Frontiers of Materials Science最新文献

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Design and fabrication of smart functional hydrogel wound dressing for diabetic foot ulcer 设计和制造用于糖尿病足溃疡的智能功能性水凝胶伤口敷料
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-08-08 DOI: 10.1007/s11706-024-0691-y
Yufei Wang, Dandan Hou, Hui Zhao, Xue Geng, Xin Wu, Gaobiao Li, Fei Sha, Zengguo Feng, Zongjian Liu, Lin Ye
{"title":"Design and fabrication of smart functional hydrogel wound dressing for diabetic foot ulcer","authors":"Yufei Wang,&nbsp;Dandan Hou,&nbsp;Hui Zhao,&nbsp;Xue Geng,&nbsp;Xin Wu,&nbsp;Gaobiao Li,&nbsp;Fei Sha,&nbsp;Zengguo Feng,&nbsp;Zongjian Liu,&nbsp;Lin Ye","doi":"10.1007/s11706-024-0691-y","DOIUrl":"10.1007/s11706-024-0691-y","url":null,"abstract":"<div><p>Diabetic foot ulcer (DFU) often evolves into chronic wounds that resist healing over an extended period, sometimes necessitating amputation in severe cases. Traditional wound management approaches generally fail to control these chronic sores successfully. Thus, it arouses a huge demand in clinic for a novel wound dressing to treat DFU effectively. Hydrogel as an ideal delivery system exhibits excellent loading capacity and sustainable release behavior. It also boasts tunable physical and chemical properties adaptable to diverse biomedical scenarios, making it a suitable material for fabricating functional wound dressings to treat DFU. The hydrogel dressings are classified into hemostatic, antibacterial and anti-inflammatory, and healing-promoting hydrogel dressings by associating the pathogenesis of DFU in this paper. The design and fabrication strategies for the dressings, as well as their therapeutic effects in treating DFU, are extensively reviewed. Additionally, this paper highlights future perspectives of multifunctional hydrogel dressings in DFU treatment. This review aims to provide valuable references for material scientists to design and develop hydrogel wound dressings with enhanced capabilities for DFU treatment, and to further translate them into the clinic in the future.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 3","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141929583","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A high-capacity and long-lifespan SnO2@K-MnO2 cathode material for aqueous zinc-ion batteries 用于锌离子水电池的高容量长寿命 SnO2@K-MnO2 阴极材料
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-08-08 DOI: 10.1007/s11706-024-0694-8
Xiaoqing Jin, Yae Qi, Yongyao Xia
{"title":"A high-capacity and long-lifespan SnO2@K-MnO2 cathode material for aqueous zinc-ion batteries","authors":"Xiaoqing Jin,&nbsp;Yae Qi,&nbsp;Yongyao Xia","doi":"10.1007/s11706-024-0694-8","DOIUrl":"10.1007/s11706-024-0694-8","url":null,"abstract":"<div><p>Aqueous Zn//MnO<sub>2</sub> rechargeable zinc-ion batteries (ZIBs) possess potential applications in electrochemical energy storage due to their safety, low cost, and environmental friendliness. However, manganese dioxide as the cathode material has poor cycle stability and low conductivity. In this work, the SnO<sub>2</sub>@K-MnO<sub>2</sub> (SMO) composite was prepared using the hydrothermal method followed by the treatment with SnCl<sub>2</sub> sensitization, and its electrochemical characteristics were examined using SMO as the cathode material for ZIBs. The reversible specific capacity reaches 298.2 mA·h·g<sup>−1</sup> at 0.5 A·g<sup>−1</sup>, and an excellent capacity retention of 86% is realized after 200 cycles, together with a high discharge capacity of 105 mA·h·g<sup>−1</sup> at 10 A·g<sup>−1</sup> and a long-term cycling life of over 8000 cycles with no apparent capacity fade. This cathode exhibits a long cycle life up to 2000 cycles at 2 A·g<sup>−1</sup> with the mass loading of 5 mg·cm<sup>−2</sup>, and the battery maintains the capacity of 80%. The reversible co-embedding mechanism of H<sup>+</sup>/Zn<sup>2+</sup> in such a Zn//SMO battery was confirmed by XRD and SEM during the charge/discharge process. This work can enlighten and promote the development of advanced cathode materials for ZIBs.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 3","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-08-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141926952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Laser-induced graphene-coated wearable smart textile electrodes for biopotentials signal monitoring 用于生物电位信号监测的激光诱导石墨烯涂层可穿戴智能织物电极
