Nano-Micro Letters最新文献_第7页

Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption 多种锡化合物改性碳纤维，构建用于防腐蚀和吸收电磁波的异质界面

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-27 DOI: 10.1007/s40820-024-01527-w

Zhiqiang Guo, Di Lan, Zirui Jia, Zhenguo Gao, Xuetao Shi, Mukun He, Hua Guo, Guanglei Wu, Pengfei Yin

{"title":"Multiple Tin Compounds Modified Carbon Fibers to Construct Heterogeneous Interfaces for Corrosion Prevention and Electromagnetic Wave Absorption","authors":"Zhiqiang Guo, Di Lan, Zirui Jia, Zhenguo Gao, Xuetao Shi, Mukun He, Hua Guo, Guanglei Wu, Pengfei Yin","doi":"10.1007/s40820-024-01527-w","DOIUrl":"10.1007/s40820-024-01527-w","url":null,"abstract":"<div><p>Currently, the demand for electromagnetic wave (EMW) absorbing materials with specific functions and capable of withstanding harsh environments is becoming increasingly urgent. Multi-component interface engineering is considered an effective means to achieve high-efficiency EMW absorption. However, interface modulation engineering has not been fully discussed and has great potential in the field of EMW absorption. In this study, multi-component tin compound fiber composites based on carbon fiber (CF) substrate were prepared by electrospinning, hydrothermal synthesis, and high-temperature thermal reduction. By utilizing the different properties of different substances, rich heterogeneous interfaces are constructed. This effectively promotes charge transfer and enhances interfacial polarization and conduction loss. The prepared SnS/SnS<sub>2</sub>/SnO<sub>2</sub>/CF composites with abundant heterogeneous interfaces have and exhibit excellent EMW absorption properties at a loading of 50 wt% in epoxy resin. The minimum reflection loss (RL) is − 46.74 dB and the maximum effective absorption bandwidth is 5.28 GHz. Moreover, SnS/SnS<sub>2</sub>/SnO<sub>2</sub>/CF epoxy composite coatings exhibited long-term corrosion resistance on Q235 steel surfaces. Therefore, this study provides an effective strategy for the design of high-efficiency EMW absorbing materials in complex and harsh environments.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01527-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142324913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Molecule-Level Multiscale Design of Nonflammable Gel Polymer Electrolyte to Build Stable SEI/CEI for Lithium Metal Battery 分子级多尺度设计不易燃凝胶聚合物电解质，为锂金属电池构建稳定的 SEI/CEI

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-27 DOI: 10.1007/s40820-024-01508-z

Qiqi Sun, Zelong Gong, Tao Zhang, Jiafeng Li, Xianli Zhu, Ruixiao Zhu, Lingxu Wang, Leyuan Ma, Xuehui Li, Miaofa Yuan, Zhiwei Zhang, Luyuan Zhang, Zhao Qian, Longwei Yin, Rajeev Ahuja, Chengxiang Wang

{"title":"Molecule-Level Multiscale Design of Nonflammable Gel Polymer Electrolyte to Build Stable SEI/CEI for Lithium Metal Battery","authors":"Qiqi Sun, Zelong Gong, Tao Zhang, Jiafeng Li, Xianli Zhu, Ruixiao Zhu, Lingxu Wang, Leyuan Ma, Xuehui Li, Miaofa Yuan, Zhiwei Zhang, Luyuan Zhang, Zhao Qian, Longwei Yin, Rajeev Ahuja, Chengxiang Wang","doi":"10.1007/s40820-024-01508-z","DOIUrl":"10.1007/s40820-024-01508-z","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Nonflammable gel polymer electrolyte (SGPE) is developed by in situ polymerizing trifluoroethyl methacrylate (TFMA) monomers with flame-retardant triethyl phosphate (TEP) solvents and LiTFSI–LiDFOB dual lithium salts.</p>\u0000 </li>\u0000 <li>\u0000 <p>Molecular polarity interaction between TEP and PTFMA mitigates interfacial reactions and changes the solvation of Li<sup>+</sup>.</p>\u0000 </li>\u0000 <li>\u0000 <p>SGPE forms stable inorganic-rich solid electrolyte interface/cathode electrolyte interface layer, exhibiting well compatibility with Li anode and LiCoO<sub>2</sub>-type high-voltage cathode.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01508-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321918","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Spontaneous Orientation Polarization of Anisotropic Equivalent Dipoles Harnessed by Entropy Engineering for Ultra-Thin Electromagnetic Wave Absorber 熵工程利用各向异性等效偶极子的自发方向极化实现超薄电磁波吸收器

