Xinhao Wang, Jingyi Xue, Honglin Zhu, Sunni Chen, Yi Wang, Zhenlei Xiao, Yangchao Luo
{"title":"Advances in biofilm characterization: utilizing rheology and atomic force microscopy in foods and related fields","authors":"Xinhao Wang, Jingyi Xue, Honglin Zhu, Sunni Chen, Yi Wang, Zhenlei Xiao, Yangchao Luo","doi":"10.1007/s42114-024-00950-2","DOIUrl":"10.1007/s42114-024-00950-2","url":null,"abstract":"<div><p>Biofilms pose significant challenges in various fields, including food, healthcare, and environmental industries, where they compromise safety, quality, and operational efficiency. Understanding their behavior, evaluating antimicrobial efficacy, developing control strategies, and implementing monitoring systems are crucial steps in mitigating biofilm-related risks. This review explores the integration of rheology and atomic force microscopy techniques as powerful tools for addressing these challenges. Rheological models provide insights into biofilm viscoelastic properties, aiding in monitoring and predicting their behavior under diverse environmental conditions. From bulk rheological characterizations to micro-scale measurements, studies elucidate the complex interplay between environmental factors and biofilm development, informing strategies for disinfection and product optimization. AFM enables visualization of biofilm morphology, quantification of surface roughness, and probing of mechanical interactions at the nanoscale. Integration with other analytical techniques offers comprehensive insights into biofilm structure–function relationships, guiding innovative biofilm management strategies. Current applications span antimicrobial effectiveness assessments, biofilm control strategy design, and monitoring of biofilm contamination across industries. Leveraging interdisciplinary approaches holds promising potential to deepen our understanding of biofilms and develop more effective interventions, safeguarding product quality and human health. This review underscores the pivotal role of rheology and AFM in characterizing biofilms and addressing biofilm-related challenges in these fields, where continued research and innovation are essential for advancing our understanding and enhancing control strategies.</p><h3>Graphic Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142248507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Yuchen He, Ziyuan Han, Juanna Ren, Hua Hou, Duo Pan
{"title":"An overview of flexible sensing nanocomposites","authors":"Yuchen He, Ziyuan Han, Juanna Ren, Hua Hou, Duo Pan","doi":"10.1007/s42114-024-00954-y","DOIUrl":"10.1007/s42114-024-00954-y","url":null,"abstract":"<div><p>With the advancement of science technology and the expansion of application area, the study and development of sensor materials and facilities has become a hot spot in today’s scientific community. As a device that can convert physical quantity, chemical properties, and biological characteristics into electrical signals, a sensor is widely used in environmental monitoring, medical diagnosis, industrial automation, and many other fields. Therefore, the study and development of sensor materials and devices not only helps to enhance the performance and sensitivity of sensors but also provides a feasible solution for solving practical problems. This work proposes a brief summary of the different classifications and applications of flexible sensor materials, as well as an outlook on their development direction and application prospects.</p><h3>Graphical abstract</h3><p>This work provides a brief overview of the different classifications and applications of flexible sensor materials, as well as an outlook on their development direction and application prospects.</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142248506","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Review: Developments and challenges of advanced flexible electronic materials for medical monitoring applications","authors":"Tao Zeng, Yufeng Wu, Ming Lei","doi":"10.1007/s42114-024-00949-9","DOIUrl":"10.1007/s42114-024-00949-9","url":null,"abstract":"<div><p>Flexible sensors, made from flexible electronic materials, are of great importance in the medical field due to the rising prevalence of cardiovascular and cerebrovascular diseases. Studies have demonstrated that timely diagnosis and continuous monitoring of relevant physiological signals can be beneficial in preventing such conditions. Although traditional rigid monitoring sensors are still widely used for medical monitoring, the EMG, ECG, and EEG signals they obtain are often significantly affected by motion artifacts and noise. Therefore, the significance of wearable smart monitoring devices based on flexible electronic materials cannot be overstated. Numerous researchers have been working tirelessly for this purpose, exploring solutions from various angles, including material choice, circuit design, and algorithmic processing. This paper begins by analyzing the causes of motion artifacts in medical smart monitoring devices. Next, it introduces the application of flexible materials and flexible electronic materials in several aspects, along with the work of some representative flexible sensors. Following this, it discusses materials selection and device designs (e.g., accelerometers, gyroscopes, differential circuits, etc.) and algorithmic approaches for eliminating motion artifacts. Finally, an outlook on motion artifact removal techniques from the perspectives of more in-depth material development, structural design, and machine learning is provided. The purpose of this paper is to offer a comprehensive overview of current motion artifact removal techniques and materials, aiming to encourage further research and effectively address the key problem of signal acquisition accuracy in smart biomonitoring.