Yiming Zhou, Xiaoqing Chen, Ming Zhang, Zhaolei Li, Lizhuang Chen
{"title":"Release of BIM from ZIF-7@GO and its effect on the anti-corrosion performance of epoxy composite coating","authors":"Yiming Zhou, Xiaoqing Chen, Ming Zhang, Zhaolei Li, Lizhuang Chen","doi":"10.1007/s11998-025-01257-7","DOIUrl":"10.1007/s11998-025-01257-7","url":null,"abstract":"<div><p>The as-prepared ZIF-7 and ZIF-7@GO was introduced into 3.5 wt.% NaCl solution with varying pH values. Ultraviolet-visible (UV–Vis) spectroscopic analysis revealed that the release kinetics of organic ligands from the composite were significantly accelerated with decreasing pH value. Furthermore, the corresponding electrochemical impedance spectroscopy (EIS) results demonstrated that the benzimidazole (BIM) exhibited remarkable inhibition properties. Later, ZIF-7@GO was incorporated into epoxy resin at varying weight percentages, with systematic evaluations of hydrophobicity, adhesion strength, and EIS performance revealing that ZIF-7@GO/EP(1%) delivered optimal coating performance. After 30 days of immersion in 3.5 wt.% NaCl solution, the low-frequency impedance modulus (|Z|<sub>0.01Hz</sub>) of ZIF-7@GO/EP(1%) remained above 1 × 10<sup>10</sup> Ω·cm<sup>2</sup>. This work establishes a novel paradigm for designing self-healing organic coatings tailored for harsh marine environments.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"2245 - 2255"},"PeriodicalIF":3.4,"publicationDate":"2026-04-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519468","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"ZnO/silicone oil-in-water microemulsion wood coatings: enhanced UV resistance and surface hydrophobicity","authors":"Danial Harandi","doi":"10.1007/s11998-025-01268-4","DOIUrl":"10.1007/s11998-025-01268-4","url":null,"abstract":"<div><p>Wood is a natural, renewable material that has been used for centuries in construction and artifacts due to its strength, light weight, insulation, and esthetic appeal. However, it is vulnerable to environmental degradation, particularly from ultraviolet (UV) radiation, which causes photochemical deterioration over time. This study evaluates oil-in-water microemulsions based on silicone oil and zinc oxide nanoparticles (ZnO-NPs) as an environmentally friendly treatment for protecting wood surfaces against UV-induced photodegradation. White poplar specimens were coated with silicone oil emulsions containing 0.1 and 0.5 wt% ZnO-NPs and subsequently subjected to 500 h of accelerated UV aging. Microscopic observations revealed a uniform distribution of nanoparticles within the coating and the formation of a stable oil layer without aggregation. Colorimetric measurements revealed that while silicone oil alone moderately reduced surface color changes, the incorporation of ZnO-NPs significantly minimized total color changes (Δ<i>E</i>*). These findings were confirmed by Fourier transform infrared (FTIR) spectroscopy, which indicated reduced lignin degradation and lower carbonyl group formation on treated surfaces compared to untreated controls. Furthermore, microemulsions with higher ZnO content (0.5 wt%) not only effectively increased the water contact angle compared to pure silicone oil, but also maintained the hydrophobicity of the surface after UV aging. This novel coating also reduced the water uptake in the treated wood, indicating the effectiveness of protecting the wood against moisture-induced damage.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2487 - 2495"},"PeriodicalIF":3.4,"publicationDate":"2026-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837694","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Behnam Doudkanlouy Milan, Hurieh Mohammadzadeh, Robabeh Jafari, Mohammad Soltani
{"title":"Effect of functionalized reduced graphene oxide on the structural and electrochemical properties of electrophoretically deposited nHA/Chitosan/Gelatin coatings on stainless steel 316","authors":"Behnam Doudkanlouy Milan, Hurieh Mohammadzadeh, Robabeh Jafari, Mohammad Soltani","doi":"10.1007/s11998-026-01288-8","DOIUrl":"10.1007/s11998-026-01288-8","url":null,"abstract":"<div><p>Hydroxyapatite (HA)-based nanocomposite coatings are widely employed to enhance the bioactivity and corrosion resistance of metallic implants in tissue engineering. In this study, the influence of reduced and magnesium-functionalized single-layer graphene oxide (rfGO) on the structural and electrochemical behavior of nano-hydroxyapatite (nHA)/chitosan (CS)/gelatin composite coatings deposited on 316L stainless steel via electrophoretic deposition (EPD) was systematically investigated. The coatings, containing varying rfGO contents (0, 0.3, 0.5, and 0.7 mg