含共沉淀磷酸盐的二氧化铈基颜料的合成:用于化妆品和油漆的调节氧化催化活性

IF 2.1 4区 材料科学 Q2 MATERIALS SCIENCE, CERAMICS
Hiroaki Onoda, Kazuto Yamaoka, Thitirat Charoonsuk, Phieraya Pulphol, Naratip Vittayakorn
{"title":"含共沉淀磷酸盐的二氧化铈基颜料的合成:用于化妆品和油漆的调节氧化催化活性","authors":"Hiroaki Onoda,&nbsp;Kazuto Yamaoka,&nbsp;Thitirat Charoonsuk,&nbsp;Phieraya Pulphol,&nbsp;Naratip Vittayakorn","doi":"10.1007/s41779-025-01190-3","DOIUrl":null,"url":null,"abstract":"<div><p>Cerium oxide, a popular ultraviolet screening agent in cosmetics, is hindered by its oxidation catalytic activity. Seeking an alternative to cerium phosphate, which increases particle size but lacks catalytic activity, we synthesized a novel cerium hydroxide-cerium oxide pigment by coprecipitating a small amount of phosphate. We chose a baseline Ce/P ratio of 10:1 based on preliminary tests showing that a moderate level of phosphate effectively reduces oxidation catalytic activity while still preserving key cerium oxide characteristics. We evaluated its composition, particle size, oxidation catalyst activity, and hue. Coprecipitation and subsequent heating yielded a yellowish pigment containing both cerium oxide and cerium phosphate. Compared to cerium oxide, our pigment exhibited superior smoothness. Additionally, samples prepared under low pH or high phosphate ratios demonstrated reduced oxidation catalytic activity. However, when applied as a pigment in oil paints, its hiding power was diminished. Our findings highlight a promising strategy for mitigating the catalytic drawbacks of cerium oxide while improving pigment properties, yet caution is warranted regarding its efficacy in paint applications. This study underscores the potential of cerium-based compounds in diverse fields, with room for optimization in specific applications. This study underscores the potential of systematically tuning cerium-based compounds for a range of applications, including cosmetics and paints, by exploring how pH and Ce/P ratio influence catalytic activity, coloration, and particle properties.</p></div>","PeriodicalId":673,"journal":{"name":"Journal of the Australian Ceramic Society","volume":"61 4","pages":"1537 - 1544"},"PeriodicalIF":2.1000,"publicationDate":"2025-04-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Synthesis of cerium dioxide-based pigments with co-precipitated phosphate: tuning oxidation catalytic activity for cosmetic and paint applications\",\"authors\":\"Hiroaki Onoda,&nbsp;Kazuto Yamaoka,&nbsp;Thitirat Charoonsuk,&nbsp;Phieraya Pulphol,&nbsp;Naratip Vittayakorn\",\"doi\":\"10.1007/s41779-025-01190-3\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<div><p>Cerium oxide, a popular ultraviolet screening agent in cosmetics, is hindered by its oxidation catalytic activity. Seeking an alternative to cerium phosphate, which increases particle size but lacks catalytic activity, we synthesized a novel cerium hydroxide-cerium oxide pigment by coprecipitating a small amount of phosphate. We chose a baseline Ce/P ratio of 10:1 based on preliminary tests showing that a moderate level of phosphate effectively reduces oxidation catalytic activity while still preserving key cerium oxide characteristics. We evaluated its composition, particle size, oxidation catalyst activity, and hue. Coprecipitation and subsequent heating yielded a yellowish pigment containing both cerium oxide and cerium phosphate. Compared to cerium oxide, our pigment exhibited superior smoothness. Additionally, samples prepared under low pH or high phosphate ratios demonstrated reduced oxidation catalytic activity. However, when applied as a pigment in oil paints, its hiding power was diminished. Our findings highlight a promising strategy for mitigating the catalytic drawbacks of cerium oxide while improving pigment properties, yet caution is warranted regarding its efficacy in paint applications. This study underscores the potential of cerium-based compounds in diverse fields, with room for optimization in specific applications. This study underscores the potential of systematically tuning cerium-based compounds for a range of applications, including cosmetics and paints, by exploring how pH and Ce/P ratio influence catalytic activity, coloration, and particle properties.</p></div>\",\"PeriodicalId\":673,\"journal\":{\"name\":\"Journal of the Australian Ceramic Society\",\"volume\":\"61 4\",\"pages\":\"1537 - 1544\"},\"PeriodicalIF\":2.1000,\"publicationDate\":\"2025-04-07\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Journal of the Australian Ceramic Society\",\"FirstCategoryId\":\"88\",\"ListUrlMain\":\"https://link.springer.com/article/10.1007/s41779-025-01190-3\",\"RegionNum\":4,\"RegionCategory\":\"材料科学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q2\",\"JCRName\":\"MATERIALS SCIENCE, CERAMICS\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Journal of the Australian Ceramic Society","FirstCategoryId":"88","ListUrlMain":"https://link.springer.com/article/10.1007/s41779-025-01190-3","RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q2","JCRName":"MATERIALS SCIENCE, CERAMICS","Score":null,"Total":0}
引用次数: 0

