Cellulose最新文献_第6页

Development of cellulose-based superabsorbent polymers: a review 纤维素基高吸水性聚合物的研究进展

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-03-02 DOI: 10.1007/s10570-025-06447-5

Wardah Shaheen, Muhammad Mudassir Iqbal, Laiba Qudrat

{"title":"Development of cellulose-based superabsorbent polymers: a review","authors":"Wardah Shaheen, Muhammad Mudassir Iqbal, Laiba Qudrat","doi":"10.1007/s10570-025-06447-5","DOIUrl":"10.1007/s10570-025-06447-5","url":null,"abstract":"<div><p>Superabsorbent polymers (SAPs) are three-dimensional crosslinked hydrophilic polymers, that can absorb and retain liquids up to hundreds of times their weight. These polymers have diverse applications across various fields, including agriculture, biomedicine, separation technologies, and wastewater treatment. Among these cellulose-based SAPs are prominent due to their biodegradable nature, sustainability, biocompatibility, cost-effectiveness, and natural abundance. The development of SAPs has evolved significantly since 1961, marked by advancements in polymerization techniques and their integration into numerous aspects of daily life. This review provides a comprehensive analysis of recent advancements in the field of cellulose-based superabsorbents, focusing on their polymerization methods, source of cellulose, and diverse applications. Furthermore, it highlights the mechanisms by which different forms of cellulose can enhance liquid absorption capacity and kinetics across various applications. The findings underscore the importance of cellulose-derived SAPs in promoting environmentally sustainable practices while addressing the growing demand for effective water retention solutions in agricultural and industrial contexts.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"2811 - 2845"},"PeriodicalIF":4.9,"publicationDate":"2025-03-02","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784113","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Layer-by-layer modification of cellulose aerogels to optimize capillary spreading rates and liquid holding capacity 纤维素气凝胶的逐层改性，以优化毛细管扩散速率和持液能力

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-28 DOI: 10.1007/s10570-025-06422-0

Fangxin Zou, Rebecca Östmans, Lars Wågberg

{"title":"Layer-by-layer modification of cellulose aerogels to optimize capillary spreading rates and liquid holding capacity","authors":"Fangxin Zou, Rebecca Östmans, Lars Wågberg","doi":"10.1007/s10570-025-06422-0","DOIUrl":"10.1007/s10570-025-06422-0","url":null,"abstract":"<div><p>Due to their excellent wetting and liquid-spreading properties, cellulose-based aerogels have shown great potential as absorbent materials in many applications. However, there is still a very limited understanding of how the aerogels should be tailored to optimize liquid spreading and liquid storage properties. The present work focuses on characterizing liquid spreading at short contact times and tailoring the surfaces within the aerogel to increase the spreading properties. Aerogels from periodate oxidized cellulose nano fibrils (CNFs) were freeze-linked to attain wet stability. Subsequently, they were modified with the layer-by-layer (LbL) assembly method using poly(diallyldimethylammonium chloride) (PDADMAC) and well-defined SiO<sub>2</sub> nanoparticles to change their surface properties. The morphology of the untreated and treated aerogels, as determined from SEM images, indicates a complete surface coverage of PDADMAC/SiO<sub>2</sub> bilayers on the inner surfaces of CNF aerogels, showing that the LbL-treatment can be used to tailor the aerogel, i.e. to increase the specific surface area of the aerogel, by changing the number of bilayers. It has also been shown that the horizontal liquid spreading rate increases significantly after surface modification. In addition, a theoretical analysis of the spreading results indicates that this is due to the increase in the specific surface area of the surface-modified aerogels. Moreover, the spreading rate can be gradually tailored by changing the number of bilayers and the dimensions of the nanoparticles. Furthermore, we provide a new method to calculate the specific surface area of aerogel materials by combining the experimentally determined liquid spreading rate and a version of the well-known Kozeny–Carman equation.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"3157 - 3172"},"PeriodicalIF":4.9,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-025-06422-0.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784172","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Fluorescent composite films of oriented cellulose nanocrystals with fluorescein 荧光素取向纤维素纳米晶体的荧光复合膜

