Advanced Composites and Hybrid Materials最新文献

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Preparation of silver-coated polystyrene microspheres intermediated with polyaniline and their application in array-patterned anisotropic conductive films
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-21 DOI: 10.1007/s42114-024-01160-6
Changxiang Hao, Junde Chen, Yonghao Chen, Chengwei Jiang, Ziqiang Wang, Tingting Pan, Xing Cheng, Yanqing Tian
{"title":"Preparation of silver-coated polystyrene microspheres intermediated with polyaniline and their application in array-patterned anisotropic conductive films","authors":"Changxiang Hao,&nbsp;Junde Chen,&nbsp;Yonghao Chen,&nbsp;Chengwei Jiang,&nbsp;Ziqiang Wang,&nbsp;Tingting Pan,&nbsp;Xing Cheng,&nbsp;Yanqing Tian","doi":"10.1007/s42114-024-01160-6","DOIUrl":"10.1007/s42114-024-01160-6","url":null,"abstract":"<div><p>Array-patterned anisotropic conductive films (A-ACFs) possessing periodically arranged conductive particles distributed in curable resins can have high circuit-bonding precision; however, the preparation of A-ACFs is a challenging work. On the other hand, the traditional electrolysis coating of metal on polymer cores as the conductive particles needs long preparation steps. Herein, a new simplified approach uses polyaniline (PANI) as an intermediate layer to wrap the polystyrene (PS) microspheres and also chelate silver to prepare silver-coated PS microspheres (PS@PANI@Ag). Through a series of experimental regulation, neat PS@PANI@Ag microspheres with an average diameter of 4.73 ± 0.13 μm possessing a silver layer of about 65 nm and weight percentage of 23.6% were prepared. For developing A-ACFs, an approach is loading the prepared particles into the microcavities with a diameter of 6 μm and depth of 4 μm in silicon template through rubbing assembly process, transferring these particles onto the surface of a kind of chosen polymerizable acrylate resin to keep their periodicity, and embedding these particles in the polymeric resin films. These A-ACFs were used to bond indium-tin-oxide (ITO) and flexible-printed circuits (FPC) with 200-μm spacing to achieve low connection resistance of 1.78 ± 0.03 Ω/0.4 mm<sup>2</sup> and high insulation resistance over 200 MΩ. After aging at 85 °C and 85% relative humidity condition for 120 h, the connection resistance change is less 9.8%, showing the bonded device’s good environmental stability. The anisotropic property was also demonstrated using a homemade device through turning LEDs on or off. Therefore, the conductive particles’ and A-ACFs’ preparation methods may provide new insights for ACFs’ designing strategy and application in industry.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859737","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation of sandwich-structured thermally conductive and insulating composite materials based on electrospinning combined with hot pressing technology
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-21 DOI: 10.1007/s42114-024-01162-4
Zijian Wu, Zhengfang Wang, Meng Wang, Defeng Zang, Haiyong Long, Mingqi Sun, Ling Weng, Ning Guo, Junguo Gao
{"title":"Preparation of sandwich-structured thermally conductive and insulating composite materials based on electrospinning combined with hot pressing technology","authors":"Zijian Wu,&nbsp;Zhengfang Wang,&nbsp;Meng Wang,&nbsp;Defeng Zang,&nbsp;Haiyong Long,&nbsp;Mingqi Sun,&nbsp;Ling Weng,&nbsp;Ning Guo,&nbsp;Junguo Gao","doi":"10.1007/s42114-024-01162-4","DOIUrl":"10.1007/s42114-024-01162-4","url":null,"abstract":"<div><p>In this paper, h-BN was firstly exfoliated into functionalized BNNS by ball milling and liquid phase exfoliation techniques. BNNS/PVA composite fiber film was subsequently obtained by electrostatic spinning to realize the directional arrangement of BNNS in the PVA matrix, and BNNS/PVA/PS composite film was obtained by filling the pores inside the fiber film with PS solution. To further improve the thermal conductivity of the composite, carboxylated MWCNT was selected as the second