Cellulose最新文献

{"title":"Dissolving-grade pulp and lyocell fibers prepared from cotton stalks","authors":"Kaihang Wang,&nbsp;Kai Li,&nbsp;Yuchen Gu,&nbsp;Gesheng Yang,&nbsp;Xiang Yao,&nbsp;Yaopeng Zhang","doi":"10.1007/s10570-025-06399-w","DOIUrl":"10.1007/s10570-025-06399-w","url":null,"abstract":"<div><p>Dissolving-grade wood pulp is one of the crucial raw materials to produce lyocell fiber. Benefit from the environmentally friendly production process of lyocell spinning and excellent comprehensive performance of lyocell fiber, the lyocell fiber’s industrialization has been rapidly developed in recent years. Limited to the shortage of wood resources, the development and expansion of alternative non-wood pulp raw materials are quite important and valuable. Herein, newly dissolving-grade pulp was developed from cotton stalks (CSs) by alkali pretreatment, kraft cooking and following post processing procedures. From orthogonal experiments, it was found that the factors affecting Kappa number and degree of polymerization (DP), from strongest to weakest, were cooking temperature, alkali dosage, cooking time, and sulfidity. Three preferred cooking schemes (A₃B₃C₃D₃, A₃B₃C₃D₁ and A₂B₃C₃D₃) were developed to prepare the final dissolving-grade CS pulp (CSP) with DP of 466, 522, and 568. FT-IR spectroscopy and the related component analyses showed that hemicellulose was substantially removed during the pretreatment process, and lignin was substantially removed during the cooking process. The corresponding dissolution and spinning experiments further illustrated that all the three kinds of dissolving-grade CSPs had good dissolution ability and spinning stability. The mechanical performance of the corresponding lyocell fibers was improved as the rising of pulp DP. Also, the CSP568 induced by a more appropriate cooking scheme showed quite similar dissolving properties, lyocell spinnability and lyocell fiber performance to that of the commercial wood pulp. Related explorations are expected to expand the high value and green utilization of crop residues and the material sources for dissolving-grade pulp, thus promoting the development of lyocell fiber industrialization.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2227 - 2243"},"PeriodicalIF":4.9,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688392","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Enhanced production of bacterial cellulose with a mesh dispenser vessel-based bioreactor","authors":"Joshua Loh,&nbsp;Thora Arnardottir,&nbsp;Katie Gilmour,&nbsp;Meng Zhang,&nbsp;Martyn Dade-Robertson","doi":"10.1007/s10570-024-06367-w","DOIUrl":"10.1007/s10570-024-06367-w","url":null,"abstract":"<div><p>Bacterial cellulose (BC) has gained significant interest for various applications due to its useful properties which include chemical stability and strong physical properties as well as its biocompatibility. However, conventional fabrication methods are limited by a lack of control over the form, particularly depth and thickness, restricting BC applications to 2D planar shapes. The production of BC is constrained by the formation of a pellicle at the liquid–air interface. To overcome this constraint and enable continuous pellicle formation, a method was established to combine intermittent batch feeding with a supportive mesh scaffold. Intermittent feeding supplies nutrients to the pellicle, promoting sustained formation at the liquid–air interface, while the supporting mesh anchors the initial pellicle to prevent submersion. This approach facilitates the continuous growth of BC pellicle at a controlled rate. Moreover, the method described here results in a single BC pellicle with enhanced thickness, weight (both wet and dry states), water-holding capacity and mechanical strength. Continuous growth is achievable with ongoing nutrient supply, allowing for precise control over the final pellicle thickness. This culturing method is scalable and has been tested for volumes ranging from 250 mL to 10 L, and significantly increases glucose-to-cellulose conversion (3.4-fold) and water utilization efficiency (2.4-fold).</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2209 - 2226"},"PeriodicalIF":4.9,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-024-06367-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688351","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Pd nanocatalyst supported on chitosan–waste oil microspheres for efficient degradation of industrial pollutants in water","authors":"Kaan Karaoğlu,&nbsp;Nuray Yılmaz Baran,&nbsp;Zehra Özçifçi,&nbsp;Hakkı Türker Akçay,&nbsp;Talat Baran","doi":"10.1007/s10570-025-06385-2","DOIUrl":"10.1007/s10570-025-06385-2","url":null,"abstract":"<div><p>Disposal of industrial pollutants is one of the most important working topics today. Pd–doped catalysts have high efficiency in the degradation of many organic pollutants. Within the scope of this study, waste engine oil (WEO) was used as activated carbon (AC) source and then AC was encapsulated with chitosan (CS) to prepared chitosan–based microbeads (CS/WEO AC) for catalyst support. After treatment with glyoxal