Carbon Resources Conversion最新文献

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Reactivity and performance of steam gasification during biomass batch feeding 生物质分批加料过程中蒸汽气化的反应性和性能
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-09-01 DOI: 10.1016/j.crcon.2023.03.001
Yuna Ma, Zefeng Ge, Mingxun Zeng, Zhenting Zha, Yujie Tao, Huiyan Zhang
{"title":"Reactivity and performance of steam gasification during biomass batch feeding","authors":"Yuna Ma,&nbsp;Zefeng Ge,&nbsp;Mingxun Zeng,&nbsp;Zhenting Zha,&nbsp;Yujie Tao,&nbsp;Huiyan Zhang","doi":"10.1016/j.crcon.2023.03.001","DOIUrl":"10.1016/j.crcon.2023.03.001","url":null,"abstract":"<div><p>The steam gasification characteristics of poplar sawdust were investigated in a piston fed fixed-bed gasifier, reflecting the batch feeding process of fixed-bed gasifiers in industrial applications. The effects of operating conditions, including steam supply, the flow rate of inert gas, gasification temperature, and feeding rate, on gasification reactivity and performance were investigated online. The major gas product during pyrolysis was CO, followed by H<sub>2</sub>, CH<sub>4</sub>, and CO<sub>2</sub>, and the gasification was greatly facilitated by the injection of steam to generate H<sub>2</sub>. The gasification reactivity and performance were improved with increased steam supply and temperature. The maximum production rate of H<sub>2</sub> by char gasification was tripled and doubled, respectively, with an increase in steam supply from 50 to 400 mL/min and a temperature rise from 800 to 900 °C, and the time required for complete gasification was also halved. Compared to pyrolysis, the volume fraction of H<sub>2</sub> increased from 23% to 37%, and correspondingly, the H<sub>2</sub>/CO ratio increased from 0.42 to 0.95.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"6 3","pages":"Pages 229-237"},"PeriodicalIF":6.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44479067","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
Immigration, transformation, and emission control of sulfur and nitrogen during gasification of MSW: Fundamental and engineering review 城市生活垃圾气化过程中硫和氮的迁移、转化和排放控制:基础和工程综述
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-09-01 DOI: 10.1016/j.crcon.2023.03.003
Shuchao Cheng , Xueyu Ding , Xinxin Dong , Mengjie Zhang , Xinqi Tian , Yang Liu , Yaji Huang , Baosheng Jin
{"title":"Immigration, transformation, and emission control of sulfur and nitrogen during gasification of MSW: Fundamental and engineering review","authors":"Shuchao Cheng ,&nbsp;Xueyu Ding ,&nbsp;Xinxin Dong ,&nbsp;Mengjie Zhang ,&nbsp;Xinqi Tian ,&nbsp;Yang Liu ,&nbsp;Yaji Huang ,&nbsp;Baosheng Jin","doi":"10.1016/j.crcon.2023.03.003","DOIUrl":"10.1016/j.crcon.2023.03.003","url":null,"abstract":"<div><p>This paper proposes a comprehensive summary and analysis of an important issue during municipal solid waste (MSW) gasification-sulfur and nitrogen pollution. It provides an overview of the fundamentals of MSW and the basic aspects of nitrogen and sulfur elements. Their characteristics of immigration, transformation and distribution during gasification with control solutions in realized or potential engineering are also concluded. The analysis indicates that the complete scenario of the occurrence form of sulfur and nitrogen elements in MSW is difficult to obtain, owing to the diverse sources and complicated compositions. However, with the assistance of advanced characterization and quantification methods (XPS, XRD, TG-FTIR, et al.), the common sulfur- and nitrogen-containing compounds in both organic and inorganic states can be detected. Adjustment of gasification conditions can regulate the transformation of these elements for emission control. The multiple pollutants including H<sub>2</sub>S, SO<em><sub>x</sub></em>, COS, NH<sub>3</sub>, HCN and NO<em><sub>x</sub></em> cannot be eliminated by one-step treatment but a combination of adsorption and catalytic treatments may realize the control goal. This research aims to benefit meeting emission standards during MSW gasification and to provide a reference for other processes such as incineration, pyrolysis and other feedstocks like biomass and refuse derived fuel (RDF).</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"6 3","pages":"Pages 184-204"},"PeriodicalIF":6.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49508040","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Green preparation of self-supporting platinum nanoflower catalyst and its electrocatalytic oxidation performance of methanol 自持铂纳米花催化剂的绿色制备及其对甲醇的电催化氧化性能
