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Pushing Q-factor limit of guided resonances by harnessing topologically protected terahertz bound states in the continuum 利用连续体中受拓扑保护的太赫兹束缚态,推动引导共振的q因子极限
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-24 DOI: 10.1063/5.0254576
Guangcheng Sun, Yue Wang, Rongbo Xie, Xiangdong Chen, Yaohe Li, Wenshuo Chen, Kebin Fan, Zijian Cui, Xiaoguang Zhao
{"title":"Pushing Q-factor limit of guided resonances by harnessing topologically protected terahertz bound states in the continuum","authors":"Guangcheng Sun, Yue Wang, Rongbo Xie, Xiangdong Chen, Yaohe Li, Wenshuo Chen, Kebin Fan, Zijian Cui, Xiaoguang Zhao","doi":"10.1063/5.0254576","DOIUrl":"https://doi.org/10.1063/5.0254576","url":null,"abstract":"Controlling and enhancing light–matter coupling at subwavelength scales is an essential requirement in the realm of meta-photonics. Recently, all-dielectric metasurfaces (MSs) governed by the physics of bound states in the continuum (BICs) have emerged as a standout platform for delivering high-quality (Q) factor resonances and near-field electromagnetic hotspots. However, in the terahertz (THz) domain, experimental validation of high-Q BICs resonances with strong robustness and advanced maneuverability in such all-dielectric photonic systems remains a long-standing challenge. Here, we demonstrate a simple and feasible fabrication approach to unlock the full potential of BICs-inspired resonances within the array of silicon cross elliptical resonators. Our results suggest that the designed THz-MS can support two symmetry-protected BICs with a topological charge of ±1 and several accidental BICs with a topological charge of +1 simultaneously. By introducing small perturbations to the individual resonator, the original two symmetry-protected BICs transform into quasi-BICs that bow to the inverse-square law. Astoundingly, for larger symmetry breaking, two additional BICs can be observed in the asymmetric THz-MSs surpass typical inverse-square rule, hence presenting a supererogatory degree of freedom for tailoring BICs resonances on demand. We bear out theoretical findings by transmission experiments implemented on the fabricated samples. We observe experimentally ultrasharp dual quasi-BICs resonances with a highest measured Q factor of up to 371, a level of performance that was previously unattainable with all-dielectric THz-MS on a substrate. The results mark an important step toward enriching the family of BICs and promise exciting opportunities in the field of THz optoelectronic devices and metadevices.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"20 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703607","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Manipulation of resonances governed by Fabry–Pérot bound states in the continuum 对连续体中由法布里-帕姆罗束缚态控制的共振的操纵
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-24 DOI: 10.1063/5.0253100
Xiaofeng Rao, Tao He, Chengfeng Li, Xinshang Niu, Chao Feng, Siyu Dong, Jingyuan Zhu, Zeyong Wei, Yuzhi Shi, Jifeng Qu, Zhanshan Wang, Xinbin Cheng
{"title":"Manipulation of resonances governed by Fabry–Pérot bound states in the continuum","authors":"Xiaofeng Rao, Tao He, Chengfeng Li, Xinshang Niu, Chao Feng, Siyu Dong, Jingyuan Zhu, Zeyong Wei, Yuzhi Shi, Jifeng Qu, Zhanshan Wang, Xinbin Cheng","doi":"10.1063/5.0253100","DOIUrl":"https://doi.org/10.1063/5.0253100","url":null,"abstract":"Bound states in the continuum (BICs) have emerged as research hotspots in optics and photonics, offering a new paradigm for achieving extreme field localization and enhancing light–matter interactions. Here, we establish for the first time the intrinsic evolution laws of Fabry–Pérot bound states in the continuum (FP-BICs), revealing that the Q factor is inversely proportional to the square of phase/frequency detuning and to the nonradiative decay rate, enabling directional engineering of FP-BIC resonances. We propose an all-dielectric multilayer film metasurface to create an optical resonator and its perfectly mirrored counterpart, inducing FP-BICs and validating the conclusions. We experimentally demonstrated the evolution of the Q factor with frequency detuning, achieving a maximum Q factor of 610 in the visible. Our work offers novel insights into BICs, promising to inspire exotic phenomena and applications.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"71 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143703606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Incubating advances in integrated photonics with emerging sensing and computational capabilities 孵化集成光子学与新兴传感和计算能力的进展
