Foundations of Chemistry最新文献

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Non-periodic table of periodicities and periodic table with additional periodicities: tetrad periodicity 非周期周期表和附加周期周期表:四元周期
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-09-16 DOI: 10.1007/s10698-022-09437-8
Naum S. Imyanitov
{"title":"Non-periodic table of periodicities and periodic table with additional periodicities: tetrad periodicity","authors":"Naum S. Imyanitov","doi":"10.1007/s10698-022-09437-8","DOIUrl":"10.1007/s10698-022-09437-8","url":null,"abstract":"<div><p>This manuscript aims to systematically consider the main periodicity and additional (secondary, internal, and tetrad) periodicities using a uniform approach. The main features are summarized in table form. The history of the origin and development of these concepts is discussed. It is described how these periodicities manifest themselves and how they are determined at the experimental and theoretical levels. Areas of manifestation of these periodicities are outlined. As the general approach to explaining internal periodicity, attention is drawn to the symmetry of the quantum number S of atoms and the principle of equivalence of electrons and holes. Arguments are presented in favor of a more correct classification of the tetrad effect as tetrad periodicity, and an overview of this regularity is provided. A small modification of the conventional Periodic table is proposed, which reflects all the mentioned periodicities.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 3","pages":"331 - 358"},"PeriodicalIF":0.9,"publicationDate":"2022-09-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4665340","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
A process ontology approach in biochemistry: the case of GPCRs and biosignaling 生物化学中的过程本体方法:以gpcr和生物信号传导为例
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-09-15 DOI: 10.1007/s10698-022-09443-w
Fiorela Alassia
{"title":"A process ontology approach in biochemistry: the case of GPCRs and biosignaling","authors":"Fiorela Alassia","doi":"10.1007/s10698-022-09443-w","DOIUrl":"10.1007/s10698-022-09443-w","url":null,"abstract":"<div><p>According to process ontology in the philosophy of biology, the living world is better understood as processes rather than as substantial individuals. Within this perspective, an organism does not consist of a hierarchy of structures like a machine, but rather a dynamic hierarchy of processes, dynamically maintained and stabilized at different time scales. With this respect, two processual approaches on enzymes by Stein (Hyle Int J Philos Chem 10(4):5–22, 2004, Process Stud 34:62–80, 2005, Found Chem 8:3–29, 2006) and by Guttinger (Everything Flows: Towards a Processual Philosophy of Biology, Oxford University Press, Oxford, 2018) allows to think of macromolecules as relational and processual entities. In this work, I propose to extend their arguments to another case study within the biochemical domain, which is the case of ligand receptors and receptor-mediated biosignaling. The aim of this work is to analyze the case of G Protein-Coupled Receptors and biosignaling under the consideration of a processual ontology. I will defend that the processual ontology framework is adequate for the biochemical domain and that it allows accounting for the current biochemical knowledge related to the case study.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 3","pages":"405 - 422"},"PeriodicalIF":0.9,"publicationDate":"2022-09-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4922403","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Models, languages and representations: philosophical reflections driven from a research on teaching and learning about cellular respiration 模型、语言和表征:基于细胞呼吸教学研究的哲学思考
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-09-10 DOI: 10.1007/s10698-022-09444-9
Martín Pérgola, Lydia Galagovsky
{"title":"Models, languages and representations: philosophical reflections driven from a research on teaching and learning about cellular respiration","authors":"Martín Pérgola,&nbsp;Lydia Galagovsky","doi":"10.1007/s10698-022-09444-9","DOIUrl":"10.1007/s10698-022-09444-9","url":null,"abstract":"<div><p>Mental model construction is supposed to be a useful cognitive devise for learning. Beyond human capacity of constructing mental models, scientists construct complex explanations about phenomena, named scientific or theoretical models. In this work we revisit three vissions: the first one concern about the polisemic term “model”. Our proposal is to discriminate between “mental models” and “explicit models”, being the former those “imaginistic” ideas constructed in scientists’—o teachers—minds, and the latter those teaching devices expressed in different languages that tend to communicate any “scientific model”. From this point of view, the class is considered a place where teachers’ mental models should be learned by novice students by decoding their teaching devices which are expressed in different languages. Other proposal of this work claims to distinguish the term “representation” with respect to its artistical or instrumental origin, highlighting that they are types of teaching devices and that artistical representations are always analogies. Finally, data about the construction of freshmen’s wrong mental models related to the use of the analogy between the chemical combustion and the global process of cellular respiration from glucose is presented to reinforce previous epistemological reflections.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"25 1","pages":"151 - 166"},"PeriodicalIF":0.9,"publicationDate":"2022-09-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4743823","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Prospective sustainable agriculture principles inspired by green chemistry 受绿色化学启发的前瞻性可持续农业原则
