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Magnetron sputtered ZnO enhances light-aging resistance of heat-treated ‘Zhongshanshan’ wood 磁控溅射ZnO增强热处理“中杉木”的耐光老化性能
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-12-09 DOI: 10.1007/s00226-025-01735-6
Zhaoyi Wang, Junyuan Li, Chuang Xu, Jie Zhang, Biao Pan, Chaoguang Yu, Xinzhou Wang
{"title":"Magnetron sputtered ZnO enhances light-aging resistance of heat-treated ‘Zhongshanshan’ wood","authors":"Zhaoyi Wang,&nbsp;Junyuan Li,&nbsp;Chuang Xu,&nbsp;Jie Zhang,&nbsp;Biao Pan,&nbsp;Chaoguang Yu,&nbsp;Xinzhou Wang","doi":"10.1007/s00226-025-01735-6","DOIUrl":"10.1007/s00226-025-01735-6","url":null,"abstract":"<div>\u0000 \u0000 <p>With the growing utilization of fast-growing timber in the wood industry, issues such as poor dimensional stability and low durability have become increasingly prominent. Although heat treatment can improve those wood properties, the material remains susceptible to photodegradation under prolonged ultraviolet (UV) exposure, which limits its applicability in outdoor environments. In this study, ZnO was deposited onto the surface of heat-treated Taxodium hybrid ‘Zhongshanshan’ wood via magnetron sputtering to improve its resistance to light-aging. Results revealed that the ZnO coating was uniformly deposited with well-defined crystallinity and it did not compromise the visibility of the wood’s natural texture. After sputtering for 120 min, the light-aging resistance of heat-treated wood improved significantly. For example, the color difference (ΔE) decreased by about 50% as compared to the uncoated wood after light aging. By the way, the coating also can improve the waterproofing of wood surface, such as the initial water contact angle only decreased from 139.5° to 122.8° after light aging. Comprehensive characterization by SEM, XPS, EPR, and UV-Vis demonstrated that the ZnO coating inhibited the formation of free radicals and surface oxidation, thereby enhancing the wood’s resistance to UV-induced photodegradation. These findings highlight the effectiveness of magnetron sputtering as a physical modification approach for improving the long-term weathering performance of heat-treated fast-growing wood.</p>\u0000 </div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-12-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145729893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Phosphorus-induced tuning of hierarchically porous N-doped lignin carbon material for boosting high-power supercapacitor performance 磷诱导调谐分层多孔n掺杂木质素碳材料提高大功率超级电容器性能
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-12-08 DOI: 10.1007/s00226-025-01734-7
Yuchen Han, Wei Zhong, Jie Zheng, Jianfeng Wu, Bo Jiang, Yongcan Jin, Wenjuan Wu
{"title":"Phosphorus-induced tuning of hierarchically porous N-doped lignin carbon material for boosting high-power supercapacitor performance","authors":"Yuchen Han,&nbsp;Wei Zhong,&nbsp;Jie Zheng,&nbsp;Jianfeng Wu,&nbsp;Bo Jiang,&nbsp;Yongcan Jin,&nbsp;Wenjuan Wu","doi":"10.1007/s00226-025-01734-7","DOIUrl":"10.1007/s00226-025-01734-7","url":null,"abstract":"<div><p>Lignin possesses the advantages of high carbon content and abundant functional groups, making it suitable as a supercapacitor electrode material. However, the microstructure of lignin-derived electrode materials obtained through traditional methods limits the effective utilization of energy storage capacity, resulting in a significant loss of electrochemical efficiency. Doping with heteroatoms in lignin-derived carbon can enhance its electrochemical performance and is a promising method for performance improvement. We employed a green and universal approach to design lignin-derived carbon materials by covalently grafting phosphorus source (DOPO) and nitrogen source (HDI) onto the lignin macromolecular framework through organic synthesis. Using modified lignin (NPAL) as a precursor, we achieved simultaneous carbonization and activation through a one-pot method. The nitrogen and phosphorus doping synergistically enhances pseudocapacitance activity (redox reactions), optimizes the hierarchical pore structure (increasing the specific surface area to 1756.79 m<sup>2</sup>/g), and improves charge transfer kinetics (reducing charge transfer resistance to 6.63 Ω). This results in a high specific capacitance (276.3 F/g @ 0.25 A/g, an increase of 275.56% compared to undoped materials), high energy density (12.5 Wh/kg), and cycling stability (capacity retention of 92.5% after 10,000 cycles), indicating a promising application prospect.