MIL-91(Al)晶体结构的再测定。

IF 16.4 1区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Accounts of Chemical Research Pub Date : 2017-01-01 Epub Date: 2016-12-16 DOI:10.1002/zaac.201600358

Nele Hermer, Michael T Wharmby, Norbert Stock

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引用次数: 8

摘要

利用高分辨率同步加速器粉末x射线衍射数据重新测定了最早的永久多孔金属磷酸盐之一MIL-91(Al)的结构。新模型在较低的对称空间群中，结构中没有无序配体，同时与报道的化合物保持一致。还开发了新的较温和的合成条件。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

Re-Determination of the Crystal Structure of MIL-91(Al).

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Re-Determination of the Crystal Structure of MIL-91(Al).

The structure of one of the first permanently porous metal phosphonates, MIL-91(Al) was re-determined using high resolution synchrotron powder X-ray diffraction data. The new model is in a lower symmetry space group, with no disordered ligands in the structure, whilst remaining otherwise consistent with the reported compound. New milder synthetic conditions were also developed.

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来源期刊

Accounts of Chemical Research 化学-化学综合

CiteScore

31.40

自引率

1.10%

发文量

312

审稿时长

2 months

期刊介绍： Accounts of Chemical Research presents short, concise and critical articles offering easy-to-read overviews of basic research and applications in all areas of chemistry and biochemistry. These short reviews focus on research from the author’s own laboratory and are designed to teach the reader about a research project. In addition, Accounts of Chemical Research publishes commentaries that give an informed opinion on a current research problem. Special Issues online are devoted to a single topic of unusual activity and significance. Accounts of Chemical Research replaces the traditional article abstract with an article "Conspectus." These entries synopsize the research affording the reader a closer look at the content and significance of an article. Through this provision of a more detailed description of the article contents, the Conspectus enhances the article's discoverability by search engines and the exposure for the research.