ACS Applied Materials & Interfaces最新文献

{"title":"Promoting Drug Delivery to the Brain by Modulating the Transcytosis Process across the Blood–Brain Barrier","authors":"Li Zhang, Zhennan Mao, Weibin Li, Siyu Chi, Hemei Cheng, Zijun Wang, Caixia Wang, Zhihong Liu","doi":"10.1021/acsami.5c02767","DOIUrl":"https://doi.org/10.1021/acsami.5c02767","url":null,"abstract":"The blood–brain barrier (BBB) presents a major challenge in the theranostics of brain diseases by impeding the delivery of drugs to the brain. Currently the most common strategy for transferring substances across the BBB is receptor-mediated transcytosis, which is restricted by several key factors, including insufficient endocytosis by brain microvessel endothelial cells (BMECs) due to underexpressed pinocytotic vesicles, lysosomal retention, and limited exocytosis to the brain parenchyma. We report a hybrid cell membrane (HCM)-coated and 2-methacryloyloxyethyl phosphorylcholine (MPC)-modified nanocarrier to promote drug delivery across the BBB by modulating the transcytosis process. The HCM incorporates a brain metastatic tumor cell membrane for recognition of BMECs and a GFP-293-S cell membrane expressing Spike protein to facilitate membrane fusion between the nanocarrier and BMECs, thereby bypassing vesicle-dependent endocytosis and enhancing cellular uptake. Membrane fusion reduces the chance of lysosomal retention, and MPC modification enhances exocytosis into the brain parenchyma via the interaction of MPC with transporters expressed on the abluminal endothelial membrane. The nanocarrier achieves significantly improved delivery of CuS, a photothermal agent, to the brain and thus enables highly efficient therapy of brain glioma.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"61 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143776150","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Correction to “Engineered Carrier-Free Nanosystem-Induced In Situ Therapeutic Vaccines for Potent Cancer Immunotherapy”","authors":"Min Zhang, Yifan Zhao, Bai Lv, Huimei Jiang, Zequn Li, Jie Cao","doi":"10.1021/acsami.5c05795","DOIUrl":"https://doi.org/10.1021/acsami.5c05795","url":null,"abstract":"In the original version of this article, on page 47274, one of the confocal microscopy images in Figure 5C was duplicated. Specifically, the living and dead cell staining in the Cel and BCC+NIR treatment groups shares the same image. This mistake occurred during the figure assembly and was noticed by the authors during regular inspection of the published raw data. The correct Figure 5C is provided below. Figure 5. (C) confocal fluorescence images of 4T1 cells treated with different samples contained with living and dead cell staining. Scale bar is100 μm. Regarding Figure S10A of the Supporting Information, during data verification, we identified a misalignment in the Saline control group images. The corrected Figure S10A is provided below. Figure S10. (A) The images of treated tumors and untreated tumors stained with H&E. Scale bar is 50 μm. These corrections do not affect the results and conclusions of this article. This article has not yet been cited by other publications.","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":"16 1","pages":""},"PeriodicalIF":9.5,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143776149","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Phase-Composite InO_<i>x</i> Semiconductors for High-Performance Flexible Thin-Film Transistors.","authors":"Quang Khanh Nguyen, Giang Hoang Pham, Thi Thu Huong Chu, Dai Cuong Tran, Sung Ho Yu, Sangho Cho, Myung Mo Sung","doi":"10.1021/acsami.5c00350","DOIUrl":"https://doi.org/10.1021/acsami.5c00350","url":null,"abstract":"<p><p>Indium oxide (InO_<i>x</i>) offers high electron mobility and optical transparency, making it a promising material for advanced thin-film transistors (TFTs). However, challenges related to the high carrier concentration, crystallization control, and instability limit its performance. In this study, we demonstrate the fabrication of amorphous/nanocrystal phase-composite InO_<i>x</i> films using high-pressure atomic layer deposition (ALD) using InCA-1 and H₂O₂ as the metal precursor and oxidant, respectively. The amorphous matrix in the phase-composite structure enables resonant hybridization, facilitating efficient electron transport by forming delocalized states via wave function overlap between nanocrystalline and amorphous regions. The systematic investigation of the deposition temperature and channel thickness allowed precise control over carrier concentration and fine-tuning of the phase-composite structure. The optimized InO_<i>x</i> films, deposited at 110 °C with a 7.0 nm thick InO_<i>x</i> channel, exhibited outstanding electrical properties, including a field-effect mobility of 61.1 cm² V^-1 s^-1, an on/off ratio of ∼0.9 × 10⁶, and a subthreshold swing of 0.45 V dec^-1. The films also demonstrate high reproducibility, high optical transmittance (>87% in the visible range), and smooth surface morphology with a root-mean-square roughness of 3.03 Å. Moreover, the devices exhibited remarkable mechanical flexibility, maintaining stable operation after 10,000 bending cycles with a bending radius of 3 mm, and excellent environmental stability, retaining performance after 60 days of ambient air exposure. This study addresses key limitations of conventional InO_<i>x</i>-based TFTs by improving the phase control, carrier concentration regulation, and mechanical durability, offering a promising pathway for next-generation electronic and optoelectronic applications.