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Microwave-initiated turpentine polymerization for multifunctional rubberwood modification: integrated antibacterial, superhydrophobic, and termite-resistant properties 微波引发松节油聚合用于多功能橡胶木改性:综合抗菌、超疏水和抗白蚁性能
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-19 DOI: 10.1007/s10570-026-07177-y
Hailun Wang, Zechang Wei, Changyin Ren, Dongbo Xia, Haina Chen, Heng Tian, Hong Lei
{"title":"Microwave-initiated turpentine polymerization for multifunctional rubberwood modification: integrated antibacterial, superhydrophobic, and termite-resistant properties","authors":"Hailun Wang,&nbsp;Zechang Wei,&nbsp;Changyin Ren,&nbsp;Dongbo Xia,&nbsp;Haina Chen,&nbsp;Heng Tian,&nbsp;Hong Lei","doi":"10.1007/s10570-026-07177-y","DOIUrl":"10.1007/s10570-026-07177-y","url":null,"abstract":"<div><p>Turpentine oil (TO) has attracted considerable interest as a promising wood preservative due to its antifungal properties, biodegradability, and low toxicity to vertebrates. However, its high volatility limits its application as a wood preservative. To resolve this problem, FeCl<sub>3</sub> was employed as a Lewis acid catalyst to initiate the cationic polymerization of α-pinene, forming a self-encapsulated poly-α-pinene system. The research results demonstrated that the water contact angle of poly-turpentine oil (Poly-TO) modified rubberwood increased from 82.34° to 117.41°. The rubberwood Poly-TO treated achieved an acceptable decay resistance rating and could satisfy the requirements on class I defined in Chinese standard GB/T 13942.1 (2009). Compared with the untreated wood, the mass loss reduced from 47.23 to 9.13% and from 37.40 to 8.34%, respectively, after 12 weeks’ exposure to white and brown rot fungi under 28 °C and 85% relative humidity storage conditions. Microstructure analysis proved Poly-TO treatment can protect internal structure of wood. The Poly-TO treated rubberwood also showed significantly improvement on termite resistance. Compared with the wood untreated, the mass loss reduced from 8.73 to 0.94%. The results indicate that Poly-TO as a wood preservative showed promise.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6867 - 6883"},"PeriodicalIF":4.6,"publicationDate":"2026-08-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027658","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Electrospun cellulose acetate nanofibers for CO₂ adsorption: the role of zeolite-polymer interactions 静电纺醋酸纤维素纳米纤维对CO₂的吸附:沸石-聚合物相互作用的作用
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-18 DOI: 10.1007/s10570-026-07182-1
Michal Syrový, Karel Soukup, Kateřina Setničková, Jiří Henych, Petr Ryšánek, Oldřich Benada, Pavla Čapková
{"title":"Electrospun cellulose acetate nanofibers for CO₂ adsorption: the role of zeolite-polymer interactions","authors":"Michal Syrový,&nbsp;Karel Soukup,&nbsp;Kateřina Setničková,&nbsp;Jiří Henych,&nbsp;Petr Ryšánek,&nbsp;Oldřich Benada,&nbsp;Pavla Čapková","doi":"10.1007/s10570-026-07182-1","DOIUrl":"10.1007/s10570-026-07182-1","url":null,"abstract":"<div><p>The urgent demand for efficient carbon capture technologies has sparked the search for simple, scalable materials with tailored sorption properties. In this study, we demonstrate that unmodified cellulose acetate (CA) nanofiber membranes can serve as effective CO<sub>2</sub> sorbents at room temperature, offering a low-cost and environmentally friendly alternative to chemically modified polymeric systems. The distinct wrinkled morphology of the CA nanofibers achieved through targeted electrospinning conditions (solvent selection and high humidity) enhances the surface area and contributes to a CO<sub>2</sub> sorption capacity of up to 2.14 mmol/g, comparable to that of more complex porous materials. Beyond single-material systems, we emphasize the often-overlooked role of matrix–additive compatibility in composite membranes. Using a CA/β-zeolite system as a case study, we show that specific interactions between the polymer matrix and active phase–β- ammonium zeolite can entirely suppress CO<sub>2</sub> sorption instead of the assumed synergy of sorption properties for both components. The cellulose-based support was chosen for its biodegradability and biocompatibility, further supporting its use in sustainable technologies. To address the stability of modifying agents, we introduce a sandwich-type nanofiber membrane architecture (CA/Zeolite/CA) in which active nanocrystals–β-zeolites are embedded and fixed within layered structures. However, the sandwich structure of the membrane in this case indicated a negative effect of the mutual interaction of the CA carrier and β-ammonium zeolites on the sorption capacity of the composite membrane. Overall, the combination of simplicity, performance, and green chemistry makes CA nanofiber membranes a promising candidate for scalable and sustainable CO<sub>2</sub> capture.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6783 - 6799"},"PeriodicalIF":4.6,"publicationDate":"2026-08-18","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-026-07182-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027682","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Enhanced antimicrobial activity of cellulose nanocrystals with added triazole and imidazolium groups 添加三唑和咪唑基团增强纤维素纳米晶的抗菌活性
