钙钛矿氧化物溶出工艺及结构调控策略综述

IF 2.3 4区 材料科学 Q3 MATERIALS SCIENCE, MULTIDISCIPLINARY
Danyang Liu, Dan Lin, Wenwen Yu, Juntao Liu, Hexuan Zhou, Ziyu Zhou, Meixia Lan, Zhimeng Li, Jingang Qi, Lidan Tang, Bing Wang
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引用次数: 0

摘要

传统的表面改性方法如物理或化学气相沉积和浸渍已被广泛应用于钙钛矿表面改性。然而,通过这些方法负载的金属纳米颗粒(NPs)与钙钛矿氧化物载体之间存在弱相互作用,这可能导致在应用过程中由于稳定性差,容易团聚和碳沉积而失活等问题。外溶是指NPs在母体氧化物表面的原位生长。NPs的存在增加了反应活性位点的数量,并且NPs与基体具有较强的相互作用,表现出优异的催化性能和较高的稳定性。因此,近年来原位溶出领域受到了广泛的关注。在此基础上,本文从钙钛矿氧化物的析出现象入手,对现有的析出方法进行了综述,从a位缺陷、b位阳离子掺杂、相变等方面梳理了结构调控的钙钛矿氧化物的析出策略,介绍了原位析出的应用领域,并展望了前景。
本文章由计算机程序翻译,如有差异,请以英文原文为准。
Perovskite oxide exsolution process and structure regulation strategy: a review

Traditional surface modification methods such as physical or chemical vapor deposition and impregnation have been widely used to modify perovskite surfaces. However, there is weak interaction between metal nanoparticles (NPs) loaded via these methods and the perovskite oxide support, which may lead to issues such as deactivation during application owing to poor stability, easy agglomeration, and carbon deposition. Exsolution refers to the in-situ growth of NPs on the surface of parent oxides. The presence of NPs increases the number of active sites for the reaction, and NPs exhibit strong interaction with the matrix, showing excellent catalytic performance and high stability. Therefore, in recent years, the field of in-situ exsolution has received extensive attention. Based on this, this paper starts from exsolution phenomena of perovskite oxides, reviews existing exsolution methods, sorts out structurally regulated exsolution strategies of perovskite oxides in terms of A-site defects, B-site cation dopants, and phase transformation, introduces application fields of the in-situ exsolution, and provides prospect.

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来源期刊
Frontiers of Materials Science
Frontiers of Materials Science MATERIALS SCIENCE, MULTIDISCIPLINARY-
CiteScore
4.20
自引率
3.70%
发文量
515
期刊介绍: Frontiers of Materials Science is a peer-reviewed international journal that publishes high quality reviews/mini-reviews, full-length research papers, and short Communications recording the latest pioneering studies on all aspects of materials science. It aims at providing a forum to promote communication and exchange between scientists in the worldwide materials science community. The subjects are seen from international and interdisciplinary perspectives covering areas including (but not limited to): Biomaterials including biomimetics and biomineralization; Nano materials; Polymers and composites; New metallic materials; Advanced ceramics; Materials modeling and computation; Frontier materials synthesis and characterization; Novel methods for materials manufacturing; Materials performance; Materials applications in energy, information and biotechnology.
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