{"title":"Synthesis of cerium dioxide-based pigments with co-precipitated phosphate: tuning oxidation catalytic activity for cosmetic and paint applications","authors":"Hiroaki Onoda, Kazuto Yamaoka, Thitirat Charoonsuk, Phieraya Pulphol, Naratip Vittayakorn","doi":"10.1007/s41779-025-01190-3","DOIUrl":"10.1007/s41779-025-01190-3","url":null,"abstract":"<div><p>Cerium oxide, a popular ultraviolet screening agent in cosmetics, is hindered by its oxidation catalytic activity. Seeking an alternative to cerium phosphate, which increases particle size but lacks catalytic activity, we synthesized a novel cerium hydroxide-cerium oxide pigment by coprecipitating a small amount of phosphate. We chose a baseline Ce/P ratio of 10:1 based on preliminary tests showing that a moderate level of phosphate effectively reduces oxidation catalytic activity while still preserving key cerium oxide characteristics. We evaluated its composition, particle size, oxidation catalyst activity, and hue. Coprecipitation and subsequent heating yielded a yellowish pigment containing both cerium oxide and cerium phosphate. Compared to cerium oxide, our pigment exhibited superior smoothness. Additionally, samples prepared under low pH or high phosphate ratios demonstrated reduced oxidation catalytic activity. However, when applied as a pigment in oil paints, its hiding power was diminished. Our findings highlight a promising strategy for mitigating the catalytic drawbacks of cerium oxide while improving pigment properties, yet caution is warranted regarding its efficacy in paint applications. This study underscores the potential of cerium-based compounds in diverse fields, with room for optimization in specific applications. This study underscores the potential of systematically tuning cerium-based compounds for a range of applications, including cosmetics and paints, by exploring how pH and Ce/P ratio influence catalytic activity, coloration, and particle properties.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1537 - 1544"},"PeriodicalIF":2.1,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929363","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Laser cladded Co08–xNi60WC coatings","authors":"Yuan Ge, Rui Shi, Dejun Kong","doi":"10.1007/s41779-025-01187-y","DOIUrl":"10.1007/s41779-025-01187-y","url":null,"abstract":"<div><p>The tribocorrosion and electrochemical performances of laser cladded Co08 coating in 3.5% NaCl solution was improved by the addition of Ni60WC, which were carried out using a reciprocating wear tester and an electrochemical workstation. The results show that the Co08–xNi60WC coatings are composed of Co(Ni, Cr, W, Mo), Ni60WC, W<sub>2</sub>C and WC phases, and their hardness is increased by the addition of Ni60WC. The coefficients of friction and wear rates of Co–xNi60WC coatings are decreased with the Ni60WC mass fraction, and the wear form is changed from fatigue wear to oxidation wear and adhesion wear, indicating that the wear resistance is enhanced by the addition of WC. The charge transfer resistance <i>R</i><sub>ct</sub> of Co08–xNi60WC coatings is increased with the Ni60WC mass fraction, and the corresponding <i>n</i><sub>ct</sub> is also increased, showing that the Co08–30%Ni60WC has the best corrosion resistance among the three kinds of coatings.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1503 - 1513"},"PeriodicalIF":2.1,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929375","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Shih-Ching Wu, Hsueh-Chuan Hsu, Lin-Chieh Ou, Wen-Fu Ho
{"title":"Effects of hydrothermal temperature on the synthesis and characterization of bioactive hydroxyapatite nanoparticles from oyster shell","authors":"Shih-Ching Wu, Hsueh-Chuan Hsu, Lin-Chieh Ou, Wen-Fu Ho","doi":"10.1007/s41779-025-01189-w","DOIUrl":"10.1007/s41779-025-01189-w","url":null,"abstract":"<div><p>Hydroxyapatite (HA), a primary inorganic component of human bone, is highly regarded for its biocompatibility and osteoconductivity, making it an ideal material for orthopedic and dental applications. In this study, HA powders were synthesized using waste oyster shells as a calcium source via a hydrothermal reaction at temperatures ranging from 100 to 200 °C. The influence of these temperatures on the morphology, particle size, and crystallinity of the synthesized products was examined. The crystallinity of the