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-28 DOI: 10.1007/s11706-024-0680-1
C. M. Vidhya, Yogita Maithani, Sakshi Kapoor, J. P. Singh
{"title":"Laser-induced graphene-coated wearable smart textile electrodes for biopotentials signal monitoring","authors":"C. M. Vidhya,&nbsp;Yogita Maithani,&nbsp;Sakshi Kapoor,&nbsp;J. P. Singh","doi":"10.1007/s11706-024-0680-1","DOIUrl":"10.1007/s11706-024-0680-1","url":null,"abstract":"<div><p>This paper describes how to produce a wearable dry electrode at a reasonable cost and how to use it for the monitoring of biopotentials in electrocardiography. Smart textiles in wearable technologies have made a great advancement in the health care management and living standards of humans. Graphene was manufactured using the low-cost single-step process, laser ablation of polyimide, a commercial polymer. Graphene dispersions were made using solvent isopropyl alcohol which has low boiling point, nontoxicity, and environmental friendliness. After successive coating of the graphene dispersion on the cotton fabric to make it conductive, the sheet resistance of the resulting fabric dropped to 3% of its initial value. The laser-induced graphene (LIG) cotton dry electrodes thus manufactured are comparable to Ag/AgCl wet electrodes in terms of the skin-to-electrode impedance, measuring between 78.0 and 7.2 kΩ for the frequency between 40 Hz and 1 kHz. The LIG cotton electrode displayed a signal-to-noise ratio of 20.17 dB. Due to its comfort, simplicity, and good performance over a longer period of time, the textile electrode appears suited for medical applications.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 1","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529919","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Fe3O4 nanoparticles encapsulated in graphitized and in-plane porous carbon nanocages derived from emulsified asphalt for a high-performance lithium-ion battery anode 将 Fe3O4 纳米颗粒封装在从乳化沥青中提取的石墨化和面内多孔碳纳米笼中,用于高性能锂离子电池负极
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-28 DOI: 10.1007/s11706-024-0687-7
Dandan Hu, Linxiu Sui, Jinjin Shi, Dongfeng Li, Yuxuan Zhang, Yimeng Li, Bingbing Hu, Xiaoya Yuan
{"title":"Fe3O4 nanoparticles encapsulated in graphitized and in-plane porous carbon nanocages derived from emulsified asphalt for a high-performance lithium-ion battery anode","authors":"Dandan Hu,&nbsp;Linxiu Sui,&nbsp;Jinjin Shi,&nbsp;Dongfeng Li,&nbsp;Yuxuan Zhang,&nbsp;Yimeng Li,&nbsp;Bingbing Hu,&nbsp;Xiaoya Yuan","doi":"10.1007/s11706-024-0687-7","DOIUrl":"10.1007/s11706-024-0687-7","url":null,"abstract":"<div><p>In this work, C@Fe<sub>3</sub>O<sub>4</sub> composites were prepared through a typical template method with emulsified asphalt as carbon source, ammonium ferric citrate as transition metal oxide precursor, and NaCl as template. As an anode for lithium-ion batteries, the optimized C@Fe<sub>3</sub>O<sub>4</sub>-1:2 composite exhibits an excellent reversible capacity of 856.6 mA·h·g<sup>−1</sup> after 100 cycles at 0.1 A·g<sup>−1</sup> and a high capacity of 531.1 mA·h·g<sup>−1</sup> after 300 cycles at 1 A·g<sup>−1</sup>, much better than those of bulk carbon/Fe<sub>3</sub>O<sub>4</sub> prepared without NaCl. Such remarkable cycling performance mainly benefits from its well-designed structure: Fe<sub>3</sub>O<sub>4</sub> nanoparticles generated from ammonium ferric citrate during pyrolysis are homogenously encapsulated in graphitized and in-plane porous carbon nanocages derived from petroleum asphalt. The carbon nanocages not only improve the conductivity of Fe<sub>3</sub>O<sub>4</sub>, but also suppress the volume expansion of Fe<sub>3</sub>O<sub>4</sub> effectively during the charge–discharge cycle, thus delivering a robust electrochemical stability. This work realizes the high value-added utilization of low-cost petroleum asphalt, and can be extended to application of other transition-metal oxides-based anodes.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529775","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
(FeO)2FeBO3 nanoparticles attached on interconnected nitrogen-doped carbon nanosheets serving as sulfur hosts for lithium–sulfur batteries 附着在相互连接的掺氮碳纳米片上的 (FeO)2FeBO3 纳米粒子作为锂硫电池的硫宿主
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-20 DOI: 10.1007/s11706-024-0683-y
Junhai Wang, Huaqiu Huang, Chen Chen, Jiandong Zheng, Yaxian Cao, Sang Woo Joo, Jiarui Huang
