Frontiers of Materials Science最新文献_第5页

Preparation of a wearable K-PAN@CuS composite fabric with excellent photothermal/electrothermal properties 制备具有优异光热/电热性能的可穿戴 K-PAN@CuS 复合织物

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-12-13 DOI: 10.1007/s11706-023-0670-8

Jintao Zhang, Qi Zhang, Wei Pan, Yu Qi, Yajie Qin, Zebo Wang, Jiarui Zhao

{"title":"Preparation of a wearable K-PAN@CuS composite fabric with excellent photothermal/electrothermal properties","authors":"Jintao Zhang, Qi Zhang, Wei Pan, Yu Qi, Yajie Qin, Zebo Wang, Jiarui Zhao","doi":"10.1007/s11706-023-0670-8","DOIUrl":"10.1007/s11706-023-0670-8","url":null,"abstract":"<div><p>Electrospun nanofibers with highly efficient photothermal/electrothermal performance are extremely popular because of their great potential in wearable heaters. However, the lack of necessary wearable properties such as high mechanical strength and quick response of electrospun micro/nanofibers seriously affects their practical application. In this work, a technical route combining electrospinning and surface modification technology is proposed. The 3-triethoxysilylpropylamine-polyacrylonitrile@ copper sulfide (K-PAN@CuS) composite fabric was achieved by modifying the original electrospinning PAN fiber and subsequently loading CuS nanoparticles. The results show that the break strength of the K-PAN@CuS fabric was increased by 10 times compared to that of the original PAN@CuS fabric. Furthermore, the saturated temperature of the K-PAN@CuS fabric heater could reach 116 °C within 15 s at a relatively low voltage of 3 V and 120.3 °C within 10 s under an infrared therapy lamp (100 W). In addition, due to its excellent conductivity, such a unique structural design enables the fiber to be closely attached to the human skin and helps to monitor human movements. This K-PAN@CuS fabric shows great potential in wearable heaters, hyperthermia, all-weather thermal management, and <i>in vitro</i> physical therapy.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-12-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138578075","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Highly reversible and long-lived zinc anode assisted by polymer-based hydrophilic coating 高可逆和长寿命锌阳极的聚合物基亲水性涂层辅助

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-12-05 DOI: 10.1007/s11706-023-0668-2

Hang Chen, Xinghan Yuan, Hongmei Qin, Chuanxi Xiong

{"title":"Highly reversible and long-lived zinc anode assisted by polymer-based hydrophilic coating","authors":"Hang Chen, Xinghan Yuan, Hongmei Qin, Chuanxi Xiong","doi":"10.1007/s11706-023-0668-2","DOIUrl":"10.1007/s11706-023-0668-2","url":null,"abstract":"<div><p>Rechargeable aqueous zinc-ion batteries (AZIBs) are the most promising candidates for the energy storage due to their high safety, rich resources, and large specific capacity. However, AZIBs using neutral or slightly acidic electrolytes still face side effects and zinc dendrites on the anode surface. To stabilize the Zn anode, a chemically stable and multi-functional coating of polyvinylidene fluoride (PVDF) and 4,4′-(hexafluoroisopropylidene)diphthalic anhydride (6FDA) was prepared on the Zn surface. The anhydride groups in 6FDA can improve the hydrophilicity, promoting the migration of zinc ions. Besides, PVDF is compatible with 6FDA because of the presence of organic F-containing groups, which can also effectively reduce the nucleation overpotential and exhibit the dendrite-free Zn deposition/stripping. The PVDF/6FDA@Zn symmetric cell can cycle for 5000 h at a current density of 0.5 mA·cm<sup>−2</sup>, maintaining the extremely low polarization voltage and overpotential of 28 and 8 mV, respectively. The PVDF/6FDA@Zn∥MnO<sub>2</sub> full cell can remain a specific capacity of ∼90 mAh·g<sup>−1</sup> after 2000 cycles at 1.5 A·g<sup>−1</sup>. This simple method achieves a reversible Zn anode, providing an inspiring strategy for ultra-long-cycle AZIBs.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-12-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138485073","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Effect of carbonization atmosphere on electrochemical properties of nitrogen-doped porous carbon 碳化气氛对掺氮多孔碳电化学性能的影响

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-12-04 DOI: 10.1007/s11706-023-0669-1