HA increased from approximately 22% for the room-temperature precipitation method to 38%–64% for the hydrothermal method, reflecting enhanced crystallinity with increasing temperature. X-ray diffraction (XRD) confirmed that the product was a pure HA phase, with no residual raw materials. Scanning electron microscopy (SEM) revealed that the HA particles synthesized hydrothermally were larger than those obtained by precipitation, with lengths ranging from 165 to 212 nm, widths from 26 to 41 nm, and aspect ratios between 5.2 and 6.3, compared to precipitation method particles which had lengths of 156 nm, widths of 24 nm, and an average aspect ratio of 6.7. Energy-dispersive X-ray spectroscopy (EDS) analysis indicated that the Ca/P ratios of the HA synthesized through hydrothermal synthesis ranged from 1.94 to 2.12, suggesting a Ca-rich structure. After immersion in simulated body fluid (SBF), needle-like apatite deposits were observed on the HA surface, demonstrating good bioactivity. Furthermore, osteoblast culture experiments confirmed the HA’s non-toxic nature, with the cells showing excellent attachment and growth. These findings highlight the potential of HA synthesized from waste oyster shells for bone regeneration and dental applications.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1525 - 1536"},"PeriodicalIF":2.1,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929376","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Magda L. G. Leite, Claudia P. Marin-Abadia, Daniela X. Lopes, Murilo C. Crovace, Oscar Peitl, Edgar D. Zanotto
{"title":"Prospecting potential nucleating agents for Biosilicate® parent glass","authors":"Magda L. G. Leite, Claudia P. Marin-Abadia, Daniela X. Lopes, Murilo C. Crovace, Oscar Peitl, Edgar D. Zanotto","doi":"10.1007/s41779-025-01186-z","DOIUrl":"10.1007/s41779-025-01186-z","url":null,"abstract":"<div><p>Biosilicate<sup>®</sup> is a strong, highly bioactive, bactericidal, machinable, (almost) fully crystalline glass–ceramic that has been successfully used in several in vivo and clinical trials. However, there is still scope to optimize its crystallization ability, resulting microstructure and properties. Here we tested 13 compounds, from which we choose six for more detailed screening (2% ZrO<sub>2</sub>, 6% Fe<sub>2</sub>O<sub>3</sub>, 3% WO<sub>3</sub>, 4% NaF, 3 and 20% TiO<sub>2</sub>, 2, 4 and 8% Li<sub>2</sub>O, and 4% TiO2 + 3% ZrO2, in wt.%) as potential nucleating agents. We used DSC analyses to estimate their tendency to boost internal nucleation. For some compositions, we also used optical microscopy. XRD was used to evaluate the crystalline phase, most of these modified BIOS glasses showed combeite as the main phase. To evaluate whether one of the key components of the formula, P<sub>2</sub>O<sub>5</sub>, significantly affects the nucleation process, a particular composition (25.97Na<sub>2</sub>O-24.23CaO-49.8SiO<sub>2</sub>, wt.%), named SS, had its P<sub>2</sub>O<sub>5</sub> content replaced by Li<sub>2</sub>O and Fe<sub>2</sub>O<sub>3</sub>. Among the additives tested, Li<sub>2</sub>O significantly increased the internal nucleation rate. This study confirmed that DSC is a practical, fast tool to assess the suitability of prospective nucleating agents, and revealed a new, unexpected, nucleating agent (Li<sub>2</sub>O) for this bioactive glass family.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 2","pages":"393 - 407"},"PeriodicalIF":1.8,"publicationDate":"2025-03-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892613","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
N. P. Bhagya, Srilatha Rao, G. K. Prashanth, A. S. Sowmyashree, Smitha Shree S, H. S. Lalithamba, S. R. Yashodha, Manoj Gadewar
{"title":"Exploring the multifaceted potential of ZrO2 nanoparticles: sustainable synthesis, anticancer properties, and electrochemical insight","authors":"N. P. Bhagya, Srilatha Rao, G. K. Prashanth, A. S. Sowmyashree, Smitha Shree S, H. S. Lalithamba, S. R. Yashodha, Manoj Gadewar","doi":"10.1007/s41779-025-01177-0","DOIUrl":"10.1007/s41779-025-01177-0","url":null,"abstract":"<div><p>This work presents a comprehensive investigation into the sustainable synthesis and extensive characterization of zirconium oxide (ZrO<sub>2</sub>) nanopowder. The study examines the anticancer properties of the synthesized nanoparticles as well as their electrochemical behavior using