Research on Chemical Intermediates最新文献

{"title":"Floating Ag-ZnO@PAN nanofiber mats with photocatalytic, piezoelectric, and plasmonic functions for wastewater treatment","authors":"Ghazale Asghari Sarabi,&nbsp;Morasae Samadi,&nbsp;Habib Bagheri,&nbsp;Md. Golam Kibria,&nbsp;Alireza Z. Moshfegh","doi":"10.1007/s11164-025-05759-2","DOIUrl":"10.1007/s11164-025-05759-2","url":null,"abstract":"<div><p>Adequate wastewater treatment is crucial for ensuring access to safe and sanitary water, which can be achieved through photocatalytic processes. This work elucidates the preparation of cost-effective and easily scalable polyacrylonitrile (PAN) electrospun nanofibers (NFs) as support for ZnO nanorods (NRs) photocatalysts. Then, Ag nanoparticles (NPs) were homogenously deposited on ZnO NRs/PAN NFs to prepare Ag NPs/ZnO NRs/PAN NFs samples. Photochemical and electrochemical characterization demonstrated a higher photocurrent density and stability for the Ag NPs/ZnO NRs/PAN NFs than ZnO NRs/PAN NFs. In addition, the prepared photocatalysts were utilized for the photodegradation of various dyes, including methylene blue (MB) and rhodamine B (RhB), as well as tetracycline (TC), an antibiotic serving as a model organic pollutant, under different light illumination conditions. The Ag NPs/ZnO NRs/PAN NFs demonstrated 2.4, 2.6, and 1.6 times higher photocatalytic activity than ZnO NRs/PAN for MB, RhB, and TC photodegradation under UV light, respectively. This floating and free-standing mat, with high stability, demonstrated 82% MB removal after 1 h of exposure to outdoor natural light. Mechanistic studies conducted by adding scavengers revealed that generating hot plasmonic electrons on the Ag NPs through illumination plays a pivotal role in improving the photodegradation activity of Ag NPs/ZnO NRs/PAN NFs mats. Furthermore, ultrasonic vibration was also utilized to induce piezoelectricity in the ternary Ag NPs/ZnO NRs/PAN NFs, resulting in an approximately 2.2-fold improvement in the MB photodegradation rate due to the synergistic effects of piezoelectricity and plasmonics. This durable and reusable photocatalyst, with its mechanical robustness and superior self-cleaning characteristics, is a promising system that offers a potential direction for future research and efficient wastewater treatment.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6487 - 6514"},"PeriodicalIF":3.5,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296718","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Application of magnetic nanocomposite Fe3O4 /SiO2/TiO2 in the preparation of phosphines: achieving high efficiency and multi-stage recyclability","authors":"Feras Alnaimat,&nbsp;Shaker Al-Hasnaawei,&nbsp;M. M. Rekha,&nbsp;Subhashree Ray,&nbsp;Kattela Chennakesavulu,&nbsp;Vipasha Sharma,&nbsp;Amanpreet Sandhu,&nbsp;Aashna Sinha,&nbsp;Kamran Hedayat","doi":"10.1007/s11164-025-05760-9","DOIUrl":"10.1007/s11164-025-05760-9","url":null,"abstract":"<div><p>This study investigates the application of the Fe₃O₄/SiO₂/TiO₂ magnetic nanocomposite for the facile and recyclable production of phosphines. The nanocomposite was fabricated by combining the magnetic properties of Fe₃O₄, the structural stability of SiO₂, and the catalytic activity of TiO₂, and was subsequently characterized using Fourier transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), scanning electron microscopy (SEM), energy dispersive X-ray spectroscopy (EDS), transmission electron microscopy (TEM), Brunauer–Emmett–Teller analysis (BET), vibrating sample magnetometry (VSM), X-ray photoelectron spectroscopy (XPS), and thermogravimetric analysis (TGA). As a heterogeneous catalyst, this nanocomposite provides high efficiency under mild reaction conditions in phosphine production. Its easy separation using a magnetic field, together with its reusability, makes this approach a sustainable solution in green chemistry. Overall, the findings demonstrate that Fe₃O₄/SiO₂/TiO₂ magnetic nanocomposites can significantly contribute to the development of efficient and environmentally friendly industrial processes for phosphine.