Fangfang Liu, Jinan Niu, Xiuyun Chuan, Yupeng Zhao

{"title":"Effect of carbonization atmosphere on electrochemical properties of nitrogen-doped porous carbon","authors":"Fangfang Liu, Jinan Niu, Xiuyun Chuan, Yupeng Zhao","doi":"10.1007/s11706-023-0669-1","DOIUrl":"10.1007/s11706-023-0669-1","url":null,"abstract":"<div><p>Nitrogen atom doping has been found to enhance the electrochemical performance of porous carbon (PC). In this study, hollow tubular nitrogen-doped porous carbon (N/PC) was synthesized using polyvinylpyrrolidone as the carbon–nitrogen source and fibrous brucite as the template through carbonization. The effects of nitrogen and argon protective atmospheres on the nitrogen content, the specific surface area (SSA), and electrochemical properties of N/PC were investigated. The results showed that compared with N/FBC-Ar, N/FBC-N<sub>2</sub> prepared in nitrogen protective atmosphere had a higher nitrogen content and a larger proportion of pyrrolic nitrogen (N-5) and pyridinic nitrogen (N-6). N/FBC-N<sub>2</sub> displayed a specific capacitance (<i>C</i>) of 194.1 F·g<sup>−1</sup> at 1 A·g<sup>−1</sup>, greater than that of N/FBC-Ar (174.3 F·g<sup>−1</sup>). This work reveals that the nitrogen doping with a higher nitrogen content in nitrogen protective atmosphere is more favorable. Furthermore, a larger proportion of pyrrolic nitrogen and pyridinic nitrogen in the doped nitrogen atoms significantly enhances the electrochemical performance.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-12-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138480837","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Preparation and characterization of enzyme-responsive zwitterionic nanoparticles for monoclonal antibody delivery 用于单克隆抗体递送的酶响应两性离子纳米颗粒的制备和表征

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-12-02 DOI: 10.1007/s11706-023-0667-3

Changxin Hou, Huike Xing, Xubo Yuan

{"title":"Preparation and characterization of enzyme-responsive zwitterionic nanoparticles for monoclonal antibody delivery","authors":"Changxin Hou, Huike Xing, Xubo Yuan","doi":"10.1007/s11706-023-0667-3","DOIUrl":"10.1007/s11706-023-0667-3","url":null,"abstract":"<div><p>Monoclonal antibodies have been used in many diseases, but how to improve their delivery efficiency is still a key issue. As the modification of zwitterionic polymers can maintain the stability and biological activity of monoclonal antibodies, in this study, zwitterionic monomers, sulfobetaine methacrylate (SBMA), and 3-[[2-(methacryloyloxy) ethyl] dimethylammonio] propionate (CBMA) were used to prepare monoclonal antibody-loaded zwitterionic nanoparticles with the aid of the crosslinker of MMP-2 enzyme-responsive peptide which was a rapid synthesis process under mild conditions. The results from dynamic light scattering (DLS), Fourier transform infrared spectroscopy (FTIR) and transmission electron microscopy (TEM) indicated that a series of zwitterionic nanoparticles had been successfully prepared by the <i>in situ</i> free radical polymerization using the MMP-2 enzyme-responsive peptide as the cross-linking agent. These nanoparticles were spherical with the sizes of (18.7±1.9) nm (SBMA nanoparticle) and (18.2±2.1) nm (CBMA nanoparticle), and the surface contained zwitterionic polymers. It was revealed that they had no cytotoxicity, could be released in tumor microenvironment by enzyme to inhibit the growth of tumor cells, and was able to effectively penetrate endothelial cells (> 2%) by transwell. Therefore, the development of this strategy has a great prospect for the delivery of monoclonal antibodies.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-12-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"138473156","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Biomimetic construction of oriented lamellar Col/nHAP composite scaffolds and mediation of macrophages to promote angiogenesis and bone regeneration 定向板层Col/nHAP复合支架的仿生构建及巨噬细胞介导血管生成和骨再生

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-11-03 DOI: 10.1007/s11706-023-0666-4

Tingting Huang, Tao Huang, Pin Luo, Di Xiao, Yiping Huang, Shenyu Yang, Rong Zeng, Mei Tu