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-12-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145729674","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Among-family variations of chemical and Kraft-pulp properties in the heartwood of the third-generation Acacia mangium in Indonesia 印度尼西亚第三代马吉相思心材的化学和牛皮纸浆特性的科间变异
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-12-05 DOI: 10.1007/s00226-025-01730-x
Masendra, Ikumi Nezu, Fanny Hidayati, Arif Nirsatmanto, Sri Sunarti,  Surip, Dwi Kartikaningtyas, Jyunichi Ohshima, Shinso Yokota, Futoshi Ishiguri
{"title":"Among-family variations of chemical and Kraft-pulp properties in the heartwood of the third-generation Acacia mangium in Indonesia","authors":"Masendra,&nbsp;Ikumi Nezu,&nbsp;Fanny Hidayati,&nbsp;Arif Nirsatmanto,&nbsp;Sri Sunarti,&nbsp; Surip,&nbsp;Dwi Kartikaningtyas,&nbsp;Jyunichi Ohshima,&nbsp;Shinso Yokota,&nbsp;Futoshi Ishiguri","doi":"10.1007/s00226-025-01730-x","DOIUrl":"10.1007/s00226-025-01730-x","url":null,"abstract":"<div><p>The content of wood chemical components (extractives, ash, Klason lignin, and polysaccharides) and Kraft-pulp properties (yield and kappa number) were directly determined for the inner and outer heartwood of 10-year-old 20 open-pollinated families in the third-generation <i>Acacia mangium</i> in Indonesia. The results show that the extractives, Klason lignin, and <i>α</i>-cellulose contents of outer heartwood were higher than those of inner heartwood. Relatively higher variance components of family were observed for polysaccharides and Kraft-pulp yield. Significant positive phenotypic correlations were found between stem diameter and either basic density or <i>α</i>-cellulose content, as well as between Kraft-pulp yield and <i>α</i>-cellulose content. Meanwhile, significant negative correlations were found between Kraft-pulp yield and organic solvent extracts or Klason lignin. Therefore, it is concluded that families with larger stem diameters and higher <i>α</i>-cellulose contents tend to produce higher pulp yield.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00226-025-01730-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145675686","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The effect of Loranthus europaeus Jacq. on certain morphological and chemical properties of Quercus infectoria G.Olivier wood 桂花的药效。栎木某些形态和化学性质的研究
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-28 DOI: 10.1007/s00226-025-01732-9
Negin Henareh Chareh, Omid Hossein Zadeh, Marzieh Hajjarian, Ahmad Alijanpour
{"title":"The effect of Loranthus europaeus Jacq. on certain morphological and chemical properties of Quercus infectoria G.Olivier wood","authors":"Negin Henareh Chareh,&nbsp;Omid Hossein Zadeh,&nbsp;Marzieh Hajjarian,&nbsp;Ahmad Alijanpour","doi":"10.1007/s00226-025-01732-9","DOIUrl":"10.1007/s00226-025-01732-9","url":null,"abstract":"<div>\u0000 \u0000 <p>The outbreak of the hemiparasitic plant <i>Loranthus europaeus</i> poses a significant challenge to the protection and sustainable management of forest ecosystems, particularly oak forests in western Iran This study aimed to investigate the effects of <i>L. europaeus</i> on the morphological and chemical properties of <i>Quercus infectoria</i> wood in the northern Zagros region of Iran. In this research, 20 <i>Q. infectoria</i> trees (10 healthy and 10 infected) were selected. Trunk and branch samples from each tree were collected and analyzed in the laboratory. Fiber separation for morphological property assessments was conducted using Franklin’s method, and chemical composition analyses of the wood were carried out based on TAPPI standards. Data analysis involved checking normality using the Kolmogorov-Smirnov test, followed by