Advanced Powder Materials最新文献

{"title":"Plasma induced dynamic coupling of microscopic factors to collaboratively promote EM losses coupling of transition metal dichalcogenide absorbers","authors":"Jiaming Wen ,&nbsp;Geng Chen ,&nbsp;Shengchong Hui ,&nbsp;Zijing Li ,&nbsp;Jijun Yun ,&nbsp;Xiaomeng Fan ,&nbsp;Limin Zhang ,&nbsp;Qian He ,&nbsp;Xingmin Liu ,&nbsp;Hongjing Wu","doi":"10.1016/j.apmate.2024.100180","DOIUrl":"10.1016/j.apmate.2024.100180","url":null,"abstract":"<div><p>Plasma as the fourth state of matter has attracted great attention for material surface modification, which could induce changes in material microscopic factors, such as defects, phase transitions, crystallinity, and so on. However, the interactions among those microscopic factors and regulation mechanism of macroscopic properties have rarely been investigated. Two-dimensional (2D) transition metal dichalcogenide with tunable structure and phase is one of the most promising electromagnetic wave (EMW) absorbers, which provides a favorable platform for systematically studying the dynamic coupling of its microscopic factors. Herein, we constructed a NaBH₄ solution-assisted Ar plasma method to modify the 2H-MoS₂ and 1T-WS₂ for exploring the regulation mechanism of microscopic factors. For MoS₂ and WS₂, NaBH₄ solution-assisted Ar plasma treatment behaves with different effects on dielectric responses, realizing dynamic coupling of material microscopic factors to collaboratively promote EM losses coupling. Consequently, the MS-D3-0.5 (MoS₂, 3 ​kV voltage, 0.5 ​mol ​L⁻¹ NaBH₄ solution) displays an optimum effective absorption bandwidth of 8.01 ​GHz, which is 319.4 ​% more than that of MS-raw sample. This study not only reveals the novel mechanism of plasma induced dynamic coupling of microscopic factors for EMW dissipation, but also presents a new method of plasma-dominated surface modification to optimize the EMW absorption performance.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X24000113/pdfft?md5=0bb578882969a3d494bfae8edc9498c5&pid=1-s2.0-S2772834X24000113-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139632466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Light-driven H2O2 production over redox-active imine-linked covalent organic frameworks","authors":"Songlin Zhang,&nbsp;Jinwen Hu,&nbsp;Wenzhe Shang,&nbsp;Jingya Guo,&nbsp;Xusheng Cheng,&nbsp;Suchan Song,&nbsp;Tianna Liu,&nbsp;Wei Liu,&nbsp;Yantao Shi","doi":"10.1016/j.apmate.2024.100179","DOIUrl":"10.1016/j.apmate.2024.100179","url":null,"abstract":"<div><p>Imine-linked covalent organic frameworks (COFs) provide distinctive prospects for promoting photocatalytic H₂O₂ production, yet the intricate involvement of imine-derived linkages chemistry under light irradiation remains incompletely elucidated. Here, imine-linked COF-LZU1 demonstrates a visible light-driven H₂O₂ evolution rate of 387 ​μmol ​g⁻¹ ​h⁻¹, particularly, negligible dependence on the sacrificial agents. By virtue of electron paramagnetic spectroscopy and solid-state nuclear magnetic resonance, we experimentally tracked the structure evolution and identified its autooxidation to Wurster's salt mimics under the photocatalytic conditioning. This finding coincides with the radical anion ·O₂⁻ governed reaction pathway and is further rationalized with additional theoretical calculations. This study provides insights into both photophysical/photochemical aspects over the imine-linkage structure.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X24000101/pdfft?md5=35c3f156dc684b753fcdeddfa4936902&pid=1-s2.0-S2772834X24000101-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139634184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Halogen modified organic porous semiconductors in photocatalysis: mechanism, synthesis, and application","authors":"Yue Yang,&nbsp;Liping Guo,&nbsp;Xuepeng Wang,&nbsp;Zhenzi Li,&nbsp;Wei Zhou","doi":"10.1016/j.apmate.2024.100178","DOIUrl":"10.1016/j.apmate.2024.100178","url":null,"abstract":"<div><p>Photocatalysis is considered as the promising energy conversion way to resolve the issues of energy crisis and environmental pollution. As the key point of the photocatalysis, the photocatalyst determines the final conversion efficiency from solar, therefore, the composition and photoelectronic nature of which deserve to be valued. Halogen often affects immensely the intrinsic electron configuration of the matrix because of electrophilic property, and thus its topic has attracted lots of attention for photocatalytic application. In this review, halogen-contained organic porous semiconductors are discussed in detailed. Firstly, the role of halogens in photocatalysis based on organic porous semiconductors are categorized. Then, the way to introduce the halogens into organic porous semiconductors and their applications in photocatalysis are reviewed. At last, the outlooks are given at the end of this paper. This review would bring new insights into the non-metal doping engineering for improving the photocatalytic performance of organic semiconductors.