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-09-01 DOI: 10.1016/j.crcon.2023.01.002
Zhen Lu , Hongjie Kang , Ji Li , Jianpeng Shang , Kun Yang , Rui Liu , Zuopeng Li , Feng Feng , Yong Guo , Haidong Zhao
{"title":"Green preparation of self-supporting platinum nanoflower catalyst and its electrocatalytic oxidation performance of methanol","authors":"Zhen Lu ,&nbsp;Hongjie Kang ,&nbsp;Ji Li ,&nbsp;Jianpeng Shang ,&nbsp;Kun Yang ,&nbsp;Rui Liu ,&nbsp;Zuopeng Li ,&nbsp;Feng Feng ,&nbsp;Yong Guo ,&nbsp;Haidong Zhao","doi":"10.1016/j.crcon.2023.01.002","DOIUrl":"10.1016/j.crcon.2023.01.002","url":null,"abstract":"<div><p>The three-dimensional (3D) self-supporting Pt nanoflower catalyst was prepared by using Pt organic compounds as precursors in a low-temperature molten salt system. The obtained Pt nanoflower nanoparticle can reach 400–500 nm with a face-centered cubic structure, which has the structural characteristics of a loose framework and more exposed active sites. The surfactant-free Pt nanoflower was directly used as methanol electrooxidation reaction (MOR) electrocatalysts without any pretreatment and activated carbon support. The results of electrochemical catalytic oxidation of methanol showed that the Pt nanoflower catalyst exhibit more enhanced electrocatalytic oxidation performance toward methanol compared with the commercial platinum black catalyst. The green and effective method can be developed and expected to enable mass production of fuel cell catalysts.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"6 3","pages":"Pages 167-172"},"PeriodicalIF":6.0,"publicationDate":"2023-09-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47204597","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Utilization of spent substrates and waste products of mushroom cultivation to produce new crops of Pleurotus ostreatus, Pleurotus eryngii and Agaricus bisporus 利用蘑菇栽培废底物和废弃物生产平菇、银杏和双孢蘑菇新作物
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-08-21 DOI: 10.1016/j.crcon.2023.08.001
Marianna Dedousi , Eirini-Maria Melanouri , Dimitris Karayannis , Eleftherios-Ikaros Kaminarides , Panagiota Diamantopoulou
{"title":"Utilization of spent substrates and waste products of mushroom cultivation to produce new crops of Pleurotus ostreatus, Pleurotus eryngii and Agaricus bisporus","authors":"Marianna Dedousi ,&nbsp;Eirini-Maria Melanouri ,&nbsp;Dimitris Karayannis ,&nbsp;Eleftherios-Ikaros Kaminarides ,&nbsp;Panagiota Diamantopoulou","doi":"10.1016/j.crcon.2023.08.001","DOIUrl":"10.1016/j.crcon.2023.08.001","url":null,"abstract":"<div><p>Five agro-industrial residues, their corresponding spent mushroom substrates (SMS), commercial fresh and spent mushroom compost of <em>Agaricus</em> (SMC) and <em>Pleurotus ostreatus</em> (SMS GZ) cultivation, <em>Pleurotus</em> and <em>Agaricus</em> waste (stipes/mishappen mushrooms) were combined and re-utilized as novel substrates for the cultivation of <em>P. ostreatus</em>, <em>P. eryngii</em> and <em>A. bisporus</em> mushrooms. SMSs/ SMC were used up to 40% (treatment 1 and 2), while 20% of mushroom waste were added in fresh and spent substrates (treatment 3 and 4). The impact of different substrates on mycelial growth rate and biomass production was examined. Then, <em>Pleurotus</em> spp. were cultivated on the most promising substrates and essential cultivation aspects (earliness, total mushroom yield, biological efficiency-BE) and carposomes’ quality parameters (weight, morphological characteristics) were evaluated. Laccase and endoglucanase production by <em>Pleurotus</em> species were also determined at 50 and 100% of colonization stages. All species showed their fastest mycelial growth rate (up to 5 mm/day) on substrates consisted of SMC, whereas many combinations of species/substrate enhanced biomass production. The SMS GZ supplementation positively affected laccase activity; in the cultures of <em>P. ostreatus</em> and <em>P. eryngii</em> the highest values were 62,539 and 17,584 U/g d.w., respectively. On the contrary, small amounts of endoglucanase were produced (0.007 to 0.322 U/g d.w.); the greatest production was recorded for <em>P. ostreatus</em> at full colonization. Regarding fermentation in bags, significant amount of total mushroom yield was produced in all substrates and those with SMS GZ supported the fastest earliness period and the highest BE for both <em>Pleurotus</em> species. BE values ranged from 54 to 133% for <em>P. ostreatus</em> and from 53 to 121% for <em>P. eryngii</em>. Concerning morphological characteristics, mushroom waste addition seemed to affect them positively. The data included in this paper support the effective re-utilization of different types of SMS and mushroom waste for fungal mass and enzymes’ production and for new high quality <em>Pleurotus</em> spp. carposomes.