Journal of the Australian Ceramic Society最新文献

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Preparation of Pt-doped hydroxyapatite via wet co-precipitation method 通过湿法共沉淀制备掺铂羟基磷灰石
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-05-09 DOI: 10.1007/s41779-024-01023-9
S. Attar Nosrati, M. R. Aboudzadeh, M. Amiri, M. Salahinejad
{"title":"Preparation of Pt-doped hydroxyapatite via wet co-precipitation method","authors":"S. Attar Nosrati,&nbsp;M. R. Aboudzadeh,&nbsp;M. Amiri,&nbsp;M. Salahinejad","doi":"10.1007/s41779-024-01023-9","DOIUrl":"10.1007/s41779-024-01023-9","url":null,"abstract":"<div><p>Doping of Hydroxyapatite (HA) with foreign ions is known as a chemical approach to improve its physicochemical characteristics and expand its biomedical applications. In the current paper, Pt-doped HA (Pt-HA) was synthesized by the co-precipitation method, and the product was characterized using conventional techniques. The XRD analysis results show that the as-synthesized Pt-HA powder exhibits apatite characteristics with lower degrees of crystallinity compared to pure hydroxyapatite, and no new phase or impurity is found. The SEM observations suggest the plate-shaped particles with homogeneous surfaces in which doping of hydroxyapatite with Pt ions led to a decrease in the length of HA particles. The EDS analysis highlighted the purity of the samples and confirmed the presence of Ca, P, O, and Pt elements in the Pt-HA sample. FTIR spectroscopy revealed the presence of the various vibrational modes corresponding to PO<sub>4</sub><sup>3−</sup>, OH<sup>−</sup> and CO<sub>3</sub><sup>2−</sup> functional groups. The mean particle size measurement of the as-prepared HA and Pt-HA samples, using the dynamic Light Scattering (DLS) analysis confirmed a decrease in particle size in the Pt-doped HA sample compared to pure HA. TGA results indicated that the prepared Pt-doped HA sample has good thermal stability.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 3","pages":"791 - 797"},"PeriodicalIF":1.8,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140928706","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Calcination-free crystallization of rare earth double tungstate Na(La1 − xEux)(WO4)2 by sacrificial-template hydrothermal reaction, restrained concentration quenching, and optical thermometry 通过牺牲模板水热反应、抑制浓度淬灭和光学测温,实现稀土双钨酸盐 Na(La1 - xEux)(WO4)2 的无煅烧结晶
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-05-09 DOI: 10.1007/s41779-024-01022-w
Changshuai Gong, Jiantong Wang, Bowen Wang, Meng Sun, Xuejiao Wang
{"title":"Calcination-free crystallization of rare earth double tungstate Na(La1 − xEux)(WO4)2 by sacrificial-template hydrothermal reaction, restrained concentration quenching, and optical thermometry","authors":"Changshuai Gong,&nbsp;Jiantong Wang,&nbsp;Bowen Wang,&nbsp;Meng Sun,&nbsp;Xuejiao Wang","doi":"10.1007/s41779-024-01022-w","DOIUrl":"10.1007/s41779-024-01022-w","url":null,"abstract":"<div><p>A series of Na(La<sub>1 − <i>x</i></sub>Eu<sub><i>x</i></sub>)(WO<sub>4</sub>)<sub>2</sub> (NLW) phosphors were directly generated without calcination and organic additive <i>via</i> reaction of the (La<sub>1 − <i>x</i></sub>Eu<sub><i>x</i></sub>)(OH)SO<sub>4</sub> template with Na<sub>2</sub>WO<sub>4</sub> by hydrothermal reaction. The XRD results show that pure Na(La<sub>1 − <i>x</i></sub>Eu<sub><i>x</i></sub>)(WO<sub>4</sub>)<sub>2</sub> can be obtained by the reaction at 150 °C for 24 h or at 200 °C for 2 h under the molar ratio of WO<sub>4</sub><sup>2−</sup>/ Ln<sup>3+</sup> = 5. The NaLa(WO<sub>4</sub>)<sub>2</sub> has a tetragonal structure in <i>I</i>4<sub>1</sub><i>/a</i> space group, and has lattice parameters of a = b = 5.332 Å, c = 11.731 Å. The FT-IR results show that the SO<sub>4</sub><sup>2−</sup> and hydroxyl vibrations of the template were hardly observed in the product and confirmed that phase conversion is complete. The UV-vis analysis yield bandgap values of 4.07 and 3.94 eV for NaLa(WO<sub>4</sub>)<sub>2</sub> and Na(La<sub>0.95</sub>Eu<sub>0.05</sub>)(WO<sub>4</sub>)<sub>2</sub> respectively. Photoluminescence