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01507-0

Honghan Wang, Xinyu Xiao, Shangru Zhai, Chuang Xue, Guangping Zheng, Deqing Zhang, Renchao Che, Junye Cheng

{"title":"Spontaneous Orientation Polarization of Anisotropic Equivalent Dipoles Harnessed by Entropy Engineering for Ultra-Thin Electromagnetic Wave Absorber","authors":"Honghan Wang, Xinyu Xiao, Shangru Zhai, Chuang Xue, Guangping Zheng, Deqing Zhang, Renchao Che, Junye Cheng","doi":"10.1007/s40820-024-01507-0","DOIUrl":"10.1007/s40820-024-01507-0","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>The strengthening mechanism of spontaneous orientation polarization of anisotropic equivalent dipoles within high-entropy alloys (HEAs) is proposed for enhancing dielectric attenuation of HEAs.</p>\u0000 </li>\u0000 <li>\u0000 <p>The source of carbon supporter is expanded to the biomass category, which can construct the shell-core heterointerfaces with HEAs by means of a reformative carbothermal shock method.</p>\u0000 </li>\u0000 <li>\u0000 <p>The sample carbonized cellulose paper/HEAs-Mn<sub>2.15</sub> achieves efficient electromagnetic wave absorption of -51.35 dB at an ultra-thin thickness of 1.03 mm.</p>\u0000 </li>\u0000 <li>\u0000 <p>This work combines theoretical calculations and electromagnetic simulations to propose feasible strategies for the design and application of electromagnetic functional devices such as ultra-wideband bandpass filter.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01507-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321219","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Constructing Donor–Acceptor-Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li+ Migration in Quasi-Solid-State Battery 构建供体-受体连接的 COFs 电解质以调节准固态电池中的电子密度并加速 Li+ 迁移

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01509-y

Genfu Zhao, Hang Ma, Conghui Zhang, Yongxin Yang, Shuyuan Yu, Haiye Zhu, Yongjiang Sun, Hong Guo

{"title":"Constructing Donor–Acceptor-Linked COFs Electrolytes to Regulate Electron Density and Accelerate the Li+ Migration in Quasi-Solid-State Battery","authors":"Genfu Zhao, Hang Ma, Conghui Zhang, Yongxin Yang, Shuyuan Yu, Haiye Zhu, Yongjiang Sun, Hong Guo","doi":"10.1007/s40820-024-01509-y","DOIUrl":"10.1007/s40820-024-01509-y","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 <ul>\u0000 <li>\u0000 <p>Donor–acceptor-linked covalent organic framework (COF)-based electrolyte can not only fulfill highly-selective Li<sup>+</sup> conduction, but also offer a crucial opportunity to understand the role of electronic density in quasi-solid-state Li metal batteries.</p>\u0000 </li>\u0000 <li>\u0000 <p>Donor–acceptor-linked COF electrolyte results in Li<sup>+</sup> transference number 0.83, high ionic conductivity 6.7 × 10<sup>–4</sup> S cm<sup>−1</sup> and excellent cyclic ability in Li metal batteries.</p>\u0000 </li>\u0000 <li>\u0000 <p>In situ characterizations, density functional theory calculation and time-of-flight secondary ion mass spectrometry are adopted to expound the mechanism of the rapid migration of Li<sup>+</sup> in the “donor–acceptor” electrolyte system.</p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01509-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Tailoring Light–Matter Interactions in Overcoupled Resonator for Biomolecule Recognition and Detection 在超耦合共振器中定制光-物质相互作用，实现生物分子识别和检测