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":""},"PeriodicalIF":8.3,"publicationDate":"2025-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143770688","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Tunable Dimensionality and Emission of Organic Metal Halides by Denser Stacking of Pb-Br Polyhedra.","authors":"Jiajing Zhou, Dongjie Tian, Wenhao Bai, Kunjie Song, Rundong Tian, Litipu Aihaiti, Rong-Jun Xie","doi":"10.1021/acsami.4c22649","DOIUrl":"10.1021/acsami.4c22649","url":null,"abstract":"<p><p>Organic metal halides (OMHs) have attracted extensive research interests due to their interesting photoluminescent properties. However, to date, most OMHs have been synthesized through the trial-and-error method, and it remains a big challenge to control the molecular-level structures through directed synthetic approaches to rationally optimize luminescence properties. In this work, we proposed a crystal structure modulation strategy to control the dimensionality and optical properties of OMHs by increasing the packing density of Pb-Br octahedra via altering the precursor stoichiometry. By precisely adjusting the ratio of 3-aminomethylpyridine to PbBr₂ in the initial reactants, (C₆N₂H₁₀)₂PbBr₆ (0D-J1) with a 0D structure, (C₆N₂H₁₀)PbBr₆ (2D-J2) with a 2D structure, and C₃NH₅PbBr (3D-J3) with a 3D structure were successfully synthesized. 0D-J1 exhibits a bright broadband yellow emission with a photoluminescence quantum yield (PLQY) of 35.40%. 2D-J2 shows a free exciton narrowband emission at room temperature and self-trapped excitons (STEs) emission at low temperatures. 3D-J3 displays a permanent defect state broad emission at room temperature. Additionally, the synthesis of compounds from the T series and P series with different dimensionalities further verifies the general applicability of this strategy. This strategy enables the directed control of the structure and optical properties of LD-OMHs while preserving the functionality of organic cations, and paves an avenue for designing and synthesizing LD-OMHs with functional coordination between organic cations and inorganic polyhedra. Together with the efficient emission and outstanding stability of 0D-J1, a high-performance white-light emitting diode (WLED) with a high color rendering index (CRI) of 92 is demonstrated.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19917-19927"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143646349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"High-Efficiency Perovskite Solar Cells with Oriented Growth and Consolidated ABX₃ Structures via Multifunctional Ionic Liquids at Buried Interfaces.","authors":"Hanyu Wang, Lang Yang, Weifeng Lv, Maoqi Gan, Zheng Zhang, Zhijiang Lv, Xingchong Liu, Haimin Li","doi":"10.1021/acsami.5c01012","DOIUrl":"10.1021/acsami.5c01012","url":null,"abstract":"<p><p>Although perovskite solar cells (PSCs) are advancing rapidly, a series of issues including interfacial nonradiative recombination losses continue to constrain their photovoltaic performance. Herein, a multifunctional fluorinated pseudohalide ionic liquid 1-ethyl-3-methylimidazolium bis(trifluoromethylsulfonyl)imide (EMIMTFSI) is introduced at the buried interface to passivate the interfacial defect and consolidate the perovskite ABX₃ structure effectively. The results reveal that the fluorine and sulfonyl groups on EMIMTFSI can passivate the oxygen vacancy defects in the SnO₂ layer, thereby enhancing the interfacial contact and effectively suppressing the nonradiative charge recombination. In addition, EMIMTFSI facilitates the oriented growth of perovskite along the (110) plane and promotes the enlargement of perovskite grains. Furthermore, the anionic TFSI^- and cationic EMIM⁺ ions stabilize the perovskite ABX₃ structure by filling X-vacancy defects in the perovskite crystals and by coordinating them with uncoordinated Pb²⁺ defects. Hence, the W EMIMTFSI device exhibits a significant increase in power conversion efficiency from 20.74% to 22.73% and obtains an excellent long-term stability. This study presents a possible innovative way to achieve a highly efficient and stabilizing PSC by EMIMTFSI multifunctional modifications at buried interfaces.