ACS Applied Materials & Interfaces最新文献_第4页

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23

Qiong Wang, Yihang Zhang, Guangyi Tian and Zhiguang Guo*,

引用次数: 0

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23

Zhexu Song, Yingjie Shi, Tianfu Zhou, Meiqi Yang, Meina Yu, Yanzi Gao, Cheng Zou* and Huai Yang*,

引用次数: 0

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23

Shuming Liu, Chunhua Ge*, Zhiqiang Li, Keke Chen, Xuefeng Li, Chengyao Peng and Xiangdong Zhang*,

引用次数: 0

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23

Masatoshi Maeki*, Ayuka Niwa, Shota Oyama, Kyoko Aratani, Rina Ito, Yuichi Suzuki, Yusuke Sato, Akihiko Ishida, Hideyoshi Harashima and Manabu Tokeshi*,

引用次数: 0

Bioinspired Body-Centered Cubic Evaporators: Leveraging Cellular Fluidics for Ultra-Efficient Solar-Driven Water Evaporation via PμSL. 以生物为灵感的以身体为中心的立方蒸发器：利用细胞流体通过PμSL进行超高效的太阳能驱动水蒸发。

IF 9.5 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23 DOI: 10.1021/acsami.5c09568

Luncao Li,Wei Mao,Tingting Luo,Yuchen Zhou,Zhe Yang,Xuesong Li,Yan Li,Kazushi Yamada,Linmei Zhang,Kunkun Fu

{"title":"Bioinspired Body-Centered Cubic Evaporators: Leveraging Cellular Fluidics for Ultra-Efficient Solar-Driven Water Evaporation via PμSL.","authors":"Luncao Li,Wei Mao,Tingting Luo,Yuchen Zhou,Zhe Yang,Xuesong Li,Yan Li,Kazushi Yamada,Linmei Zhang,Kunkun Fu","doi":"10.1021/acsami.5c09568","DOIUrl":"https://doi.org/10.1021/acsami.5c09568","url":null,"abstract":"We present a bioinspired body-centered cubic evaporator (BCE) that integrates cellular fluidics to achieve unprecedented ultrahigh evaporation flux in solar-driven interfacial evaporation (SDIE). The BCE platform features a three-dimensional cell-based structure fabricated with projection microstereolithography (PμSL) and enhanced with the gold-based photothermal conversion coating. This structure and photothermal conversion coating synergy optimizes water transport, light absorption, and thermal management, resulting in an ultrahigh evaporation flux. The BCE mimics the mechanisms that enhance performance in the tree, where each cell operates both independently and synergistically. Furthermore, the evaporator maintains exceptional structural integrity and stable operation in extreme environments, including natural seawater, acidic and alkaline solutions, and industrial wastewater. These findings position the BCE as a robust and scalable platform for sustainable water desalination and wastewater treatment technologies, contributing significantly to global water security.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"92 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144693452","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Understanding the Growth of ZIF-8 Thin Film and Its Room Temperature Carbon Dioxide Sensing via Quartz Crystal Microbalance. 通过石英晶体微天平了解ZIF-8薄膜的生长及其室温二氧化碳传感。

IF 9.5 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23 DOI: 10.1021/acsami.5c06019