potentiodynamic polarization (PDP) and electrochemical impedance spectroscopy (EIS). The fascinating attributes of ZrO<sub>2</sub> nanoparticles were elucidated through detailed analyses, including powder X-ray diffraction (PXRD), field emission scanning electron microscopy (FESEM), Fourier-transform infrared spectroscopy (FT-IR), and UV–visible spectroscopy (UV–vis). PXRD analysis confirmed a monoclinic crystal structure with crystallite size within the range of 30–40 nm. FESEM reveals irregular shapes and agglomeration of particles, UV–vis showed absorption peak at 347 nm with an energy gap (Eg) of 3.16 eV and FT-IR studies reveals metal–oxygen bonds at 594 cm⁻<sup>1</sup>. Additionally, electrochemical studies using PDP and EIS investigated the inhibition efficiency of nanoparticles dispersed in an acidic medium (1 M HCl). Anti-oncogenic studies conducted via MTT assay illustrated the efficacy of ZrO<sub>2</sub> NPs against the MDA-MB-231 cell line with an IC50 value of 22.56 µg/mL. Our findings underscore the versatile potential applications of ZrO<sub>2</sub> nanoparticles and provide significant new insights into their optical, structural, electrochemical, and anticancer properties.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1431 - 1443"},"PeriodicalIF":2.1,"publicationDate":"2025-03-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Microstructure and mechanical properties of TiC-10Mo-20Ni cermets","authors":"Xiao-Dong Kang, Guo-Hua Zhang, Kuo-Chih Chou","doi":"10.1007/s41779-025-01181-4","DOIUrl":"10.1007/s41779-025-01181-4","url":null,"abstract":"<div><p>TiC-10Mo-20Ni cermets with outstanding comprehensive properties were fabricated using Ni powder, self-synthesized ultrafine TiC and Mo powders. The effects of different liquid-phase sintering temperatures (1450–1525 °C) on the microstructure and mechanical properties of TiC-10Mo-20Ni cermets were investigated. The results demonstrated that all sintered samples exhibited a uniformly distributed core-rim structure. As the temperature increased, the degree of densification increased, and the number of gray coreless grains increased. The grain size of TiC-10Mo-20Ni cermets gradually increased with temperature, with the average grain size rising from 1.04 ± 0.29 μm to 1.43 ± 0.55 μm. The hardness of the sintered samples initially increased and then decreased with temperature, reaching a peak value of 1622 HV<sub>30</sub> at 1475 °C. The fracture toughness (K<sub>IC</sub>) and transverse rupture strength (TRS) increased with temperature, and had the values of 15.02 MPa·m<sup>1/2</sup> and 1741 MPa at 1525 °C, respectively. The sintered samples were mainly dominated by a mixed fracture pattern of intergranular fracture and transgranular fracture, with transgranular fracture increasing as the temperature rose. Meanwhile, the crack extension and fracture morphology became more intricate, thus enhancing the K<sub>IC</sub> and TRS.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1473 - 1486"},"PeriodicalIF":2.1,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929373","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Chandramohan R, Seeniappan Kaliappan, L. Natrayan, M. Muthukannan
{"title":"Optimization of tensile and water absorption properties of biosilica dispersed cardanol oil blended PLA/PCL biocomposite for packaging applications","authors":"Chandramohan R, Seeniappan Kaliappan, L. Natrayan, M. Muthukannan","doi":"10.1007/s41779-025-01175-2","DOIUrl":"10.1007/s41779-025-01175-2","url":null,"abstract":"<div><p>The present research study focuses on optimizing the formulation of (PLA/PCL) polycaprolactone/polylactic acid biocomposite films for durable packaging applications by incorporating cardanol oil and nanosilica. The materials used include PLA pellets (Mw = 207,000 g/mol) and PCL polymer (Mn = 95 kDa). Cardanol oil were utilized as compatibilization and reinforcing agents. Composite films were prepared using a film casting method with varying concentrations of PCL (8, 10, 12 wt.%), cardanol oil (5, 10, 15 wt.%), and nanosilica (1, 3, 5 wt.%) based on the L9 orthogonal design. The produced films, with thicknesses ranging from 85 to 100 microns, were conditioned at 50% relative humidity and 25 °C to stabilize their properties. The key findings reveal that the optimal combination of process parameters, A2B1C3 (10 wt.% PCL, 5 wt.% cardanol oil, and 5 wt.