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-17 DOI: 10.1007/s10570-026-07162-5
Coro Echeverría, Naroa Ayensa, Rosa Barranco-García, Alexandra Muñoz-Bonilla, Marta Fernández-García
{"title":"Enhanced antimicrobial activity of cellulose nanocrystals with added triazole and imidazolium groups","authors":"Coro Echeverría,&nbsp;Naroa Ayensa,&nbsp;Rosa Barranco-García,&nbsp;Alexandra Muñoz-Bonilla,&nbsp;Marta Fernández-García","doi":"10.1007/s10570-026-07162-5","DOIUrl":"10.1007/s10570-026-07162-5","url":null,"abstract":"<div><p>The development of sustainable materials with active functionalities is crucial for advancing a circular economy. Cellulose nanocrystals (CNCs), derived from the most abundant biopolymer, offer a renewable and biocompatible platform for such materials. In this work, CNCs were chemically modified with imidazolium and triazole-imidazolium cations to create sustainable antimicrobial agents. The strategies involved chlorination of CNCs, followed by two approaches, i) substitution with <i>N</i>-methyl imidazolium (MI) groups to obtain CNC-MI, or ii) a click chemistry reaction for triazole-imidazolium (TrMI) modification to obtain CNC-TrMI. The analysis of the modified CNCs using Fourier transform infrared spectroscopy (FTIR), elemental analysis, and solid-state nuclear magnetic resonance (ssNMR) confirmed the successful modifications, resulting in CNC-MI showing a 30% degree of substitution, and CNC-TrMI demonstrating a 50% degree of substitution. However, such modifications affected both the structure and thermal stability of the CNCs as determined by X-ray diffraction (XRD) and thermogravimetric analysis (TGA). Nevertheless, the resulting cationic CNC derivatives, confirmed by Zeta potential analysis, exhibited remarkable antimicrobial activity against both Gram-positive <i>Staphylococcus epidermidis</i> and Gram-negative <i>Pseudomonas aeruginosa</i>. In particular CNC-TrMI exhibited excellent activity giving a reduction of more than 99.99% against both bacteria.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6531 - 6547"},"PeriodicalIF":4.6,"publicationDate":"2026-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-026-07162-5.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027672","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Process development for cellulose production from in vitro shoots of Juncus rigidus treated with CaCl2 and NaCl—a potential source of high-quality cellulose 高品质纤维素的潜在来源——氯化钙和氯化钠处理下的刚硬仙人掌离体芽生产纤维素的工艺研究
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-17 DOI: 10.1007/s10570-026-07176-z
Krupali Dipakbhai Vyas, Aneesha Singh
{"title":"Process development for cellulose production from in vitro shoots of Juncus rigidus treated with CaCl2 and NaCl—a potential source of high-quality cellulose","authors":"Krupali Dipakbhai Vyas,&nbsp;Aneesha Singh","doi":"10.1007/s10570-026-07176-z","DOIUrl":"10.1007/s10570-026-07176-z","url":null,"abstract":"<div><p>Cellulose, a versatile biopolymer with high industrial and biomedical applications, requires a sustainable production strategies. <i>Juncus rigidus</i> a salt-tolerant rush that grows in inland and coastal sandy saline habitats, represents a promising biomass resource for cellulose production. In this study, a novel approach was developed to efficiently produce high-quality cellulose from callus-derived <i>J. rigidus</i>. Exploiting species’ natural salinity tolerance and optimizing the culture medium with NaCl and CaCl<sub>2</sub> considerably enhanced shoot proliferation and elongation, leading to a 25.1% cellulose content. X-ray diffraction and Fourier transform infrared spectroscopy (FTIR) analyses confirmed the presence of well-defined cellulose peaks and cellulose-specific functional bands. FTIR spectra of cellulose achieved from CaCl₂ (200 mM) and NaCl (200 mM) treated shoot samples (JT4) exhibited distinct bands at 3334 cm⁻<sup>1</sup>, 2849 cm⁻<sup>1</sup>, 1646 cm⁻<sup>1</sup>, 1429 cm⁻<sup>1</sup>, 1159 cm⁻<sup>1</sup>, and 1031 