摘要

氧化铈是化妆品中常用的紫外线屏蔽剂,但其氧化催化活性阻碍了紫外线屏蔽剂的应用。为了寻找磷酸铈的替代品,我们通过共沉淀法合成了一种新型的氢氧化铈-氧化铈颜料,该颜料增加了颗粒尺寸但缺乏催化活性。我们选择了基线Ce/P比为10:1,基于初步测试表明,中等水平的磷酸盐有效地降低了氧化催化活性,同时仍然保留了氧化铈的关键特性。我们评估了它的组成、粒度、氧化催化剂活性和色调。共沉淀和随后的加热产生含有氧化铈和磷酸铈的淡黄色颜料。与氧化铈相比,我们的颜料具有更好的光滑度。此外,在低pH或高磷酸盐比例下制备的样品显示氧化催化活性降低。然而,当用作油画颜料时,它的遮盖力就减弱了。我们的研究结果强调了一种有希望的策略,可以在改善颜料性能的同时减轻氧化铈的催化缺陷,但对其在油漆应用中的功效仍需谨慎。这项研究强调了铈基化合物在不同领域的潜力,在特定应用中有优化的空间。这项研究通过探索pH值和Ce/P比值如何影响催化活性、着色和颗粒性质,强调了系统调整铈基化合物的潜力,包括化妆品和油漆等一系列应用。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Synthesis of cerium dioxide-based pigments with co-precipitated phosphate: tuning oxidation catalytic activity for cosmetic and paint applications

Synthesis of cerium dioxide-based pigments with co-precipitated phosphate: tuning oxidation catalytic activity for cosmetic and paint applications

Synthesis of cerium dioxide-based pigments with co-precipitated phosphate: tuning oxidation catalytic activity for cosmetic and paint applications

Cerium oxide, a popular ultraviolet screening agent in cosmetics, is hindered by its oxidation catalytic activity. Seeking an alternative to cerium phosphate, which increases particle size but lacks catalytic activity, we synthesized a novel cerium hydroxide-cerium oxide pigment by coprecipitating a small amount of phosphate. We chose a baseline Ce/P ratio of 10:1 based on preliminary tests showing that a moderate level of phosphate effectively reduces oxidation catalytic activity while still preserving key cerium oxide characteristics. We evaluated its composition, particle size, oxidation catalyst activity, and hue. Coprecipitation and subsequent heating yielded a yellowish pigment containing both cerium oxide and cerium phosphate. Compared to cerium oxide, our pigment exhibited superior smoothness. Additionally, samples prepared under low pH or high phosphate ratios demonstrated reduced oxidation catalytic activity. However, when applied as a pigment in oil paints, its hiding power was diminished. Our findings highlight a promising strategy for mitigating the catalytic drawbacks of cerium oxide while improving pigment properties, yet caution is warranted regarding its efficacy in paint applications. This study underscores the potential of cerium-based compounds in diverse fields, with room for optimization in specific applications. This study underscores the potential of systematically tuning cerium-based compounds for a range of applications, including cosmetics and paints, by exploring how pH and Ce/P ratio influence catalytic activity, coloration, and particle properties.

求助全文
通过发布文献求助,成功后即可免费获取论文全文。 去求助
来源期刊
Journal of the Australian Ceramic Society
Journal of the Australian Ceramic Society Materials Science-Materials Chemistry
CiteScore
3.70
自引率
5.30%
发文量
123
期刊介绍: Publishes high quality research and technical papers in all areas of ceramic and related materials Spans the broad and growing fields of ceramic technology, material science and bioceramics Chronicles new advances in ceramic materials, manufacturing processes and applications Journal of the Australian Ceramic Society since 1965 Professional language editing service is available through our affiliates Nature Research Editing Service and American Journal Experts at the author''s cost and does not guarantee that the manuscript will be reviewed or accepted
×
引用
GB/T 7714-2015
复制
MLA
复制
APA
复制
导出至
BibTeX EndNote RefMan NoteFirst NoteExpress
×
提示
您的信息不完整,为了账户安全,请先补充。
现在去补充
×
提示
您因"违规操作"
具体请查看互助需知
我知道了
×
提示
确定
请完成安全验证×
copy
已复制链接
快去分享给好友吧!
我知道了
右上角分享
点击右上角分享
0
联系我们:info@booksci.cn Book学术提供免费学术资源搜索服务,方便国内外学者检索中英文文献。致力于提供最便捷和优质的服务体验。 Copyright © 2023 布克学术 All rights reserved.
京ICP备2023020795号-1
ghs 京公网安备 11010802042870号
Book学术文献互助
Book学术文献互助群
群 号:604180095
Book学术官方微信