{"title":"Machine-learning driven approach for exploration of properties of antimony chalcogenide perovskite based double absorber with back surface field layer","authors":"Harshit Saxena, Jaspinder Kaur, Rikmantra Basu, Ajay Kumar Sharma, Jaya Madan, Rahul Pandey","doi":"10.1007/s11082-025-08489-2","DOIUrl":"10.1007/s11082-025-08489-2","url":null,"abstract":"<div><p>To address the toxicity and stability concerns of lead-based perovskites, this study investigates a lead-free, antimony chalcogenide-based double-absorber solar cell with the structure WSe<sub>2</sub>/Sb<sub>2</sub>S<sub>3</sub>/Sb<sub>2</sub>Se<sub>3</sub>/WS<sub>2</sub>. Numerical simulations were performed using SCAPS-1D, followed by machine learning-based efficiency prediction using Support Vector Regression (SVR), Random Forest (RF), Stacked SVR + RF, and Extreme Gradient Boosting (XGBoost). The optimized configuration, with 0.2 µm Sb<sub>2</sub>S<sub>3</sub> (shallow acceptor density: 10<sup>16</sup> cm<sup>−3</sup>), 0.8 µm Sb<sub>2</sub>Se<sub>3</sub> (shallow donor density: 10<sup>19</sup> cm<sup>−3</sup>), achieved a power conversion efficiency (PCE) of 28.39%, V<sub>OC</sub> of 0.97 V, J<sub>SC</sub> of 33.32 mA/cm<sup>2</sup>, and fill factor of 87.91%. All layers were modelled with a bulk defect density of 10<sup>15</sup> cm<sup>−3</sup> and an interfacial defect density of 10<sup>10</sup> cm<sup>−2</sup>. Among the ML models, XGBoost demonstrated the best performance with an MSE of approximately 0.003 and R<sup>2</sup> of 0.9996. SHAP analysis identified Sb<sub>2</sub>Se<sub>3</sub> donor concentration as the most impactful feature, while Sb<sub>2</sub>S<sub>3</sub> thickness had the least effect. This study showcases the potential of combining SCAPS-1D simulation with interpretable ML models for accelerated design and optimization of lead-free solar cells.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Interfacial physics and electrostatic loss engineering in bandgap-engineered BaZrS3 chalcogenide solar cells: insights from numerical simulations","authors":"Surender Kumar, Devansh Gahlawat, Jaspinder Kaur, Uma Rani, Jaya Madan, Rahul Pandey, Rikmantra Basu","doi":"10.1007/s11082-025-08487-4","DOIUrl":"10.1007/s11082-025-08487-4","url":null,"abstract":"<div><p>We present a comprehensive SCAPS-1D study of BaZrS<sub>3</sub>-based chalcogenide-perovskite photovoltaics, combining bandgap engineering, parasitic-resistance analysis, ion-migration modelling, and tandem-cell design. By employing site-specific alloying strategies, the native bandgap of 1.71 eV was successfully reduced to 1.48 eV in Ba(Zr,Sn)S<sub>3</sub>, 1.35 eV in BaZr(S,Se)<sub>3</sub>, and 1.26 eV in (Ba,Ca)ZrS<sub>3</sub>—effectively extending the absorption edge to 983 nm in the Ca-alloyed variant. Device-level simulations identified parasitic resistances as key loss mechanisms, with series resistance reducing the fill factor by up to 15%, and low shunt resistance causing open-circuit voltage drops of 50–100 mV. Pronounced J–V hysteresis was reproduced via fixed interfacial ionic charge modelling in SCAPS-1D, with forward scan PCE of 18.36% in pristine BaZrS<sub>3</sub> dropping to 3.70% in the reverse scan. Additionally, two-terminal tandem architectures integrating BaZrS<sub>3</sub> as the top cell with alloyed bottom cells demonstrated promising performance, with matched short-circuit current densities of 14.80, 10.08, and 13.72 mA/cm<sup>2</sup> for Ca-, Sn-, and Se-alloyed devices, respectively. Power conversion efficiencies of 28.4, 23.4, and 27.4 were achieved, affirming the potential of bandgap engineering, interface control, and spectral filtering to drive BaZrS<sub>3</sub> photovoltaics toward their theoretical performance limits.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sergey Kudryashov, Alena Nastulyavichus, Sofia Babina, Evgeniya Ulturgasheva, Dmitry Khmelenin, Nikolay Pokryshkin, Aleksey Levchenko, Alexei Averin