</p><h3>Graphical Abstract</h3><p>TOC: Motion artifact occurrence state [40, 120]. Two methods of motion artifact removal or attenuation states are now commonly used: device design [30, 109] and algorithm development [115]. Future development focusing on machine learning and AI. [136]</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191957","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
J. Elliott Sanders, Yousoo Han, Todd S. Rushing, Evan K. Wujcik, Douglas J. Gardner
{"title":"PVA-CNCs composite electrospun nanofibers for poly(lactic acid) polymer reinforcement","authors":"J. Elliott Sanders, Yousoo Han, Todd S. Rushing, Evan K. Wujcik, Douglas J. Gardner","doi":"10.1007/s42114-024-00944-0","DOIUrl":"10.1007/s42114-024-00944-0","url":null,"abstract":"<div><p>In this study, poly(vinyl alcohol) (PVA) in a water solution was mixed with CNC suspensions in 4:1 and 3:2 weight ratios (w/w) and electrospun (ES) into aligned composite fiber mats. The electrospun mats were mechanically cut into high aspect ratio nanofibers (PVA:CNC-nf) and used as reinforcement in melt compounded thermoplastic poly(lactic acid) (PLA). A control PLA composite, containing neat electrospun PVA fibers (PVA-nf) and electrosprayed CNC nanoparticles (CNC-np), was produced for each composite fiber ratio. The electrospun nanofibers (ESNFs) were observed to maintain their morphology without exhibiting agglomeration or void formation in the PLA matrix. Composites containing 15 wt.% 4:1-nf improved tensile strength and stiffness of the PLA by 21% and 30%, while reducing strain at break by 7%, and increased PLA impact strength by 54%. In comparison, the 12 wt.% neat PVA-nf improved the PLA tensile strength and stiffness by 19% and 8%, respectively, while increasing tensile strain at break by 24% and impact strength by 30%. Toughness analysis indicated that the neat PVA-nf improved PLA specific tensile strength, despite the 4:1-nf absorbing more impact energy. Flexural strength improved slightly with the 3:2-nf, but flexural stiffness generally decreased, apart from 15% and 7.5% filled 4:1-nf and 3:2-nf filled PLA composites. Mechanical improvements were attributed to the electrospun reinforcement fibers’ nanometer dimensions and interfacial compatibility, based on by the shift to bound hydroxyl groups detected in the Fourier transform infrared spectroscopy (FTIR) analysis for the PLA composites.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191958","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chingis Daulbayev, Armanbek Nursharip, Zhandos Tauanov, Rosa Busquets, Alzhan Baimenov
{"title":"Mechanisms of mercury removal from water with highly efficient MXene and silver-modified polyethyleneimine cryogel composite filters","authors":"Chingis Daulbayev, Armanbek Nursharip, Zhandos Tauanov, Rosa Busquets, Alzhan Baimenov","doi":"10.1007/s42114-024-00945-z","DOIUrl":"10.1007/s42114-024-00945-z","url":null,"abstract":"<div><p>Safeguarding aquatic ecosystems and human health requires effective methods for removing pollutants. Mercury (Hg) is a very toxic pollutant with a global presence and is highly mobile and persistent. Here, innovative materials were prepared for separating Hg(II) from water, and the mechanisms underlying the efficient uptake of Hg species have been investigated. The sorbents include silver (Ag) nanoparticles and multilayered Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene, both incorporated into the structure of a three-dimensional polyethyleneimine porous cryogel (PEI) that acts as a scaffold holding and exposing nano active sites involved in the removal of Hg. Specifically, Ag particles were deposited onto MXene phases, and the resulting composite was embedded in the macroporous PEI polymer (PEI/MXene@Ag cryogel). The composite has beneficial properties regarding Hg removal: 99% of Hg was separated from waste within 24 h in batch studies. The maximum removal capacity of Hg reached 875 mg/g from HgCl<sub>2</sub>, and 761 mg/g and 1280 mg/g from Hg(OAc)<sub>2</sub> and Hg(NO<sub>3</sub>)<sub>2</sub> salts by PEI/MXene@Ag. The Hg uptake stems from the composite’s relatively large specific surface area, layered porous channels, and highly dispersed Ag nanoparticles in the multilayered Ti<sub>3</sub>C<sub>2</sub>T<sub>x</sub> MXene. The matrix in the water samples that were treated with the composite did not hinder the uptake of Hg by PEI/MXene@Ag. The high effectiveness achieved for the removal of Hg, combined with rapid adsorption kinetics, high efficiency, and selectivity, positions it as an efficient solution. Future work should address upscaling its preparation for increasing readiness towards mitigating Hg in surface water.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-024-00945-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142224856","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sijia Nie, Zhibin Zheng, Yanxin Qiao, Yurong Duan, Jie Cui, Saleh D. Mekkey, Mohammed A. Amin, Saad Melhi, Haokun Yang, Huiling Zhou, Shunli Zheng
