Advanced Composites and Hybrid Materials最新文献

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UCNP@SiO2-maltotrios/HMME preparation and properties study
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-04 DOI: 10.1007/s42114-024-01096-x
Chuqiang Yin, Youliang Shen, Wenqiao Wang, Feng Shen, Yuelei Wang, Zengshuai Han, Ting Wang
{"title":"UCNP@SiO2-maltotrios/HMME preparation and properties study","authors":"Chuqiang Yin,&nbsp;Youliang Shen,&nbsp;Wenqiao Wang,&nbsp;Feng Shen,&nbsp;Yuelei Wang,&nbsp;Zengshuai Han,&nbsp;Ting Wang","doi":"10.1007/s42114-024-01096-x","DOIUrl":"10.1007/s42114-024-01096-x","url":null,"abstract":"<div><p>Bone and joint infections (BJI) are common diseases in the musculoskeletal system, posing significant challenges due to their difficult early diagnosis, prolonged treatment periods, high costs, and potential for severe consequences. Building upon our previous work on maltotriose-modified magnetite nanoparticles (Fe<sub>3</sub>O<sub>4</sub>-maltotriose), we delve deeper into the research, incorporating the photosensitizer HMME. This integration enables targeted diagnosis of infectious lesions while simultaneously killing bacteria for therapeutic intervention. This study presents the development of a precision drug delivery system (UCNP@SiO<sub>2</sub>-maltotrios/HMME) for the treatment of bacterial infections in bones and joints. Through a microemulsion method, we encapsulated mesoporous SiO<sub>2</sub> onto the surface of upconversion nanoparticles (UCNPs). We then loaded the internal space with the photosensitizer porphyrin monomethyl ether (HMME) to release singlet oxygen (<sup>1</sup>O<sub>2</sub>) upon acoustic activation, and externally loaded maltotriose (maltotrios) as a targeting molecule. Our research investigates the HMME drug loading capacity, and singlet oxygen bactericidal capabilities of this material using a rat infection model. We further evaluated its bactericidal efficacy and biosafety through in vitro cell experiments and in vivo animal studies. Our results demonstrate the excellent luminescence properties and normal imaging capabilities of UCNP@SiO<sub>2</sub>-maltotrios/HMME both in vitro and in vivo. Notably, this material exhibits strong precision targeting and antibacterial activity against <i>Escherichia coli</i> and <i>Staphylococcus aureus</i>. Moreover, UCNP@SiO<sub>2</sub>-maltotrios/HMME demonstrates no cytotoxicity in cells or organs of mice, indicating its favorable biosafety.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142762025","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and properties of triboelectric nanogenerator based on PVDF-TrFE/PMMA electrospun film
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-03 DOI: 10.1007/s42114-024-01103-1
Xuesong Deng, Zijian Wu, Xin Yu, Meng Wang, Defeng Zang, Yonghai Long, Ning Guo, Ling Weng, Yonghong Liu, Junguo Gao
{"title":"Preparation and properties of triboelectric nanogenerator based on PVDF-TrFE/PMMA electrospun film","authors":"Xuesong Deng,&nbsp;Zijian Wu,&nbsp;Xin Yu,&nbsp;Meng Wang,&nbsp;Defeng Zang,&nbsp;Yonghai Long,&nbsp;Ning Guo,&nbsp;Ling Weng,&nbsp;Yonghong Liu,&nbsp;Junguo Gao","doi":"10.1007/s42114-024-01103-1","DOIUrl":"10.1007/s42114-024-01103-1","url":null,"abstract":"<div><p>With the emergence of the era of Internet of things, traditional batteries have been challenged by environmental pollution, replacement maintenance, and other problems, and the self-power technology of flexible electronic devices has received great attention. PVDF-TrFE is one of the commonly used materials for triboelectric nanogenerators (TENG) because of its high β-phase ratio and strong electron attraction ability. Electrospinning technology can further increase the proportion of β-phase in PVDF-TrFE by electric field polarization. However, the electrospun PVDF-TrFE fiber film has poor mechanical properties and is difficult to be used in electronic devices for a long time. The addition of PMMA can form hydrogen bonds in the fiber, which greatly optimizes the mechanical strength of the blended film. Therefore, in this work, PVDF-TrFE/PMMA electrospun film with mechanical and electrical stability was prepared by electrospinning method. After optimization of materials and working conditions, the optimal output performance of the hybrid membrane TA-TENG can reach 0.215 μA and 210 V. Over 2000 working cycles, the device offers excellent output stability and long-term durability. This study presents a novel approach to concurrently enhance both the electrical and mechanical properties of triboelectric materials, thereby broadening their applicability in everyday life.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142761856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A wearable ionic hydrogel strain sensor with double cross-linked network for human–machine interface