thermally conductive filler, and the MWCNT/PVA/PS composite film was prepared by the same preparation method as BNNS/PVA/PS composite film. Finally, the MWCNT/PVA/PS composite film was placed in the middle layer, the BNNS/PVA/PS composite film was placed in the outer layer, and the thermally conductive composite materials with a novel sandwich structure were obtained by lamination. The combination of electrostatic spinning and hot pressing technology enabled the efficient construction of a high thermal conductivity network with BNNS and MWCNT, and the sandwich structure achieved a balance between high thermal conductivity and electrical insulation. The composite achieved a significant improvement in its in-plane thermal conductivity due to the realization of the directional arrangement of the filler in the in-plane direction. At a filler content of 14.75 wt%, the in-plane thermal conductivity of the composite was increased to 4.69 W/mK, which is nearly 23 times higher than that of the pure polymer. Due to the strict control of the spatial distribution form of MWCNT, the composites still have excellent insulation properties even at high filler content.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859556","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Metal-organic framework derived carbon-based composites for high-performance microwave absorption
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-21 DOI: 10.1007/s42114-024-01077-0
Shanshan Ran, Kai Sun, Minhui Zhao, Zhongyang Wang, Anoud Saud Alshammari, Mohamed H. Helal, Zeinhom M. El-Bahy, Yuan Yuan, Runhua Fan
{"title":"Metal-organic framework derived carbon-based composites for high-performance microwave absorption","authors":"Shanshan Ran,&nbsp;Kai Sun,&nbsp;Minhui Zhao,&nbsp;Zhongyang Wang,&nbsp;Anoud Saud Alshammari,&nbsp;Mohamed H. Helal,&nbsp;Zeinhom M. El-Bahy,&nbsp;Yuan Yuan,&nbsp;Runhua Fan","doi":"10.1007/s42114-024-01077-0","DOIUrl":"10.1007/s42114-024-01077-0","url":null,"abstract":"<div><p>There is an urgent need to develop high-performance absorbing materials to address the challenges of military stealth and daily electromagnetic pollution. Metal-organic frameworks (MOFs) are considered promising candidates due to their high porosity, large specific surface area, and tunable chemical structures. MOFs can be templates or precursors to transform into porous carbon, porous oxides, and metal-carbon composites at elevated temperatures. This paper reviews the synthesis strategies and recent advancements in MOF-derived carbon-based composites. The impact of various components and unique microstructures on these composites’ microwave absorption (MA) properties is analyzed. The discussion encompasses a range of composites, including porous carbon (PC) composites (such as metal/PC, metal oxide/PC, and metal/metal oxide/PC), as well as MOF derivatives combined with graphene, carbon nanotubes (CNTs), and carbon fibers (CFs). Additionally, the challenges and future directions regarding developing carbon-based microwave-absorbing materials (MAMs) derived from MOFs are discussed. This review aims to provide researchers with a comprehensive understanding of the design techniques pertinent to MOF-derived carbon-based composites in high-efficiency MAMs. </p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859557","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chitosan-polylactic acid composites: from seafood waste to advanced functional materials for 3D printing
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-21 DOI: 10.1007/s42114-024-01131-x
Erika Blanzeanu, Minodora Marin, Marian Nicolae Verziu, Anca Dumitru, Bogdan Stefan Vasile, Cristina Stavarache, Derniza-Elena Cozorici, Rafael Luque, Catalin Zaharia, Ionut-Cristian Radu