as cross–linker, Pd nanoparticles with spherical shape and 16.8 nm diameter were decorated on the microbeads (Pd@CS/WEO AC). Efficiency of Pd@CS/WEO AC on the reduction of 4-nitrophenol (4-NP), 4-nitro-o-phenylenediamine (4-NPDA), 2-nitroaniline (2-NA), 4-nitroaniline (4-NA) as nitroarens; methylene blue (MB), methyl orange (MO), and rhodamine B (RhB) as organic dyes; Cr(VI) and K₃[Fe(CN)₆] was examined in aqueous media. Developed Pd@CS/WEO AC nanocatalyst reduced nitroarenes, organic dyes, Cr(VI) and K₃[Fe(CN)6] in very short times (0–130 s). Based on kinetic studies, the rate constants for Pd@CS/WEO AC–catalyzed reduction reactions of 2–NA, 4–NP, 4–NA, 4–NPDA, MO, RhB, [Fe(CN)₆]^3⁻, and Cr(VI) were found to be 0.018 s⁻¹, 0.007 s⁻¹, 0.026 s⁻¹, 0.012 s⁻¹, 0.021 s⁻¹, 0.065 s⁻¹, 0.048 s⁻¹, and 0.042 s⁻¹, respectively. Additionally, it was confirmed that Pd@CS/WEO AC is a long–lasting catalyst, as it was reused for five successive runs in the reduction of 4–NP. In this study, we aim to design new materials by modifying carbon–containing waste sources with biological macromolecules and investigate the possible applications of these materials to remove some pollutants from water sources.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2367 - 2381"},"PeriodicalIF":4.9,"publicationDate":"2025-01-29","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-025-06385-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688349","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Liquid crystal properties of cellulose/4-(ω-(methylimidazole)hexyloxy)-4'-(cyano)-biphenyl/amine-modified graphene solution and its high-strength fiber","authors":"Xuerong Wang,&nbsp;Jun Song,&nbsp;Jicheng Shan,&nbsp;Xiaosheng Qian,&nbsp;Bin Li,&nbsp;Haijing Zhu,&nbsp;Chunzu Cheng,&nbsp;Ting Li","doi":"10.1007/s10570-025-06398-x","DOIUrl":"10.1007/s10570-025-06398-x","url":null,"abstract":"<div><p>To enhance the mechanical properties of cellulose fibers for high-strength applications, this study explores the incorporation of amine-modified graphene (G-NH₂) into the cellulose/4-(ω-(methylimidazole)hexyloxy)-4'-(cyano)-biphenyl(CBP6)/ionic liquid system. By adjusting experimental temperature, time, and G-NH₂ composition, a cellulose/CBP6/G-NH₂/ionic liquid liquid crystal solution was successfully developed. The liquid crystal properties of the solution were characterized using polarizing optical microscopy and differential scanning calorimetry, among other techniques. Results indicated that the introduction of G-NH₂ altered the liquid crystal texture and introduced novel liquid crystal phenomena. Regenerated cellulose fibers from the cellulose/CBP6/G-NH₂ system exhibited a breaking strength of 3.82 cN/dtex and an elongation at break of 8.1%, prepared with 6 wt% cellulose, 3 wt% CBP6, and 0.2 wt% G-NH₂, through liquid crystal spinning. The structural and mechanical properties of these fibers were thoroughly characterized. This study not only presents a new strategy for producing high-performance regenerated cellulose fibers but also offers valuable insights for the development of cellulose-based composites.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2195 - 2208"},"PeriodicalIF":4.9,"publicationDate":"2025-01-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688343","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Water resistance of chitosan-based composite film induced by dopamine and glyoxal","authors":"Chengsheng Li,&nbsp;Ke Chen,&nbsp;Liang Jiao,&nbsp;Qing Zhu,&nbsp;Yuting Yang,&nbsp;Qianwen Cao,&nbsp;Shuzhen Ni","doi":"10.1007/s10570-025-06397-y","DOIUrl":"10.1007/s10570-025-06397-y","url":null,"abstract":"<div><p>Herein, a chitosan composite film based on a biomimetic strategy through the “brick–mortar” structure design was prepared. The glyoxal induced polymerization of dopamine acted an excellent adhesion between the “brick” and “mortar” (montmorillonite and chitosan). As a result, the resultant film presented an excellent water resistance towards acidic and alkaline solutions (pH 2, 4.5, 9 and 11) even after 24 h, with the undestroyed and intact shape. The dopamine or glyoxal content had a great influence on the water resistance, especially in the acidic media of pH 2. SEM and AFM results showed that the chitosan, montmorillonite, and dopamine formed a homogeneous film. Meanwhile, the dopamine dosage produced an obvious influence on the surface morphology of composite film. XRD patterns exhibited that in the chitosan composite film, the chitosan, montmorillonite and dopamine rearranged. At the suitable additions of dopamine or glyoxal, the chitosan composite film could keep intact shape, showed by the swelling results. The dynamic contact angles decreased with the enhanced montmorillonite or glyoxal dosages. This facile approach provided novel method for promoting the application potential and performance of chitosan-based composite film.