cm⁻<sup>1</sup>. These bands serve as fingerprints of pure cellulose components. Thermogravimetric analysis revealed the highest thermal stability in JT4, with the highest mass loss (72.73%) and lowest char residue (1.34%), indicating high cellulose purity and crystallinity. Derivative thermogravimetry and Differential scanning calorimetry of JT4 developed peak at 342 °C, and exothermic peak at 389.4 °C, indicating high crystallinity and thermal stability. In contrast, other samples showed degradation-associated endothermic transitions, influenced by cellulose quality and salt treatments. This study provides the first report on <i>J. rigidus</i> callus-derived shoots as a novel source of cellulose. Treatment with CaCl₂ and NaCl significantly improved cellulose yield, purity, and physicochemical stability, highlighting its potential for advanced biomedical and biotechnological applications.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6497 - 6515"},"PeriodicalIF":4.6,"publicationDate":"2026-08-17","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027683","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Synthesis of multifunctional hydrogels based on carboxymethyl cellulose for wound healing applications 基于羧甲基纤维素的伤口愈合多功能水凝胶的合成
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-14 DOI: 10.1007/s10570-026-07174-1
Heba Kandil, Ahmed A. F. Soliman, Eman AboBakr Ali
{"title":"Synthesis of multifunctional hydrogels based on carboxymethyl cellulose for wound healing applications","authors":"Heba Kandil,&nbsp;Ahmed A. F. Soliman,&nbsp;Eman AboBakr Ali","doi":"10.1007/s10570-026-07174-1","DOIUrl":"10.1007/s10570-026-07174-1","url":null,"abstract":"<div><p>Hydrogels derived from natural polymers are gaining attention in wound dressings due to their extracellular matrix–mimicking structures and tunable properties. In this study, carboxymethyl cellulose (CMC) based hydrogels were developed via graft copolymerization of acrylic acid (AA) and diallyldimethylammonium chloride (DADMAC), with varying DADMAC content, to obtain multifunctional wound healing materials. The hydrogels were characterized to evaluate their structural, thermal, and morphological properties. Results showed successful grafting, increased porosity (up to ~ 45%) with higher DADMAC content, enhanced thermal stability and pH-responsive swelling behavior. Controlled biodegradation was observed over 21 days, with weight loss ranging from 17.5 to 25%. In vitro cytocompatibility evaluated by assay on human fibroblast (BJ−1) cells showed high cell viability (&gt; 86%), while scratch wound assays demonstrated improved cell migration and proliferation<i>.</i> Antibacterial activity assessed using the colony-forming unit method against <i>Staphylococcus aureus</i> and <i>Escherichia coli</i> revealed effective bacterial growth reduction for DADMAC-containing hydrogels.These results indicate that the developed CMC-based hydrogels possess suitable physicochemical, biological, and antimicrobial properties for potential wound dressing applications.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6765 - 6782"},"PeriodicalIF":4.6,"publicationDate":"2026-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-026-07174-1.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027629","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Characterising fibre alignment in moulded fibre materials across X, Y, and Z axes 表征模制纤维材料在X、Y和Z轴上的纤维排列
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-14 DOI: 10.1007/s10570-026-07179-w
Emma E. Gobes, Kelly Wade, Eli Gray-Stuart, Kate Parker, John Bronlund
{"title":"Characterising fibre alignment in moulded fibre materials across X, Y, and Z axes","authors":"Emma E. Gobes,&nbsp;Kelly Wade,&nbsp;Eli Gray-Stuart,&nbsp;Kate Parker,&nbsp;John Bronlund","doi":"10.1007/s10570-026-07179-w","DOIUrl":"10.1007/s10570-026-07179-w","url":null,"abstract":"<div><p>Moulded fibre is emerging as a sustainable alternative to single-use plastic items, commonly used for food and non-food packaging. Yet its mechanical properties are often inferior to oriented paper products, due to the limited fibre alignment during forming. This study introduces a method for characterising fibre orientation (FO) within moulded fibre products, enabling analysis of pulp flow patterns and turbulence during the production of moulded fibre items. The fibre alignment is characterised by sheet splitting the samples using an automated sheet splitter, and high-resolution scans of the split layers were analysed using MATLAB Structure Tensor analysis to determine the fibre orientation (FO) in the X and Y directions. The MATLAB analyses provided FO distribution across layers, in the Z-direction and offered insights into X and Y directional alignment. Outputs included visual heatmaps using a block approach and quantitative metrics. This approach enables efficient, detailed FO characterisation throughout the layers of a product, allowing for further improvement of moulded fibre properties. Validation results showed accurate and sensitive results. This method introduces opportunities to understand and control fibre alignment, a key step toward improving the strength properties of moulded fibre packaging.