Indian Journal of Physics最新文献

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Tunable optical properties of silicon nanowires for photovoltaic devices 光电器件用硅纳米线的可调光学特性
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-12 DOI: 10.1007/s12648-026-04055-y
Vrishty Kundu, Omita Nanda, Dalip Singh Mehta, Kanchan Saxena
{"title":"Tunable optical properties of silicon nanowires for photovoltaic devices","authors":"Vrishty Kundu,&nbsp;Omita Nanda,&nbsp;Dalip Singh Mehta,&nbsp;Kanchan Saxena","doi":"10.1007/s12648-026-04055-y","DOIUrl":"10.1007/s12648-026-04055-y","url":null,"abstract":"<div><p>In recent times, silicon nanowires (Si-NWs) have been primarily used as an inorganic layer in producing hybrid solar cells, mainly because of their enhanced optical absorption characteristics. This study utilizes the metal-assisted chemical etching (MACE) technology to produce vertically aligned, long Si-NWs with a high aspect ratio. The role of metal nanoparticles in the MACE technique was investigated, and the structure optimization process was performed by altering the etching time. Observations indicate that the concentration of metal solution influences both the size and spacing of Si-NWs, whereas the etching time affects the length of the Si-NWs. The optical characteristics of the Si-NWs were also examined utilizing the experimental diffuse reflection spectra. In addition, a 3D finite difference time domain (FDTD) simulation was conducted to analyse and compare the absorption spectra of the created Si-NWs with the experimental findings. Systematic analysis of absorption as a function of the geometry of nanowires (NWs) indicates that as the length and the diameter increase it demonstrates notable anti-reflection properties. This can be attributed to the larger surface area of the NWs and increased roughness/disordered surface. Hence, the work concisely illustrates the essential significance of improved absorption of Si-NWs in attaining optimal efficiency in hybrid solar cell applications.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 10","pages":"4405 - 4416"},"PeriodicalIF":1.7,"publicationDate":"2026-05-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148909435","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Generation of plasmon modes at chiral- black phosphorus interface 手性-黑磷界面等离子体模式的产生
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-07 DOI: 10.1007/s12648-026-04054-z
M. Nadeem, M. Umair, A. Ghaffar, Imran Shakir
{"title":"Generation of plasmon modes at chiral- black phosphorus interface","authors":"M. Nadeem,&nbsp;M. Umair,&nbsp;A. Ghaffar,&nbsp;Imran Shakir","doi":"10.1007/s12648-026-04054-z","DOIUrl":"10.1007/s12648-026-04054-z","url":null,"abstract":"<div><p>This study presents a numerical analysis at the planar interface of chiral-black phosphorus (BP) and investigates the characteristics of surface plasmon polaritons (SPPs) in the terahertz (THz) spectral region. The extended electromagnetic (EM) wave theory is employed for the numerical calculations, while the impedance boundary condition approach is used to derive the dispersion relation. The results demonstrate that the strong anisotropic dispersion of BP gives direction-dependent plasmon modes. The normalized propagation constant (NPC) of plasmon modes is found to be highly sensitive to electron doping, number of BP layers, chirality, and the refractive index of the chiral medium for the conductivity components of BP along the zigzag <span>({(sigma }_{zz}))</span> and armchair <span>(({sigma}_{ac}))</span> directions. Moreover, the electromagnetic field propagation characteristics can be modified effectively by tuning both the chiral and BP parameters. The presented results can be used to fabricate tunable THz devices, providing an extra degree of freedom arising from the anisotropic conductivity of BP.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 10","pages":"4397 - 4403"},"PeriodicalIF":1.7,"publicationDate":"2026-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148909478","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Pattern of solar activity levels and their effects on galactic cosmic ray particle fluxes throughout 23rd and 24th solar cycle 第23和24个太阳活动周期的太阳活动水平模式及其对银河系宇宙射线粒子通量的影响
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-07 DOI: 10.1007/s12648-026-03984-y
Ahmad Yusof Abdo Jamal, Nurul Shazana Abdul Hamid, Idahwati Sarudin
