Journal of Radioanalytical and Nuclear Chemistry最新文献_第2页

Extraction of uranium with Hydrogen-Bonded Complex Extractants based on TBPO: chemical structure, performance and mechanism 基于TBPO的氢键络合萃取剂萃取铀：化学结构、性能及机理

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-06 DOI: 10.1007/s10967-025-10367-w

Qinqin Tao, Yusheng Wang, Chuanhong Chen, Ying Dai

{"title":"Extraction of uranium with Hydrogen-Bonded Complex Extractants based on TBPO: chemical structure, performance and mechanism","authors":"Qinqin Tao, Yusheng Wang, Chuanhong Chen, Ying Dai","doi":"10.1007/s10967-025-10367-w","DOIUrl":"10.1007/s10967-025-10367-w","url":null,"abstract":"<div><p>This study investigates the role of hydrogen bonding in Hydrogen-Bonded Complex Extractants (HBCEs) for uranium extraction from wastewater. Through integrated experimental and theoretical approaches including electrostatic potential (ESP) analysis, molecular binding energy calculations, Atoms in Molecules (AIM) theory, and spectroscopic characterization, we reveal how structural variations (carbon chain length, unsaturation degree, spatial configuration, and functional groups) modulate hydrogen bond characteristics. Results show that extending carbon chains enhances hydrogen bond strength (TBPO-18: -24.28 kcal/mol binding energy), while increasing unsaturation initially weakens then strengthens interactions. Linear structures exhibit superior hydrogen bonding versus cyclic configurations (TBPO-OH vs TBPO-HOH: 18.60 vs 14.47 kcal/mol). Extraction performance correlates with hydrogen bond stability, where TBPO-12 achieves maximum capacity (40.55 mg/L) due to optimal acid resistance. Mechanistic studies via <sup>31</sup>P NMR titration confirm a two-step process: initial <span>({text{UO}}_{2}^{2 + })</span> complexation with TBPO’s P = O group, followed by hydrogen bond formation with HBDs. This work provides fundamental insights for rational design of high-efficiency HBCEs, highlighting hydrogen bond engineering as a key strategy for nuclear wastewater treatment.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 9","pages":"6305 - 6316"},"PeriodicalIF":1.6,"publicationDate":"2025-09-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210477","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Health risk zoning and assessment of radon exposure in mining area based on Thiessen polygon and spatial autocorrelation 基于Thiessen多边形和空间自相关的矿区氡暴露健康风险区划与评价

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-06 DOI: 10.1007/s10967-025-10372-z

Decheng Qin, Mingya Wang, Mingshi Wang, Baoxian Jia, Kewu Liu, Jing Wang, Qiao Han, Fengcheng Jiang, Xiaoming Guo, Mingfei Xing

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A modified method for rapid determination of Y-90 in seawater by liquid scintillation counting 液体闪烁计数法快速测定海水中Y-90的改进方法

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-03 DOI: 10.1007/s10967-025-10275-z

Mihriban Şahin, Nihal Kaya

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Comparative study of trehalose and glucose in freeze-dried human serum albumin nanocolloids: implications for technetium-99m radiolabeling 冻干人血清白蛋白纳米胶体中海藻糖和葡萄糖的比较研究：对锝-99m放射性标记的意义

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-02 DOI: 10.1007/s10967-025-10269-x

Ratna Dini Haryuni, Wening Lestari, Mochammad Dedy Dwi Setyawan, Ega Pratama Hadinoto, Veronika Yulianti Susilo, Amal Rezka Putra, Ahsanal Fikri, Ligwina Dita Pertiwi, Alfian Mahardika Forentin, Sri Setiyowati, Grace Tjungirai Sulungbudi, Ratu Ralna Ismuha, Sumandi Juliyanto

