Advanced Composites and Hybrid Materials最新文献

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Improving properties of soy protein–based hydrogel composites by incorporating bamboo biochar towards slow release and water retention of fertilizers and enhanced plant growth 添加竹炭改善大豆蛋白基水凝胶复合材料的性能,促进肥料缓释和保水,促进植物生长
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-18 DOI: 10.1007/s42114-024-01114-y
Jingyi Liang, Zijie Zhao, Manli Xing, Xian Wang, Youming Dong, Yan Yang, Nanshan Du, Haiping Gu, Lingbo Meng, Wanxi Peng, Cheng Li
{"title":"Improving properties of soy protein–based hydrogel composites by incorporating bamboo biochar towards slow release and water retention of fertilizers and enhanced plant growth","authors":"Jingyi Liang,&nbsp;Zijie Zhao,&nbsp;Manli Xing,&nbsp;Xian Wang,&nbsp;Youming Dong,&nbsp;Yan Yang,&nbsp;Nanshan Du,&nbsp;Haiping Gu,&nbsp;Lingbo Meng,&nbsp;Wanxi Peng,&nbsp;Cheng Li","doi":"10.1007/s42114-024-01114-y","DOIUrl":"10.1007/s42114-024-01114-y","url":null,"abstract":"<div><p>The development of environmentally friendly slow-release fertilizers with effective water retention is an urgent need in modern agriculture. Although biochar can improve soil fertility as a nutrient carrier, it suffers from poor slow-release performance and water retention. Conversely, soy protein hydrogels, characterized by their hydrophilic nature with three-dimensional cross-linked networks, can retain large amounts of water and facilitate the slow release of fertilizers and water due to their high specific surface area. Hence, a novel slow-release composite material with high water retention was prepared by introducing bamboo biochar into a soy protein–based hydrogel (SPB) network through graft copolymerization. The findings indicated that the bamboo biochar promoted the SPB cross-linked network density, which improved the swelling rate of SPB materials and soil water-holding capacity. Moreover, SPB-2–4% and SPB-3–4% exhibited superior slow-release capabilities for nitrogen fertilizer. Cucumber seedlings treated with SPB materials containing bamboo biochar demonstrated enhanced growth and chlorophyll content than those treated with biochar-free SPB materials. Compared with the control, the cucumber plants treated with SPB-2–4% displayed a significant increase in fresh weight, root length, and leaf area by 139.32%, 99.20%, and 149.45%, respectively, which can be attributed to the positive synergistic effect of soy protein and bamboo biochar. Furthermore, the nutrients and porous structures of bamboo biochar favor the proliferation of microorganisms, enriching the soil microbial community. Therefore, the bamboo biochar-soybean protein hydrogel composites have great application prospects for sustainable agriculture and provide a new direction for the development of slow-release and water-retention fertilizers.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844767","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetic-driven and biocompatible radio frequency epsilon-near-zero film for wearable sensor 用于可穿戴传感器的磁驱动和生物兼容射频epsilon近零薄膜
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-18 DOI: 10.1007/s42114-024-01149-1
Haikun Wu, Yuanyuan Qi, Chong Wang, Yunchen Long, Fei Yin, Rui Yin, Qing Hou, Kai Sun, Runhua Fan, Juan Song
{"title":"Magnetic-driven and biocompatible radio frequency epsilon-near-zero film for wearable sensor","authors":"Haikun Wu,&nbsp;Yuanyuan Qi,&nbsp;Chong Wang,&nbsp;Yunchen Long,&nbsp;Fei Yin,&nbsp;Rui Yin,&nbsp;Qing Hou,&nbsp;Kai Sun,&nbsp;Runhua Fan,&nbsp;Juan Song","doi":"10.1007/s42114-024-01149-1","DOIUrl":"10.1007/s42114-024-01149-1","url":null,"abstract":"<div><p>When the permittivity is equal to zero or very close to zero, unique physical properties are triggered in epsilon-near-zero (ENZ) materials, which have broad application prospects in perfect absorption, superlens, invisible cloak, and other fields. In this work, by doping high-entropy alloy (HEA) into reduced graphene