Chemical Society Reviews最新文献_第8页

Dynamic evolution of metal structures on/in zeolites for catalysis 催化沸石上/内金属结构的动态演化。

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-07 DOI: 10.1039/D5CS00035A

Yuexin Wu, Pengcheng Deng, Lujie Liu, Junyi Zhang, Haisheng Liu, Xionghou Gao, Feng-Shou Xiao and Liang Wang

引用次数: 0

Contributors to the 2024 Emerging Investigators collection 2024 年新锐调查员文集》的撰稿人

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-03 DOI: 10.1039/D5CS90030A

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Cu-based S-scheme photocatalysts 铜基s型光催化剂

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-02 DOI: 10.1039/D4CS01091D

Mahmoud Sayed, Kezhen Qi, Xinhe Wu, Liuyang Zhang, Hermenegildo García and Jiaguo Yu

{"title":"Cu-based S-scheme photocatalysts","authors":"Mahmoud Sayed, Kezhen Qi, Xinhe Wu, Liuyang Zhang, Hermenegildo García and Jiaguo Yu","doi":"10.1039/D4CS01091D","DOIUrl":"10.1039/D4CS01091D","url":null,"abstract":"S-scheme heterojunctions have become a hot topic in photocatalysis. Copper (Cu) compounds are a versatile family of photocatalytic materials, including oxides (CuO, Cu2O), binary oxides (CuBi2O4, CuFe2O4), sulfides (CuxS, (1 ≤ x ≤ 2)), selenides (CuSe), phosphides (Cu3P), metal organic frameworks (MOFs), etc. These materials are characterized by narrow bandgaps, large absorption coefficients, and suitable band positions. To further increase the efficiency of photoinduced charge separation, Cu-based photocatalytic materials are widely integrated into S-scheme heterojunctions and exploited for the hydrogen evolution reaction (HER), CO2 reduction, H2O2 generation, N2 fixation, and pollutant degradation. This review comprehensively discusses recent progress in Cu-based S-scheme heterojunctions, and highlights their considerable potential for targeted applications in sustainable energy conversion, environmental remediation, and beyond. The fundamentals of S-scheme charge transfer, the design principles and verification tools are summarized. Then, the review describes the Cu-based photocatalytic materials, categorized according to their chemical composition, and their integration in S-scheme heterojunctions for photocatalytic applications. In particular, the implications of the S-scheme charge transfer mechanism on promoting the catalytic activity of selected systems are analyzed. Finally, current limitations and outlooks are provided to motivate future studies on developing novel and advanced Cu-based S-scheme photocatalysts with high performance and studying the underlying photocatalytic mechanisms.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 10","pages":" 4874-4921"},"PeriodicalIF":40.4,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d4cs01091d?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143758561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Alkali-induced catalytic tuning at metal and metal oxide interfaces 金属和金属氧化物界面上碱诱导的催化调谐

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-01 DOI: 10.1039/D4CS01094A

Wenjie Liao, An Nguyen and Ping Liu

{"title":"Alkali-induced catalytic tuning at metal and metal oxide interfaces","authors":"Wenjie Liao, An Nguyen and Ping Liu","doi":"10.1039/D4CS01094A","DOIUrl":"10.1039/D4CS01094A","url":null,"abstract":"Alkali metals have been recognized as effective promoters in heterogeneous catalysis, capable of enhancing catalytic activity and tuning product distributions. Over the past few decades, significant efforts have been made aiming to reveal the mechanisms underlying the promoting effect of alkalis. However, the roles that alkali metals play in the catalytic process remain elusive due to challenges in capturing their catalytic behaviours upon exposure to reactive environments. This review summarizes recent surface science and theoretical studies of alkali (potassium, cesium)-decorated metal and metal oxide model catalysts, revealing the crucial tuning by alkalis of activity and selectivity for CO2 hydrogenation. The analysis of electronic structures identifies the selective binding mechanism of the positively charged alkali ions on the surface, being able to reduce the surface work function and lead to strong electron polarization on the surfaces. Depending on the alkali–support interaction, the deposition of alkalis can selectively modify the bindings of reaction intermediates involved in CO2 hydrogenation via the interplay among the ionic, covalent and electrostatic tunings. As a result, CO2 can be effectively activated and converted into diverse products at the alkali–support interface, ranging from formic acid to methanol and ethanol. The identified selective bond-tuning advances the application of alkalis in promoting catalytic activity and controlling catalytic selectivity at alkali–support interfaces.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 9","pages":" 4164-4182"},"PeriodicalIF":40.4,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Rapid synthesis of metastable materials for electrocatalysis 用于电催化的亚稳态材料的快速合成

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-01 DOI: 10.1039/D5CS00090D

Qiao Chen, Zichao Xi, Ziyuan Xu, Minghui Ning, Huimin Yu, Yuanmiao Sun, Da-Wei Wang, Ali Sami Alnaser, Huanyu Jin and Hui-Ming Cheng