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-03 DOI: 10.1007/s42114-024-01083-2
Zijian Wu, Liying Zhang, Meng Wang, Defeng Zang, Haiyong Long, Ling Weng, Ning Guo, Junguo Gao, Yonghong Liu, Ben Bin Xu
{"title":"A wearable ionic hydrogel strain sensor with double cross-linked network for human–machine interface","authors":"Zijian Wu,&nbsp;Liying Zhang,&nbsp;Meng Wang,&nbsp;Defeng Zang,&nbsp;Haiyong Long,&nbsp;Ling Weng,&nbsp;Ning Guo,&nbsp;Junguo Gao,&nbsp;Yonghong Liu,&nbsp;Ben Bin Xu","doi":"10.1007/s42114-024-01083-2","DOIUrl":"10.1007/s42114-024-01083-2","url":null,"abstract":"<div><p>Wearable strain sensor prepared with ionic conductive hydrogel holds great promises in a variety of engineering fields. In this work, we introduce sodium casein (SC) into a dual network hydrogel system made of polyvinyl alcohol (PVA) and polyacrylamide (PAM), to prepare an ionic hydrogel sensor. Compared to the PAM/PVA dual network hydrogel, the introduction of SC plays a significant synergistic role. Such dual network PAM/PVA/SC hydrogels exhibit excellent mechanical properties (a maximum strain of 719%, a maximum stress of 444.3 kPa), low hysteresis, and rapid recovery after uni-axial stretching. Since SC drives a large number of free ions, PAM/PVA/SC hydrogels present good conductivity while maintaining high physical stability, to enable an excellent sensitivity in a comparatively large strain range (Gauge factor, GF = 2.17 under 400% strain). The unique properties allow the generation of stable and accurate electrical signals transduced from different locations of the human body. As such, the PAM/PVA/SC hydrogel has the potential to be used as human–machine interface for continuous, real-time physiological monitoring.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142761802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Flexible and biocompatible polyvinyl alcohol/nitrogen-doped porous carbon film with weakly negative permittivity in radio frequency for wearable devices
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-03 DOI: 10.1007/s42114-024-01104-0
Yuanyuan Qi, Rui Yin, Chong Wang, Kai Sun, Peng Xie, Juan Song, Qing Hou, Zhaoyan Yu, Qingli Huang, Haikun Wu, Runhua Fan
{"title":"Flexible and biocompatible polyvinyl alcohol/nitrogen-doped porous carbon film with weakly negative permittivity in radio frequency for wearable devices","authors":"Yuanyuan Qi,&nbsp;Rui Yin,&nbsp;Chong Wang,&nbsp;Kai Sun,&nbsp;Peng Xie,&nbsp;Juan Song,&nbsp;Qing Hou,&nbsp;Zhaoyan Yu,&nbsp;Qingli Huang,&nbsp;Haikun Wu,&nbsp;Runhua Fan","doi":"10.1007/s42114-024-01104-0","DOIUrl":"10.1007/s42114-024-01104-0","url":null,"abstract":"<div><p>Metacomposites with negative permittivity have attracted widespread attention due to their great application prospects in electromagnetic wave absorption, biosensors, electronic devices, and other fields. In this work, by designing nitrogen-doped porous carbon (NPC) and preparing film with polyvinyl alcohol (PVA), weakly negative permittivity in the radio frequency band is obtained when NPC content reaches 20 wt%. In NPC, the electrons around the doped nitrogen atoms are highly localized, reducing the carrier concentration. In addition, the doped nitrogen makes the band structure flatter, resulting in an increase in the effective electron mass. These two strategies reduce the plasma frequency, thereby achieving weakly negative permittivity (about − 40) from 10 kHz to 1 MHz. Moreover, the porous structure is conducive to electron transfer, achieving high carrier mobility and thus obtaining low dielectric dispersion, so that the negative permittivity is maintained at around − 40 in the range of 10 kHz to 1 MHz, which is almost unaffected by frequency. Furthermore, the film exhibits sensitive sensing performance to human motion and can be used as a wearable sensor to detect human motion. It also shows great application potential in wearable medical electronic devices, wearable invisible cloaks, and other fields.</p><h3>Graphical abstract</h3><p>Here, metacomposite with weakly negative permittivity at radio frequency is designed, via fabricating polyvinyl alcohol/nitrogen-doped porous carbon (PVA/NPC) film. Theory calculations demonstrate that doped-N atoms reduce carrier concentration and enhance effective electrons mass, through introducing localized electrons around N atoms and flatting band structure, respectively. Moreover, this film exhibits excellent capacitive sensing performance and is used in wearable devices</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142761803","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Engineering the thermal conductivity of polymer-bonded explosives by interfacial thermal resistance reduction and structural designs: a review