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6021 - 6047"},"PeriodicalIF":3.5,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296719","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Potential-induced synthesis of cavity Cu2O/Cu nanocubes for enhanced electroreduced CO2 to C2+ products","authors":"Yaping Hu,&nbsp;Shasha Zhai,&nbsp;Yaping Guo,&nbsp;Shan Dang,&nbsp;Jing Li,&nbsp;Miao Yang","doi":"10.1007/s11164-025-05766-3","DOIUrl":"10.1007/s11164-025-05766-3","url":null,"abstract":"<div><p>Electrochemical reduction reaction of CO₂ (CO₂RR) to C₁ and C₂ products can be achieved on Cu-based electrocatalysts. C₂ products exhibit higher energy density and economic value compared to C₁ products, making them more desirable as reduction products. However, the production of C₂ products on pure Cu catalysts involves multi-step proton-coupled electron transfer and C–C coupling steps, which are kinetically slow and result in poor catalytic activity and selectivity for the products. The cavity nanocubes Cu₂O(0.13-AA), Cu₂O(0.10-AA) and Cu₂O(0.15-AA) catalysts were synthesized via wet chemical reduction by adjusting the concentration of the reducing agent. The electrochemical pre-reduction method was used to obtain Cu₂O/Cu(0.13-AA), Cu₂O/Cu(0.10-AA) and Cu₂O/Cu(0.15-AA) catalysts for CO₂RR. Cu₂O/Cu(0.13 M-AA) catalyst achieves the high Faradaic efficiency (FE) of 39.98% for C₂H₄ and 54.76% for C₂ products (C₂H₄, C₂H₆, and C₂H₅OH), with significant inhibition of the hydrogen evolution reaction. In situ Raman experiments demonstrate that the cavity structure of the nanocubes enhances the local concentration of *CO intermediates, thereby promoting the C–C coupling process and improving the selectivity of CO₂ reduction to C₂ products.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6577 - 6591"},"PeriodicalIF":3.5,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296337","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Guanidine hydrochloride-catalyzed synthesis of hexahydroquinoline-3-carboxamide derivatives in aqueous medium: an efficient and expeditious approach","authors":"Angad B. Barkule,&nbsp;Yatin U. Gadkari,&nbsp;Savita B. Lomte,&nbsp;Shrikant M. Ghodse,&nbsp;Vikas N. Telvekar","doi":"10.1007/s11164-025-05754-7","DOIUrl":"10.1007/s11164-025-05754-7","url":null,"abstract":"<div><p>We have developed an eco-friendly method for synthesizing hexahydroquinoline-3-carboxamide derivatives using guanidine hydrochloride as a catalyst in water. This one-pot, multicomponent reaction combines aromatic or heteroaromatic aldehydes, dimedone, acetoacetanilide, and ammonium acetate to produce high yields of the desired compounds. The catalyst also showed remarkable reusability, maintaining its effectiveness over five successive cycles without notable degradation. The approach boasts several advantages, including a sustainable reaction profile, streamlined processing, rapid reaction times, and efficient atom economy, making it an appealing and environmentally responsible approach.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6225 - 6237"},"PeriodicalIF":3.5,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296338","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Doebner–von Miller reaction catalyzed by mesoporous polymeric solid acid: an efficient route to produce 1,10-phenanthroline","authors":"Mingliang Wu,&nbsp;Qilong Zhao,&nbsp;Ji Wang,&nbsp;Gongying Wang","doi":"10.1007/s11164-025-05733-y","DOIUrl":"10.1007/s11164-025-05733-y","url":null,"abstract":"<div><p>Exploring environmentally friendly, highly economical, resource-saving, and recyclable low-temperature heterogeneous catalysts for liquid-phase organic reactions is of great significance for the realization of green and sustainable development. In this study, mesoporous polydivinylbenzene (PDVB)-based solid acid (PDVB-SO₃H) has been successfully prepared from sulfonation of mesoporous PDVB. And the sulfonated polymeric solid acid PDVB-SO₃H was used as for catalyzing Doebner–von Miller reaction for the synthesis of 1,10-phen with choline chloride as the co-catalyst for the first time. FT-IR and XPS confirmed successful sulfonate group grafting onto PDVB. N₂ sorption isotherms, SEM, and TG curves revealed the mesoporous PDVB-SO₃H possesses a high BET surface area, superior pore structure, and thermal stability. Besides, the results of acid–base titration and elemental analysis indicate that the extremely high acid capacity. Finally, the catalytic tests show that PDVB-SO₃H exhibits excellent catalytic activities and good recyclability in synthesis of 72% yield of 1,10-phen and the 1,10-phen yield did not decrease obviously after the PDVB-SO₃H catalyst was reused for 5 times. This work highlighted the excellent catalytic activity and good recyclability of PDVB-SO₃H, and provides a method and references to produce 1,10-phenanthroline.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6113 - 6131"},"PeriodicalIF":3.