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Metal complexes of Tridentate Schiff base: Synthesis, Characterization, Biological Activity and Molecular Docking Studies with COVID-19 Protein Receptor. 三叉席夫碱金属配合物：合成、表征、生物活性以及与 COVID-19 蛋白受体的分子对接研究。
IF 1.1 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2021-12-10 Epub Date: 2021-10-11 DOI: 10.1002/zaac.202100245
Gehad G Mohamed, M M Omar, Yasmin M Ahmed
{"title":"Metal complexes of Tridentate Schiff base: Synthesis, Characterization, Biological Activity and Molecular Docking Studies with COVID-19 Protein Receptor.","authors":"Gehad G Mohamed, M M Omar, Yasmin M Ahmed","doi":"10.1002/zaac.202100245","DOIUrl":"10.1002/zaac.202100245","url":null,"abstract":"<p><p>Mononuclear chelates of Cr(III), Mn(II), Fe(III), Ni(II), Cu(II), Zn(II) and Cd(II) resulted from new tridentate Schiff base ligand, 4-((1-(5-acetyl-2,4-dihydroxyphenyl)ethylidene)amino)-1,5-dimethyl-2-phenyl-1H-pyrazol-3(2H)-one, were synthesized. Metal to ligand ratio was found to be1 : 1, which was revealed via elemental analysis and characterized via various spectroscopic tools. IR has point out that the coordination of the ligand towards the metal ions was carried out via NOO donor atoms. UV-Vis, <sup>1</sup>H NMR spectral data, molar conductivity measurements, BET surface area, melting points and theoretically through density function theory were used such as characterizing techniques in supporting further interpretation of the complexes structures. The complexes were octahedral except Cu(II) and Ni(II) complexes were tetrahedral as suggested from the magnetic moment measurement. The complexes were found to have surface area, pore volume and particle radius of 23-176 m<sup>2</sup> g<sup>-1</sup>, 0.02-0.33 cc/g and 8.71-4.32 nm, respectively, as pointed out from BET measurement. Schiff base ligand and metal complexes were tested <i>in vitro</i> to estimate their antimicrobial activity opposed to Gram-negative and Gram-positive bacterial and fungal organisms. MOE 2008 was used headed for screen potential drugs with molecular docking by the protein sites of new coronavirus and the study was constructed to molecular docking without validation through MD simulations.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"647 23-24","pages":"2201-2218"},"PeriodicalIF":1.1,"publicationDate":"2021-12-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8662136/pdf/ZAAC-647-2201.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"10271863","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Structural and Electronic Properties of Iron(0) PNP Pincer Complexes. 铁（0）PNP 钳形配合物的结构和电子特性。
IF 1.1 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2021-07-27 Epub Date: 2021-05-04 DOI: 10.1002/zaac.202100015
Mathias Glatz, Nikolaus Gorgas, Berthold Stöger, Ernst Pittenauer, Liliana Ferreira, Luis F Veiros, Maria José Calhorda, Karl Kirchner
{"title":"Structural and Electronic Properties of Iron(0) PNP Pincer Complexes.","authors":"Mathias Glatz, Nikolaus Gorgas, Berthold Stöger, Ernst Pittenauer, Liliana Ferreira, Luis F Veiros, Maria José Calhorda, Karl Kirchner","doi":"10.1002/zaac.202100015","DOIUrl":"10.1002/zaac.202100015","url":null,"abstract":"<p><p>In the present work we have prepared and fully characterized several Fe(0) complexes of the type [Fe(PNP)(CO)<sub>2</sub>] treating Fe(II) complexes [Fe(PNP)(Cl)<sub>2</sub>] with KC<sub>8</sub> in the presence of carbon monoxide. While complexes [Fe(PNP<sup>NMe</sup>-<i>i</i>Pr)(CO)<sub>2</sub>], [Fe(PNP<sup>NEt</sup>-<i>i</i>Pr)(CO)<sub>2</sub>] adopt a trigonal bipyramidal geometry, the bulkier and more electron rich [Fe(PNP<sup>NH</sup>-<i>t</i>Bu)(CO)<sub>2</sub>] is closer to a square pyramidal geometry. Mössbauer spectra showed isomer shifts very close to 0 and similar to those reported for Fe(I) systems. Quadrupole splitting values range between 2.2 and 2.7 mm s<sup>-1</sup> both in experiments and DFT calculations, while those of Fe(I) complexes are much smaller (∼0.6 mm s<sup>-1</sup>).</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"647 14","pages":"1429-1435"},"PeriodicalIF":1.1,"publicationDate":"2021-07-27","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.ncbi.nlm.nih.gov/pmc/articles/PMC8360027/pdf/","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"39327950","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Silver(I) Complexes of Two Flexible Bis-phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands. 两种柔性双膦烷配体的银(I)配合物:金属大环、聚合链和金属基。
