Mathias Glatz, Nikolaus Gorgas, Berthold Stöger, Ernst Pittenauer, Liliana Ferreira, Luis F Veiros, Maria José Calhorda, Karl Kirchner
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引用次数: 0
Abstract
In the present work we have prepared and fully characterized several Fe(0) complexes of the type [Fe(PNP)(CO)2] treating Fe(II) complexes [Fe(PNP)(Cl)2] with KC8 in the presence of carbon monoxide. While complexes [Fe(PNPNMe-iPr)(CO)2], [Fe(PNPNEt-iPr)(CO)2] adopt a trigonal bipyramidal geometry, the bulkier and more electron rich [Fe(PNPNH-tBu)(CO)2] is closer to a square pyramidal geometry. Mössbauer spectra showed isomer shifts very close to 0 and similar to those reported for Fe(I) systems. Quadrupole splitting values range between 2.2 and 2.7 mm s-1 both in experiments and DFT calculations, while those of Fe(I) complexes are much smaller (∼0.6 mm s-1).
期刊介绍：
Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance.
Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.
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