I. A. Mikhaltsova, E. A. Gerber, A. M. Fedoseev, V. P. Shilov
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Kinetics of Pu(VI) and Pu(IV) reduction with hydrazine organic derivatives in a perchloric acid solution
The kinetics of Pu(VI) and Pu(IV) reduction by carbohydrazide and diformylhydrazine in a perchloric acid has been investigated spectrophotometrically. The reaction orders with respect to each reactant (plutonium, reductant and perchloric acid) have been determined. Final products of plutonium reduction, reaction stoichiometry and activation energy have been evaluated. The observed differences in reaction kinetics between perchloric/nitric acid highlight the distinct effects of medium composition on the redox behavior of plutonium. The insights gained in perchloric acid provide a foundation for understanding how complexation in nitric acid might modulate these reactions under industrial conditions during reprocessing of spent nuclear fuel.
期刊介绍：
An international periodical publishing original papers, letters, review papers and short communications on nuclear chemistry. The subjects covered include: Nuclear chemistry, Radiochemistry, Radiation chemistry, Radiobiological chemistry, Environmental radiochemistry, Production and control of radioisotopes and labelled compounds, Nuclear power plant chemistry, Nuclear fuel chemistry, Radioanalytical chemistry, Radiation detection and measurement, Nuclear instrumentation and automation, etc.
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