{"title":"Biomimetic construction of oriented lamellar Col/nHAP composite scaffolds and mediation of macrophages to promote angiogenesis and bone regeneration","authors":"Tingting Huang, Tao Huang, Pin Luo, Di Xiao, Yiping Huang, Shenyu Yang, Rong Zeng, Mei Tu","doi":"10.1007/s11706-023-0666-4","DOIUrl":"10.1007/s11706-023-0666-4","url":null,"abstract":"<div><p>Pore characteristics have been identified as key design parameters for osteoimmunomodulation. The strategy reported here is to create an appropriate immune microenvironment by regulating pore characteristics of scaffolds, thereby promoting early angiogenesis and enhancing osteogenesis. A series of collagen/nanohydroxyapatite (Col/nHAP) composite scaffolds with ordered lamellar structures and different layer spacings were prepared by mimicking the ordered lamellar topology of the bone matrix. Our research indicated that the layer spacing and ordered topology of the scaffold exerted an important influence on phenotype transformation of macrophages and the secretion of angiogenic factors. The Col/nHAP-O(135) with large layer spacing not only supported cell attachment and diffusion <i>in vitro</i>, but also promoted early angiogenesis by timely switching from M1 to M2 macrophage phenotype. <i>In vivo</i> data showed that the layer spacing and the ordered structure of the scaffold synergistically regulated the inflammatory response and triggered macrophages to secrete more angiogenesis related cytokines. Col/nHAP-O(135) considerably promoted the neovascularization and new bone formation in the defect site, indicating that Col/nHAP-O(135) could significantly enhance the osteogenic activity of stem cells with the involvement of macrophages.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-11-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134795507","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

A nonmulberry silk fibroin-based robust mandruka for rapid hemostasis treatment 一种用于快速止血治疗的非桑蚕丝素强效曼陀罗

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-10-16 DOI: 10.1007/s11706-023-0660-x

Hao Zhang, Siyuan Luo, Weili Yang, Qisheng Luo, Perumal Ramesh Kannan, Yao Li, Xiangdong Kong

{"title":"A nonmulberry silk fibroin-based robust mandruka for rapid hemostasis treatment","authors":"Hao Zhang, Siyuan Luo, Weili Yang, Qisheng Luo, Perumal Ramesh Kannan, Yao Li, Xiangdong Kong","doi":"10.1007/s11706-023-0660-x","DOIUrl":"10.1007/s11706-023-0660-x","url":null,"abstract":"<div><p>Uncontrolled hemorrhage resulting from traumas causes severe health risks. There is an urgent need for expeditious hemostatic materials to treat bleeding incidents. Here, we developed a natural protein-based hemostatic sponge extracted from nonmulberry cocoons that exhibited rapid coagulation and effective absorption. We first built a degumming and dissolution system suitable for the <i>Dictyoploca japonica</i> cocoons to obtain regenerated silk fibroin (DSF). The DSF was then combined with carboxymethyl chitosan (CMCS) by glutaraldehyde (GA) crosslinking to ensure the structural stability of sponges. The resulting DSF–CMCS–GA exhibited remarkable hemostatic properties, displaying the highest absorption rate. It also demonstrated comparable efficacy to commercial hemostatic sponges. The blood-clotting index and hemolysis test showed that the prepared sponge possessed hemostatic activity and good hemocompatibility. Compared with mulberry silk fibroin hemostatic sponges (SF–CMCS–GA), DSF–CMCS–GA showed slightly better effects, making them a potential alternative to mulberry silk. In conclusion, our study introduces the use of <i>Dictyoploca japonica</i> silk fibroin for hemostasis, highlighting the exploitation of wild silkworm resources and providing an excellent silk fibroin-based hemostatic sealant for acute accident wounds and biomedical applications involving massive hemorrhage.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134878354","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

SnO2 nanotubes with N-doped carbon coating for advanced Li-ion battery anodes 先进锂离子电池负极用氮掺杂碳涂层SnO2纳米管

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-10-16 DOI: 10.1007/s11706-023-0663-7

Junhai Wang, Jiandong Zheng, Liping Gao, Chunyu Meng, Jiarui Huang, Sang Woo Joo

引用次数: 0

One-step synthesis of triazine-based covalent organic frameworks at room temperature for efficient photodegradation of bisphenol A under visible light irradiation 室温一步法合成三嗪基共价有机骨架，用于可见光下双酚A的高效光降解