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X24000095/pdfft?md5=a604065f7099255affb2700766d21c6e&pid=1-s2.0-S2772834X24000095-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139632831","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electron-enriched single-Pd-sites on g-C3N4 nanosheets achieved by in-situ anchoring twinned Pd nanoparticles for efficient CO2 photoreduction","authors":"Lei Li ,&nbsp;Xinyan Dai ,&nbsp;Meichi Lu ,&nbsp;Changfa Guo ,&nbsp;Saikh Mohammad Wabaidur ,&nbsp;Xi-Lin Wu ,&nbsp;Zhangrong Lou ,&nbsp;Yijun Zhong ,&nbsp;Yong Hu","doi":"10.1016/j.apmate.2024.100170","DOIUrl":"10.1016/j.apmate.2024.100170","url":null,"abstract":"<div><p>Modulating electronic structures of single-atom metal cocatalysts is vital for highly active photoreduction of CO₂, and it's especially challenging to develop a facile method to modify the dispersion of atomical photocatalytic sites. We herein report an ion-loading pyrolysis route to <em>in-situ</em> anchor Pd single atoms as well as twinned Pd nanoparticles on ultra-thin graphitic carbon nitride nanosheets (Pd_TP/Pd_SA-CN) for high-efficiency photoreduction of CO₂. The anchored Pd twinned nanoparticles donate electrons to adjacent single Pd–N₄ sites through the carbon nitride networks, and the optimized Pd_TP/Pd_SA-CN photocatalyst exhibits a CO evolution rate up to 46.5 ​μmol ​g⁻¹ ​h⁻¹ with nearly 100% selectivity. As revealed by spectroscopic and theoretical analyses, the superior photocatalytic activity is attributed to the lowered desorption barrier of carbonyl species at electron-enriched Pd single atoms, together with the improved efficiencies of light-harvesting and charge separation/transport. This work has demonstrated the engineering of the electron density of single active sites with twinned metal nanoparticles assisted by strong electronic interaction with the support of the atomic metal, and unveiled the underlying mechanism for expedited photocatalytic efficiency.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2024-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X24000010/pdfft?md5=228e102479e3d12c1b50d38eabab6970&pid=1-s2.0-S2772834X24000010-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"139458078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Insight into the effect of Ti substitutions on the static oxidation behavior of (Hf,Ti)C at 2500 ​°C","authors":"Shiyan Chen ,&nbsp;Zhaoke Chen ,&nbsp;Jinming Wang ,&nbsp;Yi Zeng ,&nbsp;Weilong Song ,&nbsp;Xiang Xiong ,&nbsp;Xingchao Li ,&nbsp;Tongqi Li ,&nbsp;Yichen Wang","doi":"10.1016/j.apmate.2023.100168","DOIUrl":"10.1016/j.apmate.2023.100168","url":null,"abstract":"<div><p>Hf-based carbides are highly desirable candidate materials for oxidizing environments above 2000 ​°C. However, the static oxidation behavior at their potential service temperatures remains unclear. To fill this gap, the static oxidation behavior of (Hf, Ti)C and the effect of Ti substitutions were investigated in air at 2500 ​°C under an oxygen partial pressure of 4.2 ​kPa. After oxidation for 2000 ​s, the thickness of the oxide layer on the surface of (Hf, Ti)C bulk ceramic is reduced by 62.29 ​% compared with that on the HfC monocarbide surface. The dramatic improvement in oxidation resistance is attributed to the unique oxide layer structure consisting of various crystalline oxycarbides, HfO₂, and carbon. The Ti-rich oxycarbide ((Ti, Hf)C_<em>x</em>O_<em>y</em>) dispersed within HfO₂ formed the major structure of the oxide layer. A coherent boundary with lattice distortion existed at the HfO₂/(Ti, Hf)C_<em>x</em>O_<em>y</em> interface along the (111) crystal plane direction, which served as an effective oxygen diffusion barrier. The Hf-rich oxycarbide ((Hf, Ti)C_<em>x</em>O_<em>y</em>) together with (Ti, Hf)C_<em>x</em>O_<em>y</em>, HfO₂, and precipitated carbon constituted a dense transition layer, ensuring favorable bonding between the oxide layer and the matrix. The Ti content affects the oxidation resistance of (Hf, Ti)C by determining the oxide layer's phase distribution and integrity.