Journal of Solid State Electrochemistry最新文献

{"title":"Electrochemical tolerance of silicon-based Li-ion batteries to formation current rate and discharge voltage window","authors":"Sheng S. Zhang","doi":"10.1007/s10008-026-06568-2","DOIUrl":"10.1007/s10008-026-06568-2","url":null,"abstract":"<div><p>Hybridization of Si with SiO_x has been recognized as an effective strategy to enhance the performance of Si-based Li-ion batteries by mitigating the rapid capacity fade of Si and the low initial coulombic efficiency of SiO_x. In this work, a 1:2 (wt.) microsized Si/SiO_x hybrid electrode is employed to elucidate the distinct electrochemical characteristics of Si-based Li-ion cells compared with conventional graphite-based systems. Owing to their fundamentally different Li storage mechanisms, Si-based cells do not need time-consuming formation cycles typically used to form a robust solid electrolyte interphase (SEI) in graphite electrodes. Furthermore, the role of the SEI in stabilizing cycling performance differs substantially between the two systems. Remarkably, Si-based Li-ion cells exhibit excellent tolerance to deep discharge. Testing on Si/LiNi_0.8Co_0.1Mn_0.1O₂ (NCM811) coin cells demonstrates stable cycling even when discharged to 0.2 V, without detrimental effects on cycling stability. Despite this advantage, relatively fast capacity fading remains a critical challenge, and the underlying mechanisms are analyzed. The findings of this work provide new fundamental insights into the electrochemical characteristics of Si-based Li-ion batteries and offer guidance for improving the cycling performance of Si-based Li-ion batteries.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2619 - 2626"},"PeriodicalIF":3.1,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357808","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Effect of quasi-solid gel electrolyte on the performance of lithium nickel cobalt manganese (NCM) ternary composite lithium manganese iron phosphate (LMFP) lithium-ion battery","authors":"Jinbiao Yi,&nbsp;Denghui Tong,&nbsp;Ye Ma","doi":"10.1007/s10008-026-06570-8","DOIUrl":"10.1007/s10008-026-06570-8","url":null,"abstract":"<div>\u0000 \u0000 <p>To improve the high-temperature performance and safety performance of the mixed system of lithium nickel cobalt manganate (NCM) and lithium manganese iron phosphate (LMFP) for lithium-ion batteries, pentaerythritol triacrylate (PETA) serves as the monomer and azodiisobutyronitrile (AIBN) as the initiator, and a quasi-solid electrolyte with high safety is prepared via in-situ curing technology. The results show that the 24 Ah square aluminum-shell battery achieves a cycle life of &gt; 1000 cycles @80% SOH at room temperature (25 ℃) under 0.5 C/0.5 C conditions, with a constant current ratio of &gt; 92%. At high temperature (45 ℃) and 0.5 C/0.5 C, its cycle life reaches approximately 700 cycles @80% SOH, which is 30% longer than that of the liquid electrolyte system, and the constant current ratio remains above 95%. After 7 days of storage at 55 ℃ (high temperature), the capacity retention rate and capacity recovery rate are 2.26% and 2.52% higher than those of the liquid system, respectively. The low-temperature (-10 ℃) direct current internal resistance (DCR) test results are consistent with those of the basic electrolyte.Safety test results demonstrate that the quasi-solid gel electrolyte shows no fire, no explosion, and no obvious volume change in overcharge, hot box, acupuncture, and extrusion tests. Differential Scanning Calorimeter (DSC) and Accelerating Rate Calorimeter (ARC) test results confirm that the quasi-solid gel electrolyte has higher thermal stability than the liquid electrolyte system. Therefore, this study helps promote the application of quasi-solid electrolytes in complex lithium-ion batteries such as NCM/LMFP composite batteries, and provides a theoretical basis for improving the safety and high-temperature cycle performance of such batteries.</p>\u0000 </div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2601 - 2618"},"PeriodicalIF":3.1,"publicationDate":"2026-03-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Boosting the zinc storage performance of sodium vanadate cathodes via V-alloyed MXene","authors":"Xiaole Zhao,&nbsp;Guanglei Zhang,&nbsp;Yitong Guo,&nbsp;Yibo Di,&nbsp;Libo Wang,&nbsp;Yukai Chang,&nbsp;Aiguo Zhou","doi":"10.1007/s10008-026-06546-8","DOIUrl":"10.1007/s10008-026-06546-8","url":null,"abstract":"<div>\u0000 \u0000 <p>This study develops high-performance zinc-ion battery cathodes through dual engineering of vanadium-alloyed MXene and its heterointerface with sodium vanadate (NaV₃O₈·1.5H₂O, NVO). By selectively etching (Ti_1-xV_x)₃AlC₂ MAX precursors (NaF/HCl, 60℃, 48 h), we synthesized (Ti_1-xV_x)₃C₂ MXene solid solutions where V-substitution optimizes electron conductivity. When composited with NVO, the 20 wt% (Ti_0.7V_0.3)₃C₂/NVO cathode delivers remarkable specific capacities of 221.6 mA h g⁻¹ at 10 A g⁻¹ – surpassing pure NVO by 4.0-fold and Ti₃C₂/NVO by 2.5-fold – and maintains 195 mA h g⁻¹ after 5,000 cycles (1.7 times of pure NVO and 4.1 times Ti₃C₂/NVO), outperforming state-of-the-art vanadate cathodes. Mechanistic analysis reveals that while NVO enables reversible Zn²⁺ redox reaction, the V-alloyed MXene simultaneously constructs a 3D conductive network suppressing electrode degradation and creates low-energy Zn²⁺ migration channels at interfaces via lattice distortion. Collectively, this interface engineering strategy unlocks ultra-stable zinc storage at practically high rates (10 A g⁻¹), providing a pathway for next-generation zinc storage cathode.