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6479 - 6496"},"PeriodicalIF":4.6,"publicationDate":"2026-08-14","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-026-07179-w.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027684","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effects of mechanical treatment, salt, and temperature on the properties of lignin-containing cellulose nanofibril/bentonite drilling fluids 机械处理、盐和温度对含木质素纤维素纳米纤维/膨润土钻井液性能的影响
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-12 DOI: 10.1007/s10570-026-07157-2
Abdullahi Ahmed Noor, Muhammad Arqam Khan, Kaihe Lv, Jinsheng Sun, Chaozheng Liu, Mei-Chun Li
{"title":"Effects of mechanical treatment, salt, and temperature on the properties of lignin-containing cellulose nanofibril/bentonite drilling fluids","authors":"Abdullahi Ahmed Noor,&nbsp;Muhammad Arqam Khan,&nbsp;Kaihe Lv,&nbsp;Jinsheng Sun,&nbsp;Chaozheng Liu,&nbsp;Mei-Chun Li","doi":"10.1007/s10570-026-07157-2","DOIUrl":"10.1007/s10570-026-07157-2","url":null,"abstract":"<div><p>Lignin-containing cellulose nanofibrils (L-CNFs) are promising rheological and filtration modifiers for bentonite water-based drilling fluids (BT-WBDFs); however, their tendency to aggregate severely limits their effectiveness. This study investigates the effects of further mechanical treatment, salt concentration, and temperature on the rheological and filtration properties of L-CNF/BT-WBDFs. Further mechanical treatment, including wet grinding and high-pressure homogenization, was applied to obtain mechanically treated L-CNFs (ML-CNFs). The results show that mechanical treatment significantly improves the dispersion and individualization of L-CNFs, thereby enhancing fluid rheology and reducing filtration loss in BT-WBDFs. Salt and hot rolling influence the rheology and filtration performance of L-CNF/BT- and ML-CNF/BT-WBDFs differently. ML-CNF/BT-WBDFs exhibit greater resistance to salt contamination due to increased fibrillation and dispersed fibrils forming a more cohesive network in solution. In contrast, L-CNF/BT-WBDFs performed better under hot rolling due to reduced surface area and fewer exposed hydroxy groups. Nevertheless, the combined effects of salinity and elevated temperature strongly impact the rheological properties and filtration-control efficiency of both systems. Under the combined effects of salinity and elevated temperature conditions, ML-CNFs display superior resistance compared with L-CNFs. This improved performance is attributed to the more stable network structure of ML-CNFs, which promotes better dispersion of bentonite platelets under saline and high-temperature conditions, thereby enhancing system stability. Overall, the study highlights ML-CNFs as a promising additive for improving the performance and sustainability of water-based drilling fluids.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6717 - 6742"},"PeriodicalIF":4.6,"publicationDate":"2026-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027647","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Hierarchical wood aerogel as a macroscopic platform for MIL-101(Fe) to enable synergistic persulfate activation and oxytetracycline degradation 层次化木气凝胶作为MIL-101(Fe)的宏观平台,实现过硫酸盐协同活化和土环素降解
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-12 DOI: 10.1007/s10570-026-07166-1
Meihua Zhao, Yijie Wu, Chunlian Chen, François Nkinahamira, Baihui Cui
{"title":"Hierarchical wood aerogel as a macroscopic platform for MIL-101(Fe) to enable synergistic persulfate activation and oxytetracycline degradation","authors":"Meihua Zhao,&nbsp;Yijie Wu,&nbsp;Chunlian Chen,&nbsp;François Nkinahamira,&nbsp;Baihui Cui","doi":"10.1007/s10570-026-07166-1","DOIUrl":"10.1007/s10570-026-07166-1","url":null,"abstract":"<div><p>Powdered metal organic frameworks (MOFs) face intrinsic challenges in stability, recovery, and processability, which limit their translation into practical water treatment systems. Here, we develop a macroscale Fe-based metal–organic framework (MIL-101(Fe)) based catalyst, MIL-101(Fe)@WA, fabricated through a facile in situ growth strategy that