excitation (PLE) studies found two distinct strong excitation peaks at ~ 395 nm and ~ 465 nm, with the former slightly stronger and both significantly stronger than other excitation peaks/bands. Under 395 nm excitation, the phosphors exhibited the strongest red emission at 614 nm (<sup>5</sup>D<sub>0</sub>→<sup>7</sup>F<sub>2</sub> transition of Eu<sup>3+</sup>). The optimal Eu<sup>3+</sup> concentration was found to be as high as 25% due to the layered structure of NLW phosphor and well isolated Eu<sup>3+</sup> activator by [WO<sub>4</sub>] polyhedron. An evaluation and comparison with other phosphors were conducted to assess the performance of optical temperature sensing. It was discovered that the NLW phosphor cannot be employed as a probe for optical thermometry <i>via</i> fluorescence intensity ratio (FIR) mode due to similar intensity loss rates with increasing temperatures for different emission peaks. The NLW was demonstrated to be well capable of temperature sensing <i>via</i> fluorescence lifetime (FL) mode. Fluorescence decay analysis found that higher measurement temperature shortened the lifetime of the 614 nm main emission, and the lifetime decreased in liner mode. The maximum absolute sensitivity (<i>S</i><sub><i>A</i></sub>) and relative sensitivity (<i>S</i><sub><i>R</i></sub>) are 43.0 × 10<sup>− 4</sup> K<sup>− 1</sup> (298–498 K) and 144 × 10<sup>− 4</sup> K<sup>− 1</sup>(498 K), respectively.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1209 - 1218"},"PeriodicalIF":1.8,"publicationDate":"2024-05-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140928864","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microstructural, mechanical and tribological characteristics of reduced graphene oxide (rGO) reinforced nanostructured Al2O3-13wt. %TiO2 coatings 还原氧化石墨烯 (rGO) 增强纳米结构 Al2O3-13wt.
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-05-01 DOI: 10.1007/s41779-024-01027-5
Akella Srikanth, Venkateshwarlu Bolleddu
{"title":"Microstructural, mechanical and tribological characteristics of reduced graphene oxide (rGO) reinforced nanostructured Al2O3-13wt. %TiO2 coatings","authors":"Akella Srikanth,&nbsp;Venkateshwarlu Bolleddu","doi":"10.1007/s41779-024-01027-5","DOIUrl":"10.1007/s41779-024-01027-5","url":null,"abstract":"<div><p>Al<sub>2</sub>O<sub>3</sub>-13wt. %TiO<sub>2</sub> is a widely used coating material for the protection of metallic surfaces. The reduced graphene oxide (rGO) added alumina-titania composite coatings deposited using Air Plasma Spraying (APS) are used for enhancing the wear resistance of engineering components. In this work, the addition of rGO at varying weight percentages of 0.5, 1, and 1.5% to the Al<sub>2</sub>O<sub>3</sub>-13wt.%TiO<sub>2</sub> powder resulted in composite coatings with improved microstructural characteristics, mechanical properties, and tribological performance. The use of SEM and XRD analyses revealed the presence of rGO between the coating splats, offering protection from crack initiation. Furthermore, there were noticeable changes in the microhardness and surface roughness of the coatings. Coatings reinforced with higher weight percentages of rGO had extremely low wear rates and offered a low coefficient of friction, with unpulled rGO acting as protective layers. However, it was also observed that the wear of coatings with 0.5 wt% and 1.0 wt% rGO addition was mainly due to the delimitation and subsequent pulverization at 1.5 kgf load and 0.17 m/s sliding speed. Overall, this work provides valuable insights into the use of composite coatings for enhancing the wear resistance of surfaces of components.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1237 - 1248"},"PeriodicalIF":1.8,"publicationDate":"2024-05-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140833663","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of Ba(Zr,Ti)2O5 particles using Zr/Ti-HPA with complexing of Ti-IPA and Zr using ZrOCl2 利用 ZrOCl2 与 Ti-IPA 和 Zr 复配,使用 Zr/Ti-HPA 合成 Ba(Zr,Ti)2O5 颗粒
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-27 DOI: 10.1007/s41779-024-01026-6