one-way ANOVA and Tukey’s post-hoc test for comparisons. The results showed that the presence of <i>L. europaeus</i> significantly affected certain morphological properties, leading to reduced fiber diameter and cell wall thickness while increasing cell lumen diameter in both trunks and branches of the host. It had a significant impact on morphological coefficients, causing an increase in the flexibility ratio, and a decrease in the Runkle ratio. In terms of chemical properties, <i>L. europaeus</i> significantly decreased hemicellulose and increased lignin and extractives content, while its effect on other components was not statistically significant. These findings suggest that <i>L. europaeus</i> reduces fiber diameter, increases cell lumen diameter, and decreases cell wall thickness, resulting in diminished mechanical strength of the wood. Additionally, the reduction in hemicellulose and changes in extractive content significantly affect the industrial quality of <i>Q. infectoria</i> wood. This study demonstrates that <i>L. europaeus</i> infestation has profound impacts on both the structural integrity and industrial quality of <i>Q. infectoria</i> wood, providing key insights for sustainable forest management and utilization.</p>\u0000 </div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145613140","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green ethanol-water stepwise fractionation of industrial lignin for phenolic-enriched fractions with enhanced antioxidant activity 绿色乙醇-水分馏法提取工业木质素富酚组分,增强抗氧化活性
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-28 DOI: 10.1007/s00226-025-01733-8
HuaiYu Xu, KongYan Li, YiRun Liu, YongCan Jin, WenJuan Wu
{"title":"Green ethanol-water stepwise fractionation of industrial lignin for phenolic-enriched fractions with enhanced antioxidant activity","authors":"HuaiYu Xu,&nbsp;KongYan Li,&nbsp;YiRun Liu,&nbsp;YongCan Jin,&nbsp;WenJuan Wu","doi":"10.1007/s00226-025-01733-8","DOIUrl":"10.1007/s00226-025-01733-8","url":null,"abstract":"<div><p>The structural complexity and inconsistent antioxidant performance of industrial lignin have long limited its high-value applications. In this study, we first clarified the central role of phenolic hydroxyl groups in antioxidant activity via targeted acetylation of tannin and lignin. Building on this insight, a green ethanol–water stepwise fractionation strategy (100%, 20%, 0%) was developed to deconstruct industrial lignin (KP) into three well-defined fractions (KE100, KE20, KE0) with tunable molecular properties. This solvent-gradient process enabled the orderly separation of high-molecular-weight hydrophobic components to low-molecular-weight hydrophilic ones. KE0, featuring the lowest molecular weight (M<sub>w</sub> = 1000 g/mol) and highest phenolic hydroxyl content (4.23 mmol/g), exhibited markedly enhanced antioxidant performance (DPPH: 62%; FRAP: 2.97 µmol/mg). These findings establish a clear structure–activity relationship and demonstrate that ethanol-based fractionation not only improves lignin homogeneity but also unlocks its potential as a sustainable antioxidant platform. This work offers a scalable, eco-friendly pathway for advancing lignin valorization toward functional material applications.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145613139","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Mapping within-tree variation of Douglas-fir wood properties for trees grown at different planting densities 更正:不同种植密度下生长的道格拉斯冷杉木材特性的树内变化图
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-28 DOI: 10.1007/s00226-025-01724-9
Ighoyivwi Onakpoma, Laurence Schimleck, Joseph Dahlen, Gerald Presley
{"title":"Correction: Mapping within-tree variation of Douglas-fir wood properties for trees grown at different planting densities","authors":"Ighoyivwi Onakpoma,&nbsp;Laurence Schimleck,&nbsp;Joseph Dahlen,&nbsp;Gerald Presley","doi":"10.1007/s00226-025-01724-9","DOIUrl":"10.1007/s00226-025-01724-9","url":null,"abstract":"","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145613141","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preservation of wood structure using stabilized alkaline bleaching agents: a novel and mild approach to enhance whitening for lignin-rich wood template 稳定碱性漂白剂对木结构的保护:一种增强富木质素模板增白的新型温和方法
