Research on Chemical Intermediates最新文献

Sustainable synthesis of 2,3-Dihydroquinazolin-4(1H)-ones using Ni-Fe2O3@SiO2-Pr-DMAP novel nanocatalyst: a profiling approach by DFT

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-19 DOI: 10.1007/s11164-025-05544-1

Lalit Dhananjay Bhosale, Akshay Pandurang Gurav, Pradeep Jangonda Patil, Dilip Hanumant Dagade, Sandeep Ashok Sankpal, Shankar Poshatti Hangirgekar

{"title":"Sustainable synthesis of 2,3-Dihydroquinazolin-4(1H)-ones using Ni-Fe2O3@SiO2-Pr-DMAP novel nanocatalyst: a profiling approach by DFT","authors":"Lalit Dhananjay Bhosale, Akshay Pandurang Gurav, Pradeep Jangonda Patil, Dilip Hanumant Dagade, Sandeep Ashok Sankpal, Shankar Poshatti Hangirgekar","doi":"10.1007/s11164-025-05544-1","DOIUrl":"10.1007/s11164-025-05544-1","url":null,"abstract":"<div><p>Synthesis and characterization of ionic liquid anchored magnetically separable novel heterogeneous Nanocatalyst Ni-Fe₂O₃@SiO₂-Pr-DMAP and its use in the synthesis of 2,3-dihydroquinazolin-4(1H)-one derivative. The nanocatalyst was thoroughly characterised by XRD, SEM, TEM, EDX, FTIR, and VSM, confirming its nanoscale morphology, magnetic properties, and chemical composition. This polycrystalline nanocatalyst demonstrated excellent catalytic activity under mild conditions, achieving high yields of various substituted derivatives (4a, 4e, and 4 g) through a three-component condensation reaction. 1H-NMR, 13C-NMR, and Mass spectroscopy confirmed the formation of catalytic products, and the proposed mechanism was investigated. A comparative analysis with existing catalysts revealed the superior efficiency, shorter reaction times, magnetically separable, excellent reusability, and reduced environmental impact of Ni-Fe₂O₃@SiO₂-Pr-DMAP due to modification in catalyst and the elimination of harmful solvents. Additionally, the catalyst was proven recyclable, making it a cost-effective and environmentally friendly option. This study introduces a facile, eco-friendly process for synthesizing 2,3-dihydroquinazolin-4(1<i>H</i>)-one derivatives, contributing to advancing green chemistry, non-chromatographic purification method, and sustainable catalytic processes.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"1827 - 1861"},"PeriodicalIF":2.8,"publicationDate":"2025-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676241","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A comparative analysis of the interactions between the anionic sunset yellow dye with cationic, nonionic, and anionic surfactants

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-17 DOI: 10.1007/s11164-025-05535-2

Bharathi Balasubramaniyan, Sukanta Kumar Pradhan, Puspalata Rajesh, Sasmita Dash

{"title":"A comparative analysis of the interactions between the anionic sunset yellow dye with cationic, nonionic, and anionic surfactants","authors":"Bharathi Balasubramaniyan, Sukanta Kumar Pradhan, Puspalata Rajesh, Sasmita Dash","doi":"10.1007/s11164-025-05535-2","DOIUrl":"10.1007/s11164-025-05535-2","url":null,"abstract":"<div><p>This work reports the comparative interaction of food dye sunset yellow (SY) with ionic, and nonionic surfactant mediums. Three different surfactants were utilized: the nonionic Pluronic. F-127 (F-127), the cationic Cetyl Pyridinium Bromide (CPB), and the anionic Ammonium Dodecyl Sulfate (ADS). The interactions were studied with the use of several methods, such as UV–visible spectroscopy, FTIR analysis, evaluating the zeta potential, dynamic light scattering (DLS), conductivity, fluorescence, and NMR spectroscopy. The binding constant values determined from UV-spectroscopic studies were 0.22 mM<sup>−1</sup>, 2.93 mM<sup>−1</sup>, and 0.02 mM<sup>−1</sup> for SY-ADS, SY-CPB, and SY-F-127 systems, respectively. From the zeta-potential values, it is also inferred that the SY-CPB system is more stable than SY-ADS and SY-F-127 dye-surfactant combinations. In comparison to ADS and F-127 surfactant systems, the conductivity, fluorescence, and 1H/13C NMR experiments also showed that SY had a stronger interaction with CPB, a higher sensitivity, and a better affinity. The in silico docking study exhibited more interactive sites in the SY-CPB combination than the other two, corroborating the experimental findings. The DLS studies displayed size enhancement in the presence of ionic surfactants and shrinking of size in the nonionic combination. The results revealed that the cationic surfactant medium of CPB are promising formulations for the food industry’s application of SY dye. To the best of our knowledge, this study is the first to report the interaction of SY with three distinct surfactant classes.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"2197 - 2222"},"PeriodicalIF":2.8,"publicationDate":"2025-03-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676196","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Photocatalytic reduction of CO2 Ag-BiVO4 composites modified with lignin carbon quantum dots