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19754-19761"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661561","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"A Redox Mediator Containing Reversible Dynamic Boron-Oxygen Bonds to Construct an Adaptive SEI Layer for Advanced Li-O₂ Batteries.","authors":"Yaling Liao, Xiaoping Zhang, Zhongyu Huang, Xinxin Zhuang, Menglin Gao","doi":"10.1021/acsami.4c21918","DOIUrl":"10.1021/acsami.4c21918","url":null,"abstract":"<p><p>Lithium-oxygen (Li-O₂) batteries have high theoretical energy density, but the discharge product Li₂O₂ of Li-O₂ batteries is difficult to decompose, resulting in the undesirably high charging potential. The use of soluble redox mediators (RMs) can usually reduce the high charging potential of Li-O₂ batteries, but the RM on the cathode side can diffuse to the Li metal anode and react with it, leading to continuous loss of the RM and causing damage to the fragile Li anode interface. So, it is necessary to develop a bifunctional redox mediator (BRM) that can simultaneously reduce the charging potential and protect the Li anode. Herein, we introduced 4-bromomethyl-phenylboronic acid (BPLA) as a BRM. The Br^- ions can be dissociated from BPLA during cycling and serve as an effective component of RM, thereby significantly facilitating the reduction of charging potential of Li-O₂ batteries. Meanwhile, the boronic acid groups in BPLA have the capability to engage in cross-linking reactions on the Li-metal surface, forming a flexible and continuous solid-electrolyte interphase (SEI) layer. More importantly, the SEI layer contains the reversible dynamic B-O covalent bond, which possesses a characteristic of continuous dissociation and rearrangement. Thereby the SEI layer possesses the shape adaptability, inhibits the growth of Li dendrites, and suppresses the reaction between RM and Li. Consequently, our BPLA, serving as the BRM, can enable Li-O₂ batteries to achieve a stable cycle life of 180 cycles under the low charge potential up to 4.0 V.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19629-19637"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661577","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Directing Ion Transport and Interfacial Chemistry in Pnictogen-Substituted Thio-LISICONs.","authors":"Philip Yox, Glenn Teeter, Lucas Baker, Drew Whitney, Annalise E Maughan","doi":"10.1021/acsami.4c22390","DOIUrl":"10.1021/acsami.4c22390","url":null,"abstract":"<p><p>Aliovalent substitution is a ubiquitous strategy to increase ionic conductivity in solid-state electrolytes, often by many orders of magnitude. However, the structural and compositional changes that occur upon aliovalent substitution are highly interrelated, and a deep understanding of how substitutions simultaneously impact ion transport and the chemical evolution of interfaces during electrochemical cycling remain as prevailing challenges. Here, we interrogate aliovalent pnictogen substitution of Li₄GeS₄ in the series Li_3.7Ge_0.7Pn_0.3S₄ (Pn = P, As, Sb) and unravel the impact on ion transport processes and degradation during electrochemical cycling. High-resolution powder X-ray diffraction and pair distribution function analysis reveal that all substituted compounds exhibit an anisometric distortion of the Li₄GeS₄ structure. Temperature-dependent potentiostatic electrochemical impedance spectroscopy reveals that aliovalent substitution increases the room-temperature lithium ionic conductivity by 2 orders of magnitude. Curiously, aliovalent substitution results in a simultaneous increase in the Arrhenius prefactor and decrease in the activation barrier, which contribute to the significant increase in lithium-ion conductivity. We attribute this apparent violation of the \"Meyer-Neldel\" entropy-enthalpy compensation to the introduction of Li⁺ vacancies that elicit a redistribution of the lithium substructure. Electrochemical stability and cycling performance were interrogated by critical current density tests on symmetric cells with Li electrodes coupled with virtual electrode X-ray photoelectron spectroscopy measurements. In all substituted compounds, we observe the growth of electronically conductive phases that result in continual growth of the solid electrolyte interphase and increase in interfacial impedance during electrochemical cycling. We find that electrochemical instability against Li⁰ is predominantly driven by reduced Ge species. Taken together, our study presents holistic insights into the structural and compositional factors that drive ionic conductivity and electrochemical degradation in lithium metal sulfide solid-state electrolytes.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19906-19916"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143661623","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Strategic Material Design for Highly Reliable QLC 3D V-NAND Using Bypass Resistive Random Access Memory.","authors":"Geonhui Han, Jongseon Seo, Junghoon Park, Minji Hong, Juhyung Kim, Kilho Lee, Wanki Kim, Daewon Ha, Hyunsang Hwang","doi":"10.1021/acsami.5c00352","DOIUrl":"10.1021/acsami.5c00352","url":null,"abstract":"<p><p>To overcome the limitation of conventional flash memory, electrochemical random-access memory (ECRAM)-based bypass memory (bypass RRAM) has been proposed as a potential candidate for V-NAND memory application. While bypass RRAM demonstrates excellent memory characteristics through ion hopping conduction, the key parameters governing multilevel cell (MLC) operation remain unexplored. In this study, we propose design guidelines for bypass RRAM, targeting highly uniform quadruple-level cell (QLC) operation by using quantized oxygen vacancy (V_o) injections. To achieve the uniform QLC operation, we precisely