Optical properties of PVC nanocomposites based on synthesized multiferroic nanoparticles

IF 4 3区工程技术 Q2 ENGINEERING, ELECTRICAL & ELECTRONIC

Optical and Quantum Electronics Pub Date : 2025-10-06 DOI:10.1007/s11082-025-08486-5

Norah A. M. Alsaif, Haifa I. Alrebdi, R. A. Elsad, M. S. Shams, Adel M. El-Refaey, W. M. Almutairi, Y. S. Rammah

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Abstract

The structure and optical characteristics of polyvinyl chloride (PVC) doped with varying concentrations of multiferroic BiNi_0.1Fe_0.9O₃ NPs (nanoparticles) have been investigated. The sol-gel method was employed to prepare multiferroic NPs. The morphology of the generated multiferroic NPs was investigated using the high-resolution transmission electron microscope (HRTEM). Solution casting was used to create PVC/BiNiFeO₃ -NPs nanocomposites. The density progressively rises as the amount of multiferroic NPs increases. As the concentration of the Multiferroic dopant rose, the values of E_g decreased from 5.241 ± 0.001 eV to 2.751 ± 0.001 eV and Urbach energy (E_U) increased from 0.458 ± 0.001 eV to 41.254 ± 0.001 eV. An increase in multiferroic nano-ferrite concentration resulted in an improvement in the polymer film samples’ refractive index. The suggested samples can be applied for optical and spintronic devices.

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聚氯乙烯纳米复合材料的光学性能研究

研究了掺杂不同浓度的多铁性BiNi0.1Fe0.9O3纳米粒子的聚氯乙烯（PVC）的结构和光学特性。采用溶胶-凝胶法制备了多铁NPs。利用高分辨率透射电镜（HRTEM）研究了合成的多铁NPs的形貌。采用溶液铸造法制备PVC/BiNiFeO3 -NPs纳米复合材料。随着多铁NPs数量的增加，密度逐渐增加。随着多铁掺杂浓度的增加，Eg值从5.241±0.001 eV下降到2.751±0.001 eV，乌尔巴赫能（EU）从0.458±0.001 eV上升到41.254±0.001 eV。多铁纳米铁氧体浓度的增加导致聚合物薄膜样品折射率的改善。所建议的样品可用于光学和自旋电子器件。

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来源期刊

Optical and Quantum Electronics 工程技术-工程：电子与电气

CiteScore

4.60

自引率

20.00%

发文量

810

审稿时长

3.8 months

期刊介绍： Optical and Quantum Electronics provides an international forum for the publication of original research papers, tutorial reviews and letters in such fields as optical physics, optical engineering and optoelectronics. Special issues are published on topics of current interest. Optical and Quantum Electronics is published monthly. It is concerned with the technology and physics of optical systems, components and devices, i.e., with topics such as: optical fibres; semiconductor lasers and LEDs; light detection and imaging devices; nanophotonics; photonic integration and optoelectronic integrated circuits; silicon photonics; displays; optical communications from devices to systems; materials for photonics (e.g. semiconductors, glasses, graphene); the physics and simulation of optical devices and systems; nanotechnologies in photonics (including engineered nano-structures such as photonic crystals, sub-wavelength photonic structures, metamaterials, and plasmonics); advanced quantum and optoelectronic applications (e.g. quantum computing, memory and communications, quantum sensing and quantum dots); photonic sensors and bio-sensors; Terahertz phenomena; non-linear optics and ultrafast phenomena; green photonics.