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Toward real-world ammonia monitoring: QCM sensors functionalized with MOF–hydrogel composites 面向现实世界的氨监测:用mof -水凝胶复合材料功能化的QCM传感器
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-18 DOI: 10.1007/s10853-026-12695-y
Marzieh Sharifi-Sangari, Setareh Homayoonnia, Sedigheh Zeinali
{"title":"Toward real-world ammonia monitoring: QCM sensors functionalized with MOF–hydrogel composites","authors":"Marzieh Sharifi-Sangari,&nbsp;Setareh Homayoonnia,&nbsp;Sedigheh Zeinali","doi":"10.1007/s10853-026-12695-y","DOIUrl":"10.1007/s10853-026-12695-y","url":null,"abstract":"<div><p>Ammonia (NH₃) is a hazardous gas with critical environmental and health impacts, requiring sensitive and selective detection technologies. This study reports the development of Quartz Crystal Microbalance (QCM) sensors using three functional sensing layers: UiO‑66 metal–organic framework (MOF), chitosan–sodium alginate hydrogel, and their composite. The materials were synthesized and characterized using SEM, XRD, BET, and FTIR. The composite sensor demonstrated enhanced performance by combining the high surface area and adsorption capability of UiO‑66 with the flexibility of the hydrogel. Gas sensing tests showed a wide detection range (9.38–70.35 ppm), strong sensor response, short response/recovery times, and ~ 74% signal retention after two months. These results confirm the enhanced sensing performance, selectivity, and long-term stability of the composite sensor. The integration of MOF and hydrogel enables a cost-effective, scalable platform for next-generation ammonia gas sensors, suitable for environmental and industrial applications.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"14709 - 14728"},"PeriodicalIF":3.9,"publicationDate":"2026-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751194","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimizing the deformation behavior and enhancing high-temperature strength of extruded Mg–Y–Zn–Co alloy via Al addition Al的加入优化了Mg-Y-Zn-Co挤压合金的变形行为,提高了合金的高温强度
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-18 DOI: 10.1007/s10853-026-12744-6
Zhichao Wei, Jing Jiang, Wei Yu, Fang wang, Guangli Bi, Yuandong Li, Tijun Chen
{"title":"Optimizing the deformation behavior and enhancing high-temperature strength of extruded Mg–Y–Zn–Co alloy via Al addition","authors":"Zhichao Wei,&nbsp;Jing Jiang,&nbsp;Wei Yu,&nbsp;Fang wang,&nbsp;Guangli Bi,&nbsp;Yuandong Li,&nbsp;Tijun Chen","doi":"10.1007/s10853-026-12744-6","DOIUrl":"10.1007/s10853-026-12744-6","url":null,"abstract":"<div><p>The effects of Al addition on the deformation behavior and high-temperature mechanical properties of an extruded Mg–Y–Zn–Co (YNC) alloy were systematically investigated. The results indicated that Al addition promoted the formation of heat-resistant long period stacking ordered (LPSO) phases, nanoscale (Al, Zn)<sub>2</sub>Y phases at the grain boundaries. Specifically, the synergistic effect of these Al-induced precipitates and the solute segregation (Zn and Y) at grain boundaries effectively inhibits grain coarsening. The deformation behavior of both the extruded YNC and Mg–Y–Zn–Co–Al (YNCA) alloys was predominantly governed by dislocation slip at low temperatures (RT &lt; T &lt; 200 °C) under different strain rates and 300 °C under high strain rates <span>({1}, times ,{1}0^{{ - {1}}} {text{s}}^{{ - }{1}} , &lt; ,mathop varepsilon limits^{ cdot } ,, &lt; ,{1}, times ,{1}0^{{ - {3}}} {text{s}}^{{ - }{1}})</span>, whereas it was jointly controlled by dislocation climb and creep, grain boundary diffusion, and grain boundary sliding at 300 °C under a strain rate 1 × 10<sup>−4</sup> s<sup>−1</sup>. Furthermore, the addition of Al reduces the SFE and accelerates atomic diffusion, thereby facilitating the activity of thermal deformation mechanisms. Tensile testing results indicated that the extruded YNCA alloy exhibited high tensile strengths at high temperature, whose tensile yield strength, ultimate tensile strength and elongation to failure reached 174.8 MPa, 196.4 MPa and 107.7% at 300 ℃ under a strain rate of 1 × 10<sup>−3</sup> s<sup>−1</sup>. The excellent high-temperature mechanical properties of the alloy were primarily attributed to the synergistic effect of the fine-grained structure with high thermal stability, the strengthening contribution of LPSO phase and high-density (Al, Zn)<sub>2</sub>Y phase.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"15275 - 15294"},"PeriodicalIF":3.9,"publicationDate":"2026-04-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751210","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of annealing temperature on interfacial microstructure evolution and mechanical properties of 316H/TC4 composite plates fabricated via asynchronous vacuum hot rolling 退火温度对异步真空热轧316H/TC4复合材料界面组织演变及力学性能的影响