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X2300060X/pdfft?md5=73f390f61c423f25fad4e48ac87d21dc&pid=1-s2.0-S2772834X2300060X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138613788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Interlayer engineering and electronic regulation of MoSe2 nanosheets rolled hollow nanospheres for high-performance sodium-ion half/full batteries","authors":"Jun Xu ,&nbsp;Junbao Jiang ,&nbsp;Heng Tang ,&nbsp;Zhao Chen ,&nbsp;Junwei Chen ,&nbsp;Yan Zhang ,&nbsp;Chun-Sing Lee","doi":"10.1016/j.apmate.2023.100169","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100169","url":null,"abstract":"<div><p>Layered transition metal dichalcogenides are promising candidates for sodium storage but suffering from low intrinsic electronic conductivity and limited interlayer spacing for fast electron/ion transport, which restricts their high-rate capability and cycling stability. In this work, rGO@MoSe₂/<span>NAC</span> hierarchical architectures, consisting of conductive reduced graphene oxide (rGO) supported by hollow nanospheres that are rolled from superlattices of alternatively overlapped MoSe₂ and N-doped amorphous carbon (<span>NAC</span>) monolayers, are synthesized as a high-performance sodium storage anode. Theoretical calculations reveal the intercalation of NAC monolayer between two adjacent MoSe₂ monolayers improving electronic conductivity of MoSe₂ in both surface and internal bulk to fully accelerate electron transport and enhance Na⁺ ​adsorption. The interoverlapped MoSe₂/NAC superlattice featuring a wide interlayer expansion (72.3 ​%) of MoSe₂ dramatically decreases Na⁺ ​diffusion barriers for fast insertion/extraction. Moreover, the hollow nanospheres and the rGO conductive network contribute to a robust hiberarchy that can well release internal stress and buffer the volume expansion, thereby enabling outstanding structural stability. Consequently, the rGO@MoSe₂/NAC anode exhibits excellent high-rate capability of 194 mAh g⁻¹ and ultralong cyclability of 12 ​000 cycles with a low capacity fading rate of 0.0038 ​% per cycle at an ultra-high current of 50 ​A ​g⁻¹, delivering the best high-rate cycling performance to date. Remarkably, the Na₃V₂(PO₄)₃‖rGO@MoSe₂/NAC full cells also present outstanding cycling stability (600 cycles) at 10C rate, which proves the great potential in fast-charging applications.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000611/pdfft?md5=0b9d0f934e2663c29f025494c24ca431&pid=1-s2.0-S2772834X23000611-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138582160","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Construction interlayer structure of hydrated vanadium oxides with tunable P-band center of oxygen towards enhanced aqueous Zn-ion batteries","authors":"Ziyi Feng ,&nbsp;Yunlong Zhang ,&nbsp;Zhanming Gao ,&nbsp;Dida Hu ,&nbsp;Hanmei Jiang ,&nbsp;Tao Hu ,&nbsp;Changgong Meng ,&nbsp;Yifu Zhang","doi":"10.1016/j.apmate.2023.100167","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100167","url":null,"abstract":"<div><p>Layered materials with adjustable framework, as the most potential cathode materials for aqueous rechargeable zinc ion batterie, have high capacity, permit of rapid ion diffusion, and charge transfer channels. Previous studies have widely investigated their preparation and storage mechanism, but the intrinsic relationship between the structural design of layered cathode materials and electrochemical performance has not been well established. In this work, based on the first principles calculations and experiments, a crucial strategy of pre-intercalated metal-ions in vanadium oxide interlayer with administrable p-band center (<em>ɛ</em>_p) of O is explored to enhance Zn²⁺ storage. This regulation of the degree of covalent bond and the average charge of O atoms varies the binding energy between Zn²⁺ and O, thus affecting the intercalation/de-intercalation of Zn²⁺. The present study demonstrates that <em>ɛ</em>_p of O can be used as an important indicator to boost Zn²⁺ storage, which provides a new concept toward the controlled design and application of layered materials.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000593/pdfft?md5=95e5e935f54476d3366e2235ee4df369&pid=1-s2.0-S2772834X23000593-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138423272","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Self-recoverable NIR mechanoluminescence from Cr3+ doped perovskite type aluminate","authors":"Peishan Shao ,&nbsp;Puxian Xiong ,&nbsp;Yao Xiao ,&nbsp;Zhicong Chen ,&nbsp;Dongdan Chen ,&nbsp;Zhongmin Yang","doi":"10.1016/j.apmate.2023.100165","DOIUrl":"10.1016/j.apmate.2023.100165","url":null,"abstract":"<div><p>Mechanoluminescent (ML) materials, which have the ability to convert mechanical energy to optical energy, have found huge promising applications such as in stress imaging and anti-counterfeiting. However, the main reported ML phosphors are based on trap-related ones, thus hindering the practical applications due to the requirement of complex light pre-irradiation process. Here, a self-recoverable near infrared (NIR) ML material of LaAl_1-xO₃: xCr³⁺ (x=0.2 ​%, 0.4 ​%, 0.6 ​%, 0.8 ​%, 1.0 ​%, and 1.2 ​%) has been developed. Based on the preheating method and corresponding ML performance analysis, the influences of residual carriers are eliminated and the detailed dynamic luminescence process analysis is realized. Systematic experiments are conducted to reveal the origin of the ML emissions, demonstrating that ML is dictated more by the non-centrosymmetric piezoelectric crystal characteristic. In general, this work has provided significant references for exploring more efficient NIR ML materials, which may provide potential applications in anti-counterfeiting and bio-stress sensing.