anchors MIL-101(Fe) in a distributed manner onto a sustainable, delignified cellulose wood-aerogel (WA) support. Leveraging the natural 3D microchannels and light-scattering properties of the cellulose, the resulting hierarchical composite exhibits improved 22d light absorption, and a narrowed bandgap (2.30–1.86 eV). This is accompanied by enhanced charge separation, as evidenced by reduced photoluminescence emission and lower charge-transfer resistance<b>,</b> supporting visible-light activation of peroxydisulfate (PS). Under optimized conditions, the MIL-101(Fe)@WA/PS/Vis system achieves 92.7% degradation of oxytetracycline (OTC) and maintains degradation efficiency ≥ 90% across a broad pH range (3–9). Unlike powder MOFs, the monolithic platform is manually retrievable and retains over 80.0% of its activity after six reuse cycles, supporting the mechanical robustness of the cellulose framework. Mechanistic analyses suggest a synergistic pathway in which photogenerated electrons support Fe<sup>3+</sup>/Fe<sup>2+</sup> cycling, promoting PS activation and promoting the formation of multiple reactive species, including SO<sub>4</sub><sup>·−</sup>, <sup>·</sup>OH, and O<sub>2</sub><sup>·−</sup> that contribute to OTC degradation. This work presents a design strategy for creating hierarchical catalysts, illustrating how functionalized cellulose aerogels can mitigate critical stability challenges of nanoscale MOFs in laboratory-scale catalytic systems.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6743 - 6763"},"PeriodicalIF":4.6,"publicationDate":"2026-08-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027681","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Modeling of drying kinetics and color change of bacterial cellulose: a comparative study of theoretical, semi-empirical, and machine learning (ANN, SVR, GPR) approaches 细菌纤维素干燥动力学和颜色变化的建模:理论、半经验和机器学习(ANN、SVR、GPR)方法的比较研究
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-10 DOI: 10.1007/s10570-026-07160-7
Fadime Begüm Tepe, Mehmet Kılınç, Nur Kılınç, Tolga Kağan Tepe
{"title":"Modeling of drying kinetics and color change of bacterial cellulose: a comparative study of theoretical, semi-empirical, and machine learning (ANN, SVR, GPR) approaches","authors":"Fadime Begüm Tepe,&nbsp;Mehmet Kılınç,&nbsp;Nur Kılınç,&nbsp;Tolga Kağan Tepe","doi":"10.1007/s10570-026-07160-7","DOIUrl":"10.1007/s10570-026-07160-7","url":null,"abstract":"<div><p>Despite its superior biological and mechanical properties, bacterial cellulose (BC) faces processing challenges in industrial applications due to its high-water content. This study represents the first investigation in literature applying the Refractance Window (RW) technique (at 45, 55, and 65 °C) for BC dehydration, analyzing drying kinetics through theoretical, semi-empirical, and machine learning (ANN, SVR, GPR) models. Experimental results indicated that increasing the temperature significantly reduced the drying time from 144 to 72 min. Regarding the diffusion mechanism, the Dincer and Dost approach provided the best statistical fit, revealing that the process is controlled by both internal and external resistances. While the Midilli model excelled among thin-layer models, Gaussian Process Regression (GPR) outperformed ANN and SVR algorithms in machine learning comparisons, demonstrating superior stability and lower RMSE and <i>χ</i><sup>2</sup> particularly suitable for limited datasets. Furthermore, the thermal properties of BC (specific heat, thermal conductivity, and diffusivity) were evaluated as a function of moisture content; the sharp decline in thermal conductivity during drying was identified as the primary mechanism driving the falling rate period behavior. Color analysis showed that higher temperatures (65 °C) triggered non-enzymatic browning reactions. These findings demonstrate that RW drying is an efficient technique for BC, and GPR serves as a robust tool for predicting drying kinetics, paving the way for the development of energy-efficient, large-scale industrial processing of high-performance biopolymer.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"33 11","pages":"6455 - 6478"},"PeriodicalIF":4.6,"publicationDate":"2026-08-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"149027657","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
A review and perspective on plant scaffolds as economical and sustainable next-generation biomaterials for bioengineering applications 植物支架作为经济、可持续的新一代生物工程材料的研究进展与展望
IF 4.6 2区 工程技术
Cellulose Pub Date : 2026-08-09 DOI: 10.1007/s10570-026-07173-2
Tukendra Kumar, Satya Eswari Jujjavarapu
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