{"title":"Reduction of 2,6-dimethoxyphenol odor emitted from Ribbed Smoked Sheet by Co(II)-salen complex","authors":"Hiroto Achira, Hirohiko Washiya","doi":"10.1007/s11869-024-01557-8","DOIUrl":"10.1007/s11869-024-01557-8","url":null,"abstract":"<div><p>Gas chromatography–mass spectroscopy (GC–MS) was used to characterize ribbed smoked sheet No. 3 (RSS 3) and latex to confirm the presence of 2,6-dimethoxyphenol odor. The selected ion monitoring (SIM) chromatogram of RSS 3 exhibited a 2,6-dimethoxyphenol peak at <i>m/z</i> 154, while the latex chromatogram did not show any peak. Using a synthetic <i>cis</i>-1,4-polyisoprene rubber and 2,6-dimethoxyphenol mixture as reference, the GC–MS analysis indicated that RSS 3 emits 4.0 mg/kg of 2,6-dimethoxyphenol. When added to the SIM chromatogram, the cobalt (II)-complex of salicylaldehyde ethylenediamine Schiff base ligand (Co(II)-salen) reduced the quantity of 2,6-dimethoxyphenol. This indicates that the odor was oxidized during physical mixing, implying that it was dissolved in the solution. Furthermore, the solubility of 2,6-dimethoxyphenol in various solvents was determined using the Hansen solubility parameters to identify the optimal solvents for the oxidation of the odor by the Co(II)-salen complex. Thermal analysis and theoretical study also indicate the generation of phenoxy radical by Co(II)-salen complex.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140667505","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Bo Jiang, Shiyu Fan, Chang Sun, Sen Mu, Tian Gao, Ling Qiu
{"title":"The regulation effect of urban green space on air particulate matter concentration under different matrices in Xi'an city","authors":"Bo Jiang, Shiyu Fan, Chang Sun, Sen Mu, Tian Gao, Ling Qiu","doi":"10.1007/s11869-024-01555-w","DOIUrl":"10.1007/s11869-024-01555-w","url":null,"abstract":"<div><p>Urban green space can effectively alleviate air pollution, in which vegetation structure plays an important role. However, these green spaces with varying vegetation structures exist in different environmental backgrounds of the city. By analyzing the influence of the different environmental backgrounds on the dust retention effect of green spaces with varying vegetation structures, green spaces can be truly utilized as a solution in alleviating air pollution. Therefore, according to the typical characteristics of landscape patterns and different coverage ratios of green areas in Xi’an city, China, the matrices of urban landscape were divided into three types, which include \"green space\", \"grey-green mixed space\" and \"gray space.\" In each environmental background, urban green space was divided into three levels: horizontal structure, species composition and vertical structure. Subsequently, 13 types of green spaces with different vegetation structures and three hard (no vegetation present) squares as control groups were selected. A one-year on-site monitoring was conducted on urban green spaces and concentrations of TSP, PM<sub>10</sub>, PM<sub>2.5</sub> and PM<sub>1</sub>. The results showed that: (1) In the green space, the concentrations of PM<sub>1</sub> and PM<sub>2.5</sub> were relatively higher. In the grey-green mixed space, the average concentration of air particle of all four particle sizes was the lowest. In the gray space, the concentrations of PM<sub>10</sub> and TSP were more concentrated. (2) Under the same matrices, due to the different locations of the plots, the concentration of air particles of different sizes was significantly different. Under the different urban environmental backgrounds, temperature, relative humidity, wind speed and air pressure all showed the same trend in the change of air particle concentration. (3) The one-layer green space structure was most suitable for planting. Considering the green space, the coniferous one-layered green space (CO) structure was recommended. The partly-closed broad-leaved one-layered green space (P-CBO) was found to be more suitable for the grey-green mixed space. Considering the gray space in the city center, it was suggested to plant the closed mixed coniferous and broad-leaved one-layered green space (CMO) structure. The findings provide empirical support for the future collocation of urban green vegetation structure and the improvement of urban air quality.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-15","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140601415","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Influence of body mass index on PM2.5 deposition in respiratory tract during urban commuting","authors":"Sneha Mahalingam, Ramsundram Narayanan","doi":"10.1007/s11869-024-01558-7","DOIUrl":"10.1007/s11869-024-01558-7","url":null,"abstract":"<div><p>This first key study examines the influence of functional residue capacity (FRC) associated with Body Mass Index (BMI) on PM<sub>2.5</sub> regional and lobar deposition. Size-segregated particulate matter (PM) was collected using the cascade impactor and multiple path particle dosimetry (MPPD) model is used to simulate the regional and lobar deposition in males and females aged 19–49, with various BMI categories. Morning and evening commutes exhibited a mean PM<sub>2.5</sub> of 127.89 ± 38.42 µg m<sup>−3</sup> and 157.2 ± 58.84 µg m<sup>−3</sup>, respectively. The elemental analysis indicated the prevalence of elements in the order of B > Ca > Fe > Pb > Al > Hg > TI > Mg > Cu > K > Na > Mn > Cr during commuting. Regardless of age and gender, the pulmonary region exhibited the highest PM<sub>2.5</sub> deposition levels in comparison to both the head and tracheobronchial regions. Females aged 19 and 49 exhibited a higher incidence of pulmonary accumulation of PM<sub>2.5</sub> than males of about 41% and 43.3% respectively. Among individuals aged 19 to 49, lobar deposition patterns of PM<sub>2.5</sub> revealed higher prevalence among females than males, showcasing relative variations across different BMI categories: 17 (3.1%), 18 (3.2%), 19 (3.12%), 22 (3.24%), 25 (3.21%), 27 (3.1%), and 30 (3.