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-21 DOI: 10.1063/5.0218564
Sourabh Jain, May H. Hlaing, Kang-Chieh Fan, Jason Midkiff, Shupeng Ning, Chenghao Feng, Po-Yu Hsiao, Patrick T. Camp, Ray T. Chen
{"title":"Incubating advances in integrated photonics with emerging sensing and computational capabilities","authors":"Sourabh Jain, May H. Hlaing, Kang-Chieh Fan, Jason Midkiff, Shupeng Ning, Chenghao Feng, Po-Yu Hsiao, Patrick T. Camp, Ray T. Chen","doi":"10.1063/5.0218564","DOIUrl":"https://doi.org/10.1063/5.0218564","url":null,"abstract":"As photonic technologies grow in multidimensional aspects, integrated photonics holds a unique position and continuously presents enormous possibilities for research communities. Applications include data centers, environmental monitoring, medical diagnosis, and highly compact communication components, with further possibilities continuously growing. Herein, we review state-of-the-art integrated photonic on-chip sensors that operate in the visible to mid-infrared wavelength region on various material platforms. Among the different materials, architectures, and technologies leading the way for on-chip sensors, we discuss the optical sensing principles that are commonly applied to biochemical and gas sensing. Our focus is on passive optical waveguides, including dispersion-engineered metamaterial-based structures, which are essential for enhancing the interaction between light and analytes in chip-scale sensors. We harness a diverse array of cutting-edge sensing technologies, heralding a revolutionary on-chip sensing paradigm. Our arsenal includes refractive-index-based sensing, plasmonics, and spectroscopy, which forge an unparalleled foundation for innovation and precision. Furthermore, we include a brief discussion of recent trends and computational concepts, incorporating Artificial Intelligence & Machine Learning (AI/ML) and deep learning approaches over the past few years to improve the qualitative and quantitative analysis of sensor measurements.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"55 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143672284","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Erbium-doped yttrium oxide thin films grown by chemical vapor deposition for quantum technologies 量子技术化学气相沉积制备掺铒氧化钇薄膜
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-19 DOI: 10.1063/5.0243958
Anna Blin, Alexander Kolar, Andrew Kamen, Qian Lin, Xiaoyang Liu, Aziz Benamrouche, Romain Bachelet, Philippe Goldner, Tian Zhong, Diana Serrano, Alexandre Tallaire
{"title":"Erbium-doped yttrium oxide thin films grown by chemical vapor deposition for quantum technologies","authors":"Anna Blin, Alexander Kolar, Andrew Kamen, Qian Lin, Xiaoyang Liu, Aziz Benamrouche, Romain Bachelet, Philippe Goldner, Tian Zhong, Diana Serrano, Alexandre Tallaire","doi":"10.1063/5.0243958","DOIUrl":"https://doi.org/10.1063/5.0243958","url":null,"abstract":"The obtention of quantum-grade rare-earth-doped oxide thin films that can be integrated with optical cavities and microwave resonators is of great interest for the development of scalable quantum devices. Among the different growth methods, chemical vapor deposition (CVD) offers high flexibility and has demonstrated the ability to produce oxide films hosting rare-earth ions with narrow linewidths. However, growing epitaxial films directly on silicon is challenging by CVD due to a native amorphous oxide layer formation at the interface. In this manuscript, we investigate the CVD growth of erbium-doped yttrium oxide (Er:Y2O3) thin films on different substrates, including silicon, sapphire, quartz, or yttria stabilized zirconia (YSZ). Alternatively, growth was also attempted on an epitaxial Y2O3 template layer on Si (111) prepared by molecular beam epitaxy (MBE) in order to circumvent the issue of the amorphous interlayer. We found that the substrate impacts the film morphology and the crystalline orientations, with different textures observed for the CVD film on the MBE-oxide/Si template (111) and epitaxial growth on YSZ (001). In terms of optical properties, Er3+ ions exhibit visible and IR emission features that are comparable for all samples, indicating a high-quality local crystalline environment regardless of the substrate. Our approach opens interesting prospects to integrate such films into scalable devices for optical quantum technologies.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"171 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143660479","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mastering the growth of antimonene on Bi2Se3: Strategies and insights 掌握Bi2Se3上锑烯的生长:策略和见解
