Zibo Niu , Daxin Li , Dechang Jia , Zhihua Yang , Kunpeng Lin , Ralf Riedel , Paolo Colombo , Yu Zhou
{"title":"Oxidation behavior of amorphous and nanocrystalline SiBCN ceramics – Kinetic consideration and microstructure","authors":"Zibo Niu , Daxin Li , Dechang Jia , Zhihua Yang , Kunpeng Lin , Ralf Riedel , Paolo Colombo , Yu Zhou","doi":"10.1016/j.apmate.2023.100163","DOIUrl":"10.1016/j.apmate.2023.100163","url":null,"abstract":"<div><p>In this study, the structural evolution of SiBCN ceramics during crystallization and its effects on oxidation behavior involving different atomic units or formed phases in amorphous or crystalline SiBCN ceramics were analyzed. The amorphous structure has exceptionally high oxidation activity but presents much better oxidation resistance due to its synchronous oxidation of atomic units and homogeneous composition in the generated oxide layer. However, the oxidation resistance of SiBCN ceramic will degrade during the continual crystallization process, especially for the formation of the nanocapsule-like structure, due to heterogeneous oxidation caused by the phase separation. Besides, the activation energy and rate-controlling mechanism of the atomic units and phases in SiBCN ceramics were obtained. The BNC<sub><em>x</em></sub> (<em>E</em><sub>a</sub> = 145 kJ/mol) and SiC<sub>(2-<em>x</em>)</sub> (<em>E</em><sub>a</sub> = 364 kJ/mol) atomic units in amorphous SiBCN structure can be oxidized at relatively lower temperatures with much lower activation energy than the corresponding BN(C) (<em>E</em><sub>a</sub> = 209 kJ/mol) and SiC (<em>E</em><sub>a</sub> = 533 kJ/mol) phases in crystalline structure, and the synchronous oxidation of the SiC<sub>(2-<em>x</em>)</sub> and BNC<sub><em>x</em></sub> units above 750 °C changes the oxidation activation energy of BNC<sub><em>x</em></sub> (<em>E</em><sub>a</sub> = 332 kJ/mol) to that similar to SiC<sub>(2-<em>x</em>)</sub>. The heterogeneous oxide layer formed from the nanocapsule-like structure will decrease the activation energy SiC (<em>E</em><sub>a</sub> = 445 kJ/mol) and t-BN (<em>E</em><sub>a</sub> = 198 kJ/mol).</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"3 1","pages":"Article 100163"},"PeriodicalIF":0.0,"publicationDate":"2023-09-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000556/pdfft?md5=1ba97d5d5fa6120b6608853b4c846c4b&pid=1-s2.0-S2772834X23000556-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134994750","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Guolong Lu , Ge Meng , Qian Liu , Ligang Feng , Jun Luo , Xijun Liu , Yang Luo , Paul K. Chu
{"title":"Advanced strategies for solid electrolyte interface design with MOF materials","authors":"Guolong Lu , Ge Meng , Qian Liu , Ligang Feng , Jun Luo , Xijun Liu , Yang Luo , Paul K. Chu","doi":"10.1016/j.apmate.2023.100154","DOIUrl":"10.1016/j.apmate.2023.100154","url":null,"abstract":"<div><p>Emerging energy technologies, aimed at addressing the challenges of energy scarcity and environmental pollution, have become a focal point for society. However, these actualities present significant challenges for modern energy storage devices. Lithium metal batteries (LMBs) have gained considerable attention due to their high energy density. Nonetheless, their use of liquid electrolytes raises safety concerns, including dendritic growth, electrode corrosion, and electrolyte decomposition. In light of these challenges, solid-state batteries (SSBs) have emerged as a highly promising next-generation energy storage solution by leveraging lithium metal as the anode to achieve improved safety and energy density. Metal organic frameworks (MOFs), characterized by their porous structure, ordered crystal frame, and customizable configuration, have garnered interest as potential materials for enhancing solid-state electrolytes (SSEs) in SSBs. The integration of MOFs into SSEs offers opportunities to enhance the electrochemical performance and optimize the interface between SSEs and electrodes. This is made possible by leveraging the high porosity, functionalized structures, and abundant open metal sites of MOFs. However, the rational design of high-performance MOF-based SSEs for high-energy Li metal SSBs (LMSSBs) remains a significant challenge. In this comprehensive review, we present an overview of recent advancements in MOF-based SSEs for LMSSBs, focusing on strategies for interface optimization and property enhancement. We categorize these SSEs into two main types: MOF-based quasi-solid-state electrolytes and MOF-based all solid-state electrolytes. Within these categories, various subtypes are identified based on the combination mode, additional materials, formation state, preparation method, and interface optimization measures employed. The review also highlights the existing challenges associated with MOF materials in SSBs applications and proposes potential solutions and future development prospects to guide the advancement of MOFs-based SSEs. By providing a comprehensive assessment of the applications of MOFs in LMSSBs, this review aims to offer valuable insights and guidance for the development of MOF-based SSEs, addressing the key issues faced by these materials in SSBs technology.