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-02 DOI: 10.1007/s42114-024-01076-1
Zhipeng Liu, Junru Wang, Guansong He, Zhijian Yang
{"title":"Engineering the thermal conductivity of polymer-bonded explosives by interfacial thermal resistance reduction and structural designs: a review","authors":"Zhipeng Liu,&nbsp;Junru Wang,&nbsp;Guansong He,&nbsp;Zhijian Yang","doi":"10.1007/s42114-024-01076-1","DOIUrl":"10.1007/s42114-024-01076-1","url":null,"abstract":"<div><p>Polymer-bonded explosives (PBXs) are a kind of specialized functional composite, exhibiting stringent comprehensive performance requirements due to their significant application value in both military and civil use. Given that PBXs inevitably face thermophysical environments during manufacturing and utilization, thermal conductivity (<i>k</i>) is crucial for them. However, the low <i>k</i> of PBXs leads to the generation of serious thermal stresses when exposed to complex thermophysical environments, resulting in internal cracks or damages that affect their safety and thermal environmental adaptability. Thus, enhancing the <i>k</i> of PBXs is emerging as a critical issue that requires immediate resolution. In this perspective, we holistically present the significant technologies and advancements in the enhancement of <i>k</i> for PBXs. This review first delves into the thermal conduction mechanisms in PBXs composites, including both the theoretical foundations and the factors influencing heat conduction. The theoretical computational studies on heat conduction in PBXs are comprehensively summarized, serving as a vital tool to comprehend and predict heat conduction behavior. Furthermore, considering the distinctive preparation processes and component characteristics of PBXs, the strategies applicable to enhance the <i>k</i> of PBXs are elaborated, which involve the adoption of thermally conductive fillers, the reduction of interfacial thermal resistance, and the design of thermally conductive structures. On this basis, the prevailing challenges and prospects for advancing the <i>k</i> of PBXs are highlighted. This review aims to provide insights and guidance for the rational design and fabrication of thermally conductive PBXs composites or highly particle-filled composites with high <i>k</i>.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142758029","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and properties of thermal yellowing resistant polyvinylidene chloride resin
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-02 DOI: 10.1007/s42114-024-01092-1
Yan Liu, Lutao Yang, Ruochen Zhang, Jiakui Su, Fengjun Gao, Qian Shao, Jing Yang, Qiuxia Han, Ruixiang Ge
{"title":"Preparation and properties of thermal yellowing resistant polyvinylidene chloride resin","authors":"Yan Liu,&nbsp;Lutao Yang,&nbsp;Ruochen Zhang,&nbsp;Jiakui Su,&nbsp;Fengjun Gao,&nbsp;Qian Shao,&nbsp;Jing Yang,&nbsp;Qiuxia Han,&nbsp;Ruixiang Ge","doi":"10.1007/s42114-024-01092-1","DOIUrl":"10.1007/s42114-024-01092-1","url":null,"abstract":"<div><p>Polyvinylidene chloride (PVDC) resin modified with γ-methylacryloxy propyl trimethoxysilane (KH570) and acrylamide (AM) was prepared by semi-continuous seed emulsion polymerization. The polymerization process and reaction temperature were optimized through conversion rate and oven heat aging test. Fourier transform infrared spectroscopy (FTIR) and X-ray photoelectron spectroscopy (XPS) analysis showed that KH570 and AM could be successfully grafted into the PVDC resin chain. When the addition amounts of KH570 and AM are 1 wt.% and 1.5 wt.%, respectively, and the reaction temperature is 74 °C, the resin film exhibits significant improvement in yellowing resistance and mechanical properties. The initial yellowing time of the resin film modified by KH570 and AM was 290 min, which was 5.8 times of the unmodified resin film, and the tensile strength can reach 10.81 MPa, which is 1.75 times of the unmodified resin film. Because the modified resin has good thermal yellowing and mechanical properties, it has potential application prospects in food and drug packaging.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142758008","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Intrinsically conductive and highly stretchable liquid metal/carbon nanotube/elastomer composites for strain sensing and electromagnetic wave absorption
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-11-30 DOI: 10.1007/s42114-024-01093-0
Haeji Kim, Gangmin Kim, Jae Hyun Kang, Min Ji Oh, Nadeem Qaiser, Byungil Hwang