{"title":"Chitosan-polylactic acid composites: from seafood waste to advanced functional materials for 3D printing","authors":"Erika Blanzeanu,&nbsp;Minodora Marin,&nbsp;Marian Nicolae Verziu,&nbsp;Anca Dumitru,&nbsp;Bogdan Stefan Vasile,&nbsp;Cristina Stavarache,&nbsp;Derniza-Elena Cozorici,&nbsp;Rafael Luque,&nbsp;Catalin Zaharia,&nbsp;Ionut-Cristian Radu","doi":"10.1007/s42114-024-01131-x","DOIUrl":"10.1007/s42114-024-01131-x","url":null,"abstract":"<div><p>The development of functional and sustainable materials for additive manufacturing is a rapidly expanding area of interest. In this context, composite blends of chitosan—including commercial low and medium molecular weight variants, as well as laboratory-extracted chitosan from shrimp head and shell waste—and polylactic acid (PLA) were prepared using extrusion molding. Filament characterization was conducted to explore the effects of chitosan molecular weight and content on the filament properties using melt flow index, tensile testing, dynamic mechanical analysis (DMA), and differential scanning calorimetry (DSC). The morphology of the extruded filaments was analyzed using scanning electron microscopy (SEM). Additionally, the possibility of incorporating a high ratio of metal into the composite filaments without compromising their printability and structural integrity was investigated. The results indicated that certain compositions of chitosan-PLA composite filaments enable the effective incorporation of nickel, highlighting their potential as innovative catalyst supports. The filaments were 3D printed in a molten state, and the resulting specimens were subsequently examined using micro-CT. This approach seeks to create an innovative material from food waste, offering a sustainable and circular solution for transforming seafood waste into advanced functional materials. The successful integration of shrimp waste-derived chitosan into PLA filaments not only enhances the material properties, but also demonstrates the potential for creating high-value products from bio-waste, contributing to environmental sustainability and advancing the field of eco-friendly additive manufacturing. This work highlights the promising application of composite filaments in various industrial sectors, emphasizing their role in promoting a circular economy.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-024-01131-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859738","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Drug-device-field integration for tumor therapeutic interference with home-tailored nano-heterojunctions
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-21 DOI: 10.1007/s42114-024-01184-y
Yandai Lin, Xueli Ren, Fengqi Xuan, Zhe Liu
{"title":"Drug-device-field integration for tumor therapeutic interference with home-tailored nano-heterojunctions","authors":"Yandai Lin,&nbsp;Xueli Ren,&nbsp;Fengqi Xuan,&nbsp;Zhe Liu","doi":"10.1007/s42114-024-01184-y","DOIUrl":"10.1007/s42114-024-01184-y","url":null,"abstract":"<div><p>Sonodynamic therapy has exhibited tremendous merits such as deep tissue penetration, minimal invasiveness, and neglectable side effects, but the strong O<sub>2</sub> dependence and complex tumor microenvironment limit the therapy efficiency. Herein, a type of BaTiO<sub>3</sub>@MnO<sub>2</sub>-based Z-scheme nano-heterojunction has been conjugated to doxorubicin-loaded carbon nanotubes to form functionalized hybrid nanocomposites for O<sub>2</sub>-independent and TME-modulating combinational tumor therapy. The existences of BaTiO<sub>3</sub> and MnO<sub>2</sub> afford a built-in microelectric field which induces band tilting to effectively transfer electrons with a Z-scheme track, prolonged the electron–hole separation lifetime, and maintained strong redox potentials for hydrolysis and abundant reactive oxygen species generation. The in vivo experiments prove that nano-heterojunctions actively accumulate at the tumor after intravenous injection and demonstrate a glutathione-responsive behavior to impair tumor anti-oxidant and enhance ROS contents. It was also noted that the ultrasound-mediated treatment in association with nano-heterojunctions showed a superior O<sub>2</sub>-independent tumor elimination (up to 90%) in company with dramatic recruitments of CD4<sup>+</sup> and CD8<sup>+</sup> T cells. Therefore, this study has validated the BaTiO<sub>3</sub>@MnO<sub>2</sub>-based Z-scheme nano-heterojunctions with tumor therapeutic interference in a drug-device-field integration manner and highlighted their promising utilities for modulating the tumor microenvironment and overcoming the O<sub>2</sub> dependence for an efficacious tumor therapy in live animals.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859544","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fabrication of metal-doped graphite phase carbon nitride-based membrane and its application