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-20 DOI: 10.1007/s00226-025-01725-8
Francesca Gullo, Massimo Messori, Paola Palmero
{"title":"Preservation of wood structure using stabilized alkaline bleaching agents: a novel and mild approach to enhance whitening for lignin-rich wood template","authors":"Francesca Gullo,&nbsp;Massimo Messori,&nbsp;Paola Palmero","doi":"10.1007/s00226-025-01725-8","DOIUrl":"10.1007/s00226-025-01725-8","url":null,"abstract":"<div><p>Preservation and enhancement of wood properties have become increasingly important due to the growing demand for sustainable materials in the construction and manufacturing industries. This study focuses on bleaching processes as an alternative to conventional delignification, aiming to retain a significant amount of lignin while achieving the desired whiteness of the wood template. In particular, stabilized alkaline hydrogen peroxide is investigated as a bleaching agent under mild conditions. The treatment preserves more than 90% of the native mass in both balsa and birch, ensuring that most of the wood’s structural components are maintained. This results in a high wood volume fraction, corresponding to reduced porosity and a structure closely resembling that of unbleached wood. Fourier Transform Infrared spectroscopy (FTIR) semi-quantitative analysis further confirms that the relative lignin content is retained, ranging between 70 and 80% depending on the species. Unlike conventional approaches that often degrade the wood structure and require long treatment times at high temperatures, the proposed process is performed at room temperature under mild conditions and completed in less than 2–4 h, thus reducing energy demand and avoiding harmful byproducts. Overall, this work provides a bleaching strategy that combines efficiency, structural integrity, and sustainability, offering bleached wood templates suitable for further characterization and advanced applications.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00226-025-01725-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561316","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Comment on the structure of softwood lignin 软木木质素的结构评述
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-20 DOI: 10.1007/s00226-025-01713-y
Göran Gellerstedt, Gunnar Henriksson
{"title":"Comment on the structure of softwood lignin","authors":"Göran Gellerstedt,&nbsp;Gunnar Henriksson","doi":"10.1007/s00226-025-01713-y","DOIUrl":"10.1007/s00226-025-01713-y","url":null,"abstract":"<div><p>Lignin is one of the most complex biopolymers and is characterized by combination of monomers to form a variety of inter-monomer linkages, which successively build up the racemic polymer. The prevailing theory of lignin formation suggests that monomers are enzymatically oxidized into resonance-stabilized radicals that subsequently couple through radical–radical reactions to generate intermediates that are then stabilized via post-coupling reactions. However, this standard model for lignin formation is challenged by certain lignin structures that cannot be easily explained by this theory. One such structure characterized by a side chain carbon (α or β-position) linked to an aromatic C6 is the focal point of this minireview. The evidence supporting the presence of this structure in softwood lignin is scrutinized, leading to the conclusion that this type of structure is most likely formed during the lignification process. Possible mechanisms for its formation are discussed.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145561315","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Improving stable anti-weathering performance of wood by impregnation with active aminated alkali lignin 用活性胺化碱木质素浸渍提高木材的稳定抗风化性能
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-18 DOI: 10.1007/s00226-025-01727-6
Yang Yu, Zengcheng He, Zhe Qiu, Tianpeng Zhang, Zefang Xiao, Yanjun Xie