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-08-09 DOI: 10.1007/s10698-022-09442-x
Praveen Kumar Sharma
{"title":"Prospective sustainable agriculture principles inspired by green chemistry","authors":"Praveen Kumar Sharma","doi":"10.1007/s10698-022-09442-x","DOIUrl":"10.1007/s10698-022-09442-x","url":null,"abstract":"<div><p>In present day’s sustainable agriculture is relatively a new area which required more attention by scientist/researchers and this one treated as basic need of human survival. In past decades, sustainable agriculture meets environmental and economic goals simultaneously, that’s why this field has received widespread interest. Green Chemistry is described as the ‘‘design of chemical products and processes to eliminate or reduce the use and generation of hazardous substances. Green chemistry mainly based on 12 principles and plays a very important role in environmental protection. For human development sustainable agriculture and green chemistry both are essential. This article discussed 12 proposed principles of sustainable agriculture inspired by existing 12 principles of Green Chemistry.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 3","pages":"359 - 362"},"PeriodicalIF":0.9,"publicationDate":"2022-08-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4371885","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Hints for a formal language inspired by Lewis structures 受刘易斯结构启发的形式语言提示
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-08-03 DOI: 10.1007/s10698-022-09439-6
Savino Longo
{"title":"Hints for a formal language inspired by Lewis structures","authors":"Savino Longo","doi":"10.1007/s10698-022-09439-6","DOIUrl":"10.1007/s10698-022-09439-6","url":null,"abstract":"<div><h2>Summary</h2><div><p>In this work we elaborate on the idea of a formal theory for a limited but important part of structural chemistry, that described by Lewis’ methods and VSEPR (Valence Shell Electron Pair Repulsion). For this purpose, recursive functions and propositional functions are defined, that apply to formal expressions of the structure, based on a finite set of symbols. This approach allows for the expression of numerous questions of chemical interest. The formalization of basic structural chemistry based on Lewis/VSEPR method is potentially useful for the automation of the related procedures, but possibly also of some use as complementary material in teaching and as a heuristic tool in structural chemistry.</p></div></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 3","pages":"315 - 330"},"PeriodicalIF":0.9,"publicationDate":"2022-08-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10698-022-09439-6.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4112441","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
Editorial 71 编辑71
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-07-29 DOI: 10.1007/s10698-022-09441-y
Eric Scerri
{"title":"Editorial 71","authors":"Eric Scerri","doi":"10.1007/s10698-022-09441-y","DOIUrl":"10.1007/s10698-022-09441-y","url":null,"abstract":"","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 2","pages":"159 - 160"},"PeriodicalIF":0.9,"publicationDate":"2022-07-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"5616573","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The case of Zinjafr in the medical and mineralogical texts of medieval Persia: a puzzle created in the absence of the concept of chemical elements 中世纪波斯医学和矿物学文献中的Zinjafr案例:在缺乏化学元素概念的情况下创造的谜题
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-07-13 DOI: 10.1007/s10698-022-09436-9
Nazila Farmani Anooshe, Aliyar Mousavi
{"title":"The case of Zinjafr in the medical and mineralogical texts of medieval Persia: a puzzle created in the absence of the concept of chemical elements","authors":"Nazila Farmani Anooshe,&nbsp;Aliyar Mousavi","doi":"10.1007/s10698-022-09436-9","DOIUrl":"10.1007/s10698-022-09436-9","url":null,"abstract":"<div><p>An examination of some of the writings in the medical and mineralogical texts of Persia in the Middle Ages, written in the Arabic language during the caliphate period, revealed an inconsistency concerning the modern chemical identity of the substance called <i>zinjafr</i>, which was recognized as a medication for wounds, burns, mange, and cavities. Although some of the literature identified it as the important ore cinnabar (red mercury(II) sulfide), some questioned that identification or even ambiguously described it as a substance produced from lead. A modern chemical study was conducted and identified the latter substance as minium (trilead tetraoxide). The reason for the medieval authors not distinguishing between those two compounds is discussed and the fact that the dictionaries of modern written Arabic commonly have the words <i>zinjafr</i> and <i>cinnabar</i> listed as equivalents is also explored. Further, the ability of Arabic alchemy to distinguish between cinnabar and minium is assessed in light of modern chemistry.</p><h3>Graphical abstract</h3><p>A 1973 Soviet postage stamp celebrating the 1000th anniversary of al-Biruni’s birth (https://sl.wikipedia.org/wiki/Slika:Biruni-russian.jpg).</p><figure><div><div><div><picture><source><img></source></picture></div></div></div></figure></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 2","pages":"277 - 284"},"PeriodicalIF":0.9,"publicationDate":"2022-07-13","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4540343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical reactivity: cause-effect or interaction? 化学反应性:因果关系还是相互作用?