{"title":"Laser-induced forward transfer nanoparticle spray for printing of metallic nanophotocatalysts","authors":"Sergey Kudryashov, Alena Nastulyavichus, Sofia Babina, Evgeniya Ulturgasheva, Dmitry Khmelenin, Nikolay Pokryshkin, Aleksey Levchenko, Alexei Averin","doi":"10.1007/s11082-025-08498-1","DOIUrl":"10.1007/s11082-025-08498-1","url":null,"abstract":"<div><p>Thin films of metallic palladium (Pd) of different thicknesses (30, 150, 450 nm) supported on silica glass slides were forward-nanosprayed in a plasma-piston regime by 1064-nm, 120-ns laser pulses at variable high (GW/cm<sup>2</sup>-level) peak laser intensities onto silicon substrates and carbon grids for chemical analysis and TEM sizing, respectively. The utilized peak laser intensities/fluences provide different spraying regimes – complete atomization/ionization, atomization or bulk boiling, depending on the Pd film thickness and the related volume energy deposition. The confined laser ablation regime, which is favorable for enlarged plasma/vapor pressure and its piston spraying, also surprisingly resulted in rather narrow dispersion state of the metallic palladium nanoparticles (50–100 nm) due to enhanced condensation in the confined vapor cavity at the film/substrate interface. The proposed procedure looks promising for direct printing large-surface Pd-based supported plasmonic nanophotocatalysts, with the minor unfavorable screening effect of the vaporized silica substrate.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Periodic waves and optical solitons in a novel resonant third-order nonlinear Schrödinger equation","authors":"Houria Triki, Elif Uyanık Ekici","doi":"10.1007/s11082-025-08481-w","DOIUrl":"10.1007/s11082-025-08481-w","url":null,"abstract":"<div><p>The existence of a rich variety of periodic and localized waves is demonstrated for an optical fiber system described by a new resonant third-order nonlinear Schrödinger equation. The derived nonlinear waves include solutions incorporating the Weierstrass function, periodic solutions, soliton solutions, and doubly periodic solutions. The newly found structures are derived by utilizing four integration approaches, namely the Weierstrass elliptic function expansion method, the Weierstrass semi-rational expansion technique, the extended Jacobi elliptic function expansion methodology, and the modified Jacobi elliptic function expansion approach. Based on a similarity transformation between the generalized resonant third-order nonlinear Schrödinger equation with variable coefficients and the related constant coefficient one, we construct the analytical nonautonomous bright and dark soliton solutions for the variable coefficient model. As an application, we discuss the evolutional dynamics of the recovered nonautonomous solitons in a periodically modulated fiber system. The results show that the dynamical behavior of nonautonomous solitons can be effectively controlled through a proper choice of the third-order dispersion and gain/loss parameters.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ahmed I. Abdel Salam, T. S. Soliman, Hanan A. Matar, A. Khalid, Mohamed Morsy
{"title":"Nickel and graphene oxide enhanced bismuth oxide for humidity sensing capabilities","authors":"Ahmed I. Abdel Salam, T. S. Soliman, Hanan A. Matar, A. Khalid, Mohamed Morsy","doi":"10.1007/s11082-025-08469-6","DOIUrl":"10.1007/s11082-025-08469-6","url":null,"abstract":"<div><p>Bismuth oxide (Bi<sub>2</sub>O<sub>2</sub>) nanoparticles have been doped with nickel (Ni) and graphene oxide (GO), acting as an efficient humidity sensor. Humidity sensors based on nanomaterials were found to be efficient in measuring and controlling humidity. Different nanostructured materials, including bare Bi<sub>2</sub>O<sub>2</sub>, Bi<sub>2</sub>O<sub>2</sub>-doped GO, Bi<sub>2</sub>O<sub>2</sub>-doped Ni, and Bi<sub>2</sub>O<sub>2</sub>-Ni-doped GO, have been synthesized through the co-precipitation method. The synthesized structure was identified and characterized through different characterization techniques, including X-ray Diffraction (XRD), Scanning Electron Microscopy (SEM), mapping analysis, Fourier Transform Infrared Spectroscopy (FTIR), and Ultraviolet–Visible Spectroscopy (UV–Vis). The average crystallite sizes as estimated from XRD were found to be 47.34 nm, 26.9 nm, 19.3 nm, and 17.5 nm for Bi<sub>2</sub>O<sub>2</sub>, Bi<sub>2</sub>O<sub>2</sub>-doped GO, Bi<sub>2</sub>O<sub>2</sub>-doped Ni, and Bi<sub>2</sub>O<sub>2</sub>-Ni-doped GO, respectively. The EDX mapping has confirmed the uniform distribution of the building elements within the matrix of the synthesized materials. The optical study revealed that the optical absorbance and the band gap energy of the Bi<sub>2</sub>O<sub>2</sub> nanoparticles were changed by adding Ni and GO to the matrix. The rGO has reduced the bandgap of the Bi<sub>2</sub>O<sub>2</sub> from 2.64 to 2.39 eV, while the addition of Ni to the Bi<sub>2</sub>O<sub>2</sub> raised the bandgap value to 3.45 eV, which slightly decreased to 3.39 eV after adding rGO to the Bi–Ni oxide composite. The humidity-sensing behavior was explored for all synthesized structures in a range of relative humidity from 11 to 97%. Among all investigated materials, Bi<sub>2</sub>O<sub>2</sub>-doped Ni revealed the lowest value of sensitivity, while Bi<sub>2</sub>O<sub>2</sub>-Ni-doped GO attained the highest value of sensitivity within the investigated range. The Nyquist plot was developed for studying the humidity-sensing behavior of the investigated samples.