A Terminal Chlorophosphinidene Complex.

Abstract

Terminal, electrophilic phosphinidene complexes (M=PR) are attractive platforms for PR-transfer to organic substrates. In contrast to aryl- or alkylphosphinidene complexes terminal chlorophosphinidenes (M=PCl) have only been proposed as transient intermediates but isolable example remain elusive. Here we present the transfer of PCl from chloro-substituted dibenzo-7λ³-phosphanorbornadiene to a square-planar osmium(II) PNP pincer complex to give the first isolable, terminal chlorophosphinidene complex with remarkable thermal stability. Os=P bonding was examined computationally giving rise to highly covalent {Os^II=P^ICl} double bonding.