</p>\u0000 </div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2587 - 2599"},"PeriodicalIF":3.1,"publicationDate":"2026-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357807","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Influence of the nature of metal M on the anodic dissolution of PdM electrolytic alloys (M = non-noble metal)","authors":"Boris I. Podlovchenko,&nbsp;Yurii M. Maksimov,&nbsp;Vitaly V. Kuznetsov,&nbsp;Vladimir V. Zhulikov","doi":"10.1007/s10008-026-06550-y","DOIUrl":"10.1007/s10008-026-06550-y","url":null,"abstract":"<div>\u0000 \u0000 <p>Anodic dissolution of electrolytic deposits of palladium PdM (M = Pb, Cu, Ag, and Mo; [M] &lt; 30 at.%) is studied in H₂SO₄ and HClO₄ solutions at electrode potentials of 0.3–1.25 V (vs. a reversible hydrogen electrode [RHE]) in various regimes. Quantitative data on sample dissolution are obtained using inductively coupled plasma atomic emission spectroscopy (ICP-AES) and inductively coupled plasma mass spectrometry (ICP-MS). The dissolution rates for palladium are compared for binary PdM and pure palladium electrolytic deposits obtained under similar conditions. It is found that the total Pd dissolved from PdM is higher than that from the monometallic palladium deposits, due to the increase in the real surface area caused by the incorporation of the second metal. On the other hand, the normalized masses of Pd dissolved from PdCu and PdMo (per cm² of the real Pd surface) are shown to be lower than in the case of pure Pd. The addition of Ag and Pb to palladium results in increased dissolution of palladium. The dependence of Pd dissolution on the standard electrode potential of the redox pair <i>E</i>°(Mn+/M) and the metal radius <i>r</i>(M) are discussed. The dissolution data for Pd and M from the PdM deposits are compared.</p>\u0000 </div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2579 - 2586"},"PeriodicalIF":3.1,"publicationDate":"2026-03-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357824","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Sustainable electrode materials from biowaste: a comprehensive review for supercapacitor applications","authors":"Jiban Podder,&nbsp;Madhu Agarwal,&nbsp;Yesu Ramya Kandregula,&nbsp;Ajay K. Dalai","doi":"10.1007/s10008-026-06551-x","DOIUrl":"10.1007/s10008-026-06551-x","url":null,"abstract":"<div>\u0000 \u0000 <p>Biomass-derived electrode materials have attracted considerable interest owing to their natural abundance, renewability, low cost, strong chemical and thermal resilience, minimal environmental impact and the ability to tailor their structural properties for targeted applications. Agricultural waste, lignocellulosic materials, and biopolymers are widely explored for producing high-performance carbon-based electrodes. Biomass-derived carbons show surface areas from ~ 200 to over 4000 m²/g, specific capacitances from ~ 50 to over 500 F/g, and energy densities typically ranging from ~ 10 to ~ 50 Wh/kg, though some exceptional materials can reach much higher values, depending heavily on the biomass source, activation methods, and pore structure, with higher areas generally boosting capacitance and energy density. The structural, chemical composition, morphological, and electrochemical measurements for jute carbon are explored in detail. The prepared active jute carbon exhibits high surface area of 1, 903.48 m²/g and high charge storage capacity with a specific capacitance of 346.00 F/g in 6 M KOH at a current density of 1.0 A/g; and shows excellent cyclic stability (the capacity retention ~ 96%) over 10, 000 cycles). Various biomass sources, including banana peel, tea residues, coconut shells, jackfruit peel, and animal-derived by-products, are discussed alongside current challenges in scalability, consistency, and integration into commercial devices. Future directions focus on optimizing structure and sustainability for next-generation energy storage systems.