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-28 DOI: 10.1007/s10570-025-06420-2

Inna Shkyliuk, Tomasz Makowski, Ewa Piorkowska

引用次数: 0

Cellulose paper-based printed sensor for efficient cure process control in fiber reinforced epoxy composite 用于纤维增强环氧复合材料固化过程有效控制的纤维素纸基印刷传感器

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-28 DOI: 10.1007/s10570-025-06451-9

Mohammed Khalifa, Herfried Lammer, Mohammed Sohail Bakshi

{"title":"Cellulose paper-based printed sensor for efficient cure process control in fiber reinforced epoxy composite","authors":"Mohammed Khalifa, Herfried Lammer, Mohammed Sohail Bakshi","doi":"10.1007/s10570-025-06451-9","DOIUrl":"10.1007/s10570-025-06451-9","url":null,"abstract":"<div><p>Fiber-reinforced epoxy composites are extensively used in aerospace, automotive, and sports industries due to their exceptional properties. Ensuring quality and production efficiency for composite manufacturing requires optimal curing and processing conditions without compromising the structural integrity. Traditionally, techniques such as differential scanning calorimetry (DSC) and dynamic mechanical analysis are used to optimize curing conditions. Still, these methods are confined to the laboratory and may not accurately reflect curing behavior during composite production. Herein, we have used a thin, flexible, and cost-effective screen-printed cellulose paper sensor for real-time cure monitoring of flax fiber-reinforced bio-epoxy composites. The sensor-enabled online monitoring of the composite curing behavior during the vacuum infusion process was carried out at various temperatures. The sensor demonstrated excellent reproducibility and durability under different temperature conditions, and the online monitoring results showed a good correlation with the DSC cure kinetic model. Furthermore, the fibrous structure of the paper-based sensor contributes to the mechanical integrity of the composite, offering reinforcement benefits. The sensor’s facile fabrication, low cost, and reinforcement characteristics present significant potential for improving process control and enhancing the production efficiency of composite structures while ensuring stringent quality control.</p><h3>Graphical abstract</h3><div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"3173 - 3188"},"PeriodicalIF":4.9,"publicationDate":"2025-02-28","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784174","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Hydrophobically modified microcrystalline cellulose for replacing silica in natural rubber composites 取代天然橡胶复合材料中二氧化硅的疏水改性微晶纤维素

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-27 DOI: 10.1007/s10570-025-06446-6

Zhenlu Li, Huaxu Song, Zhen Wang, Zhengying Qin, Linquan Wang, Xin Fan, Ziwei Li, Shaorong Lu

引用次数: 0

Pineapple leaf-derived TEMPO-oxidized cellulose nanospheres and graphene oxide composite: a green solution for ciprofloxacin adsorption 菠萝叶衍生的tempo氧化纤维素纳米球和氧化石墨烯复合材料：环丙沙星吸附的绿色溶液

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-26 DOI: 10.1007/s10570-025-06453-7

Nhung Tuyet Thi Nguyen, Minh-Anh Phan-Huynh, Khoa Le Anh, Doan Van Hong Thien, Kenji Hara, Dan-Thuy Van-Pham

