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Exploring the structure and reactivity of organic crystals: a combined crystallographic and quantum chemical analysis of a 1,5-benzodiazepine-based heterocycle 探索有机晶体的结构和反应性:基于1,5-苯二氮杂环的晶体学和量子化学结合分析
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-22 DOI: 10.1007/s11696-025-03958-0
Amel Haouas
{"title":"Exploring the structure and reactivity of organic crystals: a combined crystallographic and quantum chemical analysis of a 1,5-benzodiazepine-based heterocycle","authors":"Amel Haouas","doi":"10.1007/s11696-025-03958-0","DOIUrl":"10.1007/s11696-025-03958-0","url":null,"abstract":"<div><p>Organic crystals, composed of small organic molecules held together by noncovalent intermolecular interactions, exhibit a diverse range of properties. Careful consideration of these interactions enables scientists to tailor crystal properties for specific applications. This study investigated the structural and electronic features of a 1,5-benzodiazepine-based heterocycle, 1-((3-(2-chlorophenyl)isoxazol-5-yl)methyl)-4-(2-hydroxyphenyl)-1H-benzodiazepin-2-one. Employing a multifaceted approach combining structural and quantum chemical methods, we elucidated the molecular geometry, crystal packing, and chemical reactivity in both mono- and dimeric forms. We revealed a network of noncovalent interactions governing the solid-state structure, including C–H⋯O and C–H⋯N hydrogen bonds, alongside π-interactions (C–H⋯π and π–π stacking). Multi-approach quantum mechanics analysis using dispersion-corrected DFT (ωB97X-D/aug-cc-pVTZ) unveiled the nature and energetics of these interactions, incorporating natural bond orbital analysis, quantum theory of atoms in molecules, and Hirshfeld surfaces. Conceptual DFT identified the studied heterocycle as a moderate electrophile and strong nucleophile in polar organic reactions, while Parr functions pinpoint favourable sites for electrophilic and nucleophilic attacks.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 4","pages":"2557 - 2565"},"PeriodicalIF":2.2,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769893","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Imidazo[1,2-a]pyridine mannich bases: synthesis, anticholinesterase evaluation, and in silico studies 咪唑[1,2-a]吡啶曼尼希碱:合成、抗胆碱酯酶评价和硅研究
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-22 DOI: 10.1007/s11696-025-03947-3
Burak Kuzu, Yeliz Demir
{"title":"Imidazo[1,2-a]pyridine mannich bases: synthesis, anticholinesterase evaluation, and in silico studies","authors":"Burak Kuzu,&nbsp;Yeliz Demir","doi":"10.1007/s11696-025-03947-3","DOIUrl":"10.1007/s11696-025-03947-3","url":null,"abstract":"<div><p>In this study, a series of imidazo[1,2-a]pyridine-mannich bases were designed and synthesized for the inhibition of cholinesterases, one of the important pathways in the treatment of Alzheimer's dementia. The imidazopyridine scaffold, which is found in the structure of many active compounds in pharmaceutical use, is derived from Mannich-bases containing morpholine and various aromatic groups. In vitro AChE and BChE enzyme activities and enzyme kinetics studies of new potential drug candidates (<b>9a-j</b>) that can target the critical binding regions of cholinesterases were conducted. In vitro evaluation with donepezil, tacrine (control compounds), and <b>9a-j</b>, it was found that naphthalene-substituted compound <b>9j</b> exhibited the most potential anti-cholinesterase activity (IC<sub>50</sub>s: 57.75 nM for AChE; 99.0 nM for BChE). Molecular docking studies performed with <i>h</i>AChE and <i>h</i>BChE enzyme crystal structures revealed that compound <b>9j</b> has a higher binding affinity by targeting the CAS and PAS binding sites. Additionally, drug-likeness and <i>pre</i>-ADMET evaluation of the compounds showed that compound <b>9j</b> had the most favorable drug properties. These results might be a new milestone in terms of the promising importance of the imidazopyridine scaffold in future drug design for the treatment of AD.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 3","pages":"2005 - 2018"},"PeriodicalIF":2.2,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11696-025-03947-3.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143668119","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Study of hemocompatibility and antioxidant activity of calcium-copper titanate powders 钛酸钙铜粉末的血液相容性及抗氧化活性研究