Tzer-Rurng Su,Jeffrey A Dhas,Changqing Pan,Chih-Hung Chang

{"title":"Understanding the Growth of ZIF-8 Thin Film and Its Room Temperature Carbon Dioxide Sensing via Quartz Crystal Microbalance.","authors":"Tzer-Rurng Su,Jeffrey A Dhas,Changqing Pan,Chih-Hung Chang","doi":"10.1021/acsami.5c06019","DOIUrl":"https://doi.org/10.1021/acsami.5c06019","url":null,"abstract":"Metal-organic frameworks (MOFs), particularly zeolitic imidazolate frameworks (ZIFs), have emerged as promising materials for gas sensing applications due to their high surface area and tunable porosity. This study presents a systematic chemical bath deposition (CBD) approach for fabricating ZIF-8 films with precisely controlled thicknesses of up to 2.5 μm on functionalized surfaces. Film particle evolution and growth mechanisms were investigated by using scanning electron microscopy (SEM), X-ray diffraction (XRD), X-ray photoelectron spectroscopy (XPS), and time-of-flight secondary ion mass spectrometry (ToF-SIMS) combined with in situ growth monitoring. Imidazolate achieved a uniform growth rate of 95 nm per cycle, and imidazolate-surface interfacial coordination was elucidated. By integrating these controllable ZIF-8 films with a quartz crystal microbalance (QCM), we developed a gravimetric gas sensor that demonstrated enhanced CO2 adsorption capacity with increasing film thickness and achieved a detection limit of 0.5%. This systematic approach to controlling the ZIF-8 film thickness enables precise quantification of gas absorption, advancing the development of high-precision gas sensors for environmental monitoring applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"15 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144684189","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Near-Infrared Sm²⁺ Complexes with Temperature-Dependent Emission Mechanisms: Thermally Activated Delayed d-f Transition and f-f Transition. 具有温度依赖发射机制的近红外Sm2+配合物：热激活延迟d-f跃迁和f-f跃迁。

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23 Epub Date: 2025-07-11 DOI: 10.1021/acsami.5c09249

Ruoyao Guo, Huanyu Liu, Peiyu Fang, Wenchao Yan, Jiayin Zheng, Zuqiang Bian, Zhiwei Liu

{"title":"Near-Infrared Sm2+ Complexes with Temperature-Dependent Emission Mechanisms: Thermally Activated Delayed d-f Transition and f-f Transition.","authors":"Ruoyao Guo, Huanyu Liu, Peiyu Fang, Wenchao Yan, Jiayin Zheng, Zuqiang Bian, Zhiwei Liu","doi":"10.1021/acsami.5c09249","DOIUrl":"10.1021/acsami.5c09249","url":null,"abstract":"Due to the instability of divalent samarium, studies of luminescent Sm2+ compounds are mainly focused on doping Sm2+ ions into inorganic solids, with very limited work on molecular complexes. In this work, three Sm2+ complexes SmI2-O5, SmI2-O4, and SmI2-O6 (O5 = 15-crown-5, O6 = 18-crown-6, and O4 = 12-crown-4) were synthesized, showing near-infrared emissions with maximum wavelengths at 765, 728, and 730 nm in solid powder at room temperature, respectively. Interestingly, these Sm2+ complexes exhibit temperature-dependent emission mechanism transformation from a thermally activated delayed d-f transition at room temperature to f-f transition at low temperature, which is proven to be a fast thermal equilibrium between the two excited states 5d* and 4f*. This phenomenon results in an obvious excited state lifetime change upon temperature, and the three complexes are demonstrated as the most efficient lifetime-readout luminescence thermometer among divalent samarium compounds, showing the highest maximum temperature sensitivity of 5.9% K-1 at 75 K. Further organic ligand extension from crown ether to azacrown ether results in redshifted emission with a maximum wavelength around 900 nm. These results demonstrate the interesting photophysical properties of molecular Sm2+ complexes and will inspire their studies as well as potential applications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42128-42138"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144606802","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Antifreezing and Temperature-Responsive Ionic Hydrogels with Applications in Encryption and Sensor Technologies. 防冻和温度响应离子水凝胶及其在加密和传感器技术中的应用。

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23 Epub Date: 2025-07-14 DOI: 10.1021/acsami.5c08600

Xia Qiu, Xiaolong He, Kubra Kalayci, Paul Morandi, Petra Rudolf, Rudy Folkersma, Vincent S D Voet, Katja Loos