oxide (HEA@RGO), ENZ performance at 19 MHz is realized from three-dimensional (3D) printed polydimethylsiloxane (PDMS)/HEA@RGO film when HEA@RGO content reaches 15 wt%. However, negative permittivity from 2 to 80 MHz is realized from 3D-printed PDMS/graphene film with 15 wt% graphene content. Theory calculations are used to explore the mechanism of ENZ performance at radio frequency. Compared with the band structure of graphene, when HEA is formed, the band of HEA@RGO is flatter, resulting in an increase in the effective electron mass, which causes a decrease in the plasma frequency, realizing radio frequency ENZ performance. Moreover, the 3D-printed PDMS/HEA@RGO ENZ film exhibits excellent magnetic actuation performance because of the strong saturation magnetization of HEA@RGO. Furthermore, the film exhibits good biocompatibility and is prepared into a wearable capacitive sensor device with a laminated structure, which realizes effective monitoring of human movement.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844764","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Graphene composites for water remediation: an overview of their advanced performance with focus on challenges and future prospects 石墨烯复合材料用于水修复:概述其先进性能,重点关注挑战和未来前景
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-18 DOI: 10.1007/s42114-024-01088-x
Brij Bhushan, Priyanka Negi, Arunima Nayak, Sonali Goyal
{"title":"Graphene composites for water remediation: an overview of their advanced performance with focus on challenges and future prospects","authors":"Brij Bhushan,&nbsp;Priyanka Negi,&nbsp;Arunima Nayak,&nbsp;Sonali Goyal","doi":"10.1007/s42114-024-01088-x","DOIUrl":"10.1007/s42114-024-01088-x","url":null,"abstract":"<div><p>The last decade has seen dramatic progress in graphene-based composites as advanced adsorbents for application in wastewater treatment. The ability to be tuned and modified as per application-based requirement especially the environmental conditions, nature of different adsorbate moieties, etc. has driven extensive research activity on graphene-based composites. Research publication has shown a spurt in reviews on the synthesis, properties, modifications and applications of such adsorbents. Still a well-defined classification of graphene-based composites and a detailed assessment on the binding affinity of various materials with graphene are missing. A clear picture regarding the advanced properties exhibited by the graphene-based composites vis-à-vis their pristine counterparts is missing. Finally, the adsorption behaviour of graphene-based composites towards a particular class of pollutants is also vague in the literature. Thus, with the aim of providing information on the interfacial surface interactions between the different class of materials with graphene-based materials, the review has presented a systematic classification of graphene-based composites and provided a comprehensive overview of the updated literature on the material properties and adsorptive performance of such classified adsorbents towards the removal of different organic and metal ion pollutants. The overview has detailed not only on the experimental parameters, adsorption behaviour, regeneration efficiency but also on the mechanistic aspects. A comparative assessment has highlighted the advancements made for the graphene-based composites. Challenges and gaps thus identified have provided a road map for future research prospects in developing a general criteria for designing graphene-based composites as per the nature and behaviour of particular class of target pollutant in aqueous medium under different conditions.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844766","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
4D printing of polycarbonate ternary composites and the biomimetic folding deployment mechanisms 聚碳酸酯三元复合材料的4D打印及仿生折叠展开机制
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-18 DOI: 10.1007/s42114-024-01090-3