% nanosilica), significantly enhanced the mechanical properties, achieving a tensile strength of 91.47 MPa and hydrophobicity of 95.25°, showing a 2.57% improvement in Grey Relational Grade (GRG). These results underscore the effectiveness of using cardanol oil and nanosilica to improve the compatibility and performance of PLA/PCL blends, providing valuable insights for developing sustainable biocomposite films for packaging applications. The FTIR analysis demonstrated effective compatibility between PLA/PCL and the added components, with distinctive peaks at 2900 cm⁻<sup>1</sup> and 3300 cm⁻<sup>1</sup> indicating CH alkyl bonds and OH phenolic groups, respectively. Morphological analysis using SEM images confirmed a uniform distribution of nanosilica and cardanol oil within the PLA/PCL matrix, which enhanced the composite’s properties, although minor submicron gaps and pits were observed. Unlike previous studies, this did not explore the ideal amounts or combined effects of these additives. This work employs a systematic approach using the Taguchi L9 orthogonal array to determine optimal input process parameters. However, this study has certain limitations like requirement of raw material for mass production of biosilica, and limited properties are studied under optimization in this study. This can be overcome by upcoming research study on this background and more properties studies on this research. Moreover, the natural material influenced biofilm composite can potentially be applied in areas such as food packaging industry, pharmaceutical, biomedical field, etc.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1405 - 1416"},"PeriodicalIF":2.1,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929221","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Characterization of Moringa oleifera husk biocarbon and bagasse micro fibre toughened vinyl-based microwave shielding composite for E-Vehicle","authors":"K. K. Manivannan, V. Gnanamoorthi","doi":"10.1007/s41779-025-01178-z","DOIUrl":"10.1007/s41779-025-01178-z","url":null,"abstract":"<div><p>This study presents the development of a vinyl ester-based composite reinforced with bagasse microfibers and biocarbon derived from Moringa oleifera husks, aimed at enhancing mechanical properties, dielectric permittivity, and EMI (Electromagnetic Interference) shielding effectiveness for potential applications in electric vehicle systems. First the biomass extracted biocarbon was prepared by under slow pyrolysis technique. The composite fabrication was carried out using a hand layup method with careful mixing of biocarbon from Moringa oleifera husks and uniform dispersion of bagasse microfibers, ensuring enhanced composite performance.Further, to evaluate their performance, as per ASTM standard the composite specimen is cut under abrasive water jet machine. Based on the result obtained, the composite specimen, VB2, with 2 vol.% biocarbon and 40 vol.% bagasse microfibre, exhibited superior tensile strength (135 MPa), flexural strength (155 MPa), and hardness (83 Shore-D), due to optimal filler-matrix interaction and effective stress transfer. Dielectric permittivity was also highest for VB2, reaching 6.1 at 8 GHz, and maintaining higher values across other frequencies, indicating strong interfacial polarization. For EMI shielding, VB2 achieved the highest total shielding effectiveness of 31.5 dB at 8 GHz and 68.25 dB at 18 GHz, driven by the combined effects of enhanced absorption and reflection through synergistic filler effects. SEM analysis confirmed that VB2 had a uniform dispersion of fillers, minimizing voids and agglomerations, which is crucial for maximizing mechanical strength and electromagnetic shielding. The sustainable use of natural fibers and biocarbon also highlights the environmental benefits of this composite for automotive applications, such as battery temperature control and wireless charging in E-vehicles.