{"title":"(FeO)2FeBO3 nanoparticles attached on interconnected nitrogen-doped carbon nanosheets serving as sulfur hosts for lithium–sulfur batteries","authors":"Junhai Wang,&nbsp;Huaqiu Huang,&nbsp;Chen Chen,&nbsp;Jiandong Zheng,&nbsp;Yaxian Cao,&nbsp;Sang Woo Joo,&nbsp;Jiarui Huang","doi":"10.1007/s11706-024-0683-y","DOIUrl":"10.1007/s11706-024-0683-y","url":null,"abstract":"<div><p>There are still many challenges including low conductivity of cathodes, shuttle effect of polysulfides, and significant volume change of sulfur during cycling to be solved before practical applications of lithium–sulfur (Li–S) batteries. In this work, (FeO)<sub>2</sub>FeBO<sub>3</sub> nanoparticles (NPs) anchored on interconnected nitrogen-doped carbon nanosheets (NCNs) were synthesized, serving as sulfur carriers for Li–S batteries to solve such issues. NCNs have the cross-linked network structure, which possess good electrical conductivity, large specific surface area, and abundant micropores and mesopores, enabling the cathode to be well infiltrated and permeated by the electrolyte, ensuring the rapid electron/ion transfer, and alleviating the volume expansion during the electrochemical reaction. In addition, polar (FeO)<sub>2</sub>FeBO<sub>3</sub> can enhance the adsorption of polysulfides, effectively alleviating the polysulfide shuttle effect. Under a current density of 1.0 A·g<sup>−1</sup>, the initial discharging and charging specific capacities of the (FeO)<sub>2</sub>FeBO<sub>3</sub>@NCNs-2/S electrode were obtained to be 1113.2 and 1098.3 mA·h·g<sup>−1</sup>, respectively. After 1000 cycles, its capacity maintained at 436.8 mA·h·g<sup>−1</sup>, displaying a decay rate of 0.08% per cycle. Therefore, combining NCNs with (FeO)<sub>2</sub>FeBO<sub>3</sub> NPs is conducive to the performance improvement of Li–S batteries.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508869","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Heterostructured Co3Se4/CoSe2@C nanoparticles attached on three-dimensional reduced graphene oxide as a promising anode towards Li-ion batteries 附着在三维还原氧化石墨烯上的异质结构 Co3Se4/CoSe2@C 纳米粒子有望成为锂离子电池的阳极
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-20 DOI: 10.1007/s11706-024-0688-6
Mingjun Pang, Zhaoyang Song, Miaomiao Mao, Shang Jiang, Ruxia Zhang, Runwei Wang, Jianguo Zhao
{"title":"Heterostructured Co3Se4/CoSe2@C nanoparticles attached on three-dimensional reduced graphene oxide as a promising anode towards Li-ion batteries","authors":"Mingjun Pang,&nbsp;Zhaoyang Song,&nbsp;Miaomiao Mao,&nbsp;Shang Jiang,&nbsp;Ruxia Zhang,&nbsp;Runwei Wang,&nbsp;Jianguo Zhao","doi":"10.1007/s11706-024-0688-6","DOIUrl":"10.1007/s11706-024-0688-6","url":null,"abstract":"<div><p><i>In situ</i> carbon-coated Co<sub>3</sub>Se<sub>4</sub>/CoSe<sub>2</sub> (CO<sub><i>x</i></sub>Se<sub><i>y</i></sub>) nanoparticles (NPs) attached on three-dimensional (3D) reduced graphene oxide (rGO) sheets were skillfully developed in this work, which involved the environment-friendly hydrothermal method, freeze drying, and selenide calcination. Within the structure, the glucose-derived carbon layer exhibited significantly homogeneous dispersion under an argon environment. This structure not only has enhanced stability, but also can effectively mitigate the volume swell of Co<sub><i>x</i></sub>Se<sub><i>y</i></sub> particles. The resulted Co<sub>3</sub>Se<sub>4</sub>/CoSe<sub>2</sub>@C/rGO (CSe@C/rGO) exhibited a specific surface area (SSA) of 240.9 m<sup>2</sup>·g<sup>−1</sup>, offering more electrochemically active sites for the storage of energy related to lithium ions. The rGO matrix held exceptional flexibility and functional structural rigidity, facilitating the swift ion intercalation and ensuring the high conductivity and recyclability of the structure. When applied to anodes designed for lithium-ion batteries (LIBs), this material demonstrated distinguished rate and ultra-high reversible capacity (872.98 mA·h·g<sup>−1</sup> at 0.5 A·g<sup>−1</sup>). Meanwhile, its capacity retention reached 119.5% after 500 cycles at 2 A·g<sup>−1</sup>, with a coulombic efficiency of 100%. This work potentially paves the way for generating fast and powerful metal selenide anodes and initiating LIBs with good performance.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141525347","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