{"title":"Pattern of solar activity levels and their effects on galactic cosmic ray particle fluxes throughout 23rd and 24th solar cycle","authors":"Ahmad Yusof Abdo Jamal,&nbsp;Nurul Shazana Abdul Hamid,&nbsp;Idahwati Sarudin","doi":"10.1007/s12648-026-03984-y","DOIUrl":"10.1007/s12648-026-03984-y","url":null,"abstract":"<div><p>Since the discovery of sunspots on the Sun’s surface, solar sunspot numbers (SSN) have been widely used to study solar activity (SA) and its cyclical behaviour. These cycles arise from processes in the Sun’s core and surface, which modulate SA intensity over time. Researchers commonly divide each solar cycle (SC) into distinct phases—minimum, inclining, maximum, and declining—each characterised by different activity levels. However, few studies have systematically characterised SA intensity across these phases, particularly in relation to space weather events and cosmic ray (CR) fluxes, both of which are strongly influenced by SA. This study investigated the variation of SSN, the F10.7 index, solar flare and geomagnetic storm frequencies, and CR particle intensities across SC23 and SC24. SC phases were defined using SSN and F10.7 data, after which all variables were composited by phase and analysed using phase-averaged values. A percentage difference analysis was also conducted to assess variability between the two cycles, while Spearman correlation was employed to evaluate the alignment between SA proxies, space weather, and CR particle fluxes. The results revealed coherent trends in SA proxies across the SC phases, with SC23 showing higher activity levels than SC24. Solar flare frequency aligned closely with SA phases, while geomagnetic storms showed a lag of one to two phases. Proton flux, helium flux, and neutron counts exhibited inverse correlations with SA proxies due to solar wind modulation, although solar energetic particles introduced minor irregularities. The study recommends further use of phase-based approaches in SA research to improve understanding of the Sun’s influence on space weather and CR variability.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 6","pages":"2165 - 2178"},"PeriodicalIF":1.7,"publicationDate":"2026-05-07","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148281080","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and long afterglow characteristics of Zn2GeO4:Mn2+, Pr3+ phosphors optimized by rotational compositedesign 旋转复合设计优化Zn2GeO4:Mn2+, Pr3+荧光粉的合成及长余辉特性
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-06 DOI: 10.1007/s12648-026-04051-2
Shengyi Liu, Duan Gao, Ying Zhu, Xin Chen, Xilai Zhang, Shizhuang Guo, Tianai Zhu, Li Wang, Wenbin Song, Haoyu Liu
{"title":"Synthesis and long afterglow characteristics of Zn2GeO4:Mn2+, Pr3+ phosphors optimized by rotational composite\u0000design","authors":"Shengyi Liu,&nbsp;Duan Gao,&nbsp;Ying Zhu,&nbsp;Xin Chen,&nbsp;Xilai Zhang,&nbsp;Shizhuang Guo,&nbsp;Tianai Zhu,&nbsp;Li Wang,&nbsp;Wenbin Song,&nbsp;Haoyu Liu","doi":"10.1007/s12648-026-04051-2","DOIUrl":"10.1007/s12648-026-04051-2","url":null,"abstract":"<div><p>To maximize the effective afterglow time of Zn<sub>2</sub>GeO<sub>4</sub>: Mn<sup>2+</sup>, Pr<sup>3+</sup> phosphors, a second general rotational composite design strategy was employed to optimize the concentrations of Mn<sup>2+</sup> and Pr<sup>3+</sup>. A quadratic regression equation model was established between the doping concentration of rare-earth ions Mn<sup>2+</sup> and Pr<sup>3+</sup> and the effective afterglow time. The theoretical optimal value of the effective afterglow time was precisely solved through a genetic algorithm. Using the high-temperature solid-state method, we successfully synthesized the phosphor Zn<sub>2</sub>GeO<sub>4</sub>: 0.5 mol% Mn<sup>2+</sup>, 2.3 mol% Pr<sup>3+</sup> with the optimal doping concentration and performed detailed characterization and analysis. The results show that doping with Mn<sup>2+</sup> and Pr<sup>3+</sup> significantly improved the long afterglow properties of Zn<sub>2</sub>GeO<sub>4</sub>. Under 328 nm excitation, a characteristic emission peak at 535 nm was observed, and Zn<sub>2</sub>GeO<sub>4</sub>: Mn<sup>2+</sup>/Pr<sup>3+</sup> exhibited an emission band corresponding to the <sup>4</sup>T<sub>1</sub> → <sup>6</sup>A<sub>1</sub> transition of Mn<sup>2+</sup>. In the Zn<sub>2</sub>GeO<sub>4</sub>: Mn<sup>2+</sup>/Pr<sup>3+</sup> phosphor, Pr<sup>3+</sup> substitution of Zn<sup>2+</sup> generated positive defects of Pr<sup>′</sup><sub>Zn</sub> and vacancy defects of V<sup>′′</sup><sub>Zn</sub>. Furthermore, we measured the thermoluminescent properties of the optimal phosphor, calculating the trap depth to be 0.4608 eV, and discussed the relevant characteristics of long afterglow luminescence.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 9","pages":"3925 - 3934"},"PeriodicalIF":1.7,"publicationDate":"2026-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148751121","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis and study of nonlinear optical properties of an enaminothione derived from enaminone and Lawesson’s reagent 由漆胺酮和Lawesson试剂衍生的漆胺硫酮的合成及非线性光学性质的研究