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-20 DOI: 10.1007/s42114-024-01175-z
Wenbiao Zheng, Chengning Ye, Mingfeng Yu, Shujuan Yang, Yonghe Xiu, Xiaoxiao He, Hanyu Xue, Jianrong Xia, Renjin Gao, Zhanhui Yuan, Liwei Wang
{"title":"Fabrication of metal-doped graphite phase carbon nitride-based membrane and its application","authors":"Wenbiao Zheng,&nbsp;Chengning Ye,&nbsp;Mingfeng Yu,&nbsp;Shujuan Yang,&nbsp;Yonghe Xiu,&nbsp;Xiaoxiao He,&nbsp;Hanyu Xue,&nbsp;Jianrong Xia,&nbsp;Renjin Gao,&nbsp;Zhanhui Yuan,&nbsp;Liwei Wang","doi":"10.1007/s42114-024-01175-z","DOIUrl":"10.1007/s42114-024-01175-z","url":null,"abstract":"<div><p>Metal-doped (Cu, Zn, Mn) g-C<sub>3</sub>N<sub>4</sub> was synthesized by a simple high-temperature process, followed by the insertion of one-dimensional nanofibrillar cellulose (CNF) into the two-dimensional g-C<sub>3</sub>N<sub>4.</sub> Photocatalytic composite membranes were then prepared using a vacuum-assisted filtration method. A series of characterization techniques, including XRD, SEM, FT-IR, and UV–vis DRS, were employed to systematically analyze the microstructure, chemical composition, and physicochemical properties of the designed g-C<sub>3</sub>N<sub>4</sub>/CNF composite membranes. The results indicated that the visible photocatalytic activity of the metal-doped photocatalysts was enhanced, which is beneficial for pollutant degradation by reducing the bandgap and extending the absorption of visible light. Notably, the composite membrane prepared with Mn-doped g-C<sub>3</sub>N<sub>4</sub> demonstrated the highest photocatalytic performance in degrading rhodamine B dye, achieving a 42.6% degradation rate within 7 h. Additionally, the water flux and retention rate of the composite membranes were improved after metal doping, with Zn-doped g-C<sub>3</sub>N<sub>4</sub> showing approximately six times the water flux of undoped g-C<sub>3</sub>N<sub>4</sub>, reaching a rate of 293.64 L·m<sup>−2</sup>·h<sup>−1</sup>·bar<sup>−1</sup>.</p><h3>Graphic abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859776","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Excellent electromagnetic interference shielding of multi-layered thermoplastic poly-urethane nanocomposites with CoFe2O4 nanoparticles and graphite
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-20 DOI: 10.1007/s42114-024-01155-3
Nithiya Hanna Wilson,  Anju, Milan Masař, Michal Machovský, David Škoda, Pavel Urbánek, Michal Urbánek, Marek Pöschl, Jarmila Vilčáková, Ivo Kuřitka, Raghvendra Singh Yadav
{"title":"Excellent electromagnetic interference shielding of multi-layered thermoplastic poly-urethane nanocomposites with CoFe2O4 nanoparticles and graphite","authors":"Nithiya Hanna Wilson,&nbsp; Anju,&nbsp;Milan Masař,&nbsp;Michal Machovský,&nbsp;David Škoda,&nbsp;Pavel Urbánek,&nbsp;Michal Urbánek,&nbsp;Marek Pöschl,&nbsp;Jarmila Vilčáková,&nbsp;Ivo Kuřitka,&nbsp;Raghvendra Singh Yadav","doi":"10.1007/s42114-024-01155-3","DOIUrl":"10.1007/s42114-024-01155-3","url":null,"abstract":"<div><p>This work presents the design and development of multi-layered polymer-based nanocomposites that effectively block electromagnetic (EM) radiation by incorporating magnetic CoFe<sub>2</sub>O<sub>4</sub> nanoparticles (NPs) and conductive graphite on a thermoplastic polyurethane (TPU) matrix. The sonochemical method was employed to produce CoFe<sub>2</sub>O<sub>4</sub> NPs with a high degree of purity. The melt mixing process followed by compression