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-17 DOI: 10.1007/s10853-026-12733-9
Shiyi Zhang, Lifeng Ma, Zhihui Cai, Quan Li, Xiping Zhang, Junyi Lei, Chenchen Zhi, Qisheng Zhang
{"title":"Effect of annealing temperature on interfacial microstructure evolution and mechanical properties of 316H/TC4 composite plates fabricated via asynchronous vacuum hot rolling","authors":"Shiyi Zhang,&nbsp;Lifeng Ma,&nbsp;Zhihui Cai,&nbsp;Quan Li,&nbsp;Xiping Zhang,&nbsp;Junyi Lei,&nbsp;Chenchen Zhi,&nbsp;Qisheng Zhang","doi":"10.1007/s10853-026-12733-9","DOIUrl":"10.1007/s10853-026-12733-9","url":null,"abstract":"<div><p>Developing high-performance titanium/steel composite plates requires resolving the challenge of suppressing brittle intermetallic compounds (IMCs) and restoring the ductility of the matrix. In this study, 316H/TC4 composite plates were fabricated via asynchronous vacuum hot rolling (AVHR). The effects of annealing temperature (550–700 °C) on interfacial stability, elemental diffusion, and mechanical properties were systematically investigated. The results indicate that although the AVHR process ensures strong metallurgical bonding through vacuum heating and severe shear deformation, it also leads to the accumulation of high deformation stored energy. Subsequent annealing resulted in significant asymmetric microstructural evolution on both sides of the interface: The TC4 side exhibited temperature-sensitive recrystallization behavior, effectively released residual stress, whereas the 316H side retained a predominantly recovered microstructure. A critical kinetic threshold was determined at 600 °C. Within this temperature range, atomic diffusion was kinetically limited, which effectively suppresses the nucleation and growth of harmful brittle phases (such as FeTi, Fe<sub>2</sub>Ti, and σ phase) and substantially restored the plastic properties of the matrix. When the temperature was higher than 600 °C, the interfacial reaction was significantly enhanced, leading to rapid thickening of the IMCs layer and the formation of diffusion pores and cracks, thereby inducing premature failure. The composite annealed at 600 °C exhibited superior comprehensive properties, with shear strength, tensile strength, and elongation reaching 233.35 MPa, 771.95 MPa, and 16.6%, respectively.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"15249 - 15274"},"PeriodicalIF":3.9,"publicationDate":"2026-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751181","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced Mg–Zn–Ca alloys reinforced with rare earth oxides for biomedical applications: experimental insights and ANFIS-based modeling 用于生物医学应用的稀土氧化物增强Mg-Zn-Ca合金:实验见解和基于anfiss的建模
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-17 DOI: 10.1007/s10853-026-12728-6
Surja Deka, Farzin Mozafari, Ashis Mallick
{"title":"Enhanced Mg–Zn–Ca alloys reinforced with rare earth oxides for biomedical applications: experimental insights and ANFIS-based modeling","authors":"Surja Deka,&nbsp;Farzin Mozafari,&nbsp;Ashis Mallick","doi":"10.1007/s10853-026-12728-6","DOIUrl":"10.1007/s10853-026-12728-6","url":null,"abstract":"<div><p>To enhance the corrosion resistance, biocompatibility, tribological, and mechanical properties of magnesium (Mg) alloys intended for biomedical implants, a new approach utilizing a microwave-sintered in situ hot extrusion-based powder metallurgy process was used to develop Mg–4Zn–0.5Ca/<i>x</i>CeO<span>(_2)</span> (<i>x</i> = 0.5, 1, and 1.5 vol%) nanocomposites. The introduction of ceria nanoparticles (CONPs) has improved the compression characteristics of the nanocomposites in comparison with the monolithic Mg, and the ternary base alloy. The corrosion test results revealed that the alloy and nanocomposites promoted the formation of the magnesium hydroxide (Mg(OH)<span>(_2)</span>) and hydroxyapatite (HA) layers on the sample surface. Among all samples, Mg–4Zn–0.5Ca /1.0CeO<span>(_2)</span> demonstrated the