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"3 1","pages":"Article 100154"},"PeriodicalIF":0.0,"publicationDate":"2023-08-11","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000465/pdfft?md5=cb721ce40170afc0e0ef8948448cc958&pid=1-s2.0-S2772834X23000465-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"83853586","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Feiyue Yang , Shuang Zhao , Guobing Chen , Kunfeng Li , Zhifang Fei , Paul Mummery , Zichun Yang
{"title":"High-strength, multifunctional and 3D printable mullite-based porous ceramics with a controllable shell-pore structure","authors":"Feiyue Yang , Shuang Zhao , Guobing Chen , Kunfeng Li , Zhifang Fei , Paul Mummery , Zichun Yang","doi":"10.1016/j.apmate.2023.100153","DOIUrl":"10.1016/j.apmate.2023.100153","url":null,"abstract":"<div><p>The quest for lightweight and functional materials poses stringent requirements on mechanical performance of porous materials. However, the contradiction between high strength and elevated porosity of porous materials severely limits their application scenarios in emerging fields. Herein, high-strength multifunctional mullite-based porous ceramic monoliths were fabricated utilizing waste fly ash hollow microspheres (FAHMs) by the protein gelling technique. Owing to their unique shell-pore structure inspired by shell-protected biomaterials, the monoliths with porosity of 54.69%–70.02% exhibited a high compressive strength (32.3–42.9 MPa) which was 2–5 times that of mullite-based porous ceramics with similar density reported elsewhere. Moreover, their pore structure and properties could be tuned by regulation of the particle size and content of the FAHMs, and the resultant monoliths demonstrated superior integrated performances for multifunctional applications, such as broadband sound insulation, efficient thermal insulation, and high-temperature fire resistance (>1300 °C). On this basis, mullite-based porous ceramic lattices (porosity 68.28%–84.79%) with a hierarchical porous structure were successfully assembled by direct ink writing (DIW), which exhibited significantly higher compressive strength (3.02–10.77 MPa) than most other ceramic lattices with comparable densities. This unique shell-pore structure can be extended to other porous materials, and our strategy paves a new way for cost-effective, scalable and green production of multifunctional materials with well-defined microstructure.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"3 1","pages":"Article 100153"},"PeriodicalIF":0.0,"publicationDate":"2023-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000453/pdfft?md5=52281a2f7752c6cda4ac61421c07dd8c&pid=1-s2.0-S2772834X23000453-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"75734152","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mingyu Liu , Jiang Wang , Tao Hu , Songzhe Xu , Sansan Shuai , Weidong Xuan , Shuo Yin , Chaoyue Chen , Zhongming Ren
{"title":"Laser powder bed fusion of a Ni3Al-based intermetallic alloy with tailored microstructure and superior mechanical performance","authors":"Mingyu Liu , Jiang Wang , Tao Hu , Songzhe Xu , Sansan Shuai , Weidong Xuan , Shuo Yin , Chaoyue Chen , Zhongming Ren","doi":"10.1016/j.apmate.2023.100152","DOIUrl":"10.1016/j.apmate.2023.100152","url":null,"abstract":"<div><p>Ni<sub>3</sub>Al-based alloys are excellent candidates for the structural materials used for turbine engines due to their excellent high-temperature properties. This study aims at laser powder bed fusion and post-hot isostatic pressing (HIP) treatment of Ni<sub>3</sub>Al-based IC-221 M alloy with a high γ′ volume fraction. The as-built samples exhibits unavoidable solidification cracking and ductility dip cracking, and the laser parameter optimization can reduce the crack density to 1.34 mm/mm<sup>2</sup>. Transmission electron microscope (TEM) analysis reveals ultra-fine nanoscale γ′ phases in the as-built samples due to the high cooling rate during rapid solidification. After HIP treatment, a fully dense structure without cracking defects is achieved, which exhibits