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-22 DOI: 10.1007/s11696-025-03966-0
Konstantin V. Ivanov, Yuliya A. Filimonova, Andrew V. Noskov, Alexander V. Agafonov, Sergey B. Nazarov
{"title":"Study of hemocompatibility and antioxidant activity of calcium-copper titanate powders","authors":"Konstantin V. Ivanov,&nbsp;Yuliya A. Filimonova,&nbsp;Andrew V. Noskov,&nbsp;Alexander V. Agafonov,&nbsp;Sergey B. Nazarov","doi":"10.1007/s11696-025-03966-0","DOIUrl":"10.1007/s11696-025-03966-0","url":null,"abstract":"<div><p>The precursor of the CaCu<sub>3</sub>Ti<sub>4</sub>O<sub>12</sub> (CCTO) ceramic powder was obtained by solid-phase synthesis. The synthesized powder was thermally treated at 800 and 1100 <sup>°</sup>C in order to study its biological activity. A research of the effect of CCTO on human blood cells was carried out using the example of a certain number of women in a medical institution. It was found that the synthesized powders were hemocompatible and did not affect the spontaneous aggregation of erythrocytes. In addition, the CCTO suspension was found to have an effect on platelet aggregation. CCTO powder calcined at 800 °C inhibited platelet aggregation more strongly than that calcined at 1100 °C. Using chemiluminescent analysis, an increase in the antioxidant activity of blood serum was detected due to the presence of CCTO powders. In the course of research, we tried to find a correlation between the biological activity of powders and their physicochemical properties. For this, dynamic light scattering, scanning electron microscopy, EDX analysis, X-ray diffractometry and low-temperature nitrogen adsorption–desorption technique were used to characterize the resulting materials. We hope that the results obtained can be used to study and treat human blood diseases.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 5","pages":"2769 - 2781"},"PeriodicalIF":2.2,"publicationDate":"2025-02-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143930092","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Viscosity reduction of heavy crude oil using ultrasonication assisted by SiFe nanoparticles SiFe纳米颗粒辅助下重质原油超声降粘研究
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-21 DOI: 10.1007/s11696-025-03955-3
Athraa W. Azeez, Hussein Q. Hussein
{"title":"Viscosity reduction of heavy crude oil using ultrasonication assisted by SiFe nanoparticles","authors":"Athraa W. Azeez,&nbsp;Hussein Q. Hussein","doi":"10.1007/s11696-025-03955-3","DOIUrl":"10.1007/s11696-025-03955-3","url":null,"abstract":"<div><p>Heavy crude oil viscosity reduction is essential for the petroleum industry because of its high density and viscosity, elevated concentration of asphaltene, and limited mobility. The primary aim of this investigation is to decrease the viscosity of Sharqy Baghdad heavy crude oil with 20.32 API by ultrasonic irradiation using Fe<sub>2</sub>O<sub>3</sub>-functionalized silica nanoparticles (SiFe). SiFe of an average size of 67.11 nm and 426.12 m<sup>2</sup>/g surface area were created by the incipient wetness technique with Fe<sub>2</sub>O<sub>3</sub> over SiO<sub>2</sub> nanoparticles, prepared by the sol–gel method using local sand. The X-ray diffraction analysis (XRD) indicates the presence of an amorphous silica with <i>α</i>-Fe<sub>2</sub>O<sub>3</sub>. Scanning electron microscopy analysis (SEM) showed that SiFe nanoparticles tend to agglomerate. Energy dispersive X-ray analysis (EDX) reveals the presence of Si, O, Al, and Fe elements. Fourier transform infrared spectra (FTIR) exhibit the presence of siloxane, silanol groups, and the Fe–O stretching mode of Fe<sub>2</sub>O<sub>3</sub>. A low total weight loss of 8.23% is revealed by thermogravimetric analysis (TGA), which validates the thermal stability of SiFe nanoparticles. The optimal outcomes were observed when the ultrasound exposure time was set at 2 min, 30% power intensity, 0.8 duty cycle, 35 °C, with 1000 mg/L SiFe nanoparticles, resulting in a reduction in viscosity of 33.74%, asphaltene concentration reduced from 6.379 to 4.119 wt%, and sulfur content decreased from 4.68 to 3.85 wt%. These findings demonstrated the effectiveness of employing nanoparticles and ultrasonic waves to increase the light components in crude oil compared to ultrasonication alone, and this plays a significant role in facilitating oil transportation through pipelines and enhancing the production of lighter fractions of high economic and industrial value during oil refining.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 4","pages":"2517 - 2530"},"PeriodicalIF":2.2,"publicationDate":"2025-02-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769863","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Boron oxide and magnesium oxide as an additıve vanadic corrosion inhibitor for heavy fuel oil 氧化硼和氧化镁作为additıve重质燃料油钒缓蚀剂