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-19 DOI: 10.1063/5.0246306
Roberto Flammini, Conor Hogan, Stefano Colonna, Fabio Ronci, Mauro Satta, Marco Papagno, Ziya S. Aliev, Sergey V. Eremeev, Evgueni V. Chulkov, Zipporah R. Benher, Sandra Gardonio, Luca Petaccia, Giovanni Di Santo, Carlo Carbone, Paolo Moras, Polina M. Sheverdyaeva
{"title":"Mastering the growth of antimonene on Bi2Se3: Strategies and insights","authors":"Roberto Flammini, Conor Hogan, Stefano Colonna, Fabio Ronci, Mauro Satta, Marco Papagno, Ziya S. Aliev, Sergey V. Eremeev, Evgueni V. Chulkov, Zipporah R. Benher, Sandra Gardonio, Luca Petaccia, Giovanni Di Santo, Carlo Carbone, Paolo Moras, Polina M. Sheverdyaeva","doi":"10.1063/5.0246306","DOIUrl":"https://doi.org/10.1063/5.0246306","url":null,"abstract":"Antimonene, the two-dimensional phase of antimony, appears in two distinct allotropes when epitaxially grown on Bi2Se3: the puckered asymmetric washboard (α) and buckled honeycomb (β) bilayer structures. As-deposited antimony films exhibit varying proportions of single α and β structures. We identify the conditions necessary for ordered, pure-phase growth of single to triple β-antimonene bilayers. Additionally, we determine their electronic structure, work function, and characteristic core-level binding energies, offering an explanation for the relatively large chemical shifts observed among the different phases. This study not only establishes a protocol for achieving a single β phase of antimonene but also provides key signatures for distinguishing between the different allotropes using standard spectroscopic and microscopic techniques.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"54 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143660402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Nonlinear optics in 2D materials: From classical to quantum 二维材料中的非线性光学:从经典到量子
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-19 DOI: 10.1063/5.0242014
Liuxin Gu, You Zhou
{"title":"Nonlinear optics in 2D materials: From classical to quantum","authors":"Liuxin Gu, You Zhou","doi":"10.1063/5.0242014","DOIUrl":"https://doi.org/10.1063/5.0242014","url":null,"abstract":"Nonlinear optics has long been a cornerstone of modern photonics, enabling a wide array of technologies, from frequency conversion to the generation of ultrafast light pulses. Recent breakthroughs in two-dimensional (2D) materials have opened a frontier in this field, offering new opportunities for both classical and quantum nonlinear optics. These atomically thin materials exhibit strong light–matter interactions and large nonlinear responses, thanks to their tunable lattice symmetries, strong resonance effects, and highly engineerable band structures. In this paper, we explore the potential that 2D materials bring to nonlinear optics, covering topics from classical nonlinear optics to nonlinearities at the few-photon level. We delve into how these materials enable possibilities, such as symmetry control, phase matching, and integration into photonic circuits. The fusion of 2D materials with nonlinear optics provides insights into the fundamental behaviors of elementary excitations—such as electrons, excitons, and photons—in low-dimensional systems and has the potential to transform the landscape of next-generation photonic and quantum technologies.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"34 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143660480","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Signal enhancement and noise suppression technologies in Raman spectroscopic gas sensing 拉曼光谱气体传感中的信号增强和噪声抑制技术
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-19 DOI: 10.1063/5.0225006
Weiping Kong, Fu Wan, Rui Wang, Hongcheng Sun, Weigen Chen
{"title":"Signal enhancement and noise suppression technologies in Raman spectroscopic gas sensing","authors":"Weiping Kong, Fu Wan, Rui Wang, Hongcheng Sun, Weigen Chen","doi":"10.1063/5.0225006","DOIUrl":"https://doi.org/10.1063/5.0225006","url":null,"abstract":"Raman spectroscopy, which enables simultaneous detection of multi-gas components, is considered a valuable tool for gas analysis. However, the weak Raman scattering effect limits its application in the field of high-sensitivity gas detection. In this article, we summarize the principles and characteristics of existing techniques for improving the detection of Raman spectra, from both the perspectives of signal enhancement and noise suppression. Regarding signal enhancement techniques, the main methods include multi-pass cavity enhancement, resonant cavity enhancement, and hollow-core fiber enhancement. As for noise suppression methods, the primary approaches include spatial filtering, shifted excitation Raman difference spectroscopy, polarized Raman spectroscopy, and internal standard correction. Finally, we present and outlook on how to further enhance the sensitivity of Raman spectroscopy based on existing techniques, which can lay the foundation for the future development of robust and easy-to-use gas analysis instruments.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"8 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143660481","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Biomechanical and mechanobiological design for bioprinting functional microvasculature 生物打印功能微血管的生物力学和机械生物学设计