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256640","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Abdul-Majid Wazwaz, Weaam Alhejaili, Samir A. El-Tantawy
{"title":"Study on the (2+1)-dimensional quantum Heisenberg ferromagnetic spin chain model: envelope optical bright and dark soliton solutions and other traveling wave solutions","authors":"Abdul-Majid Wazwaz, Weaam Alhejaili, Samir A. El-Tantawy","doi":"10.1007/s11082-025-08477-6","DOIUrl":"10.1007/s11082-025-08477-6","url":null,"abstract":"<div><p>This work deals with one of the most fundamental evolutionary equations that arises in quantum mechanics and is widely used in quantum information, as well as in understanding magnetic phenomena and material properties, namely the Heisenberg ferromagnetic spin chain (HFSC) model. Thus, we investigate a nonlinear (2+1)-dimensional Heisenberg model that describes the propagation of nonlinear waves in quantum mechanics and other physical mediums. The model incorporates both linear and nonlinear dispersion, describing the dynamics of magnetic materials. This work presents interesting findings, including bright, dark, periodic, and rational solutions, as well as other traveling wave solutions. We implement a variety of powerful schemes to derive these diverse optical soliton solutions. Moreover, we derive more solutions of distinct structures, which include periodic and exponential solutions. The obtained results enhance the understanding of the dynamics of higher-dimensional nonlinear wave equations, which can be applied to model various nonlinear modulated structures in plasma physics, fluids, and optics.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256051","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Norah A. M. Alsaif, Haifa I. Alrebdi, R. A. Elsad, M. S. Shams, Adel M. El-Refaey, W. M. Almutairi, Y. S. Rammah
{"title":"Optical properties of PVC nanocomposites based on synthesized multiferroic nanoparticles","authors":"Norah A. M. Alsaif, Haifa I. Alrebdi, R. A. Elsad, M. S. Shams, Adel M. El-Refaey, W. M. Almutairi, Y. S. Rammah","doi":"10.1007/s11082-025-08486-5","DOIUrl":"10.1007/s11082-025-08486-5","url":null,"abstract":"<div><p>The structure and optical characteristics of polyvinyl chloride (PVC) doped with varying concentrations of multiferroic BiNi<sub>0.1</sub>Fe<sub>0.9</sub>O<sub>3</sub> NPs (nanoparticles) have been investigated. The sol-gel method was employed to prepare multiferroic NPs. The morphology of the generated multiferroic NPs was investigated using the high-resolution transmission electron microscope (HRTEM). Solution casting was used to create PVC/BiNiFeO<sub>3</sub> -NPs nanocomposites. The density progressively rises as the amount of multiferroic NPs increases. As the concentration of the Multiferroic dopant rose, the values of E<sub>g</sub> decreased from 5.241 ± 0.001 eV to 2.751 ± 0.001 eV and Urbach energy (E<sub>U</sub>) increased from 0.458 ± 0.001 eV to 41.254 ± 0.001 eV. An increase in multiferroic nano-ferrite concentration resulted in an improvement in the polymer film samples’ refractive index. The suggested samples can be applied for optical and spintronic devices.