{"title":"Antifreezing and Temperature-Responsive Ionic Hydrogels with Applications in Encryption and Sensor Technologies.","authors":"Xia Qiu, Xiaolong He, Kubra Kalayci, Paul Morandi, Petra Rudolf, Rudy Folkersma, Vincent S D Voet, Katja Loos","doi":"10.1021/acsami.5c08600","DOIUrl":"10.1021/acsami.5c08600","url":null,"abstract":"The use of thermoresponsive hydrogels for applications such as sensors, thermal gates, smart windows, actuators, and molecular devices has increased in popularity in the past decade. However, existing thermoresponsive biobased hydrogel sensors face challenges in rapidly responding to ambient temperature changes and retaining flexibility at subzero temperatures. To overcome these limitations, a novel hydrogel composed of dextrin, glycerol, and the ionic liquid monomer tetrabutylphosphonium styrenesulfonate (PSS) was developed and utilized as a smart sensor material for the first time. The thermoresponsive characteristics of PSS endow the hydrogel with remarkable thermoresponsiveness, which is a lower critical solution temperature (LCST)-type phase transition. In addition, the hydrogel can be used as a thermally responsive material over a broad temperature range of 20-60 °C. We used glycerol and glycidyl methacrylate dextrin (Dex-GMA) monomers with a multihydrogen bond structure to construct a Dex-GMA-PSS conductive hydrogel with antifreeze properties even at -20 °C. Hence, the hydrogels formulated in this study exhibit promising potential for several applications, including flexible wearable devices, skin-like sensors, advanced anticounterfeiting, and encryption technologies across a broad temperature range.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"42303-42320"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635701","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Edible Hybrid Sporopollenin Microspheres with Nanozyme for Oral Treatment of Inflammatory Bowel Disease. 含纳米酶的可食用杂交孢粉微球口服治疗炎症性肠病。

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23 Epub Date: 2025-07-14 DOI: 10.1021/acsami.5c08167

Peipei Xi, Xiangyu Wei, Yuting Huang, Yunan Wang, Nengjie Yang, Yongxin Xu, Hao Zhang, Yujuan Zhu, Zhifeng Gu

{"title":"Edible Hybrid Sporopollenin Microspheres with Nanozyme for Oral Treatment of Inflammatory Bowel Disease.","authors":"Peipei Xi, Xiangyu Wei, Yuting Huang, Yunan Wang, Nengjie Yang, Yongxin Xu, Hao Zhang, Yujuan Zhu, Zhifeng Gu","doi":"10.1021/acsami.5c08167","DOIUrl":"10.1021/acsami.5c08167","url":null,"abstract":"Inflammatory bowel disease (IBD) is a chronic recurrent inflammatory disease, and the treatment of IBD remains a challenge due to its limited therapeutic efficiency, high side effects, and high cost. It has been demonstrated that sporopollenin microcapsules derived from a variety of pollen species could function as efficient drug carriers due to their great thermal stability, resilience to harsh chemicals, homogeneity in size, and biocompatibility. Herein, we engineered a biohybrid nanozyme-based edible sporopollenin system, which can be applied to effectively treat IBD. The biohybrid sporopollenin (CeNP-P) loaded with a cerium oxide nanozyme (CeNP) was encapsulated in microspheres (CeNP-P/MS) by a microfluidic electrospray technique. This micronanosystem protects the CeNP-P from degradation in gastric conditions and enables the rapid release of CeNP-P in the intestine. The released CeNP exhibited the desired anti-inflammatory effects by suppressing pro-inflammatory cytokines and scavenging reactive oxygen species. To explore its practical value, in vivo experiments have been carried out with an IBD mouse model. Compared to the IBD group, the treatment groups displayed significant therapeutic outcomes, particularly the CeNP-P/MS group. Following taking CeNP-P/MS orally, key IBD symptoms were greatly alleviated, as evidenced by the restored colonic morphology, enhanced intestinal barrier integrity, and induced inflammatory responses. Collectively, these findings demonstrate that the present edible system can offer a promising strategy for the effective treatment of intestinal diseases.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"41747-41755"},"PeriodicalIF":8.3,"publicationDate":"2025-07-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144635703","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

IF 8.3 2区材料科学

ACS Applied Materials & Interfaces Pub Date : 2025-07-23

Jiayang Luo, Luyao Xu, Jing Feng, Kexin Xu, Peilin Tian, Xianyue Bai, Shihao Xu, Liewei Wen, Cuixia Lu* and Jiaxing Song*,

引用次数: 0