Hidetoshi Miyazaki, Hayato Masuda, Takeshi Kubota, Shinya Tsukada
{"title":"Synthesis of Ba(Zr,Ti)2O5 particles using Zr/Ti-HPA with complexing of Ti-IPA and Zr using ZrOCl2","authors":"Hidetoshi Miyazaki,&nbsp;Hayato Masuda,&nbsp;Takeshi Kubota,&nbsp;Shinya Tsukada","doi":"10.1007/s41779-024-01026-6","DOIUrl":"10.1007/s41779-024-01026-6","url":null,"abstract":"<div><p>For this study, Zr-substituted BaTi<sub>2</sub>O<sub>5</sub> particles were synthesized using an aqueous solution method with peroxidized polytitanic acid as the starting material. After Zr/Ti heteropolyacids were synthesized by complexing Zr with polytitanic acid (Ti-IPA) in aqueous solution using ZrOCl<sub>2</sub>, the obtained Zr/Ti heteropolyacids were mixed with barium hydroxide. Subsequently, the precipitate was dried and heat-treated at 1100 °C for 10 h. Thereby, we obtained single-phase Ba(Zr,Ti)<sub>2</sub>O<sub>5</sub> powder. Using this method, BaTi<sub>2</sub>O<sub>5</sub> was synthesized with up to 6 mol% Zr solid solution on Ti sites. These results were evaluated using XRD and XRF. The crystal structure and structural transition of the resulting Ba(Zr,Ti)<sub>2</sub>O<sub>5</sub> were evaluated using Raman measurements. All Ba(Zr,Ti)<sub>2</sub>O<sub>5</sub> samples showed a structural transition. The Curie temperatures <i>T</i><sub>c</sub> of BaTi<sub>2</sub>O<sub>5</sub>, BaZr<sub>0.034</sub>Ti<sub>0.966</sub>O<sub>5</sub>, and BaZr<sub>0.059</sub>Ti<sub>0.941</sub>O<sub>5</sub> were, respectively, 480, 450, and 430 °C.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1233 - 1236"},"PeriodicalIF":1.8,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140812209","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pore size influence in fabricating DCPD-Coated Porous β-TCP granules: compositional, morphological, and functional group perspective 制造 DCPD 涂层多孔 β-TCP 颗粒时孔径的影响:成分、形态和官能团视角
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-27 DOI: 10.1007/s41779-024-01029-3
Ahmed Hafedh Mohammed Mohammed, Khairul Anuar Shariff, Mohamad Hafizi Abu Bakar, Hasmaliza Mohamad, Kunio Ishikawa, Aira Matsugaki, Takayoshi Nakano
{"title":"Pore size influence in fabricating DCPD-Coated Porous β-TCP granules: compositional, morphological, and functional group perspective","authors":"Ahmed Hafedh Mohammed Mohammed,&nbsp;Khairul Anuar Shariff,&nbsp;Mohamad Hafizi Abu Bakar,&nbsp;Hasmaliza Mohamad,&nbsp;Kunio Ishikawa,&nbsp;Aira Matsugaki,&nbsp;Takayoshi Nakano","doi":"10.1007/s41779-024-01029-3","DOIUrl":"10.1007/s41779-024-01029-3","url":null,"abstract":"<div><p>This study aims to understand the influence of pore size on the compositional, morphological, and functional group characteristics of dicalcium phosphate dihydrate (DCPD)-coated porous β-tricalcium phosphate (β-TCP) granules. This study produced 300–600 μm granular sizes of porous β-TCP granules with various pore diameters. This was achieved by combining dry powders of DCPD and calcium carbonate (CaCO<sub>3</sub>) [Ca/P ratio: 1.5] with varied quantities of 10%, 20%, 30%, and 40% of sodium chloride (NaCl) powders to obtain mixtures composed of weight percentages (wt%) ratios of 90:10, 80:20, 70:30, and 60:40, respectively. Post-sintering, the porous β-TCP granules fabricated were soaked in an acidic calcium phosphate solution for 30 min to coat the surfaces with DCPD crystals formation via a dissolution-precipitation reaction. Subsequently, the specimens were examined with scanning electron microscopy (SEM), X-ray diffraction (XRD), and Fourier-transform infrared (FTIR). The morphological observations demonstrated that increasing NaCl powder up to 40% with a mixture of CaCO<sub>3</sub> and DCPD enhanced the β-TCP granules' pore size. Furthermore, The formation of DCPD on and inside the porous β-TCP granules has been accelerated due to the presence of large pores. Conversely, dissolution-precipitation reactions were incomplete on granules with 2.8, 4.9, and 6.91 μm pore sizes. The major XRD peaks of the DCPD and β-TCP phases with 2.8, 4.9, and 6.91 μm pores were also slightly shifted to the right, while granules with 7.53 μm pores demonstrated DCPD and β-TCP peaks aligned with pure β-TCP and DCPD phases. This study's findings are expected to offer insight into the role of pore size in influencing the dissolution-precipitation process that affects the morphological, compositional, and functional group characteristics of DCPD-coated β-TCP granules.