exploitation period. By using this strategy, users will be informed of the negative effects of their actions, as well as the encroachment on river boundaries and associated consequences.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02356-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142936898","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of several amines on the morphology, structure, purity, and photocatalytic activity of Ni6MnO8 nanostructures","authors":"Masoumeh Yaqoubi, Masoud Salavati-Niasari, Mojgan Ghanbari","doi":"10.1007/s13201-024-02347-4","DOIUrl":"10.1007/s13201-024-02347-4","url":null,"abstract":"<div><p>Water and wastewater contaminated by dyes are becoming a bigger global problem. The drawbacks of conventional treatment methods are their high prices, lack of sustainability, and partial elimination. Metal oxide semiconductor-based photocatalytic degradation has lately supplanted these techniques. One method promising for completely degrading azo dyes found in wastewater is photocatalysis. Ni<sub>6</sub>MnO<sub>8</sub> nanostructures, a novel photocatalyst, were created in this study to aid in the photocatalytic breakdown of several dyes, especially Eriochrome Black T (EBT). These nanostructures were fabricated through a simple and low-cost co-precipitation method using different amines, including ammonia, tetraethylenepentamine, triethylenetetramine, and ethylenediamine (EDA) as precipitating and capping agents. The pure phase of Ni<sub>6</sub>MnO<sub>8</sub> was achieved in the presence of ammonia. According to the DRS result (bandgap = 2.6 eV), visible light was used to conduct photocatalytic degradation tests on a several dyes solution. The results show that the degradation is greatly influenced by the type of catalyst, dye solution’s starting concentration, pH of dye solution, and the amount of catalyst used. Increased catalyst dose and acidic media result in increased degradation. The maximum degradation rate of Ni<sub>6</sub>MnO<sub>8</sub> prepared in the presence of ammonia on EBT is 96.3% under visible light, and its pseudo-first-order reaction rate constant is 0.0182 min<sup>–1</sup>. The scavenger experiment revealed the hydroxyl radicals performed the superior role in the degradation of EBT. The recycling test indicated the high stability of Ni<sub>6</sub>MnO<sub>8</sub>, with the yield reduced by only 5.6% after five cycles.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02347-4.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934612","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Morphometric and land use land cover analysis for the management of water resources in Guder sub-basin, Ethiopia","authors":"Rahel Gezahegn, Filagot Mengistu","doi":"10.1007/s13201-024-02325-w","DOIUrl":"10.1007/s13201-024-02325-w","url":null,"abstract":"<div><p>Morphometric analysis is essential for understanding the surface hydrological processes within a watershed. It enables the prediction of runoff and infiltration patterns, assesses soil erosion risks, and helps in the planning of effective water resource management practices. The integrated approach of morphometric analysis and land use land cover (LULC) analysis is vital for addressing water resource challenges and ensuring the sustainable management of watersheds. The present study aims to measure the morphometric and LULC parameters to assess and understand the morphological and hydrological properties of the Guder sub-basin. The Guder sub-basin is an ungauged watershed facing water resource challenges throughout the year. The study used data from the Shuttle Radar Topographic Mission (SRTM) Digital Elevation Model (DEM) to extract the stream network and sub-watershed (SW) through ArcGIS10.4 environment using Arc hydro tools and the SWAT model. Fourteen morphometric parameters including linear, areal, and relief were computed over thirty sub-watersheds for prioritization of watersheds. The land use land cover analysis was conducted using the Google Earth Engine platform to examine how anthropogenic factors affect hydrologic aspects. The Guder sub-basin LULC was divided into seven classes: bare land, built-up, bushland, cropland, forest, grassland, and waterbody, with 93% overall accuracy. Based on the combined results obtained, the sub-watersheds were classified into five priority categories: very low (> 9.23), low (8.82–9.23), medium (8.14–8.58), high (7.66–8.11), and very high (< 7.66). Sub-watersheds SW3, SW7, SW14, SW17, SW22, and SW29 were identified as high priority watersheds with a high probability of runoff and erosion. Sub-watersheds SW6, SW9, SW11, SW13, SW28, and SW30 were identified as low priority watersheds, indicating good infiltration. Therefore, immediate action should be applied for appropriate land and water management to mitigate the risks and optimize the benefits in these areas. The outcome of this research provides knowledge of watershed hydrologic information before planning and implementing land and water management practices.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02325-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Assessment of microplastic release from facial and body scrubs in aquatic ecosystems","authors":"Afsaneh Esmaeili Nasrabadi, Fatemeh Kabirinia, Ziaeddin Bonyadi","doi":"10.1007/s13201-024-02350-9","DOIUrl":"10.1007/s13201-024-02350-9","url":null,"abstract":"<div><p>This study investigated the presence and characteristics of MPs in commonly used face and body scrubs. Six commercially available scrub brands were analyzed using various techniques, including SEM, FTIR, EDX, and DLS. The scrubs examined in this study were meticulously selected from markets in Mashhad. These cosmetic products were treated with H₂O₂ and agitated for 15 min. Finally, the shape, color, and total number of MPs were analyzed using microscopy. The findings revealed that the concentration of MPs detected per gram of scrub across the different brands was 298.66 ± 60 particles. The MPs identified in all brands were predominantly composed of PE. The results indicated a significant correlation between the number of MPs and the brand used (<i>P</i> value < 0.05). The findings indicated that MPs were primarily composed of carbon (84.42%) and oxygen (13.73%). These materials displayed numerous grooves and a considerable degree of surface irregularity. Furthermore, the zeta potential of the MPs in all samples was measured at − 36 mV. According to the results, 50% of the MPs were colorless, 36% were white, and 14% had a shiny appearance (<i>P </i>value < 0.05). Additionally, the forms of the MPs were observed in the following order of prevalence: irregular (38%), filamentous (31%), sharp (15%), fragmentary (8%), and spherical (8%) (<i>P</i> value < 0.05). The sizes of the MPs ranged from 0.147 to 2.133 mm (<i>P </i>value < 0.05). The MPLI analysis indicated that approximately half of the scrubs exhibited significant contamination. The study also estimated the potential release of MPs into the environment via wastewater treatment plants, underscoring the substantial contribution of cosmetics to MP pollution.</p></div>","PeriodicalId":8374,"journal":{"name":"Applied Water Science","volume":"15 2","pages":""},"PeriodicalIF":5.7,"publicationDate":"2025-01-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s13201-024-02350-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142934557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}