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2020-07-15 Epub Date: 2020-05-12 DOI: 10.1002/zaac.202000001
Paul Boar, Peter Lönnecke, Evamarie Hey-Hawkins
{"title":"Silver(I) Complexes of Two Flexible Bis-phospholane Ligands: Metallamacrocycles, Polymeric Chains, and Metallacryptands.","authors":"Paul Boar, Peter Lönnecke, Evamarie Hey-Hawkins","doi":"10.1002/zaac.202000001","DOIUrl":"10.1002/zaac.202000001","url":null,"abstract":"<p><p>In a 2:2 reaction with silver(I) chloride or bromide, 1,5-bis(1-phospholano)pentane (<b>1a</b>) afforded frame-like macrocyclic structures, with intra- (<b>2</b>, Cl) or intermolecular (<b>3</b>, Br) halido bridges. In contrast, 1,7-bis(1-phospholano)heptane (<b>1b</b>) formed coordination polymers <b>4a</b> (Cl) and <b>4b</b> (Br) with bridging bis-phospholane and halido ligands. A unique paddle wheel-type metallacryptand structure <b>5</b> was obtained from <b>1a</b> and silver(I) bromide in a 2:3 reaction (M:L). All complexes were fully characterized by NMR, IR spectroscopy, mass spectrometry, and X-ray crystallography.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"646 13","pages":"915-922"},"PeriodicalIF":1.4,"publicationDate":"2020-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.202000001","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"38218297","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A Terminal Chlorophosphinidene Complex. 一个末端氯膦配合物。
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2020-07-15 Epub Date: 2020-02-11 DOI: 10.1002/zaac.202000010
Josh Abbenseth, Sven Schneider
{"title":"A Terminal Chlorophosphinidene Complex.","authors":"Josh Abbenseth, Sven Schneider","doi":"10.1002/zaac.202000010","DOIUrl":"10.1002/zaac.202000010","url":null,"abstract":"<p><p>Terminal, electrophilic phosphinidene complexes (M=PR) are attractive platforms for PR-transfer to organic substrates. In contrast to aryl- or alkylphosphinidene complexes terminal chlorophosphinidenes (M=PCl) have only been proposed as transient intermediates but isolable example remain elusive. Here we present the transfer of PCl from chloro-substituted dibenzo-7λ<sup>3</sup>-phosphanorbornadiene to a square-planar osmium(II) PNP pincer complex to give the first isolable, terminal chlorophosphinidene complex with remarkable thermal stability. Os=P bonding was examined computationally giving rise to highly covalent {Os<sup>II</sup>=P<sup>I</sup>Cl} double bonding.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"646 13","pages":"565-569"},"PeriodicalIF":1.4,"publicationDate":"2020-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.202000010","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"38218295","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Synthesis, Isolation and Crystal Structures of the Metalated Ylides [Cy3P-C-SO2Tol]M (M = Li, Na, K). 金属化Ylides [cy3c - so2tol]M (M = Li, Na, K)的合成、分离和晶体结构
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2020-07-15 Epub Date: 2020-04-22 DOI: 10.1002/zaac.201900333
Heidar Darmandeh, Thorsten Scherpf, Kai-Stephan Feichtner, Christopher Schwarz, Viktoria H Gessner
{"title":"Synthesis, Isolation and Crystal Structures of the Metalated Ylides [Cy<sub>3</sub>P-C-SO<sub>2</sub>Tol]M (M = Li, Na, K).","authors":"Heidar Darmandeh,&nbsp;Thorsten Scherpf,&nbsp;Kai-Stephan Feichtner,&nbsp;Christopher Schwarz,&nbsp;Viktoria H Gessner","doi":"10.1002/zaac.201900333","DOIUrl":"https://doi.org/10.1002/zaac.201900333","url":null,"abstract":"<p><p>The preparation and isolation of the metalated ylides [Cy<sub>3</sub>PCSO<sub>2</sub>Tol]M ( <b><sup>Cy</sup>1-M</b>) (with M = Li, Na, K) are reported. In contrast to its triphenylphosphonium analogue the synthesis of <b><sup>Cy</sup>1-M</b> revealed to be less straight forward. Synthetic routes to the phosphonium salt precursor <b><sup>Cy</sup>1</b>-<b>H<sub>2</sub></b> via different methods revealed to be unsuccessful or low-yielding. However, nucleophilic attack of the ylide Cy<sub>3</sub>P = CH<sub>2</sub> at toluenesulfonyl fluoride under basic conditions proved to be a high-yielding method directly leading to the ylide <b><sup>Cy</sup>1-H</b>. Metalation to the yldiides was finally achieved with strong bases such as <i>n</i>BuLi, NaNH<sub>2</sub>, or BnK. In the solid state, the lithium compound forms a tetrameric structure consisting of a (C-S-O-Li)<sub>4</sub> macrocycle, which incorporates an additional molecule of lithium iodide. The potassium compound forms a <i>C</i> <sub>4</sub>-symmetric structure with a (K<sub>4</sub>O<sub>4</sub>)<sub>2</sub> octahedral prism as central structural motif. Upon deprotonation the P-C-S linkage undergoes a remarkable contraction typical for metalated ylides.