High-stability double-layer polymer–inorganic composite electrolyte fabricated through ultraviolet curing process for solid-state lithium metal batteries 通过紫外线固化工艺制作用于固态锂金属电池的高稳定性双层聚合物-无机复合电解质
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-20 DOI: 10.1007/s11706-024-0685-9
Xinghua Liang, Pengcheng Shen, Lingxiao Lan, Yunmei Qin, Ge Yan, Meihong Huang, Xuanan Lu, Qiankun Hun, Yujiang Wang, Jixuan Wang
{"title":"High-stability double-layer polymer–inorganic composite electrolyte fabricated through ultraviolet curing process for solid-state lithium metal batteries","authors":"Xinghua Liang,&nbsp;Pengcheng Shen,&nbsp;Lingxiao Lan,&nbsp;Yunmei Qin,&nbsp;Ge Yan,&nbsp;Meihong Huang,&nbsp;Xuanan Lu,&nbsp;Qiankun Hun,&nbsp;Yujiang Wang,&nbsp;Jixuan Wang","doi":"10.1007/s11706-024-0685-9","DOIUrl":"10.1007/s11706-024-0685-9","url":null,"abstract":"<div><p>Electrolyte interface resistance and low ionic conductivity are essential issues for commercializing solid-state lithium metal batteries (SSLMBs). This work details the fabrication of a double-layer solid composite electrolyte (DLSCE) for SSLMBs. The composite comprises poly(vinylidene fluoride-<i>co</i>-hexafluoropropylene) (PVDF–HFP) and poly(methyl methacrylate) (PMMA) combined with 10 wt.% of Li<sub>6.4</sub>La<sub>3</sub>Zr<sub>1.4</sub>Ta<sub>0.6</sub>O<sub>12</sub> (LLZTO), synthesized through an ultraviolet curing process. The ionic conductivity of the DLSCE (2.6 × 10<sup>−4</sup> S·cm<sup>−1</sup>) at room temperature is the high lithium-ion transference number (0.57), and the tensile strength is 17.8 MPa. When this DLSCE was assembled, the resulted LFP/DLSCE/Li battery exhibited excellent rate performance, with the discharge specific capacities of 162.4, 146.9, 93.6, and 64.0 mA·h·g<sup>−1</sup> at 0.1, 0.2, 0.5, and 1 C, respectively. Furthermore, the DLSCE demonstrates remarkable stability with lithium metal batteries, facilitating the stable operation of a Li/Li symmetric battery for over 200 h at both 0.1 and 0.2 mA·cm<sup>−2</sup>. Notably, the formation of lithium dendrites is also effectively inhibited during cycling. This work provides a novel design strategy and preparation method for solid composite electrolytes.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141508870","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A new TiO2 nanorods/MoTe2 quantum dots/Al2O3 composite photocatalyst for efficient photoelectrochemical water splitting under simulated sunlight 一种新型 TiO2 纳米棒/MoTe2 量子点/Al2O3 复合光催化剂,可在模拟阳光下高效光电化学分水
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-20 DOI: 10.1007/s11706-024-0686-8
Jie Meng, Hongmei Liu, Sainan Zhang, Baogui Ye, Min Feng, Daoai Wang
{"title":"A new TiO2 nanorods/MoTe2 quantum dots/Al2O3 composite photocatalyst for efficient photoelectrochemical water splitting under simulated sunlight","authors":"Jie Meng,&nbsp;Hongmei Liu,&nbsp;Sainan Zhang,&nbsp;Baogui Ye,&nbsp;Min Feng,&nbsp;Daoai Wang","doi":"10.1007/s11706-024-0686-8","DOIUrl":"10.1007/s11706-024-0686-8","url":null,"abstract":"<div><p>The solar-to-hydrogen conversion using the photoelectrochemical (PEC) method is a practical approach to producing clean energy. However, it relies on the availability of photocatalyst materials. In this work, a novel photocatalyst comprising molybdenum telluride quantum dots (MoTe<sub>2</sub> QDs)-modified titanium dioxide nanorods (TiO<sub>2</sub> NRs) was prepared for the enhancement of the PEC water splitting performance after combination with a Al<sub>2</sub>O<sub>3</sub> layer using the atomic layer deposition (ALD) technique. MoTe<sub>2</sub> QDs were initially prepared, and then they were loaded onto TiO<sub>2</sub> NRs using a warm water bath-based heating method. After a layer of Al<sub>2</sub>O<sub>3</sub> was deposited onto resulted TiO<sub>2</sub> NRs/MoTe<sub>2</sub> QDs, the composite TiO<sub>2</sub> NRs/MoTe<sub>2</sub> QDs/Al<sub>2</sub>O<sub>3</sub> was finally obtained. Under simulated sunlight (100 mW·cm<sup>−2</sup>), such a composite exhibited a maximum photocurrent density of 2.25 mA·cm<sup>−2</sup> at 1.23 V (versus RHE) and an incident photon-to-electron conversion efficiency of 69.88% at 380 nm, which are 4.33 and 6.66 times those of pure TiO<sub>2</sub> NRs, respectively. Therefore, the composite photocatalyst fabricated in this work may have promising application in the field of PEC water splitting, solar cells and other photocatalytic devices.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141529920","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A comprehensive review on surface modifications of black phosphorus using biological macromolecules 利用生物大分子对黑磷进行表面改性综述