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 3","pages":"859 - 870"},"PeriodicalIF":1.8,"publicationDate":"2024-04-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140812350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Wetting and corrosion behavior of V– and Ti–containing slag on oxidation layer of MgO–C refractory 含 V 和 Ti- 的熔渣在 MgO-C 耐火材料氧化层上的润湿和腐蚀行为
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-23 DOI: 10.1007/s41779-024-01025-7
Zhaoyang Liu, Songyang Pan, Ruinan Zhang, Yuqing Gao, Wei Gao, Xiangnan Wang, Shan Wei, Tianpeng Wen, Beiyue Ma, Jingkun Yu
{"title":"Wetting and corrosion behavior of V– and Ti–containing slag on oxidation layer of MgO–C refractory","authors":"Zhaoyang Liu,&nbsp;Songyang Pan,&nbsp;Ruinan Zhang,&nbsp;Yuqing Gao,&nbsp;Wei Gao,&nbsp;Xiangnan Wang,&nbsp;Shan Wei,&nbsp;Tianpeng Wen,&nbsp;Beiyue Ma,&nbsp;Jingkun Yu","doi":"10.1007/s41779-024-01025-7","DOIUrl":"10.1007/s41779-024-01025-7","url":null,"abstract":"<div><p>In this study, the wetting and corrosion behavior of slags containing vanadium (V) and titanium (Ti) on the oxidized surface of MgO–C refractory (MO), were investigated. The microstructures and phase compositions were analysed at the interface between the slag and MO substrates, alongside an examination of the corrosion mechanism. The findings unveiled that adding V<sub>2</sub>O<sub>3</sub> and TiO<sub>2</sub>, whether individually or in tandem, reduced the slag’s melting point and the contact angle between the slag and MO substrate. The molten slags mainly penetrated the MO substrates through pores, cracks, and grain boundaries, forming silicate, and vanadate phases at the slag–MO interface. In particular, the V–containing slag demonstrated stronger susceptibility to corrode the MO substrate due to the capacity of V to form low–melting point phases with MgO. This led to deeper penetration and a larger corroded area within the substrate. These findings offer valuable insights for the design and optimization of slags containing V and Ti and MgO–C refractory materials in metallurgical processes.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 3","pages":"777 - 789"},"PeriodicalIF":1.8,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140636936","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessment of mechanical performance of Al2O3 ceramic honeycomb sandwich structures produced with SLA 3D-printing regarding unpolymerized slurry removal strategy 评估采用 SLA 3D 打印技术生产的 Al2O3 陶瓷蜂窝夹层结构的机械性能(未聚合浆料去除策略
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-23 DOI: 10.1007/s41779-024-01021-x
Betül Kafkaslıoğlu Yıldız
{"title":"Assessment of mechanical performance of Al2O3 ceramic honeycomb sandwich structures produced with SLA 3D-printing regarding unpolymerized slurry removal strategy","authors":"Betül Kafkaslıoğlu Yıldız","doi":"10.1007/s41779-024-01021-x","DOIUrl":"10.1007/s41779-024-01021-x","url":null,"abstract":"<div><p>Al<sub>2</sub>O<sub>3</sub> ceramic honeycomb sandwich bars with a hexagonal core were manufactured through SLA 3D-printing to analyze the impact of hole placement, designed for the removal of uncured slurry, on the bending strength of the samples. Several holes were placed specifically on the samples in the design in two different ways. In the initial design, the holes were placed on the honeycomb sandwich structure’s upper and lower face-sheets. In the second design, the holes were positioned in the direction of the sample thickness, in the lateral walls. The moment of inertia values for the honeycomb structures were calculated with the help of experimental elastic modulus results, and true bending strength was determined according to these results. Nominal strength values