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"646 13","pages":"835-841"},"PeriodicalIF":1.4,"publicationDate":"2020-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.201900333","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"38218296","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 5
Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes. 铁镓和钴镓四磷酸配合物。
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2020-07-15 Epub Date: 2020-02-25 DOI: 10.1002/zaac.201900351
Christoph G P Ziegler, Felix Hennersdorf, Jan J Weigand, Robert Wolf
{"title":"Iron-Gallium and Cobalt-Gallium Tetraphosphido Complexes.","authors":"Christoph G P Ziegler, Felix Hennersdorf, Jan J Weigand, Robert Wolf","doi":"10.1002/zaac.201900351","DOIUrl":"10.1002/zaac.201900351","url":null,"abstract":"<p><p>The synthesis and characterization of two heterobimetallic complexes [K([18]crown-6){(η<sup>4</sup>-C<sub>14</sub>H<sub>10</sub>)Fe(μ-η<sup>4</sup>:η<sup>2</sup>-P<sub>4</sub>)Ga(nacnac)}] (<b>1</b>) (C<sub>14</sub>H<sub>10</sub> = anthracene) and [K(dme)<sub>2</sub>{(η<sup>4</sup>-C<sub>14</sub>H<sub>10</sub>)Co(μ-η<sup>4</sup>:η<sup>2</sup>-P<sub>4</sub>)Ga(nacnac)}] (<b>2</b>) with strongly reduced P<sub>4</sub> units is reported. Compounds <b>1</b> and <b>2</b> are prepared by reaction of the gallium(III) complex [(nacnac)Ga(η<sup>2</sup>-P<sub>4</sub>)] (nacnac = CH[CMeN(2,6-<i>i</i>Pr<sub>2</sub>C<sub>6</sub>H<sub>3</sub>)]<sub>2</sub>) with bis(anthracene)ferrate(1-) and -cobaltate(1-) salts. The molecular structures of <b>1</b> and <b>2</b> were determined by X-ray crystallography and feature a P<sub>4</sub> chain which binds to the transition metal atom via all four P atoms and to the gallium atom via the terminal P atoms. Multinuclear NMR studies on <b>2</b> suggest that the molecular structure is preserved in solution.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"646 13","pages":"552-557"},"PeriodicalIF":1.4,"publicationDate":"2020-07-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.201900351","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"38218294","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 3
200 Years of Lithium and 100 Years of Organolithium Chemistry. 锂的200年和有机锂化学的100年
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2018-03-01 Epub Date: 2018-01-17 DOI: 10.1002/zaac.201700394
Ulrich Wietelmann, Jan Klett
{"title":"200 Years of Lithium and 100 Years of Organolithium Chemistry.","authors":"Ulrich Wietelmann,&nbsp;Jan Klett","doi":"10.1002/zaac.201700394","DOIUrl":"https://doi.org/10.1002/zaac.201700394","url":null,"abstract":"<p><p>The element lithium has been discovered 200 years ago. Due to its unique properties it has emerged to play a vital role in industry, esp. for energy storage, and lithium-based products and processes support sustainable technological developments. In addition to the many uses of lithium in its inorganic forms, lithium has a rich organometallic chemistry. The development of organometallic chemistry has been hindered by synthetic problems from the start. When <i>Wilhelm Schlenk</i> developed the basic principles to handle and synthesize air- and moisture-sensitive compounds, the road was open to further developments. After more information was available about the stability and solubility of such compounds, they started to play an essential role in other fields of chemistry as alkyl or aryl transfer reagents.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"644 4","pages":"194-204"},"PeriodicalIF":1.4,"publicationDate":"2018-03-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.201700394","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"35915828","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 43
Coordination Polymers based on the Neutral Ditopic Ligand (C6H4PO(OCH3)2)2 Involving some f-Block Elements. 基于中性二价配体 (C6H4PO(OCH3)2)2 的配位聚合物，其中涉及一些 f-嵌段元素。
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2018-02-15 Epub Date: 2018-01-17 DOI: 10.1002/zaac.201700424