molding was utilized to generate individual layers of TPU containing CoFe<sub>2</sub>O<sub>4</sub> NPs (F-TPU) and graphite (G-TPU) at a thickness of around 0.8 mm. Further, three mono-layers of either F-TPU or G-TPU were stacked in an identical and alternating fashion to create TPU-based multi-layered nanocomposites F/F/F, G/G/G, F/G/F, and G/F/G, respectively. The electromagnetic interference (EMI) total shielding effectiveness (SE<sub>T</sub>) in the X-band frequency range of 8.2–12.4 GHz was investigated and observed to be 3.7 dB, 33.8 dB, 23.9 dB, and 54.0 dB for F/F/F, G/G/G, F/G/F, and G/F/G, respectively. This research offers a guide for engineers looking to create superior EMI shielding materials, which have potential uses in radar security and information communications.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrospun 3D nanofibrous materials and their applications in orthopaedics
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-20 DOI: 10.1007/s42114-024-01120-0
Yuanhe Wang, Nana Shen, Zhongze Zhu, Jiarui Liu, Xiaoying Qi, Zhong Liu, Youfu Zhu, Xiaoxiong Wang, Yunze Long, Hongfei Xiang
{"title":"Electrospun 3D nanofibrous materials and their applications in orthopaedics","authors":"Yuanhe Wang,&nbsp;Nana Shen,&nbsp;Zhongze Zhu,&nbsp;Jiarui Liu,&nbsp;Xiaoying Qi,&nbsp;Zhong Liu,&nbsp;Youfu Zhu,&nbsp;Xiaoxiong Wang,&nbsp;Yunze Long,&nbsp;Hongfei Xiang","doi":"10.1007/s42114-024-01120-0","DOIUrl":"10.1007/s42114-024-01120-0","url":null,"abstract":"<div><p>Advancing modern technology has propelled biomedicine and materials science to the forefront of scientific interest. As modern science evolves, it demands greater synergy between disciplines. In the realm of orthopaedics, the complex architecture of bone necessitates implants that balance strength with porosity. This dual requirement beckons a profound grasp that spans the realms of biomedicine and materials science, urging a deep dive into both fields to craft the perfect synergy for bone implant materials. Journeying through materials and orthopaedic science, this article systematically discussed the preparation of 3D porous structures by electrospinning technology for orthopaedics. It began by detailing electrospinning techniques, their principles, processes, materials, and design strategies within materials science. Material characterization methods were then presented. In biomedicine, we offered a concise overview of standard testing methods, from cell viability to staining. Building on the foundational knowledge of both fields, it reviewed 3D electrospinning strategies and summarized recent research progress in bone tissue culture with this method. This review sought to offer a structured comprehension of the intersecting disciplines to researchers, establishing a robust basis for material innovation tailored to orthopaedic-specific demands.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-024-01120-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859779","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Expectations vs. reality in nacre-like composites: dominating role of particle packing and polymer confinement in mechanical performance
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-20 DOI: 10.1007/s42114-024-01107-x
V. Semeykina, C. Appiah, S. Rothberg, S. Heinrich, D. Giuntini, G. A. Schneider
{"title":"Expectations vs. reality in nacre-like composites: dominating role of particle packing and polymer confinement in mechanical performance","authors":"V. Semeykina,&nbsp;C. Appiah,&nbsp;S. Rothberg,&nbsp;S. Heinrich,&nbsp;D. Giuntini,&nbsp;G. A. Schneider","doi":"10.1007/s42114-024-01107-x","DOIUrl":"10.1007/s42114-024-01107-x","url":null,"abstract":"<div><p>After decades of research, mimicking the intricate structure of nacre shells with flawlessly packed blocks remains a laborious task in composite material design. For practical reasons, less ideal alternatives with reduced packing densities below 70 vol.