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-20 DOI: 10.1007/s11696-025-03913-z
Jwan A. M. J. Al-Hakeem, Mohammed Hadi Ali Al-Jumaili, Yücel Şahin
{"title":"Boron oxide and magnesium oxide as an additıve vanadic corrosion inhibitor for heavy fuel oil","authors":"Jwan A. M. J. Al-Hakeem,&nbsp;Mohammed Hadi Ali Al-Jumaili,&nbsp;Yücel Şahin","doi":"10.1007/s11696-025-03913-z","DOIUrl":"10.1007/s11696-025-03913-z","url":null,"abstract":"<div><p>Boron oxide (B<sub>2</sub>O<sub>3</sub>) is investigated as a second oxide with regard to magnesium oxide (MgO) to inhibit the vanadic corrosion caused by the ash resulting from burning heavy fuel oil (HFO). The inhibitory effect is achieved by changing the composition of the resultant ash by forming higher melting points components as magnesium pyroborate (Mg<sub>2</sub>B<sub>2</sub>O<sub>5</sub>) (PB) and magnesium orthoborate (Mg<sub>3</sub>B<sub>2</sub>O<sub>6</sub>) (OB) that in turn reacts with corrosive, low melting point vanadium oxide (V<sub>2</sub>O<sub>5</sub>) to yield refractory higher melting point magnesium orthovanadate (Mg<sub>3</sub>V<sub>2</sub>O<sub>8</sub>) (OV). MgO nanoparticles were successfully synthesized by co-precipitation technique at room temperature using magnesium nitrate and sodium hydroxide as a precursor, and B<sub>2</sub>O<sub>3</sub> was successfully synthesized by thermal decomposition of boric acid. Both oxides were sonicated with oleic acid (OA). The morphological investigation of both nanoparticles oxides was done by Scanning Electron Microscope (SEM–EDX), X-ray Diffraction (XRD) for indicating the crystallinity and crystal size of nanoparticle, Fourier Transform Infrared spectroscopy for analyzing the functional groups of the samples. Nanoparticle oxides suspended in OA was added to HFO which is burned to obtain ash according to ASTM D482. The morphological investigation and composition of the ash were done by (SEM) and (XRD) to identify and compare the resulting compounds before and after the addition of the oxides.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 4","pages":"2143 - 2158"},"PeriodicalIF":2.2,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769916","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent advances in medically oriented research on lactic acid detection 面向医学的乳酸检测研究进展
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-20 DOI: 10.1007/s11696-025-03907-x
Yihan Li, Yihan Xu, Yufu Liu, Xingfu Bao
{"title":"Recent advances in medically oriented research on lactic acid detection","authors":"Yihan Li,&nbsp;Yihan Xu,&nbsp;Yufu Liu,&nbsp;Xingfu Bao","doi":"10.1007/s11696-025-03907-x","DOIUrl":"10.1007/s11696-025-03907-x","url":null,"abstract":"<div><p>Lactic acid holds significant application potential across multiple domains, encompassing medicine, food science, and biotechnology, among others. Consequently, the accurate detection of lactic acid has emerged as a primary research focus. Presently, numerous lactic acid detection techniques exist, leveraging chromatography, colorimetry, and electrochemical principles to measure lactic acid concentrations both externally and internally within the human body. Furthermore, the exploration of wearable biosensors capable of directly monitoring lactic acid levels in bodily fluids is gaining momentum. Hence, this paper aims to comprehensively review the chemical structures, physiological roles, and detection techniques of lactic acid biosensors, while also exploring their future research prospects.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 3","pages":"1335 - 1353"},"PeriodicalIF":2.2,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143668333","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Recent aspects of chemical enhanced oil recovery 化学提高采收率的最新进展
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-20 DOI: 10.1007/s11696-025-03943-7
Roland Nagy, Máté Hartyányi, Rebeka Bejczi, László Bartha, Sándor Puskás