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-08 DOI: 10.1007/s11706-024-0689-5
Chaiqiong Guo, Xuhong He, Xuanyu Liu, Yuhui Wang, Yan Wei, Ziwei Liang, Di Huang
{"title":"A comprehensive review on surface modifications of black phosphorus using biological macromolecules","authors":"Chaiqiong Guo,&nbsp;Xuhong He,&nbsp;Xuanyu Liu,&nbsp;Yuhui Wang,&nbsp;Yan Wei,&nbsp;Ziwei Liang,&nbsp;Di Huang","doi":"10.1007/s11706-024-0689-5","DOIUrl":"10.1007/s11706-024-0689-5","url":null,"abstract":"<div><p>Black phosphorus (BP), a novel two-dimensional material, exhibits remarkable photoelectric characteristics, ultrahigh photothermal conversion efficiency, substantial specific surface area, high carrier mobility, and tunable band gap properties. These attributes have positioned it as a promising candidate in domains such as energy, medicine, and the environment. Nonetheless, its vulnerability to light, oxygen, and water can lead to rapid degradation and loss of crystallinity, thereby limiting its synthesis, preservation, and application. Moreover, BP has demonstrated cytotoxic tendencies, substantially constraining its viability in the realm of biomedicine. Consequently, the imperative for surface modification arises to bolster its stability and biocompatibility, while concurrently expanding its utility spectrum. Biological macromolecules, integral components of living organisms, proffer innate advantages over chemical agents and polymers for the purpose of the BP modifications. This review comprehensively surveys the advancements in utilizing biological macromolecules for the modifications of BP. In doing so, it aims to pave the way for enhanced stability, biocompatibility, and diversified applications of this material.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141391492","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review of inorganic particles synthesized through electrical discharge in different dielectric media: from devices, structures and components to applications 综述在不同介电介质中通过放电合成的无机颗粒:从设备、结构和组件到应用
IF 2.5 4区 材料科学
Frontiers of Materials Science Pub Date : 2024-06-06 DOI: 10.1007/s11706-024-0679-7
Yifan Liu, Guilu Qin, Liangjun Yin, Xian Jian, Xianglong Li
{"title":"A review of inorganic particles synthesized through electrical discharge in different dielectric media: from devices, structures and components to applications","authors":"Yifan Liu,&nbsp;Guilu Qin,&nbsp;Liangjun Yin,&nbsp;Xian Jian,&nbsp;Xianglong Li","doi":"10.1007/s11706-024-0679-7","DOIUrl":"10.1007/s11706-024-0679-7","url":null,"abstract":"<div><p>Size effects and compositions constitute new properties for inorganic particles in different application fields. The physical method has recently attracted more attention in the preparation of inorganic materials. Herein, a low-cost, eco-friendly, simple-operating, and time-saving technique, named electrical discharge, is reviewed in relation to developments from the nature of this technique in different dielectric media to the practical experience in controlling the main processing parameters, apparatuses, types of discharge, from the various structures and components to the wide applications. The development of the electrical discharge technique will play an important role in improving the technology to prepare superfine inorganic particles with high purity. Meanwhile, electrical discharge contributes to easily mixing solid materials from the atomic scale to several micrometers with different structures. Moreover, metal oxides or doping materials are accessible as the dielectric medium is changed. Considering some excellent advantages, new inorganic particles exploited through the electrical discharge method will promise to be the most rewarding in some potential applications.</p></div>","PeriodicalId":572,"journal":{"name":"Frontiers of Materials Science","volume":"18 2","pages":""},"PeriodicalIF":2.5,"publicationDate":"2024-06-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141390657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"材料科学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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