Guiwei Li, Hua Li, Qingping Liu, Haolan Sun, Yuhai Nie, Qi Li, Wenzheng Wu, Shengbo Ge, Ke Li, Ji Zhao, Luquan Ren
{"title":"4D printing of polycarbonate ternary composites and the biomimetic folding deployment mechanisms","authors":"Guiwei Li,&nbsp;Hua Li,&nbsp;Qingping Liu,&nbsp;Haolan Sun,&nbsp;Yuhai Nie,&nbsp;Qi Li,&nbsp;Wenzheng Wu,&nbsp;Shengbo Ge,&nbsp;Ke Li,&nbsp;Ji Zhao,&nbsp;Luquan Ren","doi":"10.1007/s42114-024-01090-3","DOIUrl":"10.1007/s42114-024-01090-3","url":null,"abstract":"<p>4D printing of shape-morphing systems have promising application prospects in satellites which are suffering from the complex structure of satellite solar panels, unreliable electric driving systems, and lightweight structural requirements. However, the current investigations of 4D printing are focused on shape memory materials with the lower thermal deformation temperature, which limits their practical applications in the aerospace field. Herein, the polycarbonate (PC) is selected as the base material with a thermal deformation temperature of 150 °C, and combining with carbon fiber (CF) and carbon nanotubes (CNTs). The dual percolated PC/CNT/CF ternary composite with “point + line” conductive pathways is fabricated. The material demonstrates superior electrical conductivity and shape memory behavior under a 50 V direct current voltage. The “point + line” conductive pathway exhibits excellent electrical performance without hindering the shape memory performance of PC. The PC-3%CNT-3%CF specimen reaches a temperature of 150 °C at both ends within 1 min under a voltage of 50 V. The U-shaped shape memory samples are designed to increase the shape recovery properties, and a series of biomimetic models are also developed to illustrate the shape-morphing properties of 4D printing PC composites. The 20 consecutive cycles of shape memory experiments confirm the reliability of the composites. These findings highlight the broad potential applications of the material in the aerospace field.</p>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844765","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A highly efficient adsorption-photocatalytic synergistic degradation of tetracycline by in-situ constructed Bi5O7I/ZIF-8 heterojunction 原位构建Bi5O7I/ZIF-8异质结高效吸附-光催化协同降解四环素
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-17 DOI: 10.1007/s42114-024-01116-w
Rongfei Jiang, Weiqi Luo, Jinyang Peng, Jijun Tang, Xinyue Wang, Jiaoxia Zhang, Adel Qlayel Alkhedaide, Yihui Teng, Qiuyang Dai, Guicheng Gao, Zeinhom M. El-Bahy, Mohammed A. Amin, Yonglin Ye
{"title":"A highly efficient adsorption-photocatalytic synergistic degradation of tetracycline by in-situ constructed Bi5O7I/ZIF-8 heterojunction","authors":"Rongfei Jiang,&nbsp;Weiqi Luo,&nbsp;Jinyang Peng,&nbsp;Jijun Tang,&nbsp;Xinyue Wang,&nbsp;Jiaoxia Zhang,&nbsp;Adel Qlayel Alkhedaide,&nbsp;Yihui Teng,&nbsp;Qiuyang Dai,&nbsp;Guicheng Gao,&nbsp;Zeinhom M. El-Bahy,&nbsp;Mohammed A. Amin,&nbsp;Yonglin Ye","doi":"10.1007/s42114-024-01116-w","DOIUrl":"10.1007/s42114-024-01116-w","url":null,"abstract":"<div><p>Residue organic matter such as antibiotics and dyes are left in wastewater that are difficult to remove. Herein, we reported a bismuth oxyiodide (Bi<sub>5</sub>O<sub>7</sub>I)/zeolite imidazolate framework-8 (ZIF-8) catalyst with an S-scheme heterojunction for the degradation of tetracycline (TC) using an in-situ growth strategy. The degradation process of TC is divided into two parts: adsorption and photocatalysis. Under dark reaction conditions, the Bi<sub>5</sub>O<sub>7</sub>I/ZIF-8 composites have an eminent adsorption effect on TC. When exposed to visible light, the resulting Bi<sub>5</sub>O<sub>7</sub>I/ZIF-8 composites revealed an outstanding photocatalytic activity and high stability toward TC degradation. Experiments utilizing active species trapping showed that O<sub>2</sub> is essential to the photocatalytic process and the efficacy of the process is further improved by the addition of h<sup>+</sup> and •OH. Likewise, these catalysts catalyzed the degradation of 84.6% of TC, and the Bi<sub>5</sub>O<sub>7</sub>I/ZIF-8 also exhibited high degradation stability after 4-cycle trial. This work optimizes the degradation performance of antibiotic residues by presenting a practical and doable approach for creating green semiconductor heterojunctions.