an equiaxed structure with grain size ∼120–180 μm and irregularly shaped γ′ precipitates ∼1–3 μm with a prominently high fraction of 86%. The room-temperature tensile test of as-built samples shows a high ultimate tensile strength (<em>σ</em><sub>UTS</sub>) of 1039.7 MPa and low fracture elongation of 6.4%. After HIP treatment, a significant improvement in ductility (15.7%) and a slight loss of strength (<em>σ</em><sub>UTS</sub> of 831.7 MPa) are obtained by eliminating the crack defects. Both the as-built and HIP samples exhibit retained high <em>σ</em><sub>UTS</sub> values of 589.8 MPa and 786.2 MPa, respectively, at 900 °C. The HIP samples exhibita slight decrease in ductility to ∼12.9%, indicating excellent high-temperature mechanical performance. Moreover, the abnormal increase in strength and decrease in ductility suggest the critical role of a high γ′ fraction in cracking formation. The intrinsic heat treatment during repeating thermal cycles can induce brittleness and trigger cracking initiation in the heat-affected zone with notable deteriorating ductility. The results indicate that the combination of LPBF and HIP can effectively reduce the crack density and enhance the mechanical properties of Ni<sub>3</sub>Al-based alloy, making it a promising material for high-temperature applications.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"3 1","pages":"Article 100152"},"PeriodicalIF":0.0,"publicationDate":"2023-07-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000441/pdfft?md5=920cae6cedeb9df7a696f6200100a673&pid=1-s2.0-S2772834X23000441-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"76167619","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Jie Zhao , Cao Zhou , Yue Guo , Zhen Shen , Geng Luo , Qiang Wu , Lijun Yang , Xizhang Wang , Zheng Hu
{"title":"Balancing loading mass and gravimetric capacitance of NiCo−layered double hydroxides to achieve ultrahigh areal performance for flexible supercapacitors","authors":"Jie Zhao , Cao Zhou , Yue Guo , Zhen Shen , Geng Luo , Qiang Wu , Lijun Yang , Xizhang Wang , Zheng Hu","doi":"10.1016/j.apmate.2023.100151","DOIUrl":"10.1016/j.apmate.2023.100151","url":null,"abstract":"<div><p>Delivering high areal capacitance (<em>C</em><sub>A</sub>) at high rates is crucial but challenging for flexible supercapacitors. <em>C</em><sub>A</sub> is the product of areal loading mass (<em>M</em><sub>A</sub>) and gravimetric capacitance (<em>C</em><sub>W</sub>). Finding and understanding the balance between <em>M</em><sub>A</sub> and <em>C</em><sub>W</sub> of supercapacitor materials is significant for designing high-<em>C</em><sub>A</sub> electrodes. Herein, we have systematically studied the correlation between <em>M</em><sub>A</sub> and <em>C</em><sub>W</sub> of the nanosheet arrays of NiCo−layered double hydroxide (NiCo−LDH), which were electrodeposited on carbon cloth with different heights to adjust the <em>M</em><sub>A</sub>, accompanied by the interlayer distance regulation to improve the <em>C</em><sub>W</sub>. The optimal <em>C</em><sub>W</sub> performance is achieved at the best charge transfer kinetics for each of <em>M</em><sub>A</sub> series. The NiCo−LDH electrode with the suitable <em>M</em><sub>A</sub> (2.58 mg cm<sup>−2</sup>) and the relatively high <em>C</em><sub>W</sub> (1918 F g<sup>−1</sup> at 5 A g<sup>−1</sup> and 400 F g<sup>−1</sup> at 150 A g<sup>−1</sup>) present a high <em>C</em><sub>A</sub> of 4948 mF cm<sup>−2</sup> at 12.9 mA cm<sup>−2</sup> and a record-high 1032 mF cm<sup>−2</sup> among LDHs-based flexible electrodes at an ultrahigh current density of 387 mA cm<sup>−2</sup>. The corresponding flexible supercapacitor coupled with activated carbon delivers a high energy density of 0.28 mWh cm<sup>−2</sup> at an ultrahigh power density of 712 mW cm<sup>−2</sup>, showing great potential applications.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"3 1","pages":"Article 100151"},"PeriodicalIF":0.0,"publicationDate":"2023-07-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X2300043X/pdfft?md5=270ecc38af71e922386ea714fca9813a&pid=1-s2.0-S2772834X2300043X-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"79372818","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Long Chen, Michael A. Maigbay, Miao Li, Xiaoqing Qiu
