Tonni Agustiono Kurniawan, Pow-Seng Yap, Zhonghao Chen
{"title":"Techniques for pollutant removal, nutrient recovery, and energy production from landfill leachates: a review","authors":"Tonni Agustiono Kurniawan, Pow-Seng Yap, Zhonghao Chen","doi":"10.1007/s10311-024-01805-4","DOIUrl":"https://doi.org/10.1007/s10311-024-01805-4","url":null,"abstract":"<p>Landfill leachate is a highly polluted wastewater resulting from the decomposition of organic waste in landfills. It contains high levels of organic matter, nitrogen, phosphorus, heavy metals, and other contaminants of environmental and health concerns, but landfill leachate could also be used to produce nutrient and energy. Here we review physical, chemical, and biological methods to treat landfill leachates. Methods include adsorption, membrane separation, coagulation and flocculation, ion exchange, air stripping, chemical precipitation, electrochemical oxidation, Fenton oxidation, ozonation, photocatalysis, activated sludge process, sequential batch reactor, rotating biological contactors, nitrification and denitrification, upflow anaerobic sludge blanket, phytoremediation, and bioremediation. We discuss the technical, social, economic and environmental benefits of removing contaminants, and of recovering nutrient and energy. Physicochemical methods remove 12–95% of chemical oxygen demand, 1–100% of ammonia nitrogen, 40–96% of metals, and 44–99% of color. Advanced oxidation processes remove 19–98% of the chemical oxygen demand, 12–85% of ammonia nitrogen, and 74–98% of total organic carbon. Biological methods remove 15–93% of the chemical oxygen demand, 43–97% of the biochemical oxygen demand, 14–100% of ammonia nitrogen, and 42–98% of phosphates. Optimized leachate treatment technology can recover 10–80% of nutrients and 0.1–7 kWh/m<sup>3</sup> of energy.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"81 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143020590","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Bacterial cellulose and composites for the treatment of water pollution: a review","authors":"Giang Thanh Tran, Thuy Thi Thanh Nguyen, Duyen Thi Cam Nguyen, Thuan Van Tran","doi":"10.1007/s10311-025-01818-7","DOIUrl":"https://doi.org/10.1007/s10311-025-01818-7","url":null,"abstract":"<p>Water contamination by organic, inorganic, and microplastic pollutants poses significant threats to ecosystems and public health, emphasizing the need for advanced remediation strategies. Here, we review the water treatment with composites including bacterial cellulose, with focus on synthesis and modification of bacterial cellulose and composites, and application in water treatment. Synthesis of bacterial cellulose can be done in static, agitated and bioreactor cultures. Composite materials include metal oxides, metal organic frameworks, polymers, graphene and magnetic materials. Applications comprise the removal of microplastics, heavy metals, oil, and organic and inorganic pollutants. Bacterial cellulose is biodegradable, biocompatible, and possesses customizable surface chemistry and structure, enabling exceptional pollutant removal. Surface modifications add functional groups such as hydroxyl and carboxylate groups, while reinforcement strategies improve mechanical and chemical properties. Composites exhibit pollutant removal efficiencies of up to 99.9% and oil separation stability of 99% even after 20–50 cycles. Mechanisms including adsorption, photodegradation, flocculation, and biodegradation are discussed.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"9 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990875","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sai Praneeth, Ahmed K. Sakr, Preetom K. Roy, Timothy M. Dittrich
{"title":"Efficient recovery of gadolinium from magnetic resonance imaging patient urine using a diglycolamide ligand-functionalized sorbent system","authors":"Sai Praneeth, Ahmed K. Sakr, Preetom K. Roy, Timothy M. Dittrich","doi":"10.1007/s10311-024-01815-2","DOIUrl":"https://doi.org/10.1007/s10311-024-01815-2","url":null,"abstract":"<p>Gadolinium-based contrast agents are used in more than 30 million magnetic resonance imaging procedures worldwide each year. These gadolinium complexes are excreted in urine and then end up polluting wastewater, leading to gadolinium concentration increase in rivers, known as the ‘gadolinium anomaly.’ Here we studied gadolinium recovery from patient urine using ligand-associated organosilica media impregnated with <i>N</i>,<i>N</i>,<i>N</i>′,<i>N</i>′-tetraoctyl-diglycolamide, a chelating agent traditionally used in separating lanthanides from actinides in nuclear waste applications. Gadolinium-containing urine was acidified with nitric acid and tested in batch and packed bed column experiments. Sorbent media and precipitate solids were analyzed using advanced characterization tools. Results show that more than 85% of the gadolinium was recovered with a 12.8 mg g⁻<sup>1</sup> sorption capacity. A two-cycle column study produced over 99% pure gadolinium through stripping, oxalic acid precipitation, and calcination. A binding mechanism with a 1:3 chelation and matching kinetics for a pseudo-second-order rate model can help design scaled-up systems.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"32 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142990874","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Miriana Kfoury, Céline Alamichel, Sophie Fourmentin