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256229","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Thermophoretic motion equation through graphene sheets: soliton-like, M-lump-like and hybrid thermophoresis in optics","authors":"Hajar Farhan Ismael, Tukur Abdulkadir Sulaiman, Harivan Rammadhan Nabi, Usman Younas","doi":"10.1007/s11082-025-08490-9","DOIUrl":"10.1007/s11082-025-08490-9","url":null,"abstract":"<div><p>The thermophoretic motion equation governing wrinkle propagation in substrate-supported graphene sheets is investigated. As one of the thinnest yet strongest nanoscale elastic materials, graphene has revolutionized material science with its diverse applications. Its exceptional physical and chemical properties, developed through extensive theoretical and experimental research, have made it a fundamental component in numerous electronic devices. Particularly intriguing is the study of graphene-based thermal energy conversion systems, complemented by the material’s remarkable optical characteristics. This research employs the Hirota bilinear method to derive multiple soliton solutions and M-lump-like waves, while the long-wave method is utilized to examine hybrid solutions. The physical relevance of these solutions is thoroughly explored through graphical representations that depict their behavior under specific parameter conditions. The findings confirm the reliability of the applied techniques and suggest their potential for uncovering novel solutions to nonlinear evolution equations in various scientific domains.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145256078","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Ab initio design of Zr-based bulk metallic glass for high-strength and optical coating applications","authors":"Abhay P. Srivastava, Brijesh K. Pandey","doi":"10.1007/s11082-025-08467-8","DOIUrl":"10.1007/s11082-025-08467-8","url":null,"abstract":"<div><p>This study provides a comprehensive examination of the Zr<sub>41</sub>Ti<sub>14</sub>Cu<sub>12.5</sub>Ni<sub>9</sub>Be<sub>22.5</sub>C<sub>1</sub> bulk metallic glass (BMG), utilizing a combination of melt-quench molecular dynamics and density functional theory (DFT) calculations. Crucially, the structural model’s reliability was confirmed, as the agreement with experimental density and bond lengths was close. The atomic arrangement exhibited order on both short and medium scales, with Zr-centered polyhedra playing a dominant role, which appears to be linked to its mechanical strength and thermal resistance. Our mechanical testing revealed significant stiffness, ductility, and a high ultimate tensile strength. Furthermore, calculations of optical properties, notably the refractive index, dielectric function, and absorption spectra, suggest that it could be beneficial in optoelectronics. Analysis of the band structure and DOS suggests semiconducting traits, reinforcing its potential across several functions. This study provides key insights into how atomic structure influences properties in BMGs, making this Zr-based alloy a strong choice for applications such as coatings, components in MEMS, and potentially solar cells, where a combination of mechanical robustness, thermal stability, and specific optical characteristics is required.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210878","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"27 kW peak power all-fiber chirped pulse amplification seeded by dissipative soliton at 1.5 μm","authors":"H. Ahmad, M. U. M. Ithnahaini, M. Z. Samion","doi":"10.1007/s11082-025-08480-x","DOIUrl":"10.1007/s11082-025-08480-x","url":null,"abstract":"<div><p>The high-power all-fiber femtosecond laser system demonstrated in this work operates at 1.5 μm and is integrated into a chirped-pulse amplification (CPA) setup. The system includes a dissipative soliton (DS) mode-locked oscillator that is followed by multiple amplification stages, an all-fiber pulse stretcher, power amplifiers, and a fiber-based compressor. Unlike conventional CPA setups that rely on free-space diffraction gratings requiring precise optical alignment, the all-fiber-based stretcher and compressor offer superior integration, stability, and simplicity. The CPA architecture delivers a maximum average output power of 1.12 W, with a pulse width of 363 fs and a repetition rate of 19.3 MHz. This configuration achieves a peak power of 27 kW and pulse energy of 10 nJ, with a minimal output power variation of 0.09 dB, indicating excellent long-term stability. The system’s compactness, environmental robustness, and high performance underscore its suitability for demanding applications such as supercontinuum generation, multiphoton imaging, and high-precision micromachining.</p></div>","PeriodicalId":720,"journal":{"name":"Optical and Quantum Electronics","volume":"57 10","pages":""},"PeriodicalIF":4.0,"publicationDate":"2025-10-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11082-025-08480-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210879","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}