lowest corrosion rate. In vitro cytocompatibility assessments were conducted through an extract assay method for different time periods, employing MG-63 cells. The developed alloy and nanocomposites demonstrated no harmful effects on MG-63 cells. An investigation into the dry sliding tribological characteristics of the alloy and nanocomposites at varied loads revealed several wear mechanisms, including abrasion, adhesion, delamination, oxidation, and plastic deformation. The addition of CONPs significantly enhanced the wear resistance of the nanocomposites. Our results provide a new venue to enhance the biocompatibility and in vitro degradation behavior of well-established Mg–Zn–Ca alloys, with a particular focus on the mechanical integrity of the developed samples for their clinical usage. An Adaptive Neuro-Fuzzy Inference system (ANFIS)-based modeling approach was also developed to individually characterize nanocomposite corrosion, cell viability, and wear behavior. The predictions offer compelling evidence of the reliability and accuracy of the proposed modeling strategy.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"14761 - 14801"},"PeriodicalIF":3.9,"publicationDate":"2026-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MOF-derived methanol-tolerant Fe–N–C catalyst for efficient oxygen reduction reaction in direct methanol fuel cell 直接甲醇燃料电池中高效氧还原反应用mof衍生的耐甲醇Fe-N-C催化剂
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-16 DOI: 10.1007/s10853-026-12782-0
Shiquan Guo, Le Wang, Fei Chen, Wei Liu, Congju Li
{"title":"MOF-derived methanol-tolerant Fe–N–C catalyst for efficient oxygen reduction reaction in direct methanol fuel cell","authors":"Shiquan Guo,&nbsp;Le Wang,&nbsp;Fei Chen,&nbsp;Wei Liu,&nbsp;Congju Li","doi":"10.1007/s10853-026-12782-0","DOIUrl":"10.1007/s10853-026-12782-0","url":null,"abstract":"<div><p>Pt-based electrocatalysts are recognized as the most effective materials for the oxygen reduction reaction (ORR) in fuel cells. However, their widespread application is hindered by high cost, insufficient stability, and susceptibility to methanol and CO poisoning. Therefore, it is crucial to develop non-precious metal catalysts that are efficient, durable, and tolerant to fuel crossover. Herein, we report a facile synthesis of Fe–N–C catalysts derived from transition metal-doped zeolitic imidazolate frameworks via thermal treatment. In alkaline electrolyte, the obtained catalyst exhibited a half-wave potential of 0.79 V (vs. RHE) for the ORR, only 10 mV lower than that of commercial Pt/C. Moreover, it demonstrated excellent stability with 86.7% current retention after 35,000 s, along with outstanding methanol tolerance. In addition, no significant change in current response was observed upon the addition of 1 M methanol during linear sweep voltammetry. Notably, a direct methanol fuel cell incorporating the Fe–N–C catalyst delivered a peak power density of 13.3 mW cm<sup>−2</sup> at 65 ℃. This work highlights the critical role of Fe single atoms in enhancing both ORR activity and methanol tolerance, underscoring the significance in advancing the development of high-performance electrocatalysts for fuel cell applications.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 22","pages":"15628 - 15641"},"PeriodicalIF":3.9,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147802102","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synergistic Mg and Zn dual-doping with carbon coating for advanced LiMn0.6Fe0.4PO4 cathode materials 新型LiMn0.6Fe0.4PO4正极材料的碳包覆协同镁锌双掺杂
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-16 DOI: 10.1007/s10853-026-12688-x
Tao Xie, Yuxuan Jian, Chuang Wang, Qingrui Pan, Lingzhuo Yang, Jinxiang Long, Fenglin Yang, Xianwen Wu, Xianming Wu
{"title":"Synergistic Mg and Zn dual-doping with carbon coating for advanced LiMn0.6Fe0.4PO4 cathode materials","authors":"Tao Xie,&nbsp;Yuxuan Jian,&nbsp;Chuang Wang,&nbsp;Qingrui Pan,&nbsp;Lingzhuo Yang,&nbsp;Jinxiang Long,&nbsp;Fenglin Yang,&nbsp;Xianwen Wu,&nbsp;Xianming Wu","doi":"10.1007/s10853-026-12688-x","DOIUrl":"10.1007/s10853-026-12688-x","url":null,"abstract":"<div><p>LiMn<sub>x</sub>Fe<sub>1 − x</sub>PO<sub>4</sub> (LMFP) is a promising cathode candidate due to its high working voltage, cost-effective advantages, and environmentally friendly characteristics. However, LMFP is constrained by issues such as low intrinsic electronic and ionic