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-10-16 DOI: 10.1007/s11706-023-0661-9

Pin Chen, Siyuan Di, Weixin Xie, Zihan Li, Shukui Zhu

{"title":"One-step synthesis of triazine-based covalent organic frameworks at room temperature for efficient photodegradation of bisphenol A under visible light irradiation","authors":"Pin Chen, Siyuan Di, Weixin Xie, Zihan Li, Shukui Zhu","doi":"10.1007/s11706-023-0661-9","DOIUrl":"10.1007/s11706-023-0661-9","url":null,"abstract":"<div><p>Herein, a novel visible-light-responsive photocatalyst with high efficiency was firstly synthesized at room temperature. The mild synthetic method resulted in a uniform spherical triazine-based covalent organic framework (TrCOF2) with ultra-high specific surface area as well as chemical stability. Due to the synergistic effect between the self-assembled uniform spherical structure and the abundant triazine-based structure, photoelectron–hole pairs were efficiently separated and migrated on the catalysts. On this basis, TrCOF2 was successfully applied to efficiently degrade bisphenol A (BPA). More than 98% of BPA was deraded after 60 min of visible light treatment, where the active specie of •O<span>\u0000 <sup>−</sup><sub>2</sub>\u0000 \u0000 </span> played a vital role during the degradation of BPA. The holes of TrCOF2 could produce O<sub>2</sub> by direct reaction with water or hydroxide ions. Simultaneously, photoelectrons can be captured by O<sub>2</sub> to generate •O<span>\u0000 <sup>−</sup><sub>2</sub>\u0000 \u0000 </span>. Moreover, density functional theory (DFT) calculations proved the outstanding ability of the exciting electronic conductivity. Remarkably, a reasonable photocatalytic mechanism for TrCOF2 catalysts was proposed. This research can provide a facile strategy for the synthesis of TrCOFs catalysts at room temperature, which unfolds broad application prospects in the environmental field.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134796777","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Advanced flexible humidity sensors: structures, techniques, mechanisms and performances 先进的柔性湿度传感器:结构、技术、机理和性能

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-10-16 DOI: 10.1007/s11706-023-0662-8

Yuzhe Zhang, Yuxi Liu, Lifei Lin, Man Zhou, Wang Zhang, Liwei Lin, Zhongyu Li, Yuanzhe Piao, Sun Ha Paek

引用次数: 0

Highly sensitive flexible strain sensor based on microstructured biphasic hydrogels for human motion monitoring 基于微结构双相水凝胶的高灵敏度柔性应变传感器用于人体运动监测

IF 2.7 4区材料科学

Frontiers of Materials Science Pub Date : 2023-10-16 DOI: 10.1007/s11706-023-0665-5

Xin Gao, Xinyu Wang, Xingce Fan

{"title":"Highly sensitive flexible strain sensor based on microstructured biphasic hydrogels for human motion monitoring","authors":"Xin Gao, Xinyu Wang, Xingce Fan","doi":"10.1007/s11706-023-0665-5","DOIUrl":"10.1007/s11706-023-0665-5","url":null,"abstract":"<div><p>Flexible strain sensors have been extensively used in human motion detection, medical aids, electronic skins, and other civilian or military fields. Conventional strain sensors made of metal or semiconductor materials suffer from insufficient stretchability and sensitivity, imposing severe constraints on their utilization in wearable devices. Herein, we design a flexible strain sensor based on biphasic hydrogel via an <i>in-situ</i> polymerization method, which possesses superior electrical response and mechanical performance. External stress could prompt the formation of conductive microchannels within the biphasic hydrogel, which originates from the interaction between the conductive water phase and the insulating oil phase. The device performance could be optimized by carefully regulating the volume ratio of the oil/water phase. Consequently, the flexible strain sensor with oil phase ratio of 80% demonstrates the best sensitivity with gauge factor of 33 upon a compressive strain range of 10%, remarkable electrical stability of 100 cycles, and rapid resistance response of 190 ms. Furthermore, the human motions could be monitored by this flexible strain sensor, thereby highlighting its potential for seamless integration into wearable devices.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"17 4","pages":""},"PeriodicalIF":2.7,"publicationDate":"2023-10-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"134796772","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0