Atomically dispersed NiOx cluster on high-index Pt facets boost ethanol electrooxidation through long-range synergistic sites

Advanced Powder Materials Pub Date : 2024-09-30 DOI:10.1016/j.apmate.2024.100244

Yao Wang , Meng Zheng , Yunrui Li , Lidan Zhu , Haoran Li , Qishun Wang , Hui Zhao , Jiawei Zhang , Yuming Dong , Yongfa Zhu

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Abstract

Constructing the desired long-range dual sites to enhance the C–C bond-cleavage and CO-tolerate ability during ethanol oxidation reaction is of importance for further applications. Herein, the concept of holding atomically dispersed NiO_x cluster supported on Pt-based high-index facets (NiO_x/Pt) is proposed to build O-bridged Pt–Ni dual sites. Strikingly, the obtained NiO_x/Pt dual sites show 4.97 times specific activity higher than that of commercial Pt/C (0.35 mA cm⁻²), as well as outstanding CO-tolerance and durability. The advanced electrochemical in-situ characterizations reveal that the NiO_x/Pt can accelerate rapid dehydroxylation and C–C bond-cleavage over the Pt–Ni dual sites. Theoretical calculations disclose that the atomically dispersed NiO_x species can lower the adsorption/reaction energy barriers of intermediates. This tactic provides a promising methodology on regulating the surface synergistic sites via engineering atomically dispersed oxide site.

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高指数铂表面上的原子分散氧化镍团簇通过长程协同位点促进乙醇电氧化作用

在乙醇氧化反应过程中，构建所需的长程双位点以增强 C-C 键的清除能力和 CO 的溶解能力对进一步的应用具有重要意义。本文提出了在铂基高指数面（NiOx/Pt）上支撑原子分散的 NiOx 簇的概念，以构建 O 桥接的铂镍双位点。引人注目的是，所获得的 NiOx/Pt 双基点的比活度是商用 Pt/C 的 4.97 倍（0.35 mA cm-2），而且具有出色的一氧化碳耐受性和耐久性。先进的电化学原位表征显示，NiOx/Pt 比 Pt-Ni 双位点更能加速脱羟基和 C-C 键的裂解。理论计算表明，原子分散的氧化镍物种可以降低中间产物的吸附/反应能垒。这种方法为通过设计原子分散氧化物位点来调节表面协同位点提供了一种可行的方法。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Advanced Powder Materials

CiteScore

33.30

自引率

0.00%

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