{"title":"Synthesis and modification strategies of g-C3N4 nanosheets for photocatalytic applications","authors":"Long Chen, Michael A. Maigbay, Miao Li, Xiaoqing Qiu","doi":"10.1016/j.apmate.2023.100150","DOIUrl":"10.1016/j.apmate.2023.100150","url":null,"abstract":"<div><p>Graphitic carbon nitride nanosheets (CNNs) become the most promising member in the carbon nitride family benefitted from their two-dimensional structural features. Recently, great endeavors have been made in the synthesis and modification of CNNs to improve their photocatalytic properties, and many exciting progresses have been gained. In order to elucidate the fundamentals of CNNs based catalysts and provide the insights into rational design of photocatalysis system, we describe recent progress made in CNNs preparation strategies and their applications in this review. Firstly, the physicochemical properties of CNNs are briefly introduced. Secondly, the synthesis approaches of CNNs are reviewed, including top-down stripping strategies (thermal, gas, liquid, and composite stripping) and bottom-up precursor molecules design strategies (solvothermal, template, and supramolecular self-assembly method). Subsequently, the modification strategies based on CNNs in recent years are discussed, including crystal structure design, doping, surface functionalization, constructing 2D heterojunction, and anchoring single-atom. Then the multifunctional applications of g-C<sub>3</sub>N<sub>4</sub> nanosheet based materials in photocatalysis including H<sub>2</sub> evolution, O<sub>2</sub> evolution, overall water splitting, H<sub>2</sub>O<sub>2</sub> production, CO<sub>2</sub> reduction, N<sub>2</sub> fixation, pollutant removal, organic synthesis, and sensing are highlighted. Finally, the opportunities and challenges for the development of high-performance CNNs photocatalytic systems are also prospected.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"3 1","pages":"Article 100150"},"PeriodicalIF":0.0,"publicationDate":"2023-07-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2772834X23000428/pdfft?md5=9f3e916bc55b233577cc81831e23ec14&pid=1-s2.0-S2772834X23000428-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"73834735","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Lei Wang , Mengqiu Huang , Ke Pei , Wenbin You , Biao Zhao , Limin Wu , Chongyun Liang , Jincang Zhang , Renchao Che
{"title":"Confined magnetic vortex motion from metal-organic frameworks derived Ni@C microspheres boosts electromagnetic wave energy dissipation","authors":"Lei Wang , Mengqiu Huang , Ke Pei , Wenbin You , Biao Zhao , Limin Wu , Chongyun Liang , Jincang Zhang , Renchao Che","doi":"10.1016/j.apmate.2023.100111","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100111","url":null,"abstract":"<div><p>Magnetic domain structure plays an important role in regulating the electromagnetic properties, which dominates the magnetic response behaviors. Herein, unique magnetic vortex domain is firstly obtained in the Ni nanoparticles (NPs) reduced from the Ni-based metal-organic frameworks (MOFs) precursor. Due to both the high symmetry spheres and boundary restriction of graphited carbon shell, confined magnetic vortex structure is generated in the nanoscale Ni core during the annealing process. Meanwhile, MOFs-derived Ni@C assembly powders construct special magnetic flux distribution and electron migration routes. MOFs-derived Ni@C microspheres exhibit outstanding electromagnetic (EM) wave absorption performance. The minimum reflection loss value of Ni@C–V microspheres with vortex domain can reach −54.6 dB at only 2.5 mm thickness, and the efficient absorption bandwidth up to 5.0 GHz at only 2.0 mm. Significantly, configuration evolution of magnetic vortex driven by the orientation and reversion of polarity core boosts EM wave energy dissipation. Magnetic coupling effect among neighboring Ni@C microspheres significantly enhances the magnetic reaction intensity. Graphitized carbon matrix and heterojunction Ni–C interfaces further offer the conduction loss and interfacial polarization. As result, MOFs-derived Ni@C–V powders display unique magnetic vortex, electronic migration network, and high-performance EM wave energy dissipation.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"2 3","pages":"Article 100111"},"PeriodicalIF":0.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49712256","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Fusheng Tan , Li Li , Jia Li , Bin Liu , Peter K. Liaw , Qihong Fang