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-12 DOI: 10.1007/s11164-025-05549-w

Yilin Wu, Yiping Li, Kai Zhang, Jinhai Hu, Hong Yan

{"title":"Photocatalytic reduction of CO2 Ag-BiVO4 composites modified with lignin carbon quantum dots","authors":"Yilin Wu, Yiping Li, Kai Zhang, Jinhai Hu, Hong Yan","doi":"10.1007/s11164-025-05549-w","DOIUrl":"10.1007/s11164-025-05549-w","url":null,"abstract":"<div><p>Photocatalytic CO<sub>2</sub> reduction technology can use sunlight to convert CO<sub>2</sub> into fuel or chemical raw materials, slowdown the greenhouse effect and achieve sustainable development. Therefore, we have developed a series of high-quality carbon quantum dots using alkaline lignin (AL) as the core raw material and using high efficiency hydrothermal method. Ag-BiVO<sub>4</sub> composite was prepared by hydrothermal method. Then, the Ag-BiVO<sub>4</sub>-CQDs photocatalytic composite was prepared by constant temperature water bath method. The structure and morphology of the composites were characterized by X-ray diffraction, transmission electron microscope and X-ray photoelectron spectroscopy. Through optical and electrochemical tests, it can be seen that the composite has better interfacial charge transfer and electron transport ability. In the visible light catalytic CO<sub>2</sub> reduction reaction, Ag-BiVO<sub>4</sub> can selectively reduce CO<sub>2</sub> to CH<sub>4</sub>, and the CH<sub>4</sub> yield is greatly improved after Ag-BiVO<sub>4</sub> combines with CQDs. The 3 h CH<sub>4</sub> yield increased from 17.64 μmol/g to 97.82 μmol/g after reduction by adding 40 mL CQDs to Ag-BiVO<sub>4</sub> composite, which is 5.54 times that of Ag-BiVO<sub>4</sub>. The results showed that the introduced CQDs were uniformly attached to Ag-BiVO<sub>4</sub>. As an electron transport medium, CQDs can efficiently facilitate the transfer of photogenerated carriers, suppress the recombination of electron–hole pairs, and enhance the photocatalytic performance of Ag-BiVO<sub>4</sub>-CQDs for CO<sub>2</sub> reduction.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"2071 - 2088"},"PeriodicalIF":2.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Opto-electronic studies and diode applications: synthesis, characterization, and photoconductive properties of Schiff base and its Pd(II) and Pt(II) complexes

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-12 DOI: 10.1007/s11164-025-05547-y

Nevin Turan, Kenan Buldurun, Halil Seymen, Bayram Gündüz, Naki Çolak

{"title":"Opto-electronic studies and diode applications: synthesis, characterization, and photoconductive properties of Schiff base and its Pd(II) and Pt(II) complexes","authors":"Nevin Turan, Kenan Buldurun, Halil Seymen, Bayram Gündüz, Naki Çolak","doi":"10.1007/s11164-025-05547-y","DOIUrl":"10.1007/s11164-025-05547-y","url":null,"abstract":"<div><p>This research involved the creation of a Schiff base ligand, (<i>E</i>)-6-tert-butyl 3-ethyl 2-(3-methoxy-4-phenoxybenzylideneamino)-4,5-dihydrothieno[2,3-<i>c</i>]pyridine-3,6(7H)-dicarboxylate (SB), through the condensation reaction of 6-tert-butyl 3-ethyl 2-amino-4,5-dihydrothieno[2,3-<i>c</i>]pyridine-3,6(7H)-dicarboxylate with 3-methoxy-4-phenoxybenzaldehyde. The synthesized Schiff base was then used to form metal complexes with Pd(II) and Pt(II) metal ions. Various analytical techniques, including microanalysis (C, H, N, and S), FT-IR, <sup>1</sup>H-NMR, <sup>13</sup>C-NMR, UV–Vis., thermal analysis (TGA), powder XRD analysis, mass (ESI), molar conductivity, and magnetic susceptibility, were employed to confirm the structures of synthesized compounds. Spectroscopic data indicated that the Schiff base functions as a chelating agent, utilizing oxygen and nitrogen donor sites. The molar conductance measurements suggested that both complexes are non-electrolytic. A square planar structure was proposed for the Pd(II) and Pt(II) complexes. The study also investigated the electronic and photonic characteristics of the metal complexes under different conditions. Furthermore, a basic diode was fabricated using the metal complex, and its electronic and photonic characteristics were thoroughly investigated. Current–voltage (I-V) measurements showed that the diode based on the Pd(II) complex had notable noise and a high leakage current. On the other hand, the diode with the Pt(II) complex exhibited enhanced photoconductivity as the light intensity increased.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"1989 - 2005"},"PeriodicalIF":2.8,"publicationDate":"2025-03-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11164-025-05547-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676380","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Study on the adsorption performance of tetracycline by KMnO4/KOH co-modified cow dung-based biochar