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"7 2","pages":"Article 100196"},"PeriodicalIF":6.0,"publicationDate":"2023-08-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2588913323000583/pdfft?md5=367b14c9380bc0df6e32ed420bfd7ca2&pid=1-s2.0-S2588913323000583-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49106119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in the production of single cell protein from renewable resources and applications 利用可再生资源生产单细胞蛋白的研究进展及应用
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-07-26 DOI: 10.1016/j.crcon.2023.07.004
Danai Ioanna Koukoumaki , Erminta Tsouko , Seraphim Papanikolaou , Zacharias Ioannou , Panagiota Diamantopoulou , Dimitris Sarris
{"title":"Recent advances in the production of single cell protein from renewable resources and applications","authors":"Danai Ioanna Koukoumaki ,&nbsp;Erminta Tsouko ,&nbsp;Seraphim Papanikolaou ,&nbsp;Zacharias Ioannou ,&nbsp;Panagiota Diamantopoulou ,&nbsp;Dimitris Sarris","doi":"10.1016/j.crcon.2023.07.004","DOIUrl":"10.1016/j.crcon.2023.07.004","url":null,"abstract":"<div><p>Single Cell Protein (SCP) refers to dry cells of microorganisms, and it constitutes a highly promising and alternative protein source for multiple applications. SCP presents a rich nutritional profile containing valuable amino acids and fatty acids, nucleic acids, minerals, and several vitamins. Several businesses worldwide have introduced SCP into their production cycles, hence expanding the scope of its application in value added market chains such as the edible food packaging. SCP is produced by a plethora of microorganisms, including fungi, yeasts, bacteria, and algae while many of them are Generally Recognized as Safe (GRAS). Selected microbial strains present satisfying growth capability with high yields when cultivated in renewable feedstock. Thus, production rates and process sustainability could be enhanced via the valorization of industrial and agricultural wastes as the nutrient sources, combined with optimization of process parameters, i.e fermentation mode and feeding strategy, pH, temperature, C/N ratio, agitation rate and oxygen supply. This review addresses the latest developments made towards the SCP production, highlighting efficient microbial SCP producers, and production systems that valorize solid and liquid streams from several agricultural wastes. Potential applications, challenges in sensorial-, and safety-aspects as well as consumers perception issues of SCP incorporation into food-related matrices are also discussed.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"7 2","pages":"Article 100195"},"PeriodicalIF":6.0,"publicationDate":"2023-07-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2588913323000571/pdfft?md5=e826839e333495b1c37ab3549a489770&pid=1-s2.0-S2588913323000571-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"44792980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 1
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-07-16 DOI: 10.1016/j.crcon.2023.07.002
Anthony Dufour , Liangyuan Jia
{"title":"","authors":"Anthony Dufour ,&nbsp;Liangyuan Jia","doi":"10.1016/j.crcon.2023.07.002","DOIUrl":"https://doi.org/10.1016/j.crcon.2023.07.002","url":null,"abstract":"","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"6 4","pages":"Pages 352-353"},"PeriodicalIF":6.0,"publicationDate":"2023-07-16","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49704745","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Optimal aeration management strategy for a small-scale food waste composting 小型食物垃圾堆肥的最佳曝气管理策略
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-07-08 DOI: 10.1016/j.crcon.2023.06.002
Jia Chi Lai , Yi Lung Then , Siaw San Hwang , Chung Sien Lee