{"title":"Pineapple leaf-derived TEMPO-oxidized cellulose nanospheres and graphene oxide composite: a green solution for ciprofloxacin adsorption","authors":"Nhung Tuyet Thi Nguyen, Minh-Anh Phan-Huynh, Khoa Le Anh, Doan Van Hong Thien, Kenji Hara, Dan-Thuy Van-Pham","doi":"10.1007/s10570-025-06453-7","DOIUrl":"10.1007/s10570-025-06453-7","url":null,"abstract":"<div><p>Graphene oxide (GO) is a promising material for the adsorption of contaminants from wastewater. In this study, a GO-based composite with high adsorption capacity and reduced GO content was synthesized by incorporating TEMPO-oxidized cellulose nanospheres (TO-CNS) derived from pineapple leaves. TO-CNS were effectively integrated into GO via a one-pot reaction based on Hummer’s method. In this process, TEMPO oxidation selectively converted the –CH<sub>2</sub>OH groups on cellulose nanospheres into –COOH groups, all while preserving the crystalline structure of cellulose I. Notably, the in situ integration of TO-CNS as a co-support during graphite oxidation significantly enhanced the interlayer spacing of GO sheets, expanding it from 0.34 to 0.85 nm. This increase in spacing, indicative of robust interfacial interactions, was further validated using FTIR spectroscopy. The spectra revealed hydrogen bonding and pronounced shifts in the mode and position of the functional group peaks, underscoring the structural alterations induced by TO-CNS integration. Raman spectroscopy revealed increased graphitic defects, and thermal analysis confirmed structural integration. The composite's average pore size of 40 Å demonstrated a significant enhancement that facilitated adsorption compared to 26 Å in GO. Ciprofloxacin adsorption capacities (35.95 ± 0.54–38.47 ± 0.53 mg/g) were comparable to pure GO (35.08 ± 1.10–36.83 ± 1.12 mg/g) despite a reduced GO content (73.8/26.2 wt%). Zeta potential analysis highlighted the roles of electrostatic attraction, hydrogen bonding, and π–π stacking in adsorption. This GO/TO-CNS composite demonstrates the potential for efficient, sustainable, and biocompatible antibiotic adsorption, offering significant promise for environmental remediation.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"3317 - 3334"},"PeriodicalIF":4.9,"publicationDate":"2025-02-26","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784145","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Chitosan-based polymeric dye for in-situ multifunctional dyeing of cotton fabric 壳聚糖基高分子染料在棉织物原位多功能染色中的应用

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-25 DOI: 10.1007/s10570-025-06430-0

Sanat Vohra, Shivam Chawla, Nikhil Shaiwale, Javed Sheikh

引用次数: 0

Flow dynamics of agricultural waste nanofibers: shear, temperature, and oscillatory insights 农业废弃物纳米纤维的流动动力学：剪切，温度和振荡的见解

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-25 DOI: 10.1007/s10570-025-06444-8

Bilge Nazli Altay, Burak Aksoy, James Atkinson, Christopher L. Lewis, Carlos Diaz-Acosta, Raymond Francis

{"title":"Flow dynamics of agricultural waste nanofibers: shear, temperature, and oscillatory insights","authors":"Bilge Nazli Altay, Burak Aksoy, James Atkinson, Christopher L. Lewis, Carlos Diaz-Acosta, Raymond Francis","doi":"10.1007/s10570-025-06444-8","DOIUrl":"10.1007/s10570-025-06444-8","url":null,"abstract":"<div><p>The rheology and fiber size of corn stover (CS) and cleaned cotton gin trash (CGT) cellulose nanofibers (CNFs) were studied including behaviors at both moderate and extremely high shear rates, to simulate industrial processes ranging from mixing and pumping to high-speed coating, printing, and extrusion. Particle size analyzer showed that 99% of CS fibers measured around 226 nm, while 85% of CGT fibers were approximately 143 nm. Both CS and CGT CNFs formed gel-like suspensions, and shear flow tests revealed that all samples exhibited shear-thinning behavior, allowing easy flow under shear forces. Gels with higher solid content (1%) demonstrated extended viscoelastic regions, indicating improved flexibility, structural integrity, and energy-dispersing capacity. The combination of shear-thinning behavior, flexibility, and energy absorption makes these CNFs promising for applications in papermaking, coatings, packaging, and areas where shock absorption is required.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"3077 - 3094"},"PeriodicalIF":4.9,"publicationDate":"2025-02-25","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-025-06444-8.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784144","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

Cellulose acetate blending and cellulose nanocrystal doping improve the diafiltration and antifouling properties of polyvinylidene fluoride membranes 醋酸纤维素共混和纤维素纳米晶掺杂提高了聚偏氟乙烯膜的滤除性能和防污性能