</p>\u0000 </div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2405 - 2431"},"PeriodicalIF":3.1,"publicationDate":"2026-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357844","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Review of electro-Fenton process: from basic mechanism to modification strategies of cathode materials","authors":"Jiafeng Bai,&nbsp;Xiaoqin Peng,&nbsp;Yi Zhou,&nbsp;Xiaqing Wu,&nbsp;Zhizhong Hu,&nbsp;Chunping Xu","doi":"10.1007/s10008-026-06565-5","DOIUrl":"10.1007/s10008-026-06565-5","url":null,"abstract":"<div>\u0000 \u0000 <p>Electro-Fenton process is deemed as an eco-friendly and effective technology in the removal of persistent organic pollutants in practical industrial wastewater. Many studies are devoted to the development of various electro-Fenton catalysts with high catalytic activities. However, few papers provide a relatively comprehensive understanding of the overall electro-Fenton process. In this review, we summarize the electro-Fenton reaction from the aspect of the basic mechanism, the common reactors, the cathode materials, and their modification strategies. The disadvantages and advantages of electro-Fenton reactors and cathode materials are analyzed. Moreover, from the principle of electro-Fenton process, it is crucial to accelerate the hydroxyl radical production for highly efficient electro-Fenton catalysts. Therefore, we present various modification approaches of carbon-based materials, such as increasing specific surface area, doping with heteroatoms, loading cocatalysts. Ultimately, some key challenges and perspectives in the field of electro-Fenton process are proposed.</p>\u0000 </div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2433 - 2444"},"PeriodicalIF":3.1,"publicationDate":"2026-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357825","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation of copper lanthanum oxide cathodes via pulsed electrodeposition for photoelectrochemical hydrogen production","authors":"Tomasz Baran,&nbsp;Szymon Seweryn,&nbsp;Michał Latkiewicz,&nbsp;Adrian Radoń,&nbsp;Dariusz Łukowiec,&nbsp;Piotr Zajączkowski","doi":"10.1007/s10008-026-06567-3","DOIUrl":"10.1007/s10008-026-06567-3","url":null,"abstract":"<div><p>Copper lanthanum oxide electrodes were successfully prepared via pulsed electrodeposition and evaluated for their performance in photoelectrochemical water splitting. The copper lanthanum oxide composite exhibits several advantages over pure copper oxides, including improved electrical conductivity, enhanced charge carrier separation, and increased catalytic activity, making it a promising material for hydrogen production. The pulsed electrodeposition method enables precise control over film morphology, crystallinity, and composition, leading to the formation of uniform and highly active electrode surfaces. Compared to conventional electrodeposition techniques, the pulsed approach enhances the adhesion and structural integrity of the deposited layers, reducing the risk of degradation during prolonged electrochemical operation. Photoelectrochemical characterization revealed that the Cu–La electrodes generated significantly higher photocurrent densities than pure copper oxide electrodes, indicating enhanced light absorption and improved charge transfer properties. The Cu–La electrode demonstrates high performance through stable and enhanced cathodic photocurrents under visible light and exceptionally efficient hydrogen evolution (up to 51 mmol H₂/cm² in 1 h), significantly outperforming pure Cu₂O electrodes due to synergistic interactions between the Cu₂O and La₂CuO₄ phases. These results highlight the effectiveness of Cu–La composite cathodes and the advantages of pulsed electrodeposition in designing advanced materials for sustainable hydrogen production.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2567 - 2577"},"PeriodicalIF":3.1,"publicationDate":"2026-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357851","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"In-situ monitoring-assisted synthesis of high surface area porous carbon black via CO2 activation for boosting rate performance of LiFePO4 cathodes","authors":"Hu Qichuang,&nbsp;Wang Hanjin,&nbsp;Dai Guodong,&nbsp;Zhong Shengwen","doi":"10.1007/s10008-026-06556-6","DOIUrl":"10.1007/s10008-026-06556-6","url":null,"abstract":"<div><p>The intrinsic low surface area and non-porous nature of commercial Super P carbon black limit electrolyte accessibility, hindering the high-rate performance of LiFePO₄​ (LFP) cathodes. Herein, we report a controllable high-temperature CO_2​ activation strategy, assisted by in-situ exhaust gas monitoring, to transform Super P into high-surface-area porous carbon (HSPC). We identified 1000 °C as the critical activation threshold and established a quantitative exponential relationship (<i>R</i>² = 0.98) between mass loss and specific surface area. The optimized HSPC achieves a surface area of 720.8 m2 g⁻¹, far exceeding the 55.6 m2 g⁻¹ of pristine Super P. As a conductive additive, HSPC enables LFP cathodes to deliver superior discharge capacities of 119.14 mAh g⁻¹ at 5 C and 70.16 mAh g⁻¹ at 10 C, significantly outperforming pristine Super P and commercial Ketjen Black EC300J. Additionally, the cathode maintains 97.10% capacity after 500 cycles at 1 C. Kinetic analyses (EIS, GITT, CV) confirm that the hierarchical porous network serves as a \"3D ionic highway,\" substantially enhancing ion transport and reducing charge transfer resistance.