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01520-3

Dongxiao Li, Hong Zhou, Zhihao Ren, Cheng Xu, Chengkuo Lee

{"title":"Tailoring Light–Matter Interactions in Overcoupled Resonator for Biomolecule Recognition and Detection","authors":"Dongxiao Li, Hong Zhou, Zhihao Ren, Cheng Xu, Chengkuo Lee","doi":"10.1007/s40820-024-01520-3","DOIUrl":"10.1007/s40820-024-01520-3","url":null,"abstract":"<div><p>Plasmonic nanoantennas provide unique opportunities for precise control of light–matter coupling in surface-enhanced infrared absorption (SEIRA) spectroscopy, but most of the resonant systems realized so far suffer from the obstacles of low sensitivity, narrow bandwidth, and asymmetric Fano resonance perturbations. Here, we demonstrated an overcoupled resonator with a high plasmon-molecule coupling coefficient (μ) (OC-Hμ resonator) by precisely controlling the radiation loss channel, the resonator-oscillator coupling channel, and the frequency detuning channel. We observed a strong dependence of the sensing performance on the coupling state, and demonstrated that OC-Hμ resonator has excellent sensing properties of ultra-sensitive (7.25% nm<sup>−1</sup>), ultra-broadband (3–10 μm), and immune asymmetric Fano lineshapes. These characteristics represent a breakthrough in SEIRA technology and lay the foundation for specific recognition of biomolecules, trace detection, and protein secondary structure analysis using a single array (array size is 100 × 100 µm<sup>2</sup>). In addition, with the assistance of machine learning, mixture classification, concentration prediction and spectral reconstruction were achieved with the highest accuracy of 100%. Finally, we demonstrated the potential of OC-Hμ resonator for SARS-CoV-2 detection. These findings will promote the wider application of SEIRA technology, while providing new ideas for other enhanced spectroscopy technologies, quantum photonics and studying light–matter interactions.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01520-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321801","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Alternative Strategy for Development of Dielectric Calcium Copper Titanate-Based Electrolytes for Low-Temperature Solid Oxide Fuel Cells 开发用于低温固体氧化物燃料电池的钛酸铜钙电解质的替代战略

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01523-0

Sajid Rauf, Muhammad Bilal Hanif, Zuhra Tayyab, Matej Veis, M. A. K. Yousaf Shah, Naveed Mushtaq, Dmitry Medvedev, Yibin Tian, Chen Xia, Martin Motola, Bin Zhu

引用次数: 0

Ultra-Transparent and Multifunctional IZVO Mesh Electrodes for Next-Generation Flexible Optoelectronics 用于下一代柔性光电子技术的超透明多功能 IZVO 网状电极

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01525-y

Kiran A. Nirmal, Tukaram D. Dongale, Atul C. Khot, Chenjie Yao, Nahyun Kim, Tae Geun Kim

{"title":"Ultra-Transparent and Multifunctional IZVO Mesh Electrodes for Next-Generation Flexible Optoelectronics","authors":"Kiran A. Nirmal, Tukaram D. Dongale, Atul C. Khot, Chenjie Yao, Nahyun Kim, Tae Geun Kim","doi":"10.1007/s40820-024-01525-y","DOIUrl":"10.1007/s40820-024-01525-y","url":null,"abstract":"<div><p>Mechanically durable transparent electrodes are essential for achieving long-term stability in flexible optoelectronic devices. Furthermore, they are crucial for applications in the fields of energy, display, healthcare, and soft robotics. Conducting meshes represent a promising alternative to traditional, brittle, metal oxide conductors due to their high electrical conductivity, optical transparency, and enhanced mechanical flexibility. In this paper, we present a simple method for fabricating an ultra-transparent conducting metal oxide mesh electrode using self-cracking-assisted templates. Using this method, we produced an electrode with ultra-transparency (97.39%), high conductance (<i>R</i><sub>s</sub> = 21.24 Ω sq<sup>−1</sup>), elevated work function (5.16 eV), and good mechanical stability. We also evaluated the effectiveness of the fabricated electrodes by integrating them into organic photovoltaics, organic light-emitting diodes, and flexible transparent memristor devices for neuromorphic computing, resulting in exceptional device performance. In addition, the unique porous structure of the vanadium-doped indium zinc oxide mesh electrodes provided excellent flexibility, rendering them a promising option for application in flexible optoelectronics.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01525-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Prussian Blue Analogue-Templated Nanocomposites for Alkali-Ion Batteries: Progress and Perspective 用于碱-离子电池的普鲁士蓝类似物-模板纳米复合材料：进展与展望