{"title":"Multiscale modelling of irradiation damage behavior in high entropy alloys","authors":"Fusheng Tan , Li Li , Jia Li , Bin Liu , Peter K. Liaw , Qihong Fang","doi":"10.1016/j.apmate.2023.100114","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100114","url":null,"abstract":"<div><p>The increasingly harsh environment of the nuclear reactors and the insurmountable flaws of in-service materials have created an urgent need for the development of the brand-new alloys. For last decade, the high-entropy alloys (HEAs), a novel composition-design strategy, have received much attention due to their promise for the nuclear fields. The application of the multiscale modelling is to explore the irradiation performance and underlying mechanisms of HEAs. Abundant results and data deepen the understanding of the irradiation response, and accelerate the development of advanced irradiation-resistant HEAs. This review introduces the state-of-art multiscale modelling used for studying the irradiated properties of HEAs. Representative irradiation-induced microstructures and properties, as well as damage, are summarized. By strengthening the application of multiscale modelling, a rational design of high irradiation-resistant HEAs is expected.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"2 3","pages":"Article 100114"},"PeriodicalIF":0.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49733633","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Kaina Wang , Jipeng Fu , Shuqin Chang , Xuan Sun , Tianyi Sun , Su Zhang , Ran Pang , Lihong Jiang , Xiaojun Kuang , Evan Wenbo Zhao , Chengyu Li , Shiqing Xu , Mingxue Tang
{"title":"Correlating O-deficiency and luminescence property of Tb3+ doped SrO","authors":"Kaina Wang , Jipeng Fu , Shuqin Chang , Xuan Sun , Tianyi Sun , Su Zhang , Ran Pang , Lihong Jiang , Xiaojun Kuang , Evan Wenbo Zhao , Chengyu Li , Shiqing Xu , Mingxue Tang","doi":"10.1016/j.apmate.2023.100112","DOIUrl":"https://doi.org/10.1016/j.apmate.2023.100112","url":null,"abstract":"<div><p>Cubic rock salt can lower down or break the rare earth transition barrier through interstitial or vacancy defects owing to its great deformation and rotation flexibility. Here, we demonstrate that oxygen vacancies in SrO are induced by proper oxidization and atmosphere adjustment, resulting in defects with various depths and crystal field distortion. The thermally assisted tunneling from defects to <sup>5</sup>D<sub>4</sub> state and electronic population decrease on <sup>5</sup>D<sub>3</sub> state of Tb<sup>3+</sup> are observed by the deformation of adjacent oxygen octahedral structure. Finally, the as-prepared SrO: 0.01 Tb<sup>3+</sup> phosphors, commercial BaMgAl<sub>10</sub>O<sub>17</sub>: Eu<sup>2+</sup> blue phosphor, and CaAlSiN<sub>3</sub>: Eu<sup>2+</sup> red phosphor are mixed and coated onto 280 nm deep-ultraviolet LED chip to assemble white light-emitting LED device. The LEDs show CCT of 3850 K, 4136 K, and 4741 K, with color rendering index of 90.3, 90.8, and 92.1, respectively. These insights will advance the fundamental knowledge of crystal engineering in cubic rock salt, and enable new ways to manipulate energy transfer and electronic transition via defects.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"2 3","pages":"Article 100112"},"PeriodicalIF":0.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49711913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Mingzhi Chen , Kun Yang , Zhandong Wang , Shibin Wang , Erke Wu , Zhonghua Ni , Jinzhong Lu , Guifang Sun
{"title":"Underwater laser directed energy deposition of NV E690 steel","authors":"Mingzhi Chen , Kun Yang , Zhandong Wang , Shibin Wang , Erke Wu , Zhonghua Ni , Jinzhong Lu , Guifang Sun","doi":"10.1016/j.apmate.2022.100095","DOIUrl":"https://doi.org/10.1016/j.apmate.2022.100095","url":null,"abstract":"<div><p>Powder-based laser direct metal deposition (DMD), one of the directed energy deposition, was applied in air and underwater to repair pre-machined NV E690 steel plates. Systematic investigations on the effects of underwater environment and ambient pressures (0.01–0.35 MPa) on the microstructure evolution, phase transformation, and mechanical properties were conducted. The water quenching effect refined the grain size and increased the dislocation density and lath martensite content. The theoretical models of the underwater pressurized nitriding process and the precipitation kinetics of (Ti, V)N particles were established. Moreover, the microstructure evolution and the mechanical properties of other underwater DMD repaired samples did not show obvious relation with the underwater ambient pressures. This investigation not only provides a candidate for the underwater restoration technique but also bridges marine engineering and emerging DMD technology.</p></div>","PeriodicalId":7283,"journal":{"name":"Advanced Powder Materials","volume":"2 3","pages":"Article 100095"},"PeriodicalIF":0.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49712407","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":0,"RegionCategory":"","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}