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-06 DOI: 10.1007/s12648-026-04052-1
Firas A. Nawar, Qusay M. A. Hassan, Bahjat A. Saeed, H. A. Sultan, C. A. Emshary
{"title":"Synthesis and study of nonlinear optical properties of an enaminothione derived from enaminone and Lawesson’s reagent","authors":"Firas A. Nawar,&nbsp;Qusay M. A. Hassan,&nbsp;Bahjat A. Saeed,&nbsp;H. A. Sultan,&nbsp;C. A. Emshary","doi":"10.1007/s12648-026-04052-1","DOIUrl":"10.1007/s12648-026-04052-1","url":null,"abstract":"<div><p>Lawesson’s reagent is used with β-enaminone to synthesize the compound (Z)-1,3-diphenyl-3-(phenylamino) prop-2-ene-1-thione. The 6–311 + + G(d,p) basis set is employed to evaluate the stability of the molecule’s probable tautomers via DFT with the functionals ωB97XD, M062X, B3LYP, and CAM-B3LYP. The ρBCP value for the hydrogen bond in the gas phase ranges from 0.035962 to 0.038105 e/a03. The intramolecular hydrogen bonding is relatively weak, as evidenced by atoms in molecules (AIM) computations conducted across several media and theoretical models. We examine the nonlinear optical (NLO) properties of enaminothione after illuminating with two continuous wave (CW) laser beams. We employ diffraction patterns (DPs) and the closed aperture (CA) Z-scan techniques to determine the nonlinear refractive index (NLRI) of enaminothione. The NLRI is equal 4.996 × 10<sup>–7</sup> cm<sup>2</sup>/W at the wavelength 473 nm. The application of 473 nm and 532 nm laser beams on enaminothione has demonstrated its ability to transition between all-optical switching (AOS).</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 9","pages":"3935 - 3947"},"PeriodicalIF":1.7,"publicationDate":"2026-05-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148751122","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Angle-tuned structural and optical properties of ZnTe thin films grown by glancing angle deposition 掠射角沉积ZnTe薄膜的角调谐结构和光学性能
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-04 DOI: 10.1007/s12648-026-03976-y
R. Zarei, M. H. Ehsani, R. Zarei Moghadam
{"title":"Angle-tuned structural and optical properties of ZnTe thin films grown by glancing angle deposition","authors":"R. Zarei,&nbsp;M. H. Ehsani,&nbsp;R. Zarei Moghadam","doi":"10.1007/s12648-026-03976-y","DOIUrl":"10.1007/s12648-026-03976-y","url":null,"abstract":"<div><p>Zinc telluride (ZnTe) thin films were deposited on glass substrates using the glancing angle deposition (GLAD) technique under high vacuum. The effect of deposition angle on the structural and optical properties of the films was systematically studied. X-ray diffraction (XRD) analysis revealed that varying the incident vapor angle significantly influenced the crystallographic orientation, grain size, and overall crystallinity. All samples exhibited a cubic zinc-blende structure, with a shift in preferred orientation as the deposition angle increased. Optical characterization using UV- Vis spectroscopy showed pronounced changes in absorption coefficient, optical band gap, refractive index, and dielectric constant as a function of angle. These variations were attributed to changes in film porosity and anisotropy induced by the self-shadowing effect inherent to GLAD. The results demonstrate the potential of GLAD to precisely tailor the optoelectronic properties of ZnTe films for applications in photonic crystals, angle-sensitive devices, and advanced photovoltaic structures.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 7","pages":"2695 - 2705"},"PeriodicalIF":1.7,"publicationDate":"2026-05-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148366070","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Microwave dielectric dispersion and hydration studies of maltitol‐water binary mixture using time domain reflectometry 用时域反射法研究麦芽糖醇-水二元混合物的微波介电色散和水化
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-03 DOI: 10.1007/s12648-026-04049-w