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2321 - 2335"},"PeriodicalIF":4.9,"publicationDate":"2025-01-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688291","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Hydrophobic self-sustained natural cellulose-BaSO4 composite coating for efficient daytime radiative cooling","authors":"Jay Prakash Bijarniya,&nbsp;Swikriti Tripathi,&nbsp;Sudepta Bauri,&nbsp;Jahar Sarkar,&nbsp;Pralay Maiti","doi":"10.1007/s10570-025-06392-3","DOIUrl":"10.1007/s10570-025-06392-3","url":null,"abstract":"<div><p>The utilization of natural materials along with the renewable daytime radiative cooling process is the present need to encourage better sustainable development. Natural pulp has excellent radiative cooling properties but good hydrophilicity, poor adhesive strength and limited solar reflectance (which may be a severe issue for the high solar intensity zones like India). Therefore, a composite of the barium sulphate particles in cellulose pulp is developed in this study to produce the daytime radiative cooling coating with all favorable characteristics. Barium sulphate particles physically interact with the pulp, so the pulp tends to disperse more uniformly in the dimethylformamide solution in the presence of barium sulphate particles. This composite dispersion forms a stable, adhesive, smooth and environmentally friendly coating. The developed coatings' hydrophobic nature is also detected during the experiment and sliding drops of dew form on the coating. The developed coating produced a temperature drop of 4 °C at noon and 9.1 °C in the absence of solar irradiance. The maximum cooling power observed was 85 W/m² and the minimum cooling power of nearly 40 W/m² was recorded, corresponding to a minimum temperature drop just before noon, around 9:30—10:30 am during this experimental study.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2353 - 2365"},"PeriodicalIF":4.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688341","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Preparation and electrochemical dynamics simulation of cellulose-based composite films with different hierarchical structures applied in supercapacitors","authors":"Chuanyin Xiong,&nbsp;Bo Wang,&nbsp;Yong Yin,&nbsp;Juntao Song,&nbsp;Zhao Zhang,&nbsp;Dongping Li,&nbsp;Qiusheng Zhou,&nbsp;Mengxia Shen,&nbsp;Yonghao Ni","doi":"10.1007/s10570-025-06383-4","DOIUrl":"10.1007/s10570-025-06383-4","url":null,"abstract":"<div><p>As is well known, pore structure has a significant impact on the storage and transport behavior of electrolyte ions. Cellulose nanofibers (CNFs), a green biomass material, not only have good processability and flexibility, but can also be used to design and construct membrane materials with rich pore structures. It has broad application prospects in the field of flexible energy storage and has received widespread attention from researchers. However, there is still limited research on the precise design and regulation of pore structures in CNF-based composites with different pore structures, as well as their impact mechanisms on electrolyte ion storage and transport behavior. In this study, five different hierarchical structures were set up based on CNF-loaded reduced graphene oxide (CNF@RGO) composite films that were fabricated by using different lengths of CNFs as the substrate by sequential alternating filtration method. Furthermore, COMSOL Multiphysics was used for simulation and prediction to study the influence of different pore structures on their capacitance. Finally, further verification will be conducted through experiments. The simulation and experimental results show that when the internal pore structure is distributed in the order of large, small, and large pore sizes from the outside to the inside, the CNF@RGO composite material can obtain a larger area specific capacitance of 29.7 Mf cm⁻² and a higher energy density of 14.8 mWh cm⁻². As a whole, this research provides a reference direction for designing and constructing electrode materials with different pore structure combinations in the future to improve the energy storage performance of energy storage devices or electrode materials.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 3","pages":"1821 - 1833"},"PeriodicalIF":4.9,"publicationDate":"2025-01-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143430932","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"ZIF-L coated cotton fabric for antibacterial and self-cleaning applications","authors":"Qiaohua Qiu,&nbsp;Liying Lan","doi":"10.1007/s10570-025-06400-6","DOIUrl":"10.1007/s10570-025-06400-6","url":null,"abstract":"<div><p>Textiles that possess antibacterial and self-cleaning properties play a crucial role in preventing the growth and spread of microbes. Zeolitic imidazolate framework-L (ZIF-L) nanostructures have gained significant attention in research due to their ability to sustainably release Zn²⁺ ions, coupled with the physical destruction of bacteria by their blade-like tips. However, ZIF-L has been rarely employed in preparing multifunctional hydrophobic textile surfaces. In this study, a uniform and dense coating of leaf-shaped ZIF-L nanostructures was decorated on the cotton fabric to construct a hydrophobic material by an in situ growth method combined with a chemical vapor deposition process. To enhance antibacterial properties, Cu was incorporated into the ZIF-L structure. The morphology of nanostructure-modified cotton fabric was controllable by adjustment of experimental parameters. The resulting fabrics exhibited excellent antibacterial efficacy against both Gram-negative and Gram-positive bacteria, effectively killing 5 log CFU (&gt; 99.999%) of <i>E. coli</i> and <i>S. aureus.