conductivity, as well as Jahn–Teller lattice distortion induced by Mn<sup>3+</sup>, which limit its practical performance. To synergistically optimize its electrochemical behavior, LiMn<sub>0.6 − x − y</sub>Fe<sub>0.4</sub>Mg<sub>x</sub>Zn<sub>y</sub>PO<sub>4</sub> (x = 0, y = 0; x = 0.005, y = 0.005; x = 0.01, y = 0; x = 0, y = 0.01) composite materials were designed and synthesized via a solvothermal method in this study. A comparative investigation of these samples was conducted to systematically elucidate the mechanisms underlying individual Mg and Zn doping and their synergistic co-doping. The experimental results indicate that the synergistic strategy of Mg and Zn dual-doping combined with carbon coating helps stabilize the olivine structure of LMFP, improves the reaction kinetics, and lowers the Li<sup>+</sup> diffusion energy barrier. The optimized LMFP/C-MgZn1 exhibits enhanced electrochemical performance, retaining 92.42% of its capacity after 600 cycles at 1.0 C and delivering a discharge specific capacity of 109.8 mAh g<sup>−1</sup> at 10.0 C. Furthermore, Density Functional Theory (DFT) calculations indicate that the co-doping strategy improves the reaction kinetics by reducing both the material’s band gap and the Li<sup>+</sup> diffusion energy barrier.</p><h3>Graphical abstract</h3><p>Mg Zn co doping stabilizes LMFP/C, reduces the Li diffusion barrier and band gap,and enables fast kinetics with durable cycling.</p><div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 22","pages":"15909 - 15925"},"PeriodicalIF":3.9,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147802086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Influence of the C(_2)H(_7)NO(_2) on the calcination time of the synthesis process of LaFeO(_3) by the citrate complex sol–gel method 柠檬酸盐溶胶-凝胶法合成LaFeO (_3)过程中C (_2) H (_7) NO (_2)对煅烧时间的影响
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-16 DOI: 10.1007/s10853-026-12719-7
T. E. Soto, E. Martínez-Aguilar, O. Hernández-Cristóbal, Mauricio López
{"title":"Influence of the C(_2)H(_7)NO(_2) on the calcination time of the synthesis process of LaFeO(_3) by the citrate complex sol–gel method","authors":"T. E. Soto,&nbsp;E. Martínez-Aguilar,&nbsp;O. Hernández-Cristóbal,&nbsp;Mauricio López","doi":"10.1007/s10853-026-12719-7","DOIUrl":"10.1007/s10853-026-12719-7","url":null,"abstract":"<p>LaFeO<span>(_3)</span> perovskite is a multiferroic oxide with structural, and optical properties, making the optimization of the synthesis process to obtain this type of material an important challenge in the field of materials science. In this work, the synthesis of simple perovskite compounds LaFeO<span>(_3)</span> with modification in the calcination step was investigated. This material was synthesized by the sol–gel citrate method with the addition of an ammonium salt as a pH-neutralizing agent during the formation of the solution. The orthorhombic crystal structure of the compound was confirmed by X-ray diffraction, Rietveld refinement and HRTEM image. The morphology of the compound was determined by chemical element dispersion using EDS. The band gap of the compound was calculated using UV–Vis radiation and the Tauc plot model. Computational simulations of LaFeO<span>(_3)</span> reproduce the experimental lattice parameters and band gap with high accuracy and also provide insight into the electronic applications. The integration of a refined synthesis protocol with theoretical validation shows a practical and efficient way to produce high-quality LaFeO<span>(_3)</span> powders for functional applications.</p>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 22","pages":"15507 - 15518"},"PeriodicalIF":3.9,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10853-026-12719-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147802082","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical and corrosion behavior of a biodegradable Zn composite reinforced with Fe–35Mn–5Si–0.25Cu alloy Fe-35Mn-5Si-0.25Cu合金增强Zn复合材料的力学和腐蚀行为
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-16 DOI: 10.1007/s10853-026-12749-1
Adrija Patra, Ravishankar Suman, Priyabrata Das, Debashish Mohanta, Srikant Gollapudi
