Re-Determination of the Crystal Structure of MIL-91(Al).

IF 1.1 4区化学 Q4 CHEMISTRY, INORGANIC & NUCLEAR

Zeitschrift fur Anorganische und Allgemeine Chemie Pub Date : 2017-01-01 Epub Date: 2016-12-16 DOI:10.1002/zaac.201600358

Nele Hermer, Michael T Wharmby, Norbert Stock

引用次数: 8

Abstract

The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.

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MIL-91(Al)晶体结构的再测定。

利用高分辨率同步加速器粉末x射线衍射数据重新测定了最早的永久多孔金属磷酸盐之一MIL-91(Al)的结构。新模型在较低的对称空间群中，结构中没有无序配体，同时与报道的化合物保持一致。还开发了新的较温和的合成条件。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

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来源期刊

Zeitschrift fur Anorganische und Allgemeine Chemie 化学-无机化学与核化学

CiteScore

2.60

自引率

14.30%

发文量

308

审稿时长

1 months

期刊介绍： ZAAC is an international scientific journal which publishes original papers on new relevant research results from all areas of inorganic chemistry, solid state chemistry, and co-ordination chemistry. The contributions reflect the latest findings in these research areas and serve the development of new materials, such as super-hard materials, electrical superconductors, or intermetallic compounds. Up-to-date physical methods for the characterization of new chemical compounds and materials are also described.