分析 Eu3+ 离子浓度对锌钡硼碲玻璃光谱特性的影响

IF 1.6 4区 物理与天体物理 Q2 PHYSICS, MULTIDISCIPLINARY
M. Shoaib, I. Khan, Safdar Khan, S. Mukamil, Ahmad A. Ifseisi, Mohamed E. Assal, F. Qiao, I. Ullah, S. A. Khattak, G. Rooh, J. Kaewkhao
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引用次数: 0

摘要

本研究旨在探讨 Eu3+ 离子在硼碲玻璃中的浓度效应及其如何影响玻璃的物理化学特性和光致发光特性。采用熔体淬火法合成了一系列成分为 (30-x) TeO2-30B2O3-10ZnO-30BaO-xEu2O3 (其中 x = 0.00、0.05、0.10、0.50、1.00、1.50、2.00 和 2.50 mol%)的硼碲玻璃。XRD 分析结果表明,所制备的样品是无定形的。随着 Eu2O3 浓度的增加,密度和折射率上升,但摩尔体积下降,表明玻璃基质变得更加致密。同样,用 JO 理论计算的吸收光谱和振荡器强度表明,从 7F0 到 5L6(紫外可见光区)和从 7F0 到 5L6(近红外区)的转变更为强烈。对于 TBZB-Eu7 玻璃,声子边带能量估计为 717 cm-1,与 BGO 闪烁器相比,综合闪烁效率估计为 16.14%。这些研究结果表明,目前掺杂 2 mol% Eu3+ 的玻璃具有很强的发光特性,可用于门户成像系统(MeV 能量)的非破坏性分析,如工业和医疗 X 射线成像系统,还具有激光应用的潜力。
本文章由计算机程序翻译,如有差异,请以英文原文为准。

Analysis of Eu3+-ions concentration effect on the spectral properties of zinc-barium-boron-tellurite glasses

Analysis of Eu3+-ions concentration effect on the spectral properties of zinc-barium-boron-tellurite glasses

The present study aims to examine the concentration effect of Eu3+ ions in Boro Tellurite glass and how it affects its physicochemical and photo luminescent characteristics. Using the melt quenching method, a series of Boro-Telluride glasses with the composition (30-x) TeO2–30B2O3–10ZnO–30BaO–xEu2O3 (where x = 0.00, 0.05, 0.10, 0.50, 1.00, 1.50, 2.00, and 2.50 mol%) were synthesized. The results of the XRD analysis revealed that the prepared samples are amorphous. As the concentration of the Eu2O3 increases, the density and refractive index rise, but the molar volume decreases, indicating that the glass matrix has become more compact. Similarly, the absorption spectra and oscillator strength calculated with JO theory demonstrate the transition from 7F0 to 5L6 (in the UV–Vis region) and 7F0 to 5L6 (in the NIR region) is more intense. For TBZB–Eu7 glass, the phonon sideband energy is estimated to be 717 cm−1 and compared with the BGO scintillator, the integrated scintillation efficiency is estimated to be 16.14%. These findings demonstrate that the current glasses doped with 2 mol% Eu3+ exhibit strong luminescence qualities and can be used for portal imaging systems (MeV energies) non-destructive analysis such as industrial and medical X-ray imaging systems, and also have potential for laser application.

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来源期刊
Indian Journal of Physics
Indian Journal of Physics 物理-物理:综合
CiteScore
3.40
自引率
10.00%
发文量
275
审稿时长
3-8 weeks
期刊介绍: Indian Journal of Physics is a monthly research journal in English published by the Indian Association for the Cultivation of Sciences in collaboration with the Indian Physical Society. The journal publishes refereed papers covering current research in Physics in the following category: Astrophysics, Atmospheric and Space physics; Atomic & Molecular Physics; Biophysics; Condensed Matter & Materials Physics; General & Interdisciplinary Physics; Nonlinear dynamics & Complex Systems; Nuclear Physics; Optics and Spectroscopy; Particle Physics; Plasma Physics; Relativity & Cosmology; Statistical Physics.
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