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844826","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontiers of MXenes-based hybrid materials for energy storage and conversion applications 基于 MXenes 的混合材料在能量存储和转换应用中的前沿研究
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-17 DOI: 10.1007/s42114-024-01121-z
Md. Yasir Bhat, Waheed A. Adeosun, Kaitlyn Prenger, Yarjan Abdul Samad, Kin Liao, Michael Naguib, Samuel Mao, Ahsanulhaq Qurashi
{"title":"Frontiers of MXenes-based hybrid materials for energy storage and conversion applications","authors":"Md. Yasir Bhat,&nbsp;Waheed A. Adeosun,&nbsp;Kaitlyn Prenger,&nbsp;Yarjan Abdul Samad,&nbsp;Kin Liao,&nbsp;Michael Naguib,&nbsp;Samuel Mao,&nbsp;Ahsanulhaq Qurashi","doi":"10.1007/s42114-024-01121-z","DOIUrl":"10.1007/s42114-024-01121-z","url":null,"abstract":"<div><p>Since their breakthrough in 2011, MXenes, transition metal carbides, and/or nitrides have been studied extensively. This large family of two-dimensional materials has shown enormous potential as electrode materials for different applications including catalysis, energy storage, and conversion. MXenes are suitable for the aforementioned applications due to their high electrical conductivity, tunable surface chemistry, large surface area, layered structure, flexural property, and hydrophilicity amongst others. This article aims to cover the development of MXene/hybrid structures their computational insight, synthesis techniques, structural morphology, properties, and potential applications in energy conversion and storage devices. Several approaches have been adopted to develop MXene hybrids, such as modifying traditional MXenes by decorating surfaces, intercalating, and in-situ fabrication, to target high electrochemical performance. In addition, this review has concisely and uniquely presented recent advances in the application of MXene hybrid structures in battery design, clean hydrogen fuel generation, carbon dioxide reduction, and other relevant reactions. Finally, the latest trends and prospects of hybrid MXene materials are also summarized.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-024-01121-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142844866","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of sulfonic acid doping during polypyrrole electrodeposition on the corrosion protection for AA2024-T3 聚吡咯电沉积过程中磺酸掺杂对AA2024-T3防腐性能的影响
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-17 DOI: 10.1007/s42114-024-01139-3
Mao-Chia Lin, Zhen Wei, Ruigang Wang, Xinyu Zhang
{"title":"Influence of sulfonic acid doping during polypyrrole electrodeposition on the corrosion protection for AA2024-T3","authors":"Mao-Chia Lin,&nbsp;Zhen Wei,&nbsp;Ruigang Wang,&nbsp;Xinyu Zhang","doi":"10.1007/s42114-024-01139-3","DOIUrl":"10.1007/s42114-024-01139-3","url":null,"abstract":"<div><p>The electrodeposition of polypyrrole on AA2024-T3 was prepared by applying a constant potential via three different dopants including sulfuric acid (SA), p-toluenesulfonic acid (pTSA), and 2-naphthalenesulfonic acid (2NS). The polypyrrole coating was characterized by scanning electron microscopy (SEM) and Fourier-transform infrared spectroscopy (FTIR). The anti-corrosion behavior was examined by Tafel curves to find the optimized concentration and deposition time for each dopant. Polypyrrole was successfully electrodeposited on AA2024-T3 with pTSA and 2NS dopants, which exhibited better corrosion protection compared with bare AA2024-T3. In addition, a conventional coating was applied with spray paint considered as a topcoat to further investigate the protection efficiency of the polypyrrole. The 2NS-doped polypyrrole exhibited a good protection efficiency of 99.99%. The results demonstrated that the chemical structure of the dopant influences the corrosion protection where the corrosion potential has positively increased with the extended electrodeposition time. Topcoat with spray paint working as a surface barrier can protect the polypyrrole coating and enlarge the protection time.