{"title":"Corrosion behavior of as-cast Al0.75CoCr1.25FeNi high entropy alloy in 0.5 mol/L sulfuric acid","authors":"Sijia Nie, Zhibin Zheng, Yanxin Qiao, Yurong Duan, Jie Cui, Saleh D. Mekkey, Mohammed A. Amin, Saad Melhi, Haokun Yang, Huiling Zhou, Shunli Zheng","doi":"10.1007/s42114-024-00951-1","DOIUrl":"10.1007/s42114-024-00951-1","url":null,"abstract":"<div><p>This study focuses on the corrosion behaviors of an as-cast Al<sub>0.75</sub>CoCr<sub>1.25</sub>FeNi high entropy alloy (HEA) in 0.5 mol/L H<sub>2</sub>SO<sub>4</sub> solution. The results showed that the HEA exhibited mixed column dendrite and inter-dendrite structures composed of face-centered cubic (FCC) phase, body-centered cubic (BCC) phase, and ordered BCC phase (B2). The corrosion resistance of the HEA in 0.5 mol/L H<sub>2</sub>SO<sub>4</sub> solution was inferior to that of 316L stainless steel (SS); the HEA displayed an incomplete capacitive reactance arc at higher frequencies and an inductive reactance arc at lower frequencies during the electrochemical impedance spectroscopy test. The immersion experiments demonstrated an electrical potential difference between the Ni–Al-rich phase and the Fe-Co-Cr-rich phase of the HEA, resulting in micro-galvanic corrosion. This micro-galvanic corrosion prefers on the B2 (Ni–Al-rich) phase of the HEA. Moreover, the FCC phase and BCC1 phase of HEA corroded with the prolongation of immersion time. The surface of HEA has a loose and porous corrosion product film due to its relatively high percentage of Al<sub>2</sub>O<sub>3</sub>. Additionally, the ratio of Cr<sub>2</sub>O<sub>3</sub>/(Cr + Cr(OH)<sub>3</sub>) in the corrosion product film decreased with the increase of immersion time.</p><h3>Graphical Abstract</h3><p>Al<sub>0.75</sub>CoCr<sub>1.25</sub>FeNi high entropy alloy exhibited mixed column dendrite and inter-dendrite structures composed of face-centered cubic (FCC) phase, body-centered cubic (BCC) phase, and ordered BCC phase (B2). The corrosion resistance of the high entropy alloy in 0.5 mol/L H<sub>2</sub>SO<sub>4</sub> solution was inferior to that of 316L stainless steel.</p>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191959","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"First-principles investigation on solute co-segregations and their strengthening grain boundary roles in stable nanocrystalline copper","authors":"Yanyan Shi, Dalal A. Alshammari, Chao Lei, Hamdy Khamees Thabet, Hongtao Xue, Fuling Tang","doi":"10.1007/s42114-024-00948-w","DOIUrl":"10.1007/s42114-024-00948-w","url":null,"abstract":"<div><p>Regulating the grain boundaries (GBs) via solute segregation provides a viable pathway to design stable nanocrystalline metals. This study investigates the segregation tendencies of <i>X</i> (<i>X</i> = In, Cr, Ca, Co, Zn, Ag, Zr, and Sn) at the potential sites of Cu Σ11 [110](1<span>(overline{1})</span>3) GB, as well as the co-segregation behavior of <i>Y</i> (<i>Y</i> = Cr and Co) at the Zr- and Ca-segregated Cu GBs, using first-principles calculations. Our results indicate that Cr and Co lack a thermodynamic driving force for segregating to Cu GBs, unlike other elements possessing GB segregation tendencies. The co-segregation calculations show that the presence of Zr at Cu GB can induce the segregation of Cr and Co. In comparison to the single-solute segregation of Zr, Cr, and Co, Zr-Co and Zr-Cr co-segregations exhibit synergistic enhancing effect on the GB thermodynamic stability. Regarding to the enhancement of GB fracture strength, Zr-Co co-segregation shows antagonistic effect, whereas Zr-Cr co-segregation demonstrates synergistic action. This work sheds light on accurately regulating the GB stability and strength of nanograined Cu alloys based on GB segregation.