{"title":"Combined supramolecular solvent preparation and solid extraction","authors":"Miriana Kfoury, Céline Alamichel, Sophie Fourmentin","doi":"10.1007/s10311-025-01819-6","DOIUrl":"https://doi.org/10.1007/s10311-025-01819-6","url":null,"abstract":"<p>Classical extraction involves several time-consuming and costly steps using toxic solvents. Here, we combined the preparation of a cyclodextrin-based supramolecular deep eutectic solvent and the extraction of spent coffee grounds by microwave irradiation in a single step. We tested two new solvents, randomly methylated-β-cyclodextrin:propylene glycol and hydroxypropyl-β-cyclodextrin:ethylene glycol, and compared the results with two classical solvents, chloride:urea (1:2) and ethanol/water 80/20 vol%. We also used classical Soxhlet extraction. We calculated the sustainability of the process using ComplexGAPI. Results show that the optimal one-step extraction conditions were 15 min of irradiation at 80 °C with the addition of 10 wt% water. Under these conditions, the two new solvents showed higher extraction yields of antioxidants and polyphenols than choline chloride:urea (1:2) or ethanol/water 80/20 vol%. Similarly, the half maximal effective concentration and gallic acid equivalent of the Soxhlet extracts were 5 and 3 times lower, respectively, than those obtained with hydroxypropyl-β-cyclodextrin:ethylene glycol (1:40) 10 wt% water. The composition of the extracts from the one-step process was similar to that of the Soxhlet extract. Sustainability analysis revealed low energy consumption, reduced unitary operations and less waste production.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"52 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142981157","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Xiaoya Ren, Mengqi Feng, Meiyi Mao, Xizi Long, Jiafeng Pan, Yan Tang, Pengji Zhou, Tangjian Peng, Hui Wang, Fei Yang
{"title":"Cyanobacteria for environmental, energy and biomedical application: a review","authors":"Xiaoya Ren, Mengqi Feng, Meiyi Mao, Xizi Long, Jiafeng Pan, Yan Tang, Pengji Zhou, Tangjian Peng, Hui Wang, Fei Yang","doi":"10.1007/s10311-024-01814-3","DOIUrl":"https://doi.org/10.1007/s10311-024-01814-3","url":null,"abstract":"<p>Cyanobacteria are photosynthetic prokaryotes and major contributors to global biogeochemical cycles. They possess powerful biological activity, high adaptability to extreme environment, rapid growth rate and genetic editability. Here, we review cyanobacteria with focus on their application in environmental pollution and biomedicine. Cyanobacteria can be used for pollutant removal, biofuel and biochar production, template for drug discovery, hypoxia-related disease therapy, anticancer, antiviral, antibacterial, antioxidant and antifibrotic. Spiral-shaped cyanobacteria are excellent carriers for drug delivery. The oxygen-producing capacity of cyanobacteria is promising in the treatment of hypoxia-related diseases.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"87 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142967796","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Serena Ducoli, Gabriela Kalčíková, Milica Velimirovic, Laura E. Depero, Stefania Federici
{"title":"Production, characterization, and toxicology of environmentally relevant nanoplastics: a review","authors":"Serena Ducoli, Gabriela Kalčíková, Milica Velimirovic, Laura E. Depero, Stefania Federici","doi":"10.1007/s10311-024-01810-7","DOIUrl":"https://doi.org/10.1007/s10311-024-01810-7","url":null,"abstract":"<p>Nanoplastic pollution is poorly known, in particular because research is actually mainly done using synthetic polymeric nanospheres that are not representative of environmental nanoplastics, which are very diverse in their composition, size, and shape. Here we review environmentally relevant nanoplastics with focus on their production, characterization, quantification, stability, aggregation, and toxicity. Production of environmentally relevant nanoplastics can be done by mechanical and physicochemical methods. Toxicological studies focus on internalization and toxicity on human cell lines, and bioaccumulation and systemic effects on model organisms.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"49 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142961813","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Paulo M. S. Sousa, Kerry A. Kinney, Cátia A. Sousa, Manuel Simões