{"title":"Intrinsically conductive and highly stretchable liquid metal/carbon nanotube/elastomer composites for strain sensing and electromagnetic wave absorption","authors":"Haeji Kim,&nbsp;Gangmin Kim,&nbsp;Jae Hyun Kang,&nbsp;Min Ji Oh,&nbsp;Nadeem Qaiser,&nbsp;Byungil Hwang","doi":"10.1007/s42114-024-01093-0","DOIUrl":"10.1007/s42114-024-01093-0","url":null,"abstract":"<div><p>Wearable strain sensors translate mechanical deformations into electrical signals for healthcare monitoring. However, the limited ductility of conductive metals and polymers to maintain its conductivity under high degree of mechanical deformation is a crucial problem in existing fabrication methods for strain sensors. In this study, an intrinsically conductive and highly stretchable liquid metal (LM)/carbon nanotube (CNT)/polydimethylsiloxane (PDMS) composite-based wearable strain sensor with electromagnetic wave (EMW)-absorbing properties was explored. The effect of CNT inclusion in the LM/PDMS composites was investigated, revealing enhanced electrical conductivity and EMW-absorbing characteristics without additional mechanical sintering. Through a comprehensive evaluation considering electrical resistance, stretchability, and EMW-absorbing properties, LM/CNT/PDMS composites with 1.5 wt% CNT were determined to exhibit optimal performance as EMW absorbable strain sensors. The characterization of the electromechanical properties demonstrated the high stretchability and mechanical reliability of the resulting material with a gauge factor of 5.35 within the strain range of 50–100% and a low hysteresis under a stain of 80%, confirming the reliability of the fabricated sensor. The practical performance of the LM/CNT/PDMS composites was analyzed by adhering them to various parts of the body with joints and measuring the changes in their relative resistance, affirming their potential for use in healthcare monitoring devices for point-of-care testing (POCT) that require electromechanical reliability under repeated tensile deformation.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754003","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review of conventional and stimuli-responsive delivery systems for bioactive peptides: from food to biomedical applications
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-11-30 DOI: 10.1007/s42114-024-01053-8
Shuang Wang, Xinhao Wang, Yangchao Luo, Ying Liang
{"title":"A comprehensive review of conventional and stimuli-responsive delivery systems for bioactive peptides: from food to biomedical applications","authors":"Shuang Wang,&nbsp;Xinhao Wang,&nbsp;Yangchao Luo,&nbsp;Ying Liang","doi":"10.1007/s42114-024-01053-8","DOIUrl":"10.1007/s42114-024-01053-8","url":null,"abstract":"<div><p>Bioactive peptides have garnered significant attention for their health benefits and therapeutic potential across food and biomedical industries. However, their application is often limited by poor stability, low bioavailability, and susceptibility to degradation. This review provides a comprehensive overview of conventional and stimuli-responsive delivery systems designed to enhance their stability, bioavailability and efficacy via targeted delivery and controlled release in various applications. The conventional delivery systems, including emulsion-, nanoparticle,- liposome-, and hydrogel-based delivery systems, offer effective solutions for enhancing the stability and bioavailability of food-derived peptides during storage, processing, and absorption after ingestion. Their formulations and preparation techniques are crucial for the delivery systems to be tailored to the specific characteristics of peptides, optimizing their stability, encapsulation efficiency, and release profiles. Moreover, this review also discusses stimuli-responsive delivery systems for emerging biochemical applications of therapeutic peptides. For such applications, the carriers are engineered to respond dynamically to environmental triggers, including pH changes, temperature fluctuations, enzymatic activity, light exposure, ultrasound, and magnetic fields. These systems represent a significant advancement in peptide delivery, which is particularly beneficial for therapeutic applications requiring localized or targeted delivery, such as inflamed or cancerous tissues. Understanding and leveraging these responsive mechanisms enables the delivery systems to be further designed to enhance bioavailability and therapeutic efficacy while minimizing side effects. By integrating insights from these delivery systems, this review aims to guide the development of effective delivery strategies for addressing challenges and optimizing bioactive peptide utilization in food and biomedical fields.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754011","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A novel iron ion cross-linking strategy dramatically improves the strength and flame retardant of degradable foams from rice straw fibers
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-11-30 DOI: 10.1007/s42114-024-01082-3