per 10 g HA), were fabricated under different EPD voltages. The nHA was synthesized by a sol–gel method, while graphene oxide was reduced and subsequently functionalized with Mg. The powders and coatings were characterized by Fourier-transform infrared spectroscopy (FTIR), X-ray diffraction (XRD), field-emission scanning electron microscopy (FESEM), energy-dispersive X-ray spectroscopy (EDS), and dynamic light scattering (DLS) analyses. Electrochemical performance was assessed through polarization and impedance. FTIR confirmed the successful formation of rfGO, and microstructural analyses demonstrated uniform deposition of HA/CS/gelatin/rfGO coatings. Increasing the EPD voltage promoted crack formation; however, incorporation of rfGO significantly improved coating integrity and reduced cracking, with higher rfGO contents yielding crack-free coatings even at elevated voltages. The coating thickness increased by 41% at 0.7rfGO (4.8 µm) relative to rfGO-free coating (3.4 µm). Coating mass ranged from 2.1 mg (0rfGO-80 V) to 8.1 mg (0.7rfGO-120 V). Electrochemical studies revealed that rfGO generally enhanced corrosion resistance from 165 to 177 Ω cm<sup>2</sup>, except at the highest loading (0.7rfGO), which showed inferior performance (147Ω cm<sup>2</sup>) compared to both the uncoated substrate and rfGO-free coatings. The optimal corrosion resistance was achieved for the 0.5rfGO-100 V coating, with a polarization resistance of 385 Ω·cm<sup>2</sup>. Equivalent circuit modeling of EIS data further elucidated the corrosion mechanisms governing coating behavior.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2717 - 2740"},"PeriodicalIF":3.4,"publicationDate":"2026-04-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837695","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advances in environmentally friendly antifouling coatings: from biocides to bioinspired strategies","authors":"Javed Qureshi, Pranit B. Patil, Dipak V. Pinjari","doi":"10.1007/s11998-025-01233-1","DOIUrl":"10.1007/s11998-025-01233-1","url":null,"abstract":"<div><p>This review critically examines recent advancements in antifouling technologies, emphasizing the development of environmentally sustainable coatings to mitigate biofouling in marine environments. Biofouling, the accumulation of aquatic organisms on submerged surfaces, presents significant economic and ecological challenges, including increased fuel consumption, structural degradation, and the spread of invasive species. The phase-out of toxic organotin-based antifouling paints, particularly tributyltin (TBT)-based formulations, has driven the search for safer and more effective alternatives. This review provides an in-depth analysis of the historical evolution of antifouling coatings, the impact of biofouling across various industries such as heat exchangers, jetties, offshore rigs, shipping vessels, and aquaculture cages, and the limitations of existing antifouling coatings. It highlights the role of interdisciplinary research in advancing antifouling strategies and explores emerging materials such as conducting polymers, hydrogel coatings, and bio-based formulations for antifouling and anticorrosion applications. The review underscores the potential of these innovative materials while emphasizing the need for further research to enhance their long-term effectiveness and environmental compatibility. Additionally, the current review paper covers various antifouling strategies, including biocide-based coatings, fouling-release coatings, and nonfouling coatings, which have been developed to prevent marine growth. The transition from traditional copper-based coatings to sustainable alternatives, such as silicone-based fouling-release coatings and biomimetic materials, reflects the growing regulatory and environmental concerns surrounding conventional antifouling technologies. Advancements in biomimetic, enzyme-based, and nontoxic polymer coatings are further explored, demonstrating their potential to provide durable, eco-friendly antifouling coatings. To illustrate the practical implications of biofouling and mitigation strategies, the discussion highlights the economic and operational challenges posed by biofouling and evaluates the effectiveness of antifouling interventions. The review concludes with key findings, industry implications, and future research directions, advocating for continued innovation in sustainable and efficient antifouling technologies to address the evolving demands of the maritime and naval industries.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1291 - 1334"},"PeriodicalIF":2.8,"publicationDate":"2026-04-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757179","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Ayman M. Atta, Hamad A. Al-Lohedan, Ashraf M. El-Saeed, Hussin I. Al-Shafey, Mohamed Wahby