{"title":"Comparative study of trehalose and glucose in freeze-dried human serum albumin nanocolloids: implications for technetium-99m radiolabeling","authors":"Ratna Dini Haryuni, Wening Lestari, Mochammad Dedy Dwi Setyawan, Ega Pratama Hadinoto, Veronika Yulianti Susilo, Amal Rezka Putra, Ahsanal Fikri, Ligwina Dita Pertiwi, Alfian Mahardika Forentin, Sri Setiyowati, Grace Tjungirai Sulungbudi, Ratu Ralna Ismuha, Sumandi Juliyanto","doi":"10.1007/s10967-025-10269-x","DOIUrl":"10.1007/s10967-025-10269-x","url":null,"abstract":"<div><p>Freeze-drying plays an essential role in creating human serum albumin nanocolloid kits, necessitating the careful choice of stabilizing agents to preserve structural integrity and radiochemical purity after technetium-99 m labeling. This study used trehalose, frequently employed to stabilize proteins during lyophilization, and evaluated its role as a cryoprotectant relative to glucose. Trehalose at 15 mg/mL showed favorable particle size, zeta potential, and radiochemical purity, with stability comparable to glucose. It also offered protection against structural damage. These results support the use of trehalose as a potential alternative cryoprotectant in commercial kits, making it appropriate for use in radiopharmaceutical applications.</p><h3>Graphical Abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 8","pages":"5349 - 5358"},"PeriodicalIF":1.6,"publicationDate":"2025-09-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145090386","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Global trends in uranium recovery from seawater via metal organic framework: a bibliometric review 通过金属有机框架从海水中回收铀的全球趋势：文献计量学综述

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-02 DOI: 10.1007/s10967-025-10244-6

Humaira Gul Zaman, Puganeshwary Palaniandy, Mohd Remy Rozainy Mohd Arif Zainol

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Solubility study of NpO2OH(am) under oxidizing groundwater conditions in the KAERI underground research tunnel KAERI地下研究隧道氧化地下水条件下NpO2OH（am）溶解度研究

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-01 DOI: 10.1007/s10967-025-10356-z

Hee-Kyung Kim, Sangki Cho, Hye-Ryun Cho

{"title":"Solubility study of NpO2OH(am) under oxidizing groundwater conditions in the KAERI underground research tunnel","authors":"Hee-Kyung Kim, Sangki Cho, Hye-Ryun Cho","doi":"10.1007/s10967-025-10356-z","DOIUrl":"10.1007/s10967-025-10356-z","url":null,"abstract":"<div><p>Neptunium is a key radionuclide of concern in the safety assessment of spent nuclear fuel repository systems. Under groundwater conditions, neptunium exists primarily in the tetravalent and pentavalent oxidation states, which differ significantly in solubility. In this study, the solubility of the pentavalent solid NpO<sub>2</sub>OH(am) was measured under oxidative groundwater conditions simulating those of the Korea Atomic Energy Research Institute (KAERI) Underground Research Tunnel (KURT). Amorphous NpO<sub>2</sub>OH(am) was prepared from <sup>237</sup>Np(V) solution and equilibrated in synthetic KURT groundwater (pH ≈ 9, ionic strength ≈ 2.2 mmol/kg). The dissolved Np concentration at the end of experiment was measured to be 1.67 ± 0.07 mM at pH 8.27, <i>E</i><sub>h</sub> 0.445 V, and room temperature (22 ± 5 °C). Vis–NIR spectrophotometric analysis identified NpO<sub>2</sub><sup>+</sup> and NpO<sub>2</sub>(CO<sub>3</sub>)<sup>−</sup> as the dominant aqueous species. X-ray power diffraction suggested that the residual greenish solid at the end of the experiment was amorphous NpO<sub>2</sub>OH(am). The experimental results were in good agreement with the thermodynamic modeling, confirming that integrated experimental and modeling approaches reliably describe the solubility behavior of Np(V) under the given groundwater condition.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 9","pages":"6199 - 6207"},"PeriodicalIF":1.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210231","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Bioactive Glass in a Multi Drug Resistance Osteomyelitis in Diabetic Foot: Case Report. 糖尿病足多重耐药性骨髓炎中的生物活性玻璃：病例报告

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-01 Epub Date: 2022-05-18 DOI: 10.1177/15347346221102643

Andrea Panunzi, Laura Giurato, Marco Meloni, Luigi Uccioli

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A case study to demonstrate the importance of analyte-tracer equilibrium for the quantitative analysis of plutonium by isotope dilution 一个案例研究，以证明分析物-示踪剂平衡对同位素稀释法定量分析钚的重要性

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-01 DOI: 10.1007/s10967-025-10245-5

Michael N. Harris, Zsuzsanna Macsik, Annelise M. Riggins- Cardon, Lisa A. Hudston, Dennis M. Lopez, Susan J. Eaton, Madison M. Zuniga, Katelyn B. DeBacker, Julianna Baca, Flaviano Prosperini, Jeremy D. Inglis, Robert E. Steiner, Stephen P. LaMont