were found using the common three-point bending formula. The true bending strength value of Al<sub>2</sub>O<sub>3</sub> with lateral holes was 73% higher than Al<sub>2</sub>O<sub>3</sub> with holes on face-sheets, while the nominal bending strength was 79% higher. Al<sub>2</sub>O<sub>3</sub> samples with holes on face-sheets exhibited a significantly higher failure index compared with both the bulk samples and the Al<sub>2</sub>O<sub>3</sub> samples with lateral holes. The holes on the face-sheets reduced the cross-sectional area of the tensile surface and contributed to an increase in stresses due to the stress concentration effect. The Al<sub>2</sub>O<sub>3</sub> samples with lateral holes provided a great advantage of specific strength, reaching an average value of 65% above the specific strength of the bulk samples.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1199 - 1208"},"PeriodicalIF":1.8,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s41779-024-01021-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140665993","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Investigating La2O3-enriched glass compositions: thermal, optical, structural properties and Gamma-Ray shielding efficiency 研究富含 La2O3 的玻璃成分:热学、光学、结构特性和伽马射线屏蔽效率
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-19 DOI: 10.1007/s41779-024-01017-7
Hosam M. Gomaa, H. A. Saudi, A. S. Algendy, Nouf. Almousa, M. I. Sayyed
{"title":"Investigating La2O3-enriched glass compositions: thermal, optical, structural properties and Gamma-Ray shielding efficiency","authors":"Hosam M. Gomaa,&nbsp;H. A. Saudi,&nbsp;A. S. Algendy,&nbsp;Nouf. Almousa,&nbsp;M. I. Sayyed","doi":"10.1007/s41779-024-01017-7","DOIUrl":"10.1007/s41779-024-01017-7","url":null,"abstract":"<div><p>This study involves the investigation of the effect of the replacement of B<sub>2</sub>O<sub>3</sub> with La<sub>2</sub>O<sub>3</sub> on the properties of the multi-component lead Borovanadate glass. Five samples were prepared using the fast-quenching method according to the chemical formula (43-x) mole % B<sub>2</sub>O<sub>3</sub> - x mole % La<sub>2</sub>O<sub>3</sub>- 10 mol % V<sub>2</sub>O<sub>5</sub>-12.5 mol % CaO-12.5 mol % Li<sub>2</sub>O -22 mol %PbO, where x = 0, 1, 2, 3, and 5 mol %. The amorphous character of the synthesized samples was confirmed via Fourier transform infrared and X-ray diffraction. XRD patterns suggest a lack of long-range organized crystalline structure, but FTIR reveals various structural unit blocks. On the other side, the increment of La<sub>2</sub>O<sub>3</sub> content caused a proportional increase in the glasses’ bulk density and molar volume. UV analysis revealed that the sample with 5 mol % La<sub>2</sub>O<sub>3</sub> had superior absorption properties compared to the other samples. All the samples were found to be effective in transmitting light within the energy range of 3.43–4.07 eV, with the La<sub>2</sub>O<sub>3</sub>-free sample demonstrating the highest level of light transmission among all the samples. The radiation shielding characteristics of the synthesized glasses were analyzed. The theoretical predictions for the mass attenuation coefficients using WinXCom agreed well with the measured values, providing validation for both the software and the experimental techniques used. This investigation found that La<sub>2</sub>O<sub>3</sub> concentration influenced the linear attenuation coefficient (LAC) at a defined energy level, with higher La<sub>2</sub>O<sub>3</sub> resulting in higher LAC values. The study also showed that lower energy levels had better linear attenuation compared to higher ones.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1121 - 1130"},"PeriodicalIF":1.8,"publicationDate":"2024-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140628421","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structure-property relationship and emerging applications of nano- and micro-sized fillers reinforced sialon composites: a review 纳米和微米级填料增强硅铝龙复合材料的结构-性能关系及新兴应用综述
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-19 DOI: 10.1007/s41779-024-01020-y