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advances in bifunctional electro-responsive materials for superior energy-efficient electrochromic energy storage devices","authors":"Min Zhou, Fan Li, Jidong Dong, Shang Sun, Yuanyuan Zhu, Wenjing Zhang, Zhou Lu, Wei Zhang, Haijun Niu, Jiang Guo, Lina Ma, Yudong Huang","doi":"10.1007/s42114-024-00942-2","DOIUrl":"10.1007/s42114-024-00942-2","url":null,"abstract":"<div><p>The ever-growing pressure from the energy crisis and environmental pollution has promoted the development of efficient multifunctional electric devices. The energy storage and multicolor electrochromic (EC) characteristics have gained tremendous attention for novel devices in the past several decades. The precise design of EC electroactive materials can facilitate the integration of electrochromic energy storage devices (EESDs). Such devices can be utilized not only for self-powering but also for intelligent sensing of real-time working conditions through various visualizations. In this review, we systematically introduce the concept, possibilities (electro-responsive materials, device structure, and state-switching time scale), working principles, and significant factors of EESDs. Subsequently, we comprehensively summarize the latest achievements in electro-responsive dual-functional materials, encompassing inorganic materials (transition metal oxides, Prussian blue, polyoxometalates, etc.), organic materials (small organic molecules, polymers, etc.), and hybrid materials (inorganic-inorganic hybrids, inorganic–organic hybrids). Our focus lies on structure/morphology engineering, doping techniques, and hybridization strategy design. Additionally, we illustrate the application of advanced multifunctional materials in various devices such as flexible, stretchable, self-powering, and artificial intelligence devices. Finally, we present the challenges, prospects, and opportunities of high-performance EESDs.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-08-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191964","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Han Gao, Long Qin, Shifei Tao, Ziming Xiong, Fan Wu, Ming Lei
{"title":"Multiple tuned carbon nanotubes by rare earth oxides for high-efficiency electromagnetic wave absorption","authors":"Han Gao, Long Qin, Shifei Tao, Ziming Xiong, Fan Wu, Ming Lei","doi":"10.1007/s42114-024-00946-y","DOIUrl":"10.1007/s42114-024-00946-y","url":null,"abstract":"<div><p>Optimizing high dielectric constant materials is a promising strategy for manufacturing efficient electromagnetic wave absorbing materials, which aims to fully exploit the performance advantages of micro-nano materials and overcome the adverse effects at low scales. This requires reasonable and meticulous component optimization. The low-cost and environmentally friendly fillers possess significant advantages. In this work, two specifications of carbon nanotubes (CNTs) are selected as the research objects. A simple solvothermal method is used to compound rare earth oxides (REO). Finally, CNTs/REO composites are prepared. The effects of different particle sizes on the electromagnetic wave absorption properties of the system are studied in detail from the microscopic morphology. Improve the interface effect and impedance matching in the system. When the filling amount is 30 wt.%, the minimum reflection loss (RL<sub>min</sub>) can reach − 69.94 dB, and the effective absorption bandwidth (EAB) is widened from 3.00 to 5.20 GHz. The huge performance span is attributed to the optimization of REO nanoparticles in the regulation of CNTs from morphology structure to electromagnetic parameters. The interfacial polarization, dielectric polarization, and dipole relaxation are improved significantly. The excellent electromagnetic wave absorption performance makes CNTs/REO have great application prospects in electronic devices. In addition, radar cross section (RCS) simulation provides theoretical support for the practical application of CNTs/REO composites.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-08-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191962","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Core–shell NH2-UiO-66@iCOPs with built-in “adsorption engines” for improving CO2 adsorption and conversion","authors":"Ping Liu, Kaixing Cai, Hua Liang, Peng Chen, Duan-Jian Tao, Tianxiang Zhao","doi":"10.1007/s42114-024-00947-x","DOIUrl":"10.1007/s42114-024-00947-x","url":null,"abstract":"<div><p>Integrating the advantages of metal–organic framework (MOFs) and ionic organic polymers (iCOPs), we fabricated a series of novel hybrid materials (core–shell M@iCOPs) by growing iCOP shell layers of varying thicknesses on the NH<sub>2</sub>-UiO-66. These M@iCOP hybrids, with NH<sub>2</sub>-UiO-66 serving as an embedded “adsorption engine,” exhibit richer pore channels, which combined with the nitrogen-rich structure and π-π stacking interactions in the shell layer of the iCOPs, which led to a significant enhancement of CO<sub>2</sub> adsorption with up to 3.33 mmol·g<sup>−1</sup> at 0 °C and 1 bar. Remarkably, M@iCOPs-400, which possesses abundant ionic and Lewis acid sites, demonstrates excellent performance in CO<sub>2</sub> conversion under milder conditions through interfacial synergistic effect, affording various cyclic carbonates in 90–99% yields. Overall, this research provides a straightforward and cost-effective approach for constructing core–shell M@iCOP materials.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":null,"pages":null},"PeriodicalIF":23.2,"publicationDate":"2024-08-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142191961","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}