{"title":"Rapid synthesis of metastable materials for electrocatalysis","authors":"Qiao Chen, Zichao Xi, Ziyuan Xu, Minghui Ning, Huimin Yu, Yuanmiao Sun, Da-Wei Wang, Ali Sami Alnaser, Huanyu Jin and Hui-Ming Cheng","doi":"10.1039/D5CS00090D","DOIUrl":"10.1039/D5CS00090D","url":null,"abstract":"Metastable materials are considered promising electrocatalysts for clean energy conversions by virtue of their structural flexibility and tunable electronic properties. However, the exploration and synthesis of metastable electrocatalysts via traditional equilibrium methods face challenges because of the requirements of high energy and precise structural control. In this regard, the rapid synthesis method (RSM), with high energy efficiency and ultra-fast heating/cooling rates, enables the production of metastable materials under non-equilibrium conditions. However, the relationship between RSM and the properties of metastable electrocatalysts remains largely unexplored. In this review, we systematically examine the unique benefits of various RSM techniques and the mechanisms governing the formation of metastable materials. Based on these insights, we establish a framework, linking RSM with the electrocatalytic performance of metastable materials. Finally, we outline the future directions of this emerging field and highlight the importance of high-throughput approaches for the autonomous screening and synthesis of optimal electrocatalysts. This review aims to provide an in-depth understanding of metastable electrocatalysts, opening up new avenues for both fundamental research and practical applications in electrocatalysis.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 9","pages":" 4567-4616"},"PeriodicalIF":40.4,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744812","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Polysulfide chemistry in metal–sulfur batteries 金属硫电池中的多硫化学

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-01 DOI: 10.1039/D4CS00318G

Xi-Yao Li, Meng Zhao, Yun-Wei Song, Chen-Xi Bi, Zheng Li, Zi-Xian Chen, Xue-Qiang Zhang, Bo-Quan Li and Jia-Qi Huang

{"title":"Polysulfide chemistry in metal–sulfur batteries","authors":"Xi-Yao Li, Meng Zhao, Yun-Wei Song, Chen-Xi Bi, Zheng Li, Zi-Xian Chen, Xue-Qiang Zhang, Bo-Quan Li and Jia-Qi Huang","doi":"10.1039/D4CS00318G","DOIUrl":"10.1039/D4CS00318G","url":null,"abstract":"Renowned for their high theoretical energy density and cost-effectiveness, metal–sulfur (M–S) batteries are pivotal in overcoming the current energy storage bottlenecks and accelerating the transition toward a cleaner society. Polysulfides (PSs) serve as essential intermediates in M–S batteries and bridge the electrochemical redox processes of sulfur, playing a decisive role in controlling the electrode behaviors and regulating the battery performances. Understanding PS chemistry across diverse battery environments is key to advancing M–S batteries. This review aims to provide a comprehensive overview of the PS chemistry in high-energy-density battery systems and outline future research directions. The compositions, properties, and characterization methods of PSs are introduced to facilitate a fundamental understanding of the PS chemistry in working batteries. Following this, a thorough examination of the chemical and electrochemical behaviors of PSs and their impacts on electrode performances is conducted to deepen the insights into the PS reactions in batteries. Building on this foundation, representative PS regulation strategies are discussed, focusing on molecular modification, solvation optimization, and interfacial regulation, to achieve superior M–S battery performances. Challenges of PSs in practical M–S batteries are finally analyzed, and perspectives on the future research trends of PS chemistry are presented.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 10","pages":" 4822-4873"},"PeriodicalIF":40.4,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744809","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Flexible iontronic sensing 柔性离子传感

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-04-01 DOI: 10.1039/D4CS00870G

Yang Li, Ningning Bai, Yu Chang, Zhiguang Liu, Jianwen Liu, Xiaoqin Li, Wenhao Yang, Hongsen Niu, Weidong Wang, Liu Wang, Wenhao Zhu, Di Chen, Tingrui Pan, Chuan Fei Guo and Guozhen Shen

{"title":"Flexible iontronic sensing","authors":"Yang Li, Ningning Bai, Yu Chang, Zhiguang Liu, Jianwen Liu, Xiaoqin Li, Wenhao Yang, Hongsen Niu, Weidong Wang, Liu Wang, Wenhao Zhu, Di Chen, Tingrui Pan, Chuan Fei Guo and Guozhen Shen","doi":"10.1039/D4CS00870G","DOIUrl":"10.1039/D4CS00870G","url":null,"abstract":"The emerging flexible iontronic sensing (FITS) technology has introduced a novel modality for tactile perception, mimicking the topological structure of human skin while providing a viable strategy for seamless integration with biological systems. With research progress, FITS has evolved from focusing on performance optimization and structural enhancement to a new phase of integration and intelligence, positioning it as a promising candidate for next-generation wearable devices. Therefore, a review from the perspective of technological development trends is essential to fully understand the current state and future potential of FITS devices. In this review, we examine the latest advancements in FITS. We begin by examining the sensing mechanisms of FITS, summarizing research progress in material selection, structural design, and the fabrication of active and electrode layers, while also analysing the challenges and bottlenecks faced by different segments in this field. Next, integrated systems based on FITS devices are reviewed, highlighting their applications in human–machine interaction, healthcare, and environmental monitoring. Additionally, the integration of artificial intelligence into FITS is explored, focusing on optimizing front-end device design and improving the processing and utilization of back-end data. Finally, building on existing research, future challenges for FITS devices are identified and potential solutions are proposed.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 10","pages":" 4651-4700"},"PeriodicalIF":40.4,"publicationDate":"2025-04-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143744811","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Gains and losses in zinc-ion batteries by proton- and water-assisted reactions 锌离子电池在质子和水辅助反应中的得失