{"title":"Optimal aeration management strategy for a small-scale food waste composting","authors":"Jia Chi Lai ,&nbsp;Yi Lung Then ,&nbsp;Siaw San Hwang ,&nbsp;Chung Sien Lee","doi":"10.1016/j.crcon.2023.06.002","DOIUrl":"10.1016/j.crcon.2023.06.002","url":null,"abstract":"<div><p>Food waste is a significant contributor to greenhouse gas emissions when it ends up in landfills. Composting turns out to be a sustainable solution to this problem, but it requires controlled and continuous airflow for optimal performance. This study focused on the effect of aeration rates and airflow directions on food waste composting using a closed system with forced aeration. Air was entered into the composting vessel in three directions, which were upward, downward, and a combination of both directions. Each direction was run at aeration rates of 0.1, 0.4, and 0.7 L/min. The findings showed that the compost pile aerated at 0.4 L/min by using two-directional airflow can reach the thermophilic temperature within half of the day. The compost pile achieved temperature of 40.94 °C after 10.5 h. Although the compost experienced slightly high in moisture loss (4.3%), the compost still attained the standard values for maturity. The compost produced from food waste could be applied in soil to improve its fertility.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"7 1","pages":"Article 100190"},"PeriodicalIF":6.0,"publicationDate":"2023-07-08","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2588913323000522/pdfft?md5=dba83187c3328ab005d6ae4b6c144ad8&pid=1-s2.0-S2588913323000522-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"41829555","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 2
Activated carbon derived from radiation-processed durian shell for energy storage application 辐射加工榴莲壳制备的活性炭储能应用
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-07-06 DOI: 10.1016/j.crcon.2023.07.001
Phonpimon Numee , Tanagorn Sangtawesin , Murat Yilmaz , Kotchaphan Kanjana
{"title":"Activated carbon derived from radiation-processed durian shell for energy storage application","authors":"Phonpimon Numee ,&nbsp;Tanagorn Sangtawesin ,&nbsp;Murat Yilmaz ,&nbsp;Kotchaphan Kanjana","doi":"10.1016/j.crcon.2023.07.001","DOIUrl":"10.1016/j.crcon.2023.07.001","url":null,"abstract":"<div><p>A lignocellulosic biomass, durian shell, modified by radiolytic oxidizing species from gamma and electron beam irradiations, has been used as a starting material for activated carbon (AC) production. Facile hydrothermal carbonization with ZnCl<sub>2</sub>/FeCl<sub>3</sub> and physical activation were employed in addition. The physicochemical and energy storage properties of the graphitic carbons were investigated using Field Emission Scanning Electron Microscope (FESEM), N<sub>2</sub> adsorption-desorption, Brunauer-Emmett-Teller (BET), Fourier Transform Infrared Spectroscopy (FTIR), X-ray Diffraction (XRD), Raman spectroscopy, Cyclic Voltammetry (CV), Galvanostatic Charge-Discharge (GCD) and Electrochemical Impedance Spectroscopy (EIS). Biomass modification by radiolytic oxidizing species aided in improving the energy storage properties of the resultant ACs without significantly changing the textural qualities. The radiation type played an important role on the surface functional groups, basal plane, and pore structures of the graphitic materials. The energy storage mechanism was based on a combination of EDLC and pseudo capacitances with high Coulombic efficiency. The highest specific capacitance obtained was 325.20 F/g providing capacity retention of 94.79 % after 10,000 cycles. A promising method of AC production for energy storage application has therefore been successfully demonstrated.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"7 2","pages":"Article 100192"},"PeriodicalIF":6.0,"publicationDate":"2023-07-06","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2588913323000546/pdfft?md5=14c07abc1b70c7c00d0075e78bf4aa7d&pid=1-s2.0-S2588913323000546-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"47375788","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Photocatalytic degradation of tetracycline by copper(I) oxide loaded on Daylily Stalk derived carbon material 负载氧化铜(I)的Daylily Stalk衍生碳材料光催化降解四环素
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-07-01 DOI: 10.1016/j.crcon.2023.06.003
Shuying Li , Zhinan Guo , Jing Lv , Yibo Zhao , Jianpeng Shang , Qiang Zhao , Yong Guo , Junli Wang , Jianguo Zhao , Abuliti Abudula , Guoqing Guan