controlled ion migration using material engineering in the bypass RRAM. By leveraging the unique electrical characteristic of the WO_<i>x</i> resistive switching (RS) layer, we minimized V_o migration (from WO_2.65 to WO_2.73), which enabled low-voltage operation (<5 V) and a significant on/off ratio (>10⁶) with a minimal stoichiometry (Δ<i>x</i> < 0.08) change. Additionally, key parameters, such as ionic barrier (<i>E</i>_a,ion) in the electrolyte layer and ion diffusivity (<i>D</i>_ion) in the RS layer, were identified to achieve both a high on/off ratio and a uniform sensing margin based on MATLAB simulations and experimental results. As a result, optimized parameters led to superior QLC performance, featuring a highly uniform distribution (σ/μ ∼ 0.01) and a uniform sensing margin (Δ<i>G</i> ∼ 4 μS) between each state without read disturbance issues. Finally, we also confirmed that the substantial reduction of the V_o migration at the nanometer scale suggests the potential for extending beyond QLC levels with quantized V_o injection, ensuring highly uniform switching for V-NAND memory.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"19977-19986"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143690460","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Efficient Defect Healing of Single-Walled Carbon Nanotubes through C₂H₂-Assisted Multiple-Cycle Treatment with Air Exposure.","authors":"Man Shen, Taiki Inoue, Mengyue Wang, Yuanjia Liu, Yoshihiro Kobayashi","doi":"10.1021/acsami.5c00619","DOIUrl":"10.1021/acsami.5c00619","url":null,"abstract":"<p><p>Defects in single-walled carbon nanotubes (SWCNTs) degrade their mechanical, electrical, and thermal properties, limiting their potential applications. To realize the diverse applications of SWCNTs, it is essential to enhance their crystallinity through effective defect healing. However, traditional thermal treatments typically require temperatures above 1800°C, which can alter the nanotube structure. Previously, defect healing of SWCNTs was achieved at a relatively low temperature of 1100°C, using C₂H₂ assistance, but the efficiency was limited. In this study, we developed a C₂H₂-assisted multiple-cycle process at an even lower temperature of 1000°C combined with air exposure, achieving highly efficient defect healing while preserving the nanotube structure. The combination of multiple-cycle treatment and air exposure between cycles was found to promote defect activation, suppress the formation of amorphous carbon, and enhance the effectiveness of defect healing. Additionally, we successfully healed commercially available bulk-scale SWCNTs (supergrowth SWCNTs), noting that their healing behavior differed from lab-grown SWCNTs with smaller diameters synthesized from nanodiamond. The efficient and structure-preserved healing process developed in this study broadens the potential applications of high-quality SWCNTs, including flexible electronics, high-performance composites, and energy storage devices.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"20105-20115"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143699125","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Electron-Withdrawing Effects for Tailoring Oxidative-Stress-Mediated Coating in Marine Antifouling.","authors":"Chao Wang, Rongrong Chen, Wenbin Liu, Jing Yu, Qi Liu, Jingyuan Liu, Jiahui Zhu, Cunguo Lin, Ying Li, Jun Wang","doi":"10.1021/acsami.5c00106","DOIUrl":"10.1021/acsami.5c00106","url":null,"abstract":"<p><p>Oxidative stress derived from excess reactive oxygen radicals (ROS) induces cellular damage, apoptosis, and necrosis, thus effective biofouling control by directly inhibiting primary membrane formation. However, the oxidative stress produced that does not rely on additional energy still is a challenge. Herein, an oxidative-stress-mediated marine antifouling polyurea coating is prepared leveraging the strong electron absorption effect of C═N. Given the structure of the urethane bond, the reversible reaction energy barrier of the dynamic urethane bond can be reduced, thereby enabling the urethane bond to be broken without the need for additional energy. The alkyl radical (R·) originating from the oxime-urethane bond can mediate the induction of oxidative stress in cells and microbial death, thus preserving exceptional antifouling properties and resisting most of the organism to adhere on the substrates. Notably, the coating indicates satisfactory antibacterial and antialgae performance and exhibits 8 months of marine field antifouling performance. In addition, the electron structure is investigated by theoretical calculation, and the interface behavior is investigated by molecular dynamics simulation. This work presents a pioneering example of the construction of oxidative-stress-mediated coating, which might be a judicious design strategy for an environmentally friendly marine antifouling coating.</p>","PeriodicalId":5,"journal":{"name":"ACS Applied Materials & Interfaces","volume":" ","pages":"20438-20451"},"PeriodicalIF":8.3,"publicationDate":"2025-04-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143690350","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}