Olugbenga Ogunbiyi, Tamba Jamiru, Gbolahan Joseph Adekoya, Azeez Lawan Rominiyi
{"title":"Structure-property relationship and emerging applications of nano- and micro-sized fillers reinforced sialon composites: a review","authors":"Olugbenga Ogunbiyi,&nbsp;Tamba Jamiru,&nbsp;Gbolahan Joseph Adekoya,&nbsp;Azeez Lawan Rominiyi","doi":"10.1007/s41779-024-01020-y","DOIUrl":"10.1007/s41779-024-01020-y","url":null,"abstract":"<div><p>Oxonitridoaluminosilicates (SiAlON) are renowned in advanced ceramics for their exceptional properties: high temperature stability, excellent oxidation resistance, and good wear resistance. Incorporating micro- and nano-sized fillers into SiAlON matrices enhances their properties, yielding SiAlON composite materials with superior mechanical, tribological, and thermal characteristics. This review examines fabrication techniques for producing SiAlON micro/nanocomposites and the structure-property relationships governing their performance across different phase compositions (β, α, X, and O-phases). A comprehensive literature review scrutinized fabrication techniques and structure-property relationships from various databases and scholarly articles. Although SiAlON composites with micro/nano inclusions hold promise across applications, understanding their fabrication processes, structure-property relationships, and potential applications in different fields is crucial. The review highlights diverse fabrication techniques for SiAlON micro/nanocomposites and provides insights into their structure-property relationships. Additionally, emerging applications in structural domains, cutting tools, coatings, corrosion protection, solar cells, LEDs, biomedical realms, and filtration membranes are discussed. This review is a valuable resource for researchers and engineers interested in designing SiAlON products tailored for sophisticated applications. It emphasizes understanding fabrication processes and structure-property relationships to unlock SiAlON-based materials' full potential across industries.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 4","pages":"1167 - 1198"},"PeriodicalIF":1.8,"publicationDate":"2024-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s41779-024-01020-y.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140628415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Combustion synthesis of porous β-SiAlON from aluminum ferrosilicon and aluminosilicate hollow microspheres 利用铝硅铁和硅酸铝空心微球燃烧合成多孔 β-SiAlON
IF 1.8 4区 材料科学
Journal of the Australian Ceramic Society Pub Date : 2024-04-19 DOI: 10.1007/s41779-024-01015-9
Anton Reger, Konstantin Bolgaru, Alexander Akulinkin, Pavel Vashurkin, Anna Nevmyvaka, Lidiya Skvortsova
{"title":"Combustion synthesis of porous β-SiAlON from aluminum ferrosilicon and aluminosilicate hollow microspheres","authors":"Anton Reger,&nbsp;Konstantin Bolgaru,&nbsp;Alexander Akulinkin,&nbsp;Pavel Vashurkin,&nbsp;Anna Nevmyvaka,&nbsp;Lidiya Skvortsova","doi":"10.1007/s41779-024-01015-9","DOIUrl":"10.1007/s41779-024-01015-9","url":null,"abstract":"<div><p>SiAlON ceramics is a unique material used in various applications. Producing porous SiAlON material from available industrial waste by combustion is of great interest. In this work, a porous SiAlON composite was synthesized by the combustion of a mixture of aluminum ferrosilicon powder and aluminosilicate hollow microspheres in nitrogen. Aluminosilicate hollow microspheres were used as a pore-forming agent. The addition of aluminosilicate hollow microspheres to aluminum ferrosilicon powder increased the total porosity from 34.1 to 90.3%, the open porosity from 16.4 to 88.2%, and the maximum pore size from 53 to 413 μm in the final product. The porosity of the synthesized samples was predominantly open.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"60 3","pages":"849 - 857"},"PeriodicalIF":1.8,"publicationDate":"2024-04-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140628710","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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