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-024-01139-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Elevating CO2 selective conversion: Insights into copper-based single atom alloy catalysts 提高二氧化碳的选择性转化:对铜基单原子合金催化剂的见解
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-16 DOI: 10.1007/s42114-024-01105-z
Di Tian, Zefeng Wang, Zhou Xu, Yiquan Zhu, Yan Yan, Jifeng Yang, Siyuan He, Zaibin Xue, Zhenzhen Wang, Kang Li, Wenxuan Fan, Miaomiao Xue, Zehua Qu, Wei Xia, Mingkai Liu
{"title":"Elevating CO2 selective conversion: Insights into copper-based single atom alloy catalysts","authors":"Di Tian,&nbsp;Zefeng Wang,&nbsp;Zhou Xu,&nbsp;Yiquan Zhu,&nbsp;Yan Yan,&nbsp;Jifeng Yang,&nbsp;Siyuan He,&nbsp;Zaibin Xue,&nbsp;Zhenzhen Wang,&nbsp;Kang Li,&nbsp;Wenxuan Fan,&nbsp;Miaomiao Xue,&nbsp;Zehua Qu,&nbsp;Wei Xia,&nbsp;Mingkai Liu","doi":"10.1007/s42114-024-01105-z","DOIUrl":"10.1007/s42114-024-01105-z","url":null,"abstract":"<div><p>The electrochemical reduction of carbon dioxide (CO<sub>2</sub>RR) stands as a pivotal pathway for mitigating atmospheric CO<sub>2</sub> levels and realizing carbon neutrality objectives. Among the investigated metal elements, copper (Cu) has emerged as a key heterogeneous catalyst capable of facilitating the formation of C<sub>2+</sub> products in CO<sub>2</sub>RR. However, challenges persist, including subpar activity and selectivity in CO<sub>2</sub>RR, hampering the widespread application of Cu-based catalysts. The construction of single-atom sites represents a promising strategy to enhance the catalytic efficiency of CO<sub>2</sub> conversion. Heteroatom doping offers a means to alter the coordination environment and influence the electronic state of active sites. Single-atom alloy catalysts (SAAs), with their distinctive structure and superior catalytic selectivity, have emerged as significant players in the realm of CO<sub>2</sub>RR. This review work provides a comprehensive summary of recent advancements in Cu-based SAAs for CO<sub>2</sub>RR, with particular emphasis on synthesis strategies and selective CO<sub>2</sub> conversion. Ultimately, this review aims to offer fresh insights into the design and preparation of Cu-based SAAs for enhanced CO<sub>2</sub>RR performance.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826111","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Evolution of microstructure, electromagnetic shielding, and in vitro corrosion properties of Mg-Ni composites for cancer biomarker applications 用于癌症生物标记物的镁镍复合材料的微观结构、电磁屏蔽和体外腐蚀特性的演变
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-16 DOI: 10.1007/s42114-024-01150-8
Ming Yan, Martin Gosau, Reinhard E. Friedrich, Ralf Smeets, Yi Yang, Ling-ling Fu
{"title":"Evolution of microstructure, electromagnetic shielding, and in vitro corrosion properties of Mg-Ni composites for cancer biomarker applications","authors":"Ming Yan,&nbsp;Martin Gosau,&nbsp;Reinhard E. Friedrich,&nbsp;Ralf Smeets,&nbsp;Yi Yang,&nbsp;Ling-ling Fu","doi":"10.1007/s42114-024-01150-8","DOIUrl":"10.1007/s42114-024-01150-8","url":null,"abstract":"<p>The heavily deformed composites are increasingly used in various applications such as nuclear power plants, medical, cancer biomarker, and aerospace industries. This research investigates the effect of rolling strain, reinforcing layer thickness, and layer stacking on microstructure, grain refinement, hardness, shielding effectiveness, and in vitro corrosion and degradation properties of Ni/Mg/Ni and Mg/Ni/Mg multilayered composites. The composites