</i> Furthermore, the prepared cotton fabric not only showed hydrophobicity with a water contact angle of 132° ± 0.58 but also displayed good self-cleaning capabilities. The incorporation of nanostructures significantly improved the tensile strength of the cotton fabric, resulting in a 43% increase, while having a minimal impact on breaking elongation. Additionally, these fabricated fabrics maintained their functional stability after washing. It is therefore believed these valuable functions could significantly enhance the practical feasibility of the fabric in various application scenarios.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2663 - 2678"},"PeriodicalIF":4.9,"publicationDate":"2025-01-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688560","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Durable flame-retardant finishing of cotton fabric via constructing multiple crosslinked layers","authors":"Zuwei Fan,&nbsp;Yihai Xue,&nbsp;Hao Liu,&nbsp;Yuanyuan Yu,&nbsp;Rangtong Liu","doi":"10.1007/s10570-025-06393-2","DOIUrl":"10.1007/s10570-025-06393-2","url":null,"abstract":"<div><p>To improve the flame-retardant performance of cotton fabric, multiple crosslinked layers were constructed on cotton fiber surfaces through polymerization of <i>m</i>-phenylenediamine (MPD)/tetrakis hydroxymethyl phosphonium chloride (THPC) and trimesoyl chloride (TMC). The resulting morphology, general properties, flame retardancy, and durability were characterized and analyzed. Cotton fabric alternately finished with MPD-TMC and THPC-TMC displayed greater changes in surface morphology than that finished with single crosslinked products. The former material had the highest weight gain percentage and so possessed significantly higher limiting oxygen index (LOI) value and weaker heat release, accompanied by formation of a more robust carbonaceous layer during micro combustion calorimetry. After alternating finishing with MPD-TMC and THPC-TMC, the cotton fabric exhibited increased flexural rigidity and decreased air permeability, with the change influenced by the number of finishing cycles. Increased finishing cycles also resulted in an increased LOI, up to 33.5% after five cycles. According to micro combustion calorimetry results, heat release was suppressed more effectively as long as the number of finishing cycles reached three, such that finishing with 3 cycles was optimal in this study. Moreover, a fabric with 3 cycles of alternating finishing almost kept its LOI value after washing in disturbed water for 24 h, exhibiting good durability for flame retardancy, which would be beneficial in real applications.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 4","pages":"2649 - 2661"},"PeriodicalIF":4.9,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143688514","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

{"title":"Using low concentration polyethylene glycol to regulate the microstructure of ink to improve the printing quality of cotton fabric","authors":"Zhiyuan Tang,&nbsp;Xueyuan Yang,&nbsp;Fuyun Sun,&nbsp;Kun Zhang,&nbsp;Kuanjun Fang","doi":"10.1007/s10570-024-06366-x","DOIUrl":"10.1007/s10570-024-06366-x","url":null,"abstract":"<div><p>Satellite droplets, excessive ink spreading and penetration present significant obstacles to the advancement of inkjet printing on cotton fabrics. Traditional ink preparation methods utilizing organic solvents are unable to effectively address these issues. This study addressed these challenges by investigating polyethylene glycol (PEG) as a component in reactive dye ink. It was found that the PEG with longer molecular chain formed more complex coil after dissolution, which could increase ink viscosity and inhibit satellite droplets more effective. Meanwhile, the reduction of PEG concentration promoted the swelling of ink to sodium alginate (SA) film. High swelling degree and complex PEG coil could limit the ink spreading and penetration. Solid state PEG further restricted the ink spreading and penetration during the dye fixation process. Ink prepared by 3.2 wt% PEG20000 achieved no satellite droplets, the smallest spreading area and lowest permeability, and the highest dye fixation rate. Compared to commercial (CI) ink, it was evident that PEG20000/Red 218 ink exhibited less spreading and penetration, and had a higher dye fixation rate. This study introduces a promising approach for the production of high-quality, cost-effective reactive dye inks using the coil structure of polymer after dissolution.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 3","pages":"2107 - 2123"},"PeriodicalIF":4.9,"publicationDate":"2025-01-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143431091","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}