{"title":"Microalgae for microplastic removal from water and wastewater: a review","authors":"Paulo M. S. Sousa, Kerry A. Kinney, Cátia A. Sousa, Manuel Simões","doi":"10.1007/s10311-024-01809-0","DOIUrl":"https://doi.org/10.1007/s10311-024-01809-0","url":null,"abstract":"<p>The worldwide microplastic pollution in waters requires efficient removal techniques, yet actual wastewater treatment methods are limited. Here we review the use of microalgae for microplastic removal, with focus on microplastics in aquatic systems and wastewaters, legislation and regulations, common removal techniques, and microalgae for microplastic removal. We describe the mechanisms involved in microalgae-microplastics aggregation. We also present the criteria for selecting adequate microalgae for microplastics removal from wastewater.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"72 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142925101","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Underestimated sequestration of soil organic carbon in China","authors":"Yulong Yin, Haiqing Gong, Zhong Chen, Xingshuai Tian, Yingcheng Wang, Zihan Wang, Kai He, Qi Miao, Yiyan Chu, Yanfang Xue, Qingsong Zhang, Zhenling Cui","doi":"10.1007/s10311-024-01813-4","DOIUrl":"https://doi.org/10.1007/s10311-024-01813-4","url":null,"abstract":"<p>Soil carbon sequestration is a climate engineering process that could significantly reduce global warming, yet actual estimates of soil organic carbon sequestration in China’s croplands are probably underestimated. Here we estimated soil organic carbon sequestration across China’s croplands from 1980 to 2018 using four different methods. We found that the average sequestration rate in China’s croplands is 298.5 kg ha<sup>−1</sup>. We present management strategies that could increase the mean soil organic carbon stock by 58.2 Mg ha<sup>−1</sup>. Insights into the potential for region-specific strategies to enhance soil carbon sequestration are given.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"2 2 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142924981","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Proteomics technologies in toxicity screening: a review","authors":"Yushi Jin, Zhejia Sun, April Z. Gu, Xiaohong Zhou","doi":"10.1007/s10311-024-01816-1","DOIUrl":"10.1007/s10311-024-01816-1","url":null,"abstract":"<div><p>The presence of natural and synthetic toxic compounds in the environment requires the development of advanced detection methods. Here we review proteomics technologies for toxicity screening, with focus on principles, current status, mass spectrometry-based proteomics, protein microarray, and in-frame tagging method. Concerning mass spectrometry-based proteomics, we detail liquid chromatography-tandem mass spectrometry, label-free quantification, and thermal proteome profiling. We discuss the integration of the latest advances in proteomics technologies, such as single-cell proteomics, data-independent acquisition, and multi-omics approaches.</p></div>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"23 1","pages":"67 - 80"},"PeriodicalIF":15.0,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142917214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Tomas Rozsypal, Jaroslav Pejchal, Jakub Opravil, Mihail Haralampiev, Victor Bocos-Bintintan, Zbynek Kobliha
{"title":"Destruction of chemical weapons stockpiles in the Russian Federation: a review","authors":"Tomas Rozsypal, Jaroslav Pejchal, Jakub Opravil, Mihail Haralampiev, Victor Bocos-Bintintan, Zbynek Kobliha","doi":"10.1007/s10311-024-01812-5","DOIUrl":"https://doi.org/10.1007/s10311-024-01812-5","url":null,"abstract":"<p>Chemical weapons, designed for mass harm, are posing risks of contamination, accidents, and ecological damage, and thus require their destruction. However, destruction of chemical weapons is challenging, notably in the Russian Federation due to the large scale and complexity of chemical weapons stockpiles, the diverse toxic agents stored under varying conditions, logistical and political obstacles, financial constraints, and the disposal process. Here we review the Russian Federation’s chemical weapons disposal program with an emphasis on the political context, declared chemical weapons stockpiles, methods for destruction, health and environmental issues, and nerve agents. We analyze stockpiles totaling nearly 40,000 tonnes of chemical agents across seven facilities, focusing on their composition, storage conditions, and destruction technologies. Methods such as neutralization, bituminization, and thermal destruction are compared. Environmental risks include arsenic migration and groundwater contamination near disposal sites. We observe the limitations of using bitumen salt masses as a safe disposal method.</p>","PeriodicalId":541,"journal":{"name":"Environmental Chemistry Letters","volume":"56 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2025-01-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142917215","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}