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-07-06 DOI: 10.1007/s10698-022-09430-1
Alfio Zambon
{"title":"Chemical reactivity: cause-effect or interaction?","authors":"Alfio Zambon","doi":"10.1007/s10698-022-09430-1","DOIUrl":"10.1007/s10698-022-09430-1","url":null,"abstract":"<div><p>From the perspective of successive events, chemical reactions are expressed or thought about, in terms of the cause-effect category. In this work, I will firstly discuss some aspects of causation and interaction in chemistry, argue for the interaction, and propose an alternative or complementary representation scheme called “interaction diagram”, that allows representing chemical reactions through a geometric diagram. The understanding of this diagram facilitates the analysis of reactions in terms of the interaction, or reciprocal action, among the participating entities. Secondly, I will describe the model and provide examples and finally, I will discuss the scope and limitations of the current development status of the model.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 3","pages":"375 - 387"},"PeriodicalIF":0.9,"publicationDate":"2022-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4583086","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
In praise of triads 赞美三合会
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-06-16 DOI: 10.1007/s10698-022-09434-x
Eric R. Scerri
{"title":"In praise of triads","authors":"Eric R. Scerri","doi":"10.1007/s10698-022-09434-x","DOIUrl":"10.1007/s10698-022-09434-x","url":null,"abstract":"<div><p>The article begins with a response to a recent contribution by Jensen, in which he has criticized several aspects of the use of triads of elements, including Döbereiner’s original introduction of the concept and the modern use of atomic number triads by some authors including myself. Such triads are groups of three elements, one of which has approximately the average atomic weight of the other two elements, as well as having intermediate chemical reactivity. I also examine Jensen’s attempted reconstruction Mendeleev’s use of triads in predicting the atomic weights of three hitherto unknown elements, that were subsequently named gallium, germanium and scandium. The present article then considers the use of atomic number triads, in conjunction with the phenomenon of first member anomaly, in order to offer support for Janet’s left-step periodic table, in which helium is relocated into group 2 of the table. Such a table features triads in which the 2nd and third elements of each group, without fail, fall into periods of equal length, a feature that is absent in the conventional 18-column or the conventional 32-column table. The dual sense of the term element, which is the source of much discussion in the philosophy of chemistry, is alluded to in further support of such a relocation of helium that may at first appear to contradict chemical intuition.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"24 2","pages":"285 - 300"},"PeriodicalIF":0.9,"publicationDate":"2022-06-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10698-022-09434-x.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4651745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Philosophical grounds for designing invisible molecules 设计隐形分子的哲学基础
IF 0.9 3区 化学
Foundations of Chemistry Pub Date : 2022-06-04 DOI: 10.1007/s10698-022-09433-y
Hirofumi Ochiai
{"title":"Philosophical grounds for designing invisible molecules","authors":"Hirofumi Ochiai","doi":"10.1007/s10698-022-09433-y","DOIUrl":"10.1007/s10698-022-09433-y","url":null,"abstract":"<div><p>‘Structure’ is the term whose proper use is exemplified by an expression like ‘the structure of a diesel-engine,’ in which what is referred to is accessible to immediate observation. It is also used figuratively like ‘social structure.’ While unobservable, what is referred to is empirically accessible. By contrast, molecules are neither observable nor empirically accessible. What philosophical grounds enable us to design invisible structure of molecules? Our cognition of objects becomes realized as phenomena when objects are given to our phenomenal fields. (Ochiai, Found Chem 22:77–86, 2020a, Found Chem 22:457–465, 2020b, A philosophical essay on molecular structure, Cambridge Scholars Publishing, Newcastle upon Tyne, pp 147–174, 2021) A phenomenal field is a pictorial representation of the mind’s self-transcending character and shows the relation between ‘self’ and ‘world.’ Molecular structure becomes realized as an affordance of molecules in a phenomenal field proper to organic chemists. It is a context-sensitive dispositional attribute of an {organic chemist-world} complex. Although designing molecules presupposes molecular structure, the latter is not sufficient for the former to make sense. Molecules must be designable as well. Designing molecules aims to create or modify molecular structure in order to provide compounds with certain chemical and/or physical properties. That is, designable molecules make sense in contexts in which they serve as a means to achieve this purpose and become realized as an affordance. Given that molecular structure and designable molecules are affordances of molecules, the fact that there are contexts in which they make sense provides grounds for conceiving and designing invisible structure of molecules. Heidegger’s arguments in <i>Being and Time</i> about characteristics of the being of beings corroborate our argument that what becomes realized as an affordance exists as what he calls a useful thing for us.</p></div>","PeriodicalId":568,"journal":{"name":"Foundations of Chemistry","volume":"25 1","pages":"141 - 149"},"PeriodicalIF":0.9,"publicationDate":"2022-06-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"4170446","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
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