{"title":"Recent aspects of chemical enhanced oil recovery","authors":"Roland Nagy,&nbsp;Máté Hartyányi,&nbsp;Rebeka Bejczi,&nbsp;László Bartha,&nbsp;Sándor Puskás","doi":"10.1007/s11696-025-03943-7","DOIUrl":"10.1007/s11696-025-03943-7","url":null,"abstract":"<div><p>The majority of the world’s current crude oil production comes from mature fields. In addition, the rate of replenishment of reserves produced by new discoveries has been decreasing steadily over the past decades. This article provides a comprehensive overview of the status of CEOR and the opportunities for increasing ultimate recovery factors in reservoirs ranging from extra heavy oil to gas condensate. The review specifically discusses the status of CEOR and the chemicals used. Our aim in this work was to present both traditional and newer chemicals used. The relevant pilot tests were collected, because the literature on these is scarce. The published pilot projects are for the period after 2018. This article also describes chemical EOR opportunities, which also represent new CEOR drivers and challenges, especially economics. Recent CEOR technological developments and future CEOR opportunities will be discussed. State-of-the-art CEOR technologies were presented. This review provides comprehensive information on chemical EOR applications in sustainable energy production. After studying the professional publications, it is clear that CEOR technologies will be increasingly needed in the future.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 5","pages":"2695 - 2716"},"PeriodicalIF":2.2,"publicationDate":"2025-02-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11696-025-03943-7.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143929986","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Novel photodamage-free bioimaging and anticancer studies using ultra-bright near-infrared emitting nitrogen-doped carbon dots intercalated Zn(OH)2 nanosheets 利用超亮近红外发射氮掺杂碳点嵌入Zn(OH)2纳米片的新型无光损伤生物成像和抗癌研究
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-19 DOI: 10.1007/s11696-025-03961-5
G. Gnanamani Simiyon, B. Nivetha, T. Mary Vergheese, N. Jayaprakash
{"title":"Novel photodamage-free bioimaging and anticancer studies using ultra-bright near-infrared emitting nitrogen-doped carbon dots intercalated Zn(OH)2 nanosheets","authors":"G. Gnanamani Simiyon,&nbsp;B. Nivetha,&nbsp;T. Mary Vergheese,&nbsp;N. Jayaprakash","doi":"10.1007/s11696-025-03961-5","DOIUrl":"10.1007/s11696-025-03961-5","url":null,"abstract":"<div><p>Near-infrared (NIR) fluorescence emitting probes are of potential interest in the field of bioimaging due to good penetration and minimal photodamage to tissues. Despite the remarkable fluorescence properties of carbon dots (CDs), their low emission quantum yield and need for surface modification limit their applicability. CDs are intercalated into multilayer structures to minimize internal quenching and modify surface functional groups, which improve sensitivity and selectivity. Layered zinc hydroxide (LZH) stands out among other layered materials because of its stability, biocompatibility, luminescence, and capacity to be used as a drug delivery system. By incorporating LZH with fluorophore can transform it as prominent bioimaging probe. In this study, we used a direct and low-cost microwave-assisted technique to successfully intercalate nitrogen-doped carbon dots (NCDs) in layers of zinc hydroxide (NCLZH). Formation of layers of NCLZH is supported by the HRSEM image. When excited at 700 nm, NCLZH exhibit high NIR emission at 768 nm, suggesting that it could be a viable substitute for contact-free bioimaging in healthcare. Furthermore, addition of NCDs to LZH enhanced the anticancer activity of NCLZH with IC<sub>50</sub> 75 µg/mL, and cytotoxicity studies of NCLZH show 92% cell viability towards adult dermal fibroblast cell lines which confirms NCLZH as Photodamage-Free Bioimaging Tool. Hence, NCLZH can function in future as an efficient fluorescent probe in real-time fluorescence-guided surgery for cancer diagnosis and treatment which is a potential extension of the current work in future.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 4","pages":"2629 - 2636"},"PeriodicalIF":2.2,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769903","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chalcone-based colorimetric naked eye detection of vanadium in crude oil using a new microfluidic device 基于查尔酮的肉眼比色法检测原油中钒的新型微流体装置
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-19 DOI: 10.1007/s11696-025-03960-6