% are often being explored. However, the extent to which the features of the nacre structure can be exploited remains unclear. This paper investigates whether mimicking nacre design in non-densely packed composites can still deliver exceptional mechanical performance. A wide range of ceramic particles (80–100 µm, including spheres and platelets) and methacrylate-based polymers was studied. All the composites exhibited little variation in strength (100–150 MPa) and E-modulus regardless of hierarchical structure, particle size, shape, or interfacial bonding, highlighting the greater importance of particle packing over these factors for ceramic loadings below 65 vol.%. In particular, the benefits of micron-sized anisotropic particles were diminished by the fundamental challenges in aligning such blocks: although these assemblies significantly enhanced fracture resistance, the elastic modulus was still lower than expected (25 GPa). A polydisperse mixture of irregularly shaped micron-sized particles surprisingly achieved a high elastic modulus of 20 GPa, suggesting that an optimized size distribution can provide benefits comparable to those of particle anisotropy. Composites loaded with small particles (&lt; 500 nm) exhibited two key effects: the solvation shells contributed to the total organic content significantly, limiting the maximum ceramic loading, and the polymer confined within small interparticle voids exhibited increased stiffness, leading to more brittle fracture despite the abundance of organic phase. Both phenomena should be accounted for in theoretical simulations and the practical design of composite materials.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s42114-024-01107-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859780","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional MXenes nanocomposite platforms for biosensing and wearable sensor technologies
IF 23.2 2区 材料科学
Advanced Composites and Hybrid Materials Pub Date : 2024-12-20 DOI: 10.1007/s42114-024-01118-8
Ali Mohammad Amani, Hesam Kamyab, Ehsan Vafa, Alireza Jahanbin, Milad Abbasi, Ahmad Vaez, Ganesh Munuswamy-Ramanujam, Balasubramani Ravindran, Lalitha Gnanasekaran, Daniele Rocchio, Mohammad Yusuf
{"title":"Multifunctional MXenes nanocomposite platforms for biosensing and wearable sensor technologies","authors":"Ali Mohammad Amani,&nbsp;Hesam Kamyab,&nbsp;Ehsan Vafa,&nbsp;Alireza Jahanbin,&nbsp;Milad Abbasi,&nbsp;Ahmad Vaez,&nbsp;Ganesh Munuswamy-Ramanujam,&nbsp;Balasubramani Ravindran,&nbsp;Lalitha Gnanasekaran,&nbsp;Daniele Rocchio,&nbsp;Mohammad Yusuf","doi":"10.1007/s42114-024-01118-8","DOIUrl":"10.1007/s42114-024-01118-8","url":null,"abstract":"<div><p>MXenes are nanostructures with unique characteristics, such as hydrophilicity, large surface area, strong metallic conductivity, strong ion transport capabilities, biocompatibility, minimal diffusion barrier, and easy functionalization, which make these compounds suitable for bioanalytical applications. These materials are formed of transition metallic nitrides, carbides, or carbonitrides. Owing to their unique properties, MXenes have gained interest in various fields, including sustainable energy generation, fuel cells, supercapacitors, electronics, and catalysis. The composition and layered structure have made MXenes particularly appealing to biosensing applications. They can be used in electrochemical biosensors because of their high conductivity and multilayered architecture, which ensure the retention of activity in immobilized biomolecules. This review highlights the application of MXenes in electrochemical and optical biosensors, identifying future requirements and potential in this sector, particularly in the development of wearable sensors and platforms with integrated biomolecule detection.</p></div>","PeriodicalId":7220,"journal":{"name":"Advanced Composites and Hybrid Materials","volume":"8 1","pages":""},"PeriodicalIF":23.2,"publicationDate":"2024-12-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142859778","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
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