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296617","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Degradation of methyl orange dye by Fenton oxidation process using hydrolyzed PAN fibers loaded with FeMOF as the heterogeneous catalyst","authors":"Yushan Wang,&nbsp;Jianlin Liu,&nbsp;Chengbing Yu","doi":"10.1007/s11164-025-05769-0","DOIUrl":"10.1007/s11164-025-05769-0","url":null,"abstract":"<div><p>The efficient degradation of dye pollutants continues to pose a significant challenge in wastewater treatment, primarily due to constraints in degradation efficiency and complications in catalyst recovery. To address these issues, a novel catalyst has been synthesized utilizing polyacrylonitrile fibers as a support material, which were subsequently loaded with iron-based metal–organic framework through a solvothermal approach. This catalyst, when combined with hydrogen peroxide (H₂O₂), forms a heterogeneous Fenton catalytic system that promotes the degradation of methyl orange (MO) in wastewater. A thorough investigation was conducted to examine the catalytic degradation performance of dyes and the underlying reaction mechanisms. The catalyst demonstrates outstanding performance in dye degradation, achieving 95.7% removal of methyl orange under ambient conditions. Moreover, it retains over 80% degradation efficiency after four consecutive reaction cycles, highlighting its strong recyclability and minimal loss of catalytic activity. Radical quenching experiments and electron paramagnetic resonance analyses confirm that the primary reactive oxygen species involved are hydroxyl radicals (·OH) and superoxide anions (·O₂⁻). Furthermore, both Fe^II and Fe^III ions can be recycled and regenerated in-situ, thereby continuously catalyzing H₂O₂ to produce ·OH and ·O₂⁻, which facilitates the sustained mineralization of dye molecules, thus enabling high dye degradation.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6335 - 6352"},"PeriodicalIF":3.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296618","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Coconut waste–derived sulfonated magnetic biochar: an efficient catalyst for the synthesis of 2,3-dihydroquinazolinone","authors":"Sarthak Sharma,&nbsp;Gobind Kumar,&nbsp;Navneet Kaur,&nbsp;Gaurav Bhargava,&nbsp;Rupesh Kumar","doi":"10.1007/s11164-025-05753-8","DOIUrl":"10.1007/s11164-025-05753-8","url":null,"abstract":"<div><p>This work reports the environment-friendly synthesis of nature-derived biochar-based catalyst for synthesis of pharmaceutically significant 2,3-dihydroquinazolin-4(1H)-ones. A Magnetic biochar catalyst was synthesized from coconut waste using a simple hydrothermal reactor followed by 2-step functionalization steps to achieve sulphonated magnetic biochar, Fe@SO₃H-BC. The structural and morphological characterization of the synthesized catalysts was done using XRD, FTIR, FESEM and EDS. The catalytic activity of Fe@SO₃H-BC was studied for the synthesis of 2,3-dihydroquinazolin-4(1H)-ones by condensation of 2-aminobenzamide with carbonyls including acetophenones and aldehydes in solvent-free conditions, resulting in moderate to high yields 83–94% and 70–95%, respectively. The methodology offered advantages by giving an operationally easier and greener chemical route for fabrication of environmentally derived biochar-based catalyst showing notable catalytic activity, recyclability and versatility.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6203 - 6223"},"PeriodicalIF":3.5,"publicationDate":"2025-09-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Facile synthesis of carbon-doped ZnCo2O4/ZnO p-n heterojunction via in situ carbonization of Prussian blue analogue for efficient photocatalytic hydrogen generation","authors":"Liping Wang,&nbsp;Xin Tao,&nbsp;Renxing Li,&nbsp;Lirong Jiang,&nbsp;Lin Chen,&nbsp;Bingqian Li","doi":"10.1007/s11164-025-05749-4","DOIUrl":"10.1007/s11164-025-05749-4","url":null,"abstract":"<div><p>Hydrogen is recognized as a clean and efficient energy carrier, and photocatalytic hydrogen generation represents a pivotal technology for sustainable energy development. In this work, a highly active noble metal-free ZnCo₂O₄/ZnO/C composite has been successfully synthesized via in situ carbonization of a ZnCo-based Prussian blue analogue (PBA), exhibiting remarkable photocatalytic hydrogen generation activity. Under simulated solar irradiation, the optimized composite achieves a high hydrogen generation rate of 2039.3 μmol/(g·h), along with excellent stability. The significantly enhanced photocatalytic activity originates from a unique S-scheme heterojunction charge transfer mechanism and multi-component synergistic effects. Specifically, the intimate interfacial contact among graphitic carbon, ZnCo₂O₄, and ZnO facilitates efficient separation and migration of photogenerated electron–hole pairs. The S-scheme mechanism not only preserves photogenerated electrons with strong reduction capability but also enhances charge carrier utilization. Furthermore, the graphitic carbon improves the electrical conductivity and light-harvesting capability. These factors are responsible for the remarkable photocatalytic performance and good stability. This work provides a compelling demonstration of utilizing PBA-derived carbonization as a versatile platform for fabricating efficient, stable, and scalable photocatalysts for practical hydrogen production.