{"title":"Retraction Note: Salt-controlled self-healing nanogel composite embedded with epoxy as environmentally friendly organic coating","authors":"Ayman M. Atta, Hamad A. Al-Lohedan, Ashraf M. El-Saeed, Hussin I. Al-Shafey, Mohamed Wahby","doi":"10.1007/s11998-026-01339-0","DOIUrl":"10.1007/s11998-026-01339-0","url":null,"abstract":"","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 5","pages":"2821 - 2821"},"PeriodicalIF":3.4,"publicationDate":"2026-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148837827","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Introduction to the special issue","authors":"Marcel Schmitt","doi":"10.1007/s11998-026-01301-0","DOIUrl":"10.1007/s11998-026-01301-0","url":null,"abstract":"","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1079 - 1079"},"PeriodicalIF":2.8,"publicationDate":"2026-04-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757180","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Effect of thickness variation on impact damage characteristics of indicative coatings","authors":"Caixia Jia, Tianyu Yang, Qian Wang, Zhixin Li, Chao Yan, Xin Liu","doi":"10.1007/s11998-025-01256-8","DOIUrl":"10.1007/s11998-025-01256-8","url":null,"abstract":"<div><p>This study investigated an epoxy indicative coating designed to reveal the degree of damage through changes in its cracking characteristics after low-energy impact. Thickness was a critical factor in the pattern of crack extension and distribution of the indicative coating upon impact. Therefore, experiments and finite element analysis were used to reveal the correspondence between epoxy coating (EC) thickness and the damage indications in terms of the number of cracks, the direct cracking area, and the energy absorption-to-mass ratio. Results showed that EC of different thicknesses from 0.5 to 1.0 mm all had the function of indicating damage. The number of cracks and the direct cracking area both increased with impact energy from 1.0 to 3.0 J. The former was relatively independent of coating thickness, whereas the latter was largely influenced. Meanwhile, the coating’s ability to absorb energy also enhanced with its thickness. However, if the effects of weight increase and crack clarity were taken into account, a suitable coating thickness should be selected. For instance, in this study, the 0.8 mm EC achieved an energy consumption effect close to the 1.0 mm EC, but with a lower weight, as well as better regularity and clarity in its crack distribution.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"2231 - 2243"},"PeriodicalIF":3.4,"publicationDate":"2026-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519471","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Advances in lanthanide-doped upconversion nanomaterials in security inks: a comprehensive review","authors":"Anand P. J., Rakshitha K. Jain, Dhanya Sunil","doi":"10.1007/s11998-025-01227-z","DOIUrl":"10.1007/s11998-025-01227-z","url":null,"abstract":"<div><p>Smart functional materials with intriguing optical properties play a crucial role due to their diverse applications in anticounterfeiting solutions. This review addresses the challenges posed by different counterfeiting activities and introduces various techniques to contest the ever-growing threats. The focus is primarily on potential lanthanide-doped upconversion nanomaterials, which are engineered to create different versions of security inks as countermeasures for counterfeiting. Furthermore, the evolution of these nanomaterials is discussed, showcasing their contribution towards enhancing the complexity of anticounterfeit solutions. The article also discusses the limitations and future scope of synthesizing smart nanomaterials to tackle counterfeiting issues. This comprehensive review will be beneficial in developing futuristic anticounterfeit solutions by exploiting the unique features of Ln-doped nanomaterials to the demanding and challenging field of anti-counterfeiting through security inks.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture><span>The alternative text for this image may have been generated using AI.