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-17 DOI: 10.1063/5.0227692
Dongrui Zhang, Jiangyue Liu, Xiao Liu, Yubo Fan
{"title":"Biomechanical and mechanobiological design for bioprinting functional microvasculature","authors":"Dongrui Zhang, Jiangyue Liu, Xiao Liu, Yubo Fan","doi":"10.1063/5.0227692","DOIUrl":"https://doi.org/10.1063/5.0227692","url":null,"abstract":"Functional microvasculature is essential for in vitro tissue constructs, ensuring efficient transport of oxygen, nutrients, and waste and supporting vital paracrine signaling for tissue stability. Recent advancements in both direct and indirect 3D bioprinting offer promising solutions to construct complex vascular networks by allowing precise control over cell and extracellular matrix placement. The process from shape printing of microvasculature to function formation involves dynamic shift of bioink mechanical properties, mechanical microenvironments, and mechanobiology of endothelial and supporting cells. This review explores how biomechanical and mechanobiological principles are integrated into the bioprinting process to develop functional microvascular networks. Before printing, a top-level design approach based on these principles focuses on the interactions among biomaterials, cell behaviors, and mechanical environments to guide microvascular network fabrication. During printing, biomechanical design of bioinks for different bioprinting techniques, along with optimized biomechanical factors of bioprinting process, ensures accurate microvascular structure reproduction while maintaining cell viability. After printing, the emphasis is on creating a suitable mechanical environment to modulate the mechanobiology of multiple steps of neovascularization, including initiation, morphogenesis, lumen formation, stabilization, and maturation of functional microvasculature. Finally, we discuss future developments based on biomechanical and mechanobiological design to drive the bioprinting of functionalized microvascular networks.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"19 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640381","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Smart biomaterials in healthcare: Breakthroughs in tissue engineering, immunomodulation, patient-specific therapies, and biosensor applications 医疗保健中的智能生物材料:在组织工程、免疫调节、患者特异性治疗和生物传感器应用方面的突破
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-17 DOI: 10.1063/5.0238817
Ansheed Raheem, Kalpana Mandal, Swarup Biswas, Amir Ahari, Alireza Hassani Najafabadi, Neda Farhadi, Fatemeh Zehtabi, Ankit Gangrade, Marvin Mecwan, Surjendu Maity, Saurabh Sharma, Joseph Nathanael Arputharaj, Pearlin Amaan Khan, Anjaneyulu Udduttula, Negar Hosseinzadeh Kouchehbaghi, Danial Khorsandi, Rajesh Vasita, Reihaneh Haghniaz, Rondinelli Donizetti Herculano, Johnson V. John, Hyeok Kim, Mehmet Remzi Dokmeci, Ketul C. Popat, Yangzhi Zhu, Geetha Manivasagam
{"title":"Smart biomaterials in healthcare: Breakthroughs in tissue engineering, immunomodulation, patient-specific therapies, and biosensor applications","authors":"Ansheed Raheem, Kalpana Mandal, Swarup Biswas, Amir Ahari, Alireza Hassani Najafabadi, Neda Farhadi, Fatemeh Zehtabi, Ankit Gangrade, Marvin Mecwan, Surjendu Maity, Saurabh Sharma, Joseph Nathanael Arputharaj, Pearlin Amaan Khan, Anjaneyulu Udduttula, Negar Hosseinzadeh Kouchehbaghi, Danial Khorsandi, Rajesh Vasita, Reihaneh Haghniaz, Rondinelli Donizetti Herculano, Johnson V. John, Hyeok Kim, Mehmet Remzi Dokmeci, Ketul C. Popat, Yangzhi Zhu, Geetha Manivasagam","doi":"10.1063/5.0238817","DOIUrl":"https://doi.org/10.1063/5.0238817","url":null,"abstract":"Smart biomaterials have significantly impacted human healthcare by advancing the development of medical devices designed to function within human tissue, mimicking the behavior of natural tissues. While the intelligence of biomaterials has evolved from inert to active over the past few decades, smart biomaterials take this a step further by making their