Astabraq H. Zaalan, Hanan A. Al-hazam, Hassan T. Abdulsahib, Zaidon T. Al-aqbi
{"title":"Chalcone-based colorimetric naked eye detection of vanadium in crude oil using a new microfluidic device","authors":"Astabraq H. Zaalan,&nbsp;Hanan A. Al-hazam,&nbsp;Hassan T. Abdulsahib,&nbsp;Zaidon T. Al-aqbi","doi":"10.1007/s11696-025-03960-6","DOIUrl":"10.1007/s11696-025-03960-6","url":null,"abstract":"<div><p>Chalcones are a highly effective chelating agent used in spectrophotometric vanadium ion detection. It was observed that potassium (E)-(4-(3-(4-hydroxy-3- methoxyphenyl) acryloyl)phenyl) carbamodithioat (HMAPC) reagent formed a yellow colored complex with vanadium ion at 420 nm. Vanadium ion was chelated with the chalcone (HMAPC) reagent in acidic medium at pH = 6 using Britton–Robinson buffer (BRB). The effect of reagent volume, pH, temperature, time, and interferences was studied. The stoichiometric composition of the formed complex was found to be 1:2 (metal: reagent) by Job's method of continuous variation and mole ratio methods. Beer's law was obeyed in the range of 1–32 µg mL<sup>−1</sup> with molar absorptivity of 1589.32 L mol<sup>−1</sup>cm<sup>−1</sup>, sensitivity of 0.03225 µg mL<sup>−1</sup>, regression coefficient of 0.9945 and an estimated detection limit of 0.1354 µg mL<sup>−1</sup>. The accuracy (recovery percentage) was ranged between 97.2 and 104.8%, and precision (R.S.D.%) is less than 1.5%. A colorimetric method equipped with a portable microfluidic device (µ-chip), as well as a smartphone (iPhone), is used to measure vanadium concentrations. The resulting color changes were taken by a smartphone camera. The obtained images were analyzed by ImageJ software to assay the vanadium concentration. Under the identical experimental settings, the suggested approach and the spectrophotometric method were compared, and it was discovered that both were advantageous. The suggested approach technique was straightforward and easy to use, and the findings indicated that it was practical and might be used for on-site analysis. It also had promising properties of mobility and low manufacturing cost, making it appropriate for the detection of vanadium in crude oil.</p></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 4","pages":"2585 - 2601"},"PeriodicalIF":2.2,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143769913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Banana peel as potential bioadsorbent toward removal of emerging contaminants from wastewater for sustainable environment: a review 香蕉皮作为生物吸附剂去除废水中新出现的污染物的研究进展
IF 2.2 4区 化学
Chemical Papers Pub Date : 2025-02-19 DOI: 10.1007/s11696-025-03945-5
Susmita Sen Gupta, Mehdi Al Kausor, Dhruba Chakrabortty
{"title":"Banana peel as potential bioadsorbent toward removal of emerging contaminants from wastewater for sustainable environment: a review","authors":"Susmita Sen Gupta,&nbsp;Mehdi Al Kausor,&nbsp;Dhruba Chakrabortty","doi":"10.1007/s11696-025-03945-5","DOIUrl":"10.1007/s11696-025-03945-5","url":null,"abstract":"<div><p>Adsorption technology has gained popularity for removing contaminants from waste water during the last few decades. Banana peel is a popular choice as adsorbent due to its availability, cost-effectiveness, non-hazardous, and biodegradation quality. It is an attractive material for generation of emerging biosorbents by various chemical treatment methods. The use of both naturally and chemically activated biomass therefore got attention in the waste water treatment. The collection of data on decontamination of waste water by various adsorbents derived from the agro-waste, banana peel was found to be potential biomaterials in removal of various emerging water pollutants. This review paper analyzes the use of banana peel-based adsorbents for water pollution remediation, focusing on potential removing organic dyes, phenols, heavy metal ions, antibiotics, and pesticides. Future work should consider the use of agro-waste for actual contaminated water in single as well as multi-pollutants; regeneration, reuse, etc. should get importance.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":513,"journal":{"name":"Chemical Papers","volume":"79 5","pages":"2717 - 2750"},"PeriodicalIF":2.2,"publicationDate":"2025-02-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143929938","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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