{"title":"A case study to demonstrate the importance of analyte-tracer equilibrium for the quantitative analysis of plutonium by isotope dilution","authors":"Michael N. Harris, Zsuzsanna Macsik, Annelise M. Riggins- Cardon, Lisa A. Hudston, Dennis M. Lopez, Susan J. Eaton, Madison M. Zuniga, Katelyn B. DeBacker, Julianna Baca, Flaviano Prosperini, Jeremy D. Inglis, Robert E. Steiner, Stephen P. LaMont","doi":"10.1007/s10967-025-10245-5","DOIUrl":"10.1007/s10967-025-10245-5","url":null,"abstract":"<div><p>This case study from the in-vitro bioassay program of the Los Alamos National Laboratory (LANL) demonstrates the importance of analyte-tracer equilibrium when determining plutonium (Pu) using isotope dilution methods. The program utilizes externally produced urine QC materials spiked with known quantities of Pu isotopes to validate performance. In early 2019, we started observing a significant low bias between measured and expected results for the QC samples, and as part of an investigation into the root cause, conducted a study into tracer—analyte equilibrium chemistry. During the study, we also uncovered that a contributing cause of the low bias was the use of a new urine donor that had a high EDTA diet, which was likely complexing Pu in the urine QC samples. A modified radiochemistry procedure that more effectively destroys the EDTA-Pu complex and ensures equilibrium between tracer and analyte Pu was validated.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 9","pages":"6109 - 6118"},"PeriodicalIF":1.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210227","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

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Kinetics of Pu(VI) and Pu(IV) reduction with hydrazine organic derivatives in a perchloric acid solution 高氯酸溶液中肼类有机衍生物对Pu（VI）和Pu（IV）的还原动力学

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-01 DOI: 10.1007/s10967-025-10357-y

I. A. Mikhaltsova, E. A. Gerber, A. M. Fedoseev, V. P. Shilov

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Detailed analysis of gamma-shielding characteristics of poly methyl methacrylate reinforced with micro/nano zirconium oxide and tungsten carbide 微纳米氧化锆和碳化钨增强聚甲基丙烯酸甲酯的γ屏蔽特性分析

IF 1.6 3区化学

Journal of Radioanalytical and Nuclear Chemistry Pub Date : 2025-09-01 DOI: 10.1007/s10967-025-10369-8

Samy A. Dwidar, Wageeh Ramadan, Mohamed Soliman, A. M. Abdelmonem

{"title":"Detailed analysis of gamma-shielding characteristics of poly methyl methacrylate reinforced with micro/nano zirconium oxide and tungsten carbide","authors":"Samy A. Dwidar, Wageeh Ramadan, Mohamed Soliman, A. M. Abdelmonem","doi":"10.1007/s10967-025-10369-8","DOIUrl":"10.1007/s10967-025-10369-8","url":null,"abstract":"<div><p>This research analyzes polymeric composites based on polymethyl methacrylate loaded with micro/nano particles of zirconium oxide (ZrO<sub>2</sub>) and tungsten carbide (WC) for gamma-ray protection. The PMMA matrix was reinforced with 15%, 30%, and 45% ZrO<sub>2</sub> and 20%, 40%, and 60% WC. An assessment employed <sup>137</sup>Cs, <sup>60</sup>Co, and <sup>152</sup>Eu point gamma sources using a NaI(Tl) detector. Key parameters—including the linear attenuation coefficient (LAC), half value layer (HVL), effective atomic number (Z<sub>eff</sub>), specific gamma constant (GC), gamma dose rate (Dr)were analyzed across a wide energy range (0.015–15 MeV). Additionally, the relative KERMA (K<sub>air</sub>) in air was calculated using PAGEX software over a broad energy range varied from 0.0015 to 20 MeV. Measured LAC values reasonable agreement with that calculated by Phy-X/PSD software. Notably, the composite with 60 wt% nano WC provided the most effective gamma-ray attenuation, outperforming ZrO<sub>2</sub> at similar loadings.</p></div>","PeriodicalId":661,"journal":{"name":"Journal of Radioanalytical and Nuclear Chemistry","volume":"334 9","pages":"6371 - 6386"},"PeriodicalIF":1.6,"publicationDate":"2025-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"145210228","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0