surfaces or bulk respond based on interactions with surrounding tissues, imparting outcomes similar to natural tissue functions. This interaction with the surrounding tissue helps in creating stimuli-responsive biomaterials, which can be useful in tissue engineering, regenerative medicine, autonomous drug delivery, orthopedics, and much more. Traditionally, material engineering focused on refining the static properties of biomaterials to accommodate them within the body without evoking an immune response, which was a major obstacle to their unrestricted operation. This review highlights and explains various engineering approaches currently under research for developing stimuli-responsive biomaterials that tune their outcomes based on responses to bodily factors like temperature, pH, and ion concentration or external factors like magnetism, light, and conductivity. Applications in soft and hard tissue engineering, 4D printing, and scaffold design are also discussed. The advanced application of microfluidics, like organ-on-a-chip models, extensively benefits from the intrinsic smart properties of biomaterials, which are also discussed below. The review further elaborates on how smart biomaterial engineering could revolutionize biosensor applications, thereby improving patient care quality. We delineate the limitations and key challenges associated with biomaterials, providing insights into the path forward and outlining future directions for developing next-generation biomaterials that will facilitate clinical translation.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"1 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143640380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Ionic conduction and interfacial stability in Na1+xZr2SixP3−xO12 solid electrolytes: Past, present, and future perspectives Na1+xZr2SixP3−xO12固体电解质中的离子传导和界面稳定性:过去,现在和未来的观点
IF 15 1区 物理与天体物理
Applied physics reviews Pub Date : 2025-03-12 DOI: 10.1063/5.0241000
Zhengwu Fang, Jacob Smith, Kevin Clelland, Kang-Ting Tseng, Jeff Wolfenstine, Olivier Delaire, Jeff Sakamoto, Miaofang Chi
{"title":"Ionic conduction and interfacial stability in Na1+xZr2SixP3−xO12 solid electrolytes: Past, present, and future perspectives","authors":"Zhengwu Fang, Jacob Smith, Kevin Clelland, Kang-Ting Tseng, Jeff Wolfenstine, Olivier Delaire, Jeff Sakamoto, Miaofang Chi","doi":"10.1063/5.0241000","DOIUrl":"https://doi.org/10.1063/5.0241000","url":null,"abstract":"While the development of new solid electrolytes (SEs) is crucial for advancing energy storage technologies, revisiting existing materials with significantly improved knowledge of their physical properties and synthesis control offers significant opportunities for breakthroughs. Na1+xZr2SixP3−xO12 (NaSICON) SEs have recently regained attention for applications in both solid-state and aqueous redox flow batteries due to their improved electrochemical and mechanical properties, along with their inherent electrochemical stability, air robustness, and low manufacturing cost. Recent improvements in NaSICON have primarily targeted macroscopic property enhancements and synthesis techniques. To enable further breakthroughs in the performance of NaSICON SEs, future efforts should focus on understanding how modified synthesis conditions influence atomic and microscopic-scale features, such as conduction channels, electronic structures, phase distributions, and grain boundaries. These features ultimately control ion conductivity, mechanical properties, and electrochemical stability of NaSICON and its interfaces. Here, we review the current understanding of the structure-chemistry-property relationships of NaSICON SEs, focusing on atomic and microscopic levels. First, we introduce the proposed ionic conduction mechanisms in NaSICON crystallites. Then, we explore experimental investigations at phase and grain boundaries to assess ionic conduction and interfacial stability. We also examine strategies to address interfacial challenges such as high resistance and chemical reactions between SEs and electrodes, highlighting the difficulties in analyzing interfaces at the nano/atomic scale. Finally, we provide an outlook on advancing microscopy and spectroscopy techniques to enhance insights into NaSICON SEs ionic conduction and interfacial stability, supporting the development of improved long-duration energy storage devices.","PeriodicalId":8200,"journal":{"name":"Applied physics reviews","volume":"124 1","pages":""},"PeriodicalIF":15.0,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143608591","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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