Kristijan Krekić, Eireen Käkel, Dieter Klintuch, Dana Bloß, Rudolf Pietschnig
{"title":"Coordination Polymers based on the Neutral Ditopic Ligand (C<sub>6</sub>H<sub>4</sub>PO(OCH<sub>3</sub>)<sub>2</sub>)<sub>2</sub> Involving some f-Block Elements.","authors":"Kristijan Krekić, Eireen Käkel, Dieter Klintuch, Dana Bloß, Rudolf Pietschnig","doi":"10.1002/zaac.201700424","DOIUrl":"10.1002/zaac.201700424","url":null,"abstract":"<p><p>An improved synthesis using microwave heating affords (C<sub>6</sub>H<sub>4</sub>PO(OCH<sub>3</sub>)<sub>2</sub>)<sub>2</sub> in excellent isolated yield (95 %). The ligand properties of this bisphosphonateester were explored towards hard metal centers <i>M</i><sup>2+</sup> (<i>M</i> = Ca, UO<sub>2</sub>) and <i>M</i><sup>3+</sup> (<i>M</i> = La, Ce, Sm, Eu) resulting in coordination polymers, for which the reduction of ionic size of the central metal atom resulted in lower-dimensional structural motifs as opposed to higher dimensional networks obtained for the larger ions. All coordination polymers were characterized by single-crystal X-ray diffraction, IR spectroscopy, and combustion analysis. The ligand was furthermore characterized with multinuclear NMR spectroscopy.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"644 3","pages":"149-154"},"PeriodicalIF":1.4,"publicationDate":"2018-02-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://ftp.ncbi.nlm.nih.gov/pub/pmc/oa_pdf/66/0d/ZAAC-644-149.PMC5888180.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"36013470","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Power Electronic Semiconductor Materials for Automotive and Energy Saving Applications - SiC, GaN, Ga2O3, and Diamond. 用于汽车和节能应用的电力电子半导体材料- SiC, GaN, Ga2O3和金刚石。
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2017-11-17 Epub Date: 2017-10-20 DOI: 10.1002/zaac.201700270
Peter J Wellmann
{"title":"Power Electronic Semiconductor Materials for Automotive and Energy Saving Applications - SiC, GaN, Ga<sub>2</sub>O<sub>3</sub>, and Diamond.","authors":"Peter J Wellmann","doi":"10.1002/zaac.201700270","DOIUrl":"https://doi.org/10.1002/zaac.201700270","url":null,"abstract":"<p><p>Power electronics belongs to the future key technologies in order to increase system efficiency as well as performance in automotive and energy saving applications. Silicon is the major material for electronic switches since decades. Advanced fabrication processes and sophisticated electronic device designs have optimized the silicon electronic device performance almost to their theoretical limit. Therefore, to increase the system performance, new materials that exhibit physical and chemical properties beyond silicon need to be explored. A number of wide bandgap semiconductors like silicon carbide, gallium nitride, gallium oxide, and diamond exhibit outstanding characteristics that may pave the way to new performance levels. The review will introduce these materials by (i) highlighting their properties, (ii) introducing the challenges in materials growth, and (iii) outlining limits that need innovation steps in materials processing to outperform current technologies.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"643 21","pages":"1312-1322"},"PeriodicalIF":1.4,"publicationDate":"2017-11-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.201700270","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"35611589","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 58
Re-Determination of the Crystal Structure of MIL-91(Al). MIL-91(Al)晶体结构的再测定。
IF 1.4 4区 化学
Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2017-01-01 Epub Date: 2016-12-16 DOI: 10.1002/zaac.201600358
Nele Hermer, Michael T Wharmby, Norbert Stock
{"title":"Re-Determination of the Crystal Structure of MIL-91(Al).","authors":"Nele Hermer,&nbsp;Michael T Wharmby,&nbsp;Norbert Stock","doi":"10.1002/zaac.201600358","DOIUrl":"https://doi.org/10.1002/zaac.201600358","url":null,"abstract":"<p><p>The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.</p>","PeriodicalId":54398,"journal":{"name":"Zeitschrift fur Anorganische und Allgemeine Chemie","volume":"643 2","pages":"137-140"},"PeriodicalIF":1.4,"publicationDate":"2017-01-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://sci-hub-pdf.com/10.1002/zaac.201600358","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"34806045","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 8
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