{"title":"Improving stable anti-weathering performance of wood by impregnation with active aminated alkali lignin","authors":"Yang Yu,&nbsp;Zengcheng He,&nbsp;Zhe Qiu,&nbsp;Tianpeng Zhang,&nbsp;Zefang Xiao,&nbsp;Yanjun Xie","doi":"10.1007/s00226-025-01727-6","DOIUrl":"10.1007/s00226-025-01727-6","url":null,"abstract":"<div><p>Alkali lignin (AL), as a bio-based industrial byproduct, has certain potential in improving the photostability of wood in outdoor applications based on its UV absorption feature. The present study developed aminated low molecular weight depolymerized AL for wood impregnation, and evaluated the pre- and post-modification weathering resistance of the wood. The filling of aminated AL within the wood matrix was demonstrated using methods including scanning electron microscopy (SEM), Fourier-transform infrared spectroscopy (FTIR) and fluorescence microscopy. Compared with AL treated wood, modified poplar and Chinese fir showed a high weight gain rate increased by 251.8 and 320.9%, respectively, and a low loss resistance rate decreased by 39.9 and 32.5%, respectively. Free radicals exhibited a reduced generation during in situ irradiation. Changes in composition over the same period of weathering treatment were minimized, thereby delaying the structural and morphological alterations induced by weathering. Macroscopic photodegradation and morphological damage observed in the modified wood were substantially mitigated, with the integrity of the anatomical structure preserved. These findings substantiate the protective effect of aminated AL treatment on wood weathering behavior, which is beneficial for enhancing the stability of wood in outdoor applications.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145560903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Potential of iron-loaded Japanese cedar charcoal as a collectable adsorbent for 3d-block metal ions 载铁日本雪松炭作为3d块金属离子可收集吸附剂的潜力
IF 3 2区 农林科学
Wood Science and Technology Pub Date : 2025-11-18 DOI: 10.1007/s00226-025-01722-x
Takayuki Yamagishi, Sakae Shibutani, Yasuji Kurimoto, Shigeru Yamauchi
{"title":"Potential of iron-loaded Japanese cedar charcoal as a collectable adsorbent for 3d-block metal ions","authors":"Takayuki Yamagishi,&nbsp;Sakae Shibutani,&nbsp;Yasuji Kurimoto,&nbsp;Shigeru Yamauchi","doi":"10.1007/s00226-025-01722-x","DOIUrl":"10.1007/s00226-025-01722-x","url":null,"abstract":"<div><p>Iron-loaded Japanese cedar (JC) charcoal adsorbents were synthesized under various conditions to investigate their ability to adsorb 3d-block metal ions. The metal ions (M<sup>n+</sup>) examined in this study were Cr<sup>3+</sup>, Co<sup>2+</sup>, Ni<sup>2+</sup>, Cu<sup>2+</sup>, and Zn<sup>2+</sup>. Ordinary JC charcoal adsorbents used as references were also prepared under the same synthetic conditions. The aqueous M<sup>n+</sup> solutions were prepared using metal chlorides and deionized water, and the concentration of M<sup>n+</sup> was set to 2.5 × 10<sup>− 2</sup> mmol/L or 2.5 mmol/L. Fe(NO<sub>3</sub>)<sub>3</sub> was used to synthesize iron-loaded charcoal. The Fe<sup>3+</sup> content in JC wood, which was the crude material for iron-loaded charcoal, was set to 3 or 7% w/w by adding an appropriate amount of aqueous Fe(NO<sub>3</sub>)<sub>3</sub> solution. JC wood powder impregnated with Fe<sup>3+</sup> was heated at 600 or 800 °C for 1.0 h under a N<sub>2</sub> gas flow. The charcoal adsorbents were analyzed using Raman spectroscopy and X-ray diffractometry. The adsorption abilities of the JC charcoal adsorbents for M<sup>n+</sup> ions were assessed based on adsorption isotherms, which consisted of double logarithmic plots of the adsorbed M<sup>n+</sup> concentrations on charcoal versus the dissolved M<sup>n+</sup> concentrations in aqueous solution.</p></div>","PeriodicalId":810,"journal":{"name":"Wood Science and Technology","volume":"60 1","pages":""},"PeriodicalIF":3.0,"publicationDate":"2025-11-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s00226-025-01722-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145560904","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"农林科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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