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2551 - 2565"},"PeriodicalIF":3.1,"publicationDate":"2026-03-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357806","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Inkjet-printed Pt/C materials on CuS photocathodes for photoelectrochemical water splitting","authors":"Moisés A. de Araújo,&nbsp;Carlos André G. Bezerra,&nbsp;Germano Tremiliosi-Filho,&nbsp;Edson A. Ticianelli","doi":"10.1007/s10008-026-06538-8","DOIUrl":"10.1007/s10008-026-06538-8","url":null,"abstract":"<div><p>Copper(II) sulphide (CuS) exhibits suitable optical properties for photoelectrochemical (PEC) H₂ generation, a non-polluting energy carrier; however, the PEC performance of this material is still unsatisfactory. In this work, we aimed to improve PEC H₂ generation via modifying the surface of CuS films with Pt/C materials deposited using a low-cost commercial inkjet printer (a conventional desktop printer). The inkjet deposition approach enabled deposition of ultra-low Pt loadings (range of 0.00036–0.0096 mg Pt cm⁻²), representing high Pt utilisation. The presence of Pt/C on CuS films delivered a considerable cathodic photocurrent density of (−3.17 ± 0.56) mA cm⁻² at 0 V vs. RHE for the hydrogen evolution reaction (HER), which is 7.93 times higher than that of the bare CuS film. Additionally, a positive onset potential under illumination for the HER was observed for the CuS-Pt/C films (up to approximately 0.025 V vs. RHE) compared to that of the bare CuS film (ca. −0.013 V vs. RHE), indicating co-catalytic contribution of the Pt in the Pt/C materials for the improvement of the HER. Electrochemical impedance measurements revealed a 2.1-fold reduction in charge transfer resistance of CuS-Pt/C films compared to bare CuS films. This indicates that the enhanced PEC H₂ generation is associated with the facilitation of photogenerated electrons transfer at the photocathode|electrolyte interface for the occurrence of the HER. In terms of PEC stability, the cathodic photocurrent density of the CuS-Pt/C film at −0.04 V vs. RHE remained steady for 20 min during the PEC experiment; however, a considerable decrease was observed for longer times, which is attributed to the photoelectrochemical decomposition of CuS. A similar stability trend was observed for the amount of H₂ generated by the CuS-Pt/C film at −0.04 V vs. RHE under illumination.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2533 - 2550"},"PeriodicalIF":3.1,"publicationDate":"2026-03-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10008-026-06538-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357805","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Advancements of additive manufacturing for proton exchange membrane","authors":"Kabir R Raut,&nbsp;Shruti Gupta,&nbsp;Jigar Patadiya,&nbsp;Balasubramanian Kandasubramanian","doi":"10.1007/s10008-026-06558-4","DOIUrl":"10.1007/s10008-026-06558-4","url":null,"abstract":"<div><p>This article assesses the usage of additive manufacturing (AM) techniques to fabricate custom parts for proton exchange membrane fuel cells (PEMFCs). It delves into various studies and methodologies employed in 3D printing for fuel cell (FC) components, including cathode catalyst layers, polymer composite membranes, flow fields, and end plates. The study highlights the potential of AM in producing components via topological optimization for PEM fuel cells, emphasizing reduced material waste and energy consumption in manufacturing methods. Additionally, it discusses the life cycle analysis (LCA) for additively manufactured fuel cell components, encompassing its evaluation of environmental effects across the entire life span of these elements. The document introduces inventive methodologies and materials deployed within 3D printing techniques for PEMFC, specifically emphasizing the 3D printing of PEMs. This demonstration highlights the capabilities of Additive Manufacturing (AM) compared to traditional methods, underscoring its potential superiority concerning effectiveness and efficiency. The current study offers a thorough evaluation of additive manufacturing’s (AM) ability to produce PEM fuel cell components, providing important information to direct the development of clean energy technologies in the future.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":665,"journal":{"name":"Journal of Solid State Electrochemistry","volume":"30 7","pages":"2381 - 2403"},"PeriodicalIF":3.1,"publicationDate":"2026-03-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148357843","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}