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-24 DOI: 10.1007/s10570-025-06436-8

Xiaoyu Bai, Yuan Zhou, Jiangtao Li, Zhaoxia Xia, Zhaojiang Wang, Qiang Zhang, Yuanzhang Jiang, Guixin Wang, Lin Tan, Yong Zhang

{"title":"Cellulose acetate blending and cellulose nanocrystal doping improve the diafiltration and antifouling properties of polyvinylidene fluoride membranes","authors":"Xiaoyu Bai, Yuan Zhou, Jiangtao Li, Zhaoxia Xia, Zhaojiang Wang, Qiang Zhang, Yuanzhang Jiang, Guixin Wang, Lin Tan, Yong Zhang","doi":"10.1007/s10570-025-06436-8","DOIUrl":"10.1007/s10570-025-06436-8","url":null,"abstract":"<div><p>In this paper, cellulose acetate (CA) and cellulose nanocrystal (CNC) modified polyvinylidene fluoride (PVDF) membranes were prepared by solution blending and non-solvent induced phase separation methods to improve the hydrophilicity and diafiltration capacity of the membranes. The changes in membrane performance before and after modification were systematically studied through simulated dialysis experiments, antifouling performance tests and biocompatibility analysis. The results show that CA blending and CNC doping will change the morphology and structure of the PVDF membrane, improve its hydrophilicity and permeability, and make it show better filtration capacity and antifouling performance. The modified PVDF membrane has higher clearance and diafiltration efficiency for small molecular solutes urea and creatinine, especially for the middle molecular solute lysozyme, while retaining most of the protein molecules, with a flux recovery rate of more than 95%. The modified PVDF membrane also has good biocompatibility. Bio-based CA and CNCs play an important role in improving the antifouling and diafiltration capacity of PVDF membranes.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"3299 - 3316"},"PeriodicalIF":4.9,"publicationDate":"2025-02-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784138","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0

The fiber saturation point: does it mean what you think it means? 纤维饱和点：它的意思和你想的一样吗？

IF 4.9 2区工程技术

Cellulose Pub Date : 2025-02-23 DOI: 10.1007/s10570-025-06412-2

Maria Fredriksson, Emil Engelund Thybring, Samuel L. Zelinka, Samuel V. Glass

{"title":"The fiber saturation point: does it mean what you think it means?","authors":"Maria Fredriksson, Emil Engelund Thybring, Samuel L. Zelinka, Samuel V. Glass","doi":"10.1007/s10570-025-06412-2","DOIUrl":"10.1007/s10570-025-06412-2","url":null,"abstract":"<div><p>Wood–water interactions are central to wood science, technology, and engineering. In the early twentieth century, the term “fiber saturation point” was coined to refer to the point of transition from the domain where wood properties change with moisture content to the domain where wood properties are constant. This conceptual model assumed that the wood cell walls are water saturated at this transition point and that capillary water appears above this point. This has since then been contradicted by multiple studies. Additionally, the fiber saturation point has been associated with techniques that do not necessarily measure the same moisture state. Some techniques characterize either the transition state at which wood properties change, or the state at which the cell walls are water saturated. These are, however, not the same moisture state. The aim of this paper is to clarify which moisture states the various fiber saturation points represent discussed from a conceptual model consistent with current experimental evidence. To avoid confusion, we propose that the transition state at which wood properties change is the only state called “the fiber saturation point”, or, for even more clarity, “the property intersection point”. For other moisture states, we strongly recommend that the term fiber saturation point is avoided. The term “maximum cell wall moisture content” should be used for the state at which the cell walls are water saturated. Finally, we highlight the importance of considering which moisture state is relevant for a specific application and selecting an appropriate method to characterize that state.</p></div>","PeriodicalId":511,"journal":{"name":"Cellulose","volume":"32 5","pages":"2901 - 2918"},"PeriodicalIF":4.9,"publicationDate":"2025-02-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s10570-025-06412-2.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"143784106","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}

引用次数: 0