Shilpa S. Patange, Aniket D. Bokhare, Ashok C. Kumbharkhane
{"title":"Microwave dielectric dispersion and hydration studies of maltitol‐water binary mixture using time domain reflectometry","authors":"Shilpa S. Patange,&nbsp;Aniket D. Bokhare,&nbsp;Ashok C. Kumbharkhane","doi":"10.1007/s12648-026-04049-w","DOIUrl":"10.1007/s12648-026-04049-w","url":null,"abstract":"<div><p>The complex permittivity spectra for the binary system maltitol‐water, within the frequency spectrum of 10 MHz 30 GHz have to been investigated employing the Time Domain Reflectometry (TDR). An analytical approach was undertaken to determine the static dielectric constant (ε<sub>0</sub>) and relaxation time (τ) corresponding to various volume fractions of water (V<sub>water</sub>) across various temperature conditions. These dielectric parameters were accurately fitted to the Cole–Davidson model to elucidate the relaxation dynamics. The Refractive Indices, Kirkwood Correlation Factor (KCF), Hydration number (N<sub>hyd</sub>) and Thermodynamic parameters (∆H and ∆S) have been calculated thereby elucidating the intermolecular interactions present within the binary mixture. The observed increase in the dielectric constant coupled with a reduction in relaxation time, accompanying with an increase in the water content of the solution, suggests that these properties vary with solute concentration and temperature, shaped by the molecular structure of the solute. The empirically obtained static dielectric constants exhibit a strong correlation with the theoretical values, thereby substantiating the validity of the Alenka Luzar hydrogen-bonding model within this framework.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 9","pages":"3915 - 3923"},"PeriodicalIF":1.7,"publicationDate":"2026-05-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148750668","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Soliton mode-locked erbium-doped fiber laser employing a Zn(II) schiff base complex coated side-polished fiber saturable absorber 采用锌(II)希夫碱络合物包覆侧面抛光光纤饱和吸收器的孤子锁模掺铒光纤激光器
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-02 DOI: 10.1007/s12648-026-04048-x
Nurul Izzah S. Wadi, Aeriyn D. Ahmad, A. A. Latiff, Ahmad Shuhaimi A. Bakar, Muhammad Ameerullah Sahudin, Khairun Nasriah Azmi, Muhammad Imran M. A. Khudus
{"title":"Soliton mode-locked erbium-doped fiber laser employing a Zn(II) schiff base complex coated side-polished fiber saturable absorber","authors":"Nurul Izzah S. Wadi,&nbsp;Aeriyn D. Ahmad,&nbsp;A. A. Latiff,&nbsp;Ahmad Shuhaimi A. Bakar,&nbsp;Muhammad Ameerullah Sahudin,&nbsp;Khairun Nasriah Azmi,&nbsp;Muhammad Imran M. A. Khudus","doi":"10.1007/s12648-026-04048-x","DOIUrl":"10.1007/s12648-026-04048-x","url":null,"abstract":"<div><p>We report the first demonstration of a Zn (II) Schiff base complex deposited onto a side-polished fiber (SPF) as a saturable absorber (SA) for soliton mode-locking in an erbium-doped fiber laser (EDFL). The complex was synthesized via a one-pot reflux condensation of 1,2-phenylenediamine and 2,4-dihydroxybenzaldehyde, followed by coordination with zinc (II) acetate, and subsequently dissolved in dimethyl sulfoxide solution. The mixed solution was drop-cast onto the SPF to harness the strong evanescent field interaction, forming an integrated all-fiber SA device. Incorporation of the device into a ring-cavity EDFL enabled stable soliton pulse generation at 1569.03 nm, delivering 1.30 ps pulses at a repetition rate of 1.91 MHz. The laser exhibited a linear increase in output power, pulse energy, and peak power with pump power. At a pump power of 138.68 mW, the pulse energy and peak power reached 1.96 nJ and 1.51 kW, respectively. These results demonstrate that the Zn (II)-complex-coated SPF serves as a novel, practical, and efficient SA for compact and power-scalable ultrafast fiber lasers.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 9","pages":"3905 - 3913"},"PeriodicalIF":1.7,"publicationDate":"2026-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148750753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Magnetocaloric effect, magnetic properties and compensation behaviors of a ferrimagnetic Ising nanowire with a core–shell structure (1, 3/2): Monte Carlo study 具有核壳结构的铁磁Ising纳米线的磁热效应、磁性能和补偿行为(1,3 /2):蒙特卡罗研究
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-05-02 DOI: 10.1007/s12648-026-04032-5
R. Lahlimi, A. Lahbibi, A. Elidrysy, M. Choubi, S. Harir, Y. Lghazi