</span></div></div></figure></div></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1239 - 1260"},"PeriodicalIF":2.8,"publicationDate":"2026-04-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11998-025-01227-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757207","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"A multifunctional superamphiphobic coating with anticorrosion and antibacterial properties","authors":"Rong Wei, Yixing Qi, Guang Feng, Juantao Zhang, Juntao Yuan, Naixin Lv, Anqing Fu, Qiuli Zhang","doi":"10.1007/s11998-025-01252-y","DOIUrl":"10.1007/s11998-025-01252-y","url":null,"abstract":"<div><p>Microbiologically influenced corrosion (MIC), caused by microorganisms such as sulfate-reducing bacteria (SRB), iron bacteria (FB), and heterotrophic bacteria (TGB), accelerates metal oxidation and damages the protective film of coatings through their metabolic activities. Despite the development of various coatings, those capable of preventing microbiologically influenced corrosion (MIC) in metals remain limited. In this research, we have developed a novel type of coating that combines superhydrophobic and antibacterial characteristics, suppressing biofilm formation and preventing corrosion. Two antibacterial superamphiphobic coatings, termed as FPPDC and FPPTC, were created by synthesizing antibacterial fluorinated silica particles through a sol–gel process and incorporating them with two quaternary ammonium salts, i.e., DMOAP and TMAPS, respectively. The FPPDC coating outperforms the FPPTC counterpart in antibacterial performance, mechanical durability, and corrosion resistance. The FPPDC coating achieves a bactericidal efficiency of 99.99% against sulfate-reducing bacteria, higher than 99.00% for the FPPTC coating. Additionally, the FPPDC coating maintains its superhydrophobicity after 1200 abrasion cycles, while the FPPTC loses this property after 1000 cycles. The FPPDC coating successfully combines fluorinated chains and quaternary ammonium salts to achieve both antibacterial and anticorrosion functions, with excellent mechanical stability, making it suitable for MIC mitigation in oilfield environments. This research paves the way for new possibilities in developing multifunctional coatings.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 4","pages":"2175 - 2186"},"PeriodicalIF":3.4,"publicationDate":"2026-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148519469","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
C. Anu, D. Inbakandan, S. Manikandan, Clarita Clements, Subham Chakraborty, T. Naren Kumar, V. Jeevitha
{"title":"Revolutionizing marine antifouling: metal-based nanoparticles and polymer hybrid coatings","authors":"C. Anu, D. Inbakandan, S. Manikandan, Clarita Clements, Subham Chakraborty, T. Naren Kumar, V. Jeevitha","doi":"10.1007/s11998-025-01223-3","DOIUrl":"10.1007/s11998-025-01223-3","url":null,"abstract":"<div><p>Metal and metal oxide (M and MO) nanoparticles are nanosized materials in the size range of 10–100 nm along one dimension. M and MO can be synthesized either by top-down or bottom-up approach. Among the synthesis methods, biological routes of synthesis have been demonstrated to be more eco-friendly exhibiting enhanced activity, compared to nanoparticles synthesized by physical and chemical methods. However, poor reproducibility of the biological route of synthesis is a matter of concern. M and MO nanoparticles find extensive application in marine antifouling coatings, exterior paint coatings, antimicrobial protective coatings for surfaces in clinical settings and hospital environments, and antimicrobial textiles. Apart from environmental applications, to a certain extent, M and MO nanoparticles have achieved success as drug delivery agents and in targeted treatment of cancer cells. Among the various metal and MO nanoparticles, nanoparticles like silver, gold, copper, iron, and zinc and their composites find wide applications as antimicrobial and antifouling protective coatings. This review brings out their antimicrobial, antibiofilm, and antifouling activity focusing mainly on marine biofouling. Methods for surface immobilization of M and MO nanoparticles to develop an antimicrobial surface were actively researched during the last two decades; however, recently M and MO nanoparticles have found increasing application in combination with polymer matrix to form antimicrobial polymer nanocomposites. This advantage is due to the new generation of antifouling coatings, known as nanocomposite polymer coatings, having a chemical composition free of toxins and being simple to apply on a large scale. This comprehensive review paper discusses the present state of research on M and MO nanoparticles along with polymer-based nanocomposites as effective antifouling agents in marine environments.</p></div>","PeriodicalId":619,"journal":{"name":"Journal of Coatings Technology and Research","volume":"23 3","pages":"1217 - 1237"},"PeriodicalIF":2.8,"publicationDate":"2026-04-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"147757198","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}