Yilin Wang, Yuheng Zhang, Jian Du, Yehan Tao, Jinwen Hu, Yanna lv, Jie Lu, Chenglong Fu, Haisong Wang, Zhanhui Yuan
{"title":"A novel iron ion cross-linking strategy dramatically improves the strength and flame retardant of degradable foams from rice straw fibers","authors":"Yilin Wang,&nbsp;Yuheng Zhang,&nbsp;Jian Du,&nbsp;Yehan Tao,&nbsp;Jinwen Hu,&nbsp;Yanna lv,&nbsp;Jie Lu,&nbsp;Chenglong Fu,&nbsp;Haisong Wang,&nbsp;Zhanhui Yuan","doi":"10.1007/s42114-024-01082-3","DOIUrl":"10.1007/s42114-024-01082-3","url":null,"abstract":"<div><p>Biodegradable natural cellulose-based foams have received increasing attention in the area of logistical transport, construction, healthcare, and chemicals, whereas the flammability and poor mechanical behaviors of foams restricted its application. Herein, a clean production route was proposed to fabricate biodegradable rice straw fiber foam containing ammonium polyphosphate (APP), phytic acid (PA), and iron ions through simple foam molding technology. The introduction of PA and APP as flame retardants acted as an acid source to form phosphorus-containing carbon layers on the surface of the fiber to achieve flame retardant effect. Moreover, the incorporation of iron ions for cross-linking resulted in the formation of Fe<sup>3+</sup>-APP/PA complexes on fibers, which further improved the mechanical properties and flame retardant of the foams. Compared with pristine LCF, compressive strength of LCF/APP-PA/Fe<sup>3+</sup> was improved by 254.6% and 107.9% in XY and Z directions, respectively. The total heat release and smoke release of LCF/APP-PA/Fe<sup>3+</sup> were reduced by 27.1% and 27.4%, respectively. Moreover, the optimized LCF/APP-PA/Fe<sup>3+</sup> possessed well flame retardancy metrics, which can be directly reflected from the self-extinguishing of flame after removing alcohol lamp. This work presented a novel and versatile green approach to improve the strength and flame retardant properties of renewable wood fiber foams. Fiber foams with properties such as lightweight, high strength, flame retardant, and thermal insulation have promising applications in logistics and transport, construction, healthcare, and chemicals.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754290","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Graphene oxide/carbon fiber composite structural supercapacitor with stable electrochemical performance under surface load bearing
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-11-30 DOI: 10.1007/s42114-024-01085-0
Zheng Zhang, Laifa Shen, Xin Xu, Jun Guo, Yang Liu, Jie Zhang, Zhen Zhu, Jiayi Xu, Dingwei Ji, Zhihan Kong, Jing Wang, Qi Wu, Kang Yan, Jinsong Liu, Kongjun Zhu
{"title":"Graphene oxide/carbon fiber composite structural supercapacitor with stable electrochemical performance under surface load bearing","authors":"Zheng Zhang,&nbsp;Laifa Shen,&nbsp;Xin Xu,&nbsp;Jun Guo,&nbsp;Yang Liu,&nbsp;Jie Zhang,&nbsp;Zhen Zhu,&nbsp;Jiayi Xu,&nbsp;Dingwei Ji,&nbsp;Zhihan Kong,&nbsp;Jing Wang,&nbsp;Qi Wu,&nbsp;Kang Yan,&nbsp;Jinsong Liu,&nbsp;Kongjun Zhu","doi":"10.1007/s42114-024-01085-0","DOIUrl":"10.1007/s42114-024-01085-0","url":null,"abstract":"<div><p>In response to the development needs for lightweight and functional aviation electric aircraft, as well as cleaner and sustainable green energy, this study designed a graphene oxide-based carbon fiber structural supercapacitor with integrated structure and energy storage capabilities. It possesses electrical storage stability and meets mechanical load-bearing requirements. We focused on the electrochemical stability of the GO/CF<sub>1</sub> structural supercapacitor under load-bearing conditions. Experimental results showed that capacitance retention was 99.98% over 10,000 cycles, with a coulombic efficiency of 96.27% at 0.1 mA/cm<sup>2</sup>. Under a 30 kPa load-bearing condition, the capacitance retention and coulombic efficiency of the GO/CF<sub>1</sub> structural supercapacitor were approximately 99.58% and 94.34%, respectively, at 0.05 mA/cm<sup>2</sup> over 15,000 cycles. The GO/CF<sub>1</sub> structural electrode exhibited similar morphology and almost the same specific surface area in both unloaded and load-bearing states, elucidating the mechanism behind the stability of its electrochemical properties. Furthermore, the tensile strength and elastic modulus were 139.2 MPa and 8.6 GPa, respectively. This study demonstrated that the GO/CF<sub>1</sub> structural supercapacitor maintains stable electrochemical performance under load-bearing conditions, offering a design solution for optimizing structural energy storage devices in aerospace applications.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-11-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142754010","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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