{"title":"Magnetocaloric effect, magnetic properties and compensation behaviors of a ferrimagnetic Ising nanowire with a core–shell structure (1, 3/2): Monte Carlo study","authors":"R. Lahlimi,&nbsp;A. Lahbibi,&nbsp;A. Elidrysy,&nbsp;M. Choubi,&nbsp;S. Harir,&nbsp;Y. Lghazi","doi":"10.1007/s12648-026-04032-5","DOIUrl":"10.1007/s12648-026-04032-5","url":null,"abstract":"<div><p>This work investigates the magnetic and magnetocaloric characteristics of a square-based Ising nanowire using Monte Carlo simulations and the Metropolis technique. Ground-state diagrams are explored to identify ferrimagnetic behavior. Subsequently, observations from the ground-state diagrams are confirmed through analysis of the reduced compensation temperature as a function of the interaction parameters p, q, and the reduced crystal field d. Additionally, it appears that only the crystal field (d) significantly influences the critical temperature of the system. Examining the hysteresis loops shows that the coercive field Hc decreases as the temperature rises, disappearing at the critical temperature Tc. Finally, concerning the magnetocaloric effect, we observed that the relative cooling power (RCP) grows linearly with the external magnetic field strength, suggesting that this type of structure is an excellent candidate for magnetic refrigeration applications.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 8","pages":"3259 - 3271"},"PeriodicalIF":1.7,"publicationDate":"2026-05-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148433665","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
One-step sol–gel synthesis of Ag–TiO2 nanophotocatalyst for visible LED light-driven methylene blue degradation 一步溶胶-凝胶法制备可见光LED光驱动亚甲基蓝降解用Ag-TiO2纳米光催化剂
IF 1.7 4区 物理与天体物理
Indian Journal of Physics Pub Date : 2026-04-30 DOI: 10.1007/s12648-026-04034-3
Agidew Sewnet, Solomon Demiss Negedu, Melese Yalew Ayalew, Esayas Alemayehu
{"title":"One-step sol–gel synthesis of Ag–TiO2 nanophotocatalyst for visible LED light-driven methylene blue degradation","authors":"Agidew Sewnet,&nbsp;Solomon Demiss Negedu,&nbsp;Melese Yalew Ayalew,&nbsp;Esayas Alemayehu","doi":"10.1007/s12648-026-04034-3","DOIUrl":"10.1007/s12648-026-04034-3","url":null,"abstract":"<div><p>This study explores the structural, morphological, optical, and photocatalytic properties of pure TiO<sub>2</sub> and silver-doped TiO<sub>2</sub> (Ag–TiO<sub>2</sub>) nanoparticles synthesized via a simple one-step sol–gel method with Ag concentrations of 1, 3, 5, 7, and 9 mol%. Structural analysis confirmed the formation of a pure anatase phase in all prepared TiO<sub>2</sub> samples, with crystallite sizes decreasing from 9.46 to 6.82 nm upon Ag incorporation. FE-SEM and HR-TEM images revealed uniformly distributed nanosized Ag particles on the TiO<sub>2</sub> surface, whereas the SAED patterns indicated a polycrystalline nature. Optical studies showed a redshift in the absorption edge and band gap narrowing from 3.10 to 2.91 eV, which was attributed to localized surface plasmon resonance (LSPR) effects. The photoluminescence (PL) intensity decreased with increasing Ag content, suggesting the suppression of the recombination of photogenerated carriers. Photocatalytic experiments using methylene blue (MB) under visible LED irradiation demonstrated that 3 mol% Ag–TiO<sub>2</sub> achieved the highest degradation efficiency of 95.7% within 240 min, with an apparent first-order rate constant of 1.37 × 10<sup>–2</sup> min<sup>−1</sup>, representing an approximately 8.5-fold increase over that of pristine TiO<sub>2</sub> (1.62 × 10<sup>–3</sup> min<sup>−1</sup>). Radical scavenging- tests identified ·O<sub>2</sub><sup>−</sup> and h<sup>+</sup> as the dominant reactive species. The optimized photocatalyst retained over 90% of its activity after five consecutive cycles, confirming its high stability. Overall, Ag doping effectively tailors the physicochemical and catalytic properties of TiO<sub>2</sub>, yielding a robust and sustainable photocatalyst for visible-light-driven-environmental remediation.</p></div>","PeriodicalId":584,"journal":{"name":"Indian Journal of Physics","volume":"100 8","pages":"3273 - 3284"},"PeriodicalIF":1.7,"publicationDate":"2026-04-30","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"148433998","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"物理与天体物理","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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