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-10 DOI: 10.1007/s11164-025-05543-2

He-Song Wang, Li-Hong Zhao, Liang-Bin Chen, Yu-Fei Liang, Jia-Qi Tang

{"title":"Study on the adsorption performance of tetracycline by KMnO4/KOH co-modified cow dung-based biochar","authors":"He-Song Wang, Li-Hong Zhao, Liang-Bin Chen, Yu-Fei Liang, Jia-Qi Tang","doi":"10.1007/s11164-025-05543-2","DOIUrl":"10.1007/s11164-025-05543-2","url":null,"abstract":"<div><p>Tetracycline (TC) is a broad-spectrum antibiotic whose residues in water systems present a significant risk to both environmental ecosystems and human health. There is an increasing demand for the development of environmentally friendly and efficient adsorbents to effectively remove TC from water. In response to this need, the present study first involved the preparation of cow dung-based biochar through high-temperature pyrolysis. Subsequently, a co-modification process using KMnO<sub>4</sub> and KOH was employed to obtain Mn-K-DMBC, the modified biochar. Microscopic characterization revealed that the introduction of KMnO<sub>4</sub> and KOH significantly altered both the surface morphology and the pore structure of the biochar. Batch adsorption experiments demonstrated that Mn-K-DMBC exhibited a high adsorption capacity for TC, with a value of 142.58 mg/g at 308.15 K. The adsorption behavior was most effectively characterized by the Langmuir isotherm model and the pseudo-second-order kinetic model. Thermodynamic assessments demonstrated that the process was spontaneous and exhibited endothermic properties. Finally, the analysis revealed that the adsorption of TC onto Mn-K-DMBC is primarily driven by mechanisms such as pore filling, hydrogen bonding, metal complexation, and π-π interactions. This study offers valuable insights into the resource utilization of cow dung biomass and presents novel approaches for the preparation and modification of biochar.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"2171 - 2196"},"PeriodicalIF":2.8,"publicationDate":"2025-03-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Correction: Synthesis of pyrazolyl phosphonates by using amine-functionalized metakaolin

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-04 DOI: 10.1007/s11164-025-05523-6

Kasaram Roja, Reddi Mohan Naidu Kalla, Araveeti Eswar Reddy, D. K. Venkata Ramana, Tahani Mazyad Almutairi, Jaewoong Lee

引用次数: 0

Direct catalyst-free synthesis of substituted imidazolidinone-rhodanine hybrids via functional group migration

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-04 DOI: 10.1007/s11164-025-05542-3

Parisa Nazari, Farough Nasiri

引用次数: 0

One-pot synthesis of magnetic reduced graphene oxide as a support of Pd/PdO nanoparticles for hydrogen generation from formic acid

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-02 DOI: 10.1007/s11164-025-05541-4

Sajjad Keshipour, Mina Hadidi

引用次数: 0

Doxorubicin-functionalized graphene nanoribbons as novel assistant for ionic liquid-based electrolyte in DSSCs: an experimental and DFT study 多柔比星功能化石墨烯纳米带作为 DSSC 中离子液体基电解质的新型助手：实验和 DFT 研究

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-03-01 DOI: 10.1007/s11164-025-05539-y

Mehrnaz Davoudabdollah, Elaheh Kowsari, Mohammad Mohammadizadeh Boghrabad, Saeedeh Sarabadani Tafreshi, Mahboobeh Rafieepoor Chirani, Nora H. de Leeuw