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-11-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X2300057X/pdfft?md5=b41af3accf095f55601b158f3e931ec7&pid=1-s2.0-S2772834X2300057X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"135515647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Facet-engineered growth of non-layered 2D manganese chalcogenides","authors":"Jingwei Wang ,&nbsp;Junyang Tan ,&nbsp;Liqiong He ,&nbsp;Zhenqing Li ,&nbsp;Shengnan Li ,&nbsp;Yunhao Zhang ,&nbsp;Huiyu Nong ,&nbsp;Qinke Wu ,&nbsp;Qiangmin Yu ,&nbsp;Xiaolong Zou ,&nbsp;Hui-Ming Cheng ,&nbsp;Bilu Liu","doi":"10.1016/j.apmate.2023.100164","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100164","url":null,"abstract":"<div><p>Non-layered two-dimensional (2D) materials have sparked much interest recently due to their atomic thickness, large surface area, thickness- and facet-dependent properties. Currently, these materials are mainly grown from wet-chemistry methods but suffer from small size, low quality, and multi-facets, which is a major challenge hindering their facet-dependent property studies and applications. Here, we report the facet-engineered growth (FEG) of non-layered 2D manganese chalcogenides (MnX, X ​= ​S, Se, Te) based on the chemical vapor deposition method. The as-grown samples exhibit large-area surfaces of single facet, high-crystallinity, and ordered domain orientation. As a proof-of-concept, we show the facet-dependent electrocatalytic property of non-layered 2D MnSe, proving they are ideal candidates for fundamental research. Furthermore, we elucidate the underlying mechanism of FEG during the vapor growth process by the interfacial energy derived nucleation models. The method developed in this work provides new opportunities for regulating and designing the structure of 2D materials.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000568/pdfft?md5=5b4b6da275c3382896c48e0092e7f387&pid=1-s2.0-S2772834X23000568-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"92002029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Microstructure evolution and mechanical properties of Al2O3 foams via laser powder bed fusion from Al particles","authors":"Ye Dong ,&nbsp;Annan Chen ,&nbsp;Ting Yang ,&nbsp;Shuai Gao ,&nbsp;Shuning Liu ,&nbsp;Bingjian Guo ,&nbsp;Hongyi Jiang ,&nbsp;Yusheng Shi ,&nbsp;Chunze Yan","doi":"10.1016/j.apmate.2023.100135","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100135","url":null,"abstract":"<div><p>Laser powder bed fusion (LPBF) combined with reaction bonding (RB) of Al particles is an effective method for preparing high-performance 3D Al₂O₃ ceramic foams. However, the indistinct microstructure evolution hinders the regulation of pore features and the improvement of synthetic properties. Herein, the microstructure evolution of the Al₂O₃ ceramic foams during the LPBF/RB process is clarified by various characterization methods, and the corresponding mechanical property modulation is realized by optimizing LPBF parameters, organic binder (E12 epoxy resin) content, heating rate, sintering time, and coral-like Al₂O₃ content. The expansion from Al₂O₃ outward growth and Al granule precipitation counteracts the shrinkage from E12 decomposition and Al₂O₃ sintering, resulting in an ultra-low shrinkage of 0.94%–3.01%. The pore structures of particle packing pores, hollow spheres, and microporous structures allow a tunable porosity of 52.6%–73.7%. The <em>in-situ</em> formation of multi-scale features including hollow spheres, flaky grains, whiskers, nanofibers, and bond bridges brings about a remarkably high bending strength of 6.5–38.3 ​MPa. Our findings reveal the relationship between microstructure evolution and property optimization of high-performance ceramic foams, with potential significance for microstructure design and practical application.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":null,"pages":null},"PeriodicalIF":0.0,"publicationDate":"2023-10-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49712124","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}