{"title":"Mechanical and corrosion behavior of a biodegradable Zn composite reinforced with Fe–35Mn–5Si–0.25Cu alloy","authors":"Adrija Patra,&nbsp;Ravishankar Suman,&nbsp;Priyabrata Das,&nbsp;Debashish Mohanta,&nbsp;Srikant Gollapudi","doi":"10.1007/s10853-026-12749-1","DOIUrl":"10.1007/s10853-026-12749-1","url":null,"abstract":"<p>Zinc, a promising material for biodegradable implants, is limited by its low mechanical strength. In this work, we report reinforcement of Zn with 5 wt% of the alloy Fe–35Mn–5Si–0.25Cu to improve its mechanical performance. The reinforcement produced by mechanical alloying route exhibited face centered cubic (FCC) solid solution structure. The Zn composite prepared by double vacuum hot pressing at a temperature of 673 K demonstrated a flexural strength of 124.5 ± 6.2 MPa which is 89% higher than Zn. The corrosion current density was found to be 31.4 ± 1 µA/cm<sup>2</sup> which is also higher than that of Zn at 5.39 ± 0.55 µA/cm<sup>2</sup>. The thickness of the corrosion film over the Zn and Zn composite sample was calculated from the effective capacitance of the film and determined to be 1.55 nm and 2.85 nm, respectively. Irrespective of a thicker corrosion film, the Zn composite sample exhibited lower film resistance which indicates a non-homogeneous and porous nature of the film.</p>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"15295 - 15310"},"PeriodicalIF":3.9,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751184","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Corrosion behavior of warm-rolled and annealed Al–Mg–Mn alloy in 3.5 wt% NaCl solution 热轧退火Al-Mg-Mn合金在3.5 wt% NaCl溶液中的腐蚀行为
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-16 DOI: 10.1007/s10853-026-12779-9
Yanyin Qin, Junwei Fu, Jiaxin Chen, Qixin Tian, Yunfang Wan, Zhaoxia Lu, Baorong Hou
{"title":"Corrosion behavior of warm-rolled and annealed Al–Mg–Mn alloy in 3.5 wt% NaCl solution","authors":"Yanyin Qin,&nbsp;Junwei Fu,&nbsp;Jiaxin Chen,&nbsp;Qixin Tian,&nbsp;Yunfang Wan,&nbsp;Zhaoxia Lu,&nbsp;Baorong Hou","doi":"10.1007/s10853-026-12779-9","DOIUrl":"10.1007/s10853-026-12779-9","url":null,"abstract":"<div><p>Corrosion behavior of warm-rolled and stress relief annealed Al–Mg–Mn alloy in 3.5 wt% NaCl solution was investigated using potentiodynamic polarization techniques, electron probe microanalysis (EPMA), electron backscatter diffraction (EBSD), and scanning Kelvin probe force microscopy (SKPFM). For the warm-rolled and stress relief annealed Al–Mg–Mn alloy, the texture can be expressed as {110} &lt;112 &gt; . EBSD analysis demonstrates that pitting sites are unrelated to the texture formed in the alloy. Pitting is resulted from the preferential galvanic dissolution of <i>α</i>-Al matrix around the Al<sub>6</sub>(Fe, Mn) particles (1– 30 μm) at or near the grain boundaries (GBs). In contrast, the finer Mg<sub>2</sub>Si particles (&lt; 6 μm) do not act as pitting initiators. SKPFM measurements indicate the Al<sub>6</sub>(Fe, Mn) phase exhibits a higher work function than the α-Al matrix, which drives galvanic corrosion in 3.5 wt% NaCl solution. Thus, during galvanic corrosion, Al<sub>6</sub>(Fe, Mn) phase acts as cathode to accelerate the dissolution of the α-Al matrix to initiate pitting as a result.</p></div>","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"15311 - 15327"},"PeriodicalIF":3.9,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751185","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Correction: Effect of neodymium doping on the structural and electrochemical behavior of copper oxide for supercapacitor electrode material 修正:钕掺杂对超级电容器电极材料氧化铜结构和电化学行为的影响
IF 3.9 3区 材料科学
Journal of Materials Science Pub Date : 2026-04-16 DOI: 10.1007/s10853-026-12786-w
Sudhakar B. Satpal, Gazala I. Khan, Prakash B. Rathod, Gaurav S. Sase, Shambhuraje R. Sakhare, Tukaram D. Dongale, Bharat G. Pawar, Hemraj M. Yadav
{"title":"Correction: Effect of neodymium doping on the structural and electrochemical behavior of copper oxide for supercapacitor electrode material","authors":"Sudhakar B. Satpal,&nbsp;Gazala I. Khan,&nbsp;Prakash B. Rathod,&nbsp;Gaurav S. Sase,&nbsp;Shambhuraje R. Sakhare,&nbsp;Tukaram D. Dongale,&nbsp;Bharat G. Pawar,&nbsp;Hemraj M. Yadav","doi":"10.1007/s10853-026-12786-w","DOIUrl":"10.1007/s10853-026-12786-w","url":null,"abstract":"","PeriodicalId":645,"journal":{"name":"Journal of Materials Science","volume":"61 21","pages":"15355 - 15355"},"PeriodicalIF":3.9,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147751186","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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