{"title":"Doxorubicin-functionalized graphene nanoribbons as novel assistant for ionic liquid-based electrolyte in DSSCs: an experimental and DFT study","authors":"Mehrnaz Davoudabdollah, Elaheh Kowsari, Mohammad Mohammadizadeh Boghrabad, Saeedeh Sarabadani Tafreshi, Mahboobeh Rafieepoor Chirani, Nora H. de Leeuw","doi":"10.1007/s11164-025-05539-y","DOIUrl":"10.1007/s11164-025-05539-y","url":null,"abstract":"<div><p>Dye-sensitized solar cells (DSSCs) have attracted attention due to their efficiency, and researchers are exploring various techniques to enhance their performance. Graphene nanoribbons and doxorubicin with their specific structures can improve these cells' performances. This study is the first application of doxorubicin-functionalized graphene nanoribbons (DF-GNR) as an electrolyte additive in DSSCs. One of the most innovative parts of this research is applying doxorubicin as an expired medicinal drug to embrace the circular economy. The graphene-oxide nanoribbon (GONR) synthesis began with carbon nanotube oxidation, followed by GONR and doxorubicin reacting in 1-butyl 3-methyl imidazolium bromide (as a solvent and catalyst) and triphenyl phosphate to generate DF-GNR. The electrolytes were composed of various amounts of DF-GNR and ionic liquids, including 1-butyl-3-methyl imidazolium iodide and 1-ethyl-3-methyl imidazolium iodide. The results showed that adding an optimum amount of DF-GNR increased the open-circuit voltage (<i>V</i><sub>OC</sub>) from 0.713 to 0.749 V, the short-circuit current density (<i>J</i><sub>SC</sub>) from 8.559 to 13.781 (mA/cm<sup>2</sup>), and the DSSCs' efficiency from 4.276% (the standard cells based on a graphene-free electrolyte in which DF-GNR is not added) to 7.126%. Furthermore, density functional theory studies revealed that the adsorption of DF-GNR electrolyte additives onto the TiO<sub>2</sub> surface induced the formation of midgap states within the electrode’s bandgap. These states facilitated electron transport by lowering the energy barrier, leading to a reduction in the bandgap caused by additive adsorption. This change also resulted in a redshift in the absorption edge and a significant enhancement in the efficiency of DSSCs.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"2105 - 2126"},"PeriodicalIF":2.8,"publicationDate":"2025-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676188","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Sol–gel synthesis, structure, and morphology of M0.2Ni0.8MoO4 (M = Fe, Cu, and Zn) layered double hydroxide as a novel electrocatalysts for the hydrogen evolution reaction in alkaline media 作为碱性介质中氢进化反应新型电催化剂的 M0.2Ni0.8MoO4（M = Fe、Cu 和 Zn）层状双氢氧化物的溶胶凝胶合成、结构和形貌

IF 2.8 3区化学

Research on Chemical Intermediates Pub Date : 2025-02-26 DOI: 10.1007/s11164-025-05537-0

H. Nady, Salah Eid, Ebtsam K. Alenezy, Ahmed A. Elhenawy, Ibrahim O. Ali

{"title":"Sol–gel synthesis, structure, and morphology of M0.2Ni0.8MoO4 (M = Fe, Cu, and Zn) layered double hydroxide as a novel electrocatalysts for the hydrogen evolution reaction in alkaline media","authors":"H. Nady, Salah Eid, Ebtsam K. Alenezy, Ahmed A. Elhenawy, Ibrahim O. Ali","doi":"10.1007/s11164-025-05537-0","DOIUrl":"10.1007/s11164-025-05537-0","url":null,"abstract":"<div><p>The fabrication of transition metal-based electrocatalysts with superior performance for the hydrogen evolution reaction (HER) remains a major challenge in the field of electrocatalysis. Here, the sol–gel method is used to synthesize three of <i>M</i><sub>0.2</sub>Ni<sub>0.8</sub>Mo-LDH (where <i>M</i> is Fe, Cu, and Zn) layered double hydroxide precursors, which are then used as effective electrocatalysts for the alkaline HER. XRD, HRSEM, ATR-FT-IR, energy-dispersive X-ray, and thermokinetic analysis using TGA methods were used to characterize the structure of the prepared materials. Several investigations have been carried out with thermal kinetic analysis using the Coats–Redfern and Horowitz–Metzger equations. In comparison with Zn<sub>0.2</sub>Ni<sub>0.8</sub>Mo-LDH and Fe<sub>0.2</sub>Ni<sub>0.8</sub>Mo-LDH electrocatalysts, the results show increased electrocatalytic activity of Cu<sub>0.2</sub>Ni<sub>0.8</sub>Mo-LDH in alkaline conditions. For the Cu<sub>0.2</sub>Ni<sub>0.8</sub>Mo-LDH to supply a cathodic current density of 10 mA cm<sup>−2</sup> for the HER, an overpotential as low as 211 mV was needed. The Tafel slopes for different materials were measured, and the results show that the HER follows the Volmer–Heyrovsky reaction. The 3D Hirshfeld surface analysis indicates that van der Waals and dispersion forces play a significant role in the packing of the crystal, with specific interactions between different metal centers—Ni•••H, Mo•••H, and <i>M</i>•••H—being particularly influential. The percentages provided in range (13.6–30.6%) for Cu, (5.5–30.1%) for Zn, and (20.5–33.4%) for Fe—highlight the relative contributions of these interactions to the overall stability and structure of the crystal lattice involving Fe, Cu, and Zn.</p></div>","PeriodicalId":753,"journal":{"name":"Research on Chemical Intermediates","volume":"51 4","pages":"2145 - 2169"},"PeriodicalIF":2.8,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143676238","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0