were produced by seven passes of the accumulative roll bonding (ARB) process at room temperature. The microstructural characterization showed the grain refinement in all layers. By increasing the thickness of reinforcing layers, the grain sizes of the inner layers decreased although the outer layers showed finer grains. The outer layers in composites also indicated higher hardness than the inner layers. The maximum hardness of the Mg layer in Mg/Ni/Mg and Ni/Mg/Ni was 85 and 77 HV while the maximum hardness of the Ni layer in Mg/Ni/Mg and Ni/Mg/Ni was 161 and 164 HV. In addition, the Ni/Mg/Ni composites with 57 dB showed better electromagnetic interference shielding effectiveness than Mg/Ni/Mg composites with 44 dB. Furthermore, the mass attenuation coefficient of gamma rays of composites grew at higher rolling strains. The attenuation coefficients of composites were respectively 0.12 and 0.088 cm<sup>2</sup>/g for Ni/Mg/Ni and Mg/Ni/Mg composites after the final pass. Also, based on the results of in vitro corrosion and degradation, Ni/Mg/Ni and Mg/Ni/Mg composites revealed adverse behaviors versus rolling strain and thickness of the inner layer. The Ni/Mg/Ni composite showed maximum corrosion resistance and minimum degradation rate after the first pass with the thinnest Mg layer while the Mg/Ni/Mg composite showed maximum corrosion potential and minimum degradation rate after the final pass with the thickest Ni layer.</p>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826114","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mitochondria- and anaerobic glycolysis-targeted self-assembled copper complex nanoparticles for boosting cuproptosis-immunotherapy 以线粒体和厌氧糖酵解为靶向的自组装复合铜纳米粒子促进杯突免疫疗法
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-16 DOI: 10.1007/s42114-024-01138-4
Hanyu Zhang, Jing Xia, Lingling Xie, Meng Hao, Wenlong Liang, Sizhang Wang, Xiao Dong, Yongxin Li, Qiang Mu
{"title":"Mitochondria- and anaerobic glycolysis-targeted self-assembled copper complex nanoparticles for boosting cuproptosis-immunotherapy","authors":"Hanyu Zhang,&nbsp;Jing Xia,&nbsp;Lingling Xie,&nbsp;Meng Hao,&nbsp;Wenlong Liang,&nbsp;Sizhang Wang,&nbsp;Xiao Dong,&nbsp;Yongxin Li,&nbsp;Qiang Mu","doi":"10.1007/s42114-024-01138-4","DOIUrl":"10.1007/s42114-024-01138-4","url":null,"abstract":"<div><p>Cuproptosis is an emerging regulated cell death that depends on the intracellular copper ion and mitochondrial respiration, showing great potential in cancer treatment. However, increasing the specific accumulation of copper ions in mitochondria while simultaneously enhancing mitochondrial respiration is highly needed and still a major challenge to promote cuproptosis. Herein, the lactate dehydrogenase (LDH) inhibitor galloflavin (GF) self-assembles with the copper ionophore elesclomol (ES) through copper ion-driven cooperative coordination to form GF/CuES hybrid nanoparticles, synergistically targeting mitochondria and anaerobic glycolysis to boost cuproptosis-immunotherapy. After cellular internalization, the GF/CuES hybrid nanoparticles responsively dissociate to release Cu<sup>2+</sup> and ES, co-transporting into mitochondria to collaboratively trigger cuproptosis, which subsequently evokes immunogenic cell death (ICD). Notably, the liberated GF leads to effective LDH suppression, which not only further amplifies cuproptosis via disrupting anaerobic glycolysis and enhancing mitochondrial respiration but also reduces lactate production, thus alleviating the immunosuppressive tumor microenvironment and augmenting anti-tumor immunity driven by ICD. Thus, the GF/CuES hybrid nanoparticles exhibit strong antitumor effects through cooperatively targeting glycolysis, cuproptosis, and immunotherapy, offering a unique opportunity to enhance cancer treatment strategies.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142826115","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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