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01517-y

Jian-En Zhou, Yilin Li, Xiaoming Lin, Jiaye Ye

引用次数: 0

Boosting Oxygen Evolution Reaction Performance on NiFe-Based Catalysts Through d-Orbital Hybridization 通过 d 轨道杂化提高镍铁合金催化剂的氧气进化反应性能

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01528-9

Xing Wang, Wei Pi, Sheng Hu, Haifeng Bao, Na Yao, Wei Luo

{"title":"Boosting Oxygen Evolution Reaction Performance on NiFe-Based Catalysts Through d-Orbital Hybridization","authors":"Xing Wang, Wei Pi, Sheng Hu, Haifeng Bao, Na Yao, Wei Luo","doi":"10.1007/s40820-024-01528-9","DOIUrl":"10.1007/s40820-024-01528-9","url":null,"abstract":"<div><p>Anion-exchange membrane water electrolyzers (AEMWEs) for green hydrogen production have received intensive attention due to their feasibility of using earth-abundant NiFe-based catalysts. By introducing a third metal into NiFe-based catalysts to construct asymmetrical M-NiFe units, the <i>d</i>-orbital and electronic structures can be adjusted, which is an important strategy to achieve sufficient oxygen evolution reaction (OER) performance in AEMWEs. Herein, the ternary NiFeM (M: La, Mo) catalysts featured with distinct M-NiFe units and varying <i>d</i>-orbitals are reported in this work. Experimental and theoretical calculation results reveal that the doping of La leads to optimized hybridization between <i>d</i> orbital in NiFeM and 2<i>p</i> in oxygen, resulting in enhanced adsorption strength of oxygen intermediates, and reduced rate-determining step energy barrier, which is responsible for the enhanced OER performance. More critically, the obtained NiFeLa catalyst only requires 1.58 V to reach 1 A cm<sup>−2</sup> in an anion exchange membrane electrolyzer and demonstrates excellent long-term stability of up to 600 h.</p><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01528-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321216","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Designing Electronic Structures of Multiscale Helical Converters for Tailored Ultrabroad Electromagnetic Absorption 为定制超宽电磁吸收设计多尺度螺旋转换器的电子结构

IF 26.6 1区材料科学

Nano-Micro Letters Pub Date : 2024-09-26 DOI: 10.1007/s40820-024-01513-2

Zhaobo Feng, Chongbo Liu, Xin Li, Guangsheng Luo, Naixin Zhai, Ruizhe Hu, Jing Lin, Jinbin Peng, Yuhui Peng, Renchao Che

{"title":"Designing Electronic Structures of Multiscale Helical Converters for Tailored Ultrabroad Electromagnetic Absorption","authors":"Zhaobo Feng, Chongbo Liu, Xin Li, Guangsheng Luo, Naixin Zhai, Ruizhe Hu, Jing Lin, Jinbin Peng, Yuhui Peng, Renchao Che","doi":"10.1007/s40820-024-01513-2","DOIUrl":"10.1007/s40820-024-01513-2","url":null,"abstract":"<div><h2>Highlights</h2><div>\u0000 \u0000 \u0000<ul>\u0000 <li>\u0000 <p>The energy conversion mechanism is thoroughly analyzed, with a detailed quantitative characterization of the dissipation capacities of polarization, conduction, and magnetic loss.</p>\u0000 </li>\u0000 <li>\u0000 <p>Inspired by DNA transcription, atom and geometry configurations co-modulating multi-scale helical converters achieve the <i>RL</i><sub><i>min</i></sub> of −63.13 dB at 1.29 mm, and the maximum RCS reduction value reach 36.4 dB m<sup>2</sup>.</p>\u0000 </li>\u0000 <li>\u0000 <p>Orbital coupling, spin and cross polarization synergize to realize a 6.08 GHz EAB, further expanding to ultrabroad electromagnetic wave absorption of 12.16 GHz through metamaterial design<i>.</i></p>\u0000 </li>\u0000 </ul>\u0000 </div></div>","PeriodicalId":714,"journal":{"name":"Nano-Micro Letters","volume":"17 1","pages":""},"PeriodicalIF":26.6,"publicationDate":"2024-09-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s40820-024-01513-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142321220","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0