{"title":"Photocatalytic degradation of tetracycline by copper(I) oxide loaded on Daylily Stalk derived carbon material","authors":"Shuying Li ,&nbsp;Zhinan Guo ,&nbsp;Jing Lv ,&nbsp;Yibo Zhao ,&nbsp;Jianpeng Shang ,&nbsp;Qiang Zhao ,&nbsp;Yong Guo ,&nbsp;Junli Wang ,&nbsp;Jianguo Zhao ,&nbsp;Abuliti Abudula ,&nbsp;Guoqing Guan","doi":"10.1016/j.crcon.2023.06.003","DOIUrl":"10.1016/j.crcon.2023.06.003","url":null,"abstract":"<div><p>In this work, Daylily Stalks derived N doped carbon material (N-DSC) with a high specific surface area was firstly prepared by a chemical activation method, and then cubic Cu<sub>2</sub>O nanoparticles were combined with the prepared N-DSC to obtain N-DSC/Cu<sub>2</sub>O composite as the catalyst for the photocatalytic degradation of tetracycline (TC) antibiotics under visible light. It is found that the obtained composite had higher photocatalytic activity than pure Cu<sub>2</sub>O. Particularly, 25 wt% N-DSC/Cu<sub>2</sub>O composite showed the highest photocatalytic performance with 95 % of TC degradation within 100 min and more excellent stability. Combined with various characterizations, it is confirmed that carbon bonds should be conducive to the separation of photoelectron and hole, and the carbon layer with an excellent electrical conductivity on Cu<sub>2</sub>O can reduce the charge transfer resistance between N-DSC and Cu<sub>2</sub>O, thereby improving the absorption of visible light and enhancing the photocatalytic activity. Moreover, it is considered that the synergistic effect of photo-generated electron pair in Cu<sub>2</sub>O and N-DSC could promote the photodegradation efficiency of N-DSC/Cu<sub>2</sub>O composite. In addition, the active species capture experiment confirmed that •OH and •O<sub>2</sub><sup>−</sup> should be the main active species for TC degradation under visible light. This study is expected to provide a novel low-cost photocatalysts for pollutants removal.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"7 2","pages":"Article 100191"},"PeriodicalIF":6.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2588913323000534/pdfft?md5=16728d967fa868255759e62d54fdd76a&pid=1-s2.0-S2588913323000534-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"49501529","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
MCM-22 zeolite-based system to produce jet fuel from the 1-hexene oligomerization 基于MCM-22沸石的1-己烯低聚制备喷气燃料系统
IF 6 3区 环境科学与生态学
Carbon Resources Conversion Pub Date : 2023-07-01 DOI: 10.1016/j.crcon.2023.06.001
Hao Yang, Qi Zuo, Xin Ning, Jiajun Zheng, Wenlin Li, Ruifeng Li
{"title":"MCM-22 zeolite-based system to produce jet fuel from the 1-hexene oligomerization","authors":"Hao Yang,&nbsp;Qi Zuo,&nbsp;Xin Ning,&nbsp;Jiajun Zheng,&nbsp;Wenlin Li,&nbsp;Ruifeng Li","doi":"10.1016/j.crcon.2023.06.001","DOIUrl":"10.1016/j.crcon.2023.06.001","url":null,"abstract":"<div><p>The oligomerization of light olefins is an alternative for generating clean liquid fuels. In this study, the MCM-22 zeolite featuring a partially disordered layered structure with framework combined 10 membered ring (10 MR) was discussed for 1-hexene oligomerization. MCM-22 and Y zeolite were compared to investigate the influences of the framework and acidity strength on the activity and yield in the 1-hexene oligomerization. The results indicated that the MCM-22 zeolite was an efficient catalyst for oligomerization compared to Y zeolite. The MCM-22 zeolite was characterized in detail by NMR, Py-FTIR, and TG analyses. The catalytic performance and deactivation properties of MCM-22 zeolite in the oligomerization reaction of 1-hexene were investigated. Structure–activity relationships were established through the kinetic study. Although the density of strong acid sites was essential for the oligomerization of 1-hexene, the presence of low pressure was also necessary for the formation of dimers. Thus, MCM-22 zeolite demonstrates a substantial improvement in initial conversion and catalyst lifespan for 1-hexene oligomerization.</p></div>","PeriodicalId":52958,"journal":{"name":"Carbon Resources Conversion","volume":"7 1","pages":"Article 100189"},"PeriodicalIF":6.0,"publicationDate":"2023-07-01","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://www.sciencedirect.com/science/article/pii/S2588913323000510/pdfft?md5=63dfc79d8577054fd23f9a43de670b3f&pid=1-s2.0-S2588913323000510-main.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"48646214","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":3,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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