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-31 DOI: 10.1039/D4CS00810C

Yauhen Aniskevich and Seung-Taek Myung

引用次数: 0

Algorithm in chemistry: molecular logic gate-based data protection 化学算法：基于分子逻辑门的数据保护

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-31 DOI: 10.1039/D4CS01104J

Yu Dong, Shiyu Feng, Weiguo Huang and Xiang Ma

{"title":"Algorithm in chemistry: molecular logic gate-based data protection","authors":"Yu Dong, Shiyu Feng, Weiguo Huang and Xiang Ma","doi":"10.1039/D4CS01104J","DOIUrl":"10.1039/D4CS01104J","url":null,"abstract":"Data security is crucial for safeguarding the integrity, authenticity, and confidentiality of documents, currency, merchant labels, and other paper-based assets, which sequentially has a profound impact on personal privacy and even national security. High-security-level logic data protection paradigms are typically limited to software (digital circuits) and rarely applied to physical devices using stimuli-responsive materials (SRMs). The main reason is that most SRMs lack programmable and controllable switching behaviors. Traditional SRMs usually produce static, singular, and highly predictable signals in response to stimuli, restricting them to simple “BUFFER” or “INVERT” logic operations with a low security level. However, recent advancements in SRMs have collectively enabled dynamic, multidimensional, and less predictable output signals under external stimuli. This breakthrough paves the way for sophisticated encryption and anti-counterfeiting hardware based on SRMs with complicated logic operations and algorithms. This review focuses on SRM-based data protection, emphasizing the integration of intricate logic and algorithms in SRM-constructed hardware, rather than chemical or material structural evolutions. It also discusses current challenges and explores the future directions of the field—such as combining SRMs with artificial intelligence (AI). This review fills a gap in the existing literature and represents a pioneering step into the uncharted territory of SRM-based encryption and anti-counterfeiting technologies.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 8","pages":" 3681-3735"},"PeriodicalIF":40.4,"publicationDate":"2025-03-31","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143736668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Protein-derived cofactors: chemical innovations expanding enzyme catalysis 蛋白质衍生的辅助因子：扩大酶催化的化学创新

IF 40.4 1区化学

Chemical Society Reviews Pub Date : 2025-03-28 DOI: 10.1039/D4CS00981A

Angelica Graciano and Aimin Liu

{"title":"Protein-derived cofactors: chemical innovations expanding enzyme catalysis","authors":"Angelica Graciano and Aimin Liu","doi":"10.1039/D4CS00981A","DOIUrl":"10.1039/D4CS00981A","url":null,"abstract":"Protein-derived cofactors, formed through posttranslational modification of a single amino acid or covalent crosslinking of amino acid side chains, represent a rapidly expanding class of catalytic moieties that redefine enzyme functionality. Once considered rare, these cofactors are recognized across all domains of life, with their repertoire growing from 17 to 38 types in two decades in our survey. Their biosynthesis proceeds via diverse pathways, including oxidation, metal-assisted rearrangements, and enzymatic modifications, yielding intricate motifs that underpin distinctive catalytic strategies. These cofactors span paramagnetic and non-radical states, including both mono-radical and crosslinked radical forms, sometimes accompanied by additional modifications. While their discovery has accelerated, mechanistic understanding lags, as conventional mutagenesis disrupts cofactor assembly. Emerging approaches, such as site-specific incorporation of non-canonical amino acids, now enable precise interrogation of cofactor biogenesis and function, offering a viable and increasingly rigorous means to gain mechanistic insights. Beyond redox chemistry and electron transfer, these cofactors confer enzymes with expanded functionalities. Recent studies have unveiled new paradigms, such as long-range remote catalysis and redox-regulated crosslinks as molecular switches. Advances in structural biology, mass spectrometry, and biophysical spectroscopy continue to elucidate their mechanisms. Moreover, synthetic biology and biomimetic chemistry are increasingly leveraging these natural designs to engineer enzyme-inspired catalysts. This review integrates recent advances in cofactor biogenesis, reactivity, metabolic regulation, and synthetic applications, highlighting the expanding chemical landscape and growing diversity of protein-derived cofactors and their far-reaching implications for enzymology, biocatalysis, and biotechnology.","PeriodicalId":68,"journal":{"name":"Chemical Society Reviews","volume":" 9","pages":" 4502-4530"},"PeriodicalIF":40.4,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://pubs.rsc.org/en/content/articlepdf/2025/cs/d4cs00981a?page=search","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143723349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":1,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0