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6437 - 6463"},"PeriodicalIF":3.5,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296896","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Development of a green electrode based on fullerene oxide functionalized with L-alanine and MIL101@Fe MOFs for enantioselective electro-organic carboxylation in NaCl electrolyte","authors":"Zaman Abdalhussein Ibadi Alarsidhee,&nbsp;Matheel D. Al-Sabti,&nbsp;Majid S. Jabir,&nbsp;Egambergan Xudaynazarov,&nbsp;Amer Alhaj Zen,&nbsp;Elyor Berdimurodov,&nbsp;Ilyos Eliboev,&nbsp;Usmonova Lola Mallaevna,&nbsp;Mirjalol Ismoilov Ruziboy Ugli,&nbsp;Abdulrahman A. Almehizia,&nbsp;Mohammed B. Alqaraguly,&nbsp;Iman I. Jabbar","doi":"10.1007/s11164-025-05746-7","DOIUrl":"10.1007/s11164-025-05746-7","url":null,"abstract":"<div><p>Conventional synthetic methods for organic compounds are associated with significant environmental concerns, primarily due to the reliance on metal-based catalysts. Furthermore, the employment of toxic solvents combined with prolonged reaction durations presents substantial obstacles to the commercial scalability and practical application of these approaches. In this study, we developed a sustainable green electrode by functionalizing fullerene oxide with L-alanine and incorporating MIL-101@Fe metal–organic frameworks. This innovative approach is designed for enantioselective electro-organic carboxylation in a NaCl electrolyte. The study examines how the biocompatibility of L-alanine and the structural robustness of MIL-101@Fe enhance catalytic efficiency while maintaining environmental sustainability. Functionalizing fullerene oxide with L-alanine improves the electrode's selectivity for the desired enantiomers and increases electron transfer efficiency. The resulting catalytic substrate, oxC60-Ala-MIL101@Fe, was characterized employing various analytical techniques, including EDX, TGA, SEM, EDS, BET, CV, XPS, FT-IR, and DFT calculation to assess its morphology, thermal stability, elemental composition, surface area, and electrochemical behavior. To evaluate the electrode’s performance, we conducted the electro-organic carboxylation of ethylbenzene <b>1(a-l)</b> derivatives under electro-organic synthesis conditions, yielding various (R)-2-phenylpropanoic acids <b>4(a-l)</b> with excellent yields (92–97%). Optimal results were obtained at a current of 10 mA, over a duration of 2 h, and at room temperature and Ala-MIL101@Fe exhibited good performance for up to 9 cycles. The products were confirmed using ¹HNMR, CHN analysis, FT-IR spectroscopy, and melting point determination.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6297 - 6333"},"PeriodicalIF":3.5,"publicationDate":"2025-09-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296895","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Synthesis and evaluation of the catalytic activity of Ni, Cu, and Zn-doped α-Fe2O3 microspheres for N-formylation of aromatic amines","authors":"Reza Pourfaraj,&nbsp;Sayed Yahya Kazemi,&nbsp;Pourya Biparva,&nbsp;Hoda Khasayesi","doi":"10.1007/s11164-025-05747-6","DOIUrl":"10.1007/s11164-025-05747-6","url":null,"abstract":"<div><p>A simple synthetic method was developed to fabricate three transition metals (M = Ni, Cu, and Zn) doped α-Fe₂O₃ catalysts via a solvothermal approach eliminating the need for a precipitation agent. The synthesized nanocatalysts were characterized using XRD, FT-IR, FE-SEM, EDS, and UV–Vis techniques, and their activity was optimized for the <i>N</i>-formylation of aniline under solvent-free conditions at room temperature. A study of surface morphology revealed that we successfully prepared microspheres of α-Fe₂O₃, Ni–Fe₂O₃, Cu–Fe₂O₃, and Zn–Fe₂O₃. All forms doped represented higher catalytic activity compared to the pristine α-Fe₂O₃, due to a synergistic effect resulting from the presence of transition metals along with Fe. Among all the as-synthesized doped catalysts, Cu–Fe₂O₃ showed the highest activity due to the greater electronegativity of Cu compared to that of Ni or Zn. Thus, Cu–Fe₂O₃ nanocatalyst was selected for the chemoselective transformation of various amines to the corresponding formamides as a sole product (average reaction time: 14 min, average conversion: 90%, average TOF: 0.42 min^–1). Finally, the catalyst could be reused for up to six runs without notable decrease in its activity.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 11","pages":"6185 - 6201"},"PeriodicalIF":3.5,"publicationDate":"2025-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145296524","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}