\u0000</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1445 - 1457"},"PeriodicalIF":2.1,"publicationDate":"2025-03-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929218","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of Si3N4 doping and annealing on the thermal conductivity and mechanical properties of AlN ceramics","authors":"H. Peng, L. J. Wei, Y. Liu, D. L. Ma, Y. X. Leng","doi":"10.1007/s41779-025-01182-3","DOIUrl":"10.1007/s41779-025-01182-3","url":null,"abstract":"<div><p>AlN ceramics are widely used in power electronics packaging due to their excellent thermal conductivity. In order to prepare AlN ceramics with good mechanical properties and thermal conductivity, 0–3 wt% Si<sub>3</sub>N<sub>4</sub> was doped and annealed at 1600 °C. The effects of Si<sub>3</sub>N<sub>4</sub> doping and annealing on the microstructure, thermal conductivity, and mechanical properties of the fabricated AlN ceramics were investigated. The study demonstrated that the incorporation of Si<sub>3</sub>N<sub>4</sub> resulted in the generation of Y<sub>2</sub>Si<sub>3</sub>O<sub>3</sub>N<sub>4</sub> and SiAl<sub>4</sub>O<sub>2</sub>N<sub>4</sub>, which not only refined the AlN grains but also enhanced the strength of the grain boundary phase, ultimately enhanced the hardness and fracture toughness of the ceramic samples. Furthermore, the annealing process facilitated AlN grain growth and improved the crystallinity of the grain boundary phase, which increased the thermal conductivity of the AlN ceramics. Notably, after the annealing process, 0.5 SiN samples exhibited a 37% increase in thermal conductivity, and a concurrent 30% increase in fracture toughness and a 23% increase in hardness, reaching 4.2 MPa·m<sup>1/2</sup> and 12.8 GPa, respectively. Finally, this study explores the mechanism of Si<sub>3</sub>N<sub>4</sub> doping in order to modulate the properties of AlN ceramics by changing the liquid phase composition.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1487 - 1502"},"PeriodicalIF":2.1,"publicationDate":"2025-03-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144929374","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Eisa Mahmoudsaleh, Ali Heidari, Farshid Fathi, Seyed Ali Hassanzadeh-Tabrizi
{"title":"Effect of nano MgO/SiO2 additive on hydration and strength of self-compacting concrete fabricated by different processing methods","authors":"Eisa Mahmoudsaleh, Ali Heidari, Farshid Fathi, Seyed Ali Hassanzadeh-Tabrizi","doi":"10.1007/s41779-024-01146-z","DOIUrl":"10.1007/s41779-024-01146-z","url":null,"abstract":"<div><p>The effects of the addition of 0–4 wt% nano MgO and 0–2 wt% nano SiO<sub>2</sub> (with respect to cement content) on hydration, microstructural, and compressive/flexural strength of Self-Compacting Concrete (SCC) were investigated. Two different post-treatment conditions with water and CO<sub>2</sub> gas were used to study the processing method on the samples. The results of rheological tests showed that the addition of nanoparticles decreased the flowability of SCC. The results of the density showed that the sample containing 4 wt% of MgO processed in the water environment had the lowest density and the sample processed in the CO<sub>2</sub> environment had the highest density. In the samples containing SiO<sub>2</sub> nanoparticles, an increase in density was observed with the increase of SiO<sub>2</sub> nanoparticles in both cases. It was also determined the amount of heat released for the samples with nano MgO was higher than the samples with nano SiO<sub>2</sub>, which can be attributed to the heat of the hydration reaction of MgO or the formation of calcium carbonate. The mechanical properties of the samples were investigated. The compressive strength significantly improved after the addition of MgO/SiO<sub>2</sub> nanoparticles. However, this improvement was more remarkable in the case of post-treatment with CO<sub>2</sub> compared to the samples fabricated with water. SEM results showed that the samples treated under CO<sub>2</sub> gas had irregular and needle-like morphology. The samples prepared by normal processing had CaCO<sub>3</sub> and SiO<sub>2</sub> phases, whereas the ones fabricated under CO<sub>2</sub> gas contained CaCO<sub>3</sub>, SiO<sub>2</sub>, and Ca(OH)<sub>2</sub>. With the addition of nano MgO, the density of concrete decreases in the samples post-treated with water, whereas it increases for the samples post-treatment with CO<sub>2</sub> gas. Adding nano MgO-SiO<sub>2</sub> to concrete and further post-treatment with CO<sub>2</sub> for 45 days could increase the mechanical properties.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 2","pages":"443 - 461"},"PeriodicalIF":1.8,"publicationDate":"2025-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143892606","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}