Dynamic evolution of metal structures on/in zeolites for catalysis.

Abstract

Dynamic changes of metal species always occur during catalysis, and primarily rely on forming mobile metal species initiated by thermal or chemical conditions. During these processes, a support is important in affecting the catalyst stability and dynamic change pathways. Among several supports, zeolites provide ideal features for regulating the migration of metal species due to their unique pore structures and specific defect sites. This review provides a comprehensive summary of typical cases about dynamic migration of metal species on/in metal-zeolite catalysts, analyzing the mechanisms and driving factors of metal migration under different reaction conditions. We discuss the roles of zeolite supports in the migration process of metal species, particularly their crucial contributions to the stability of metal species and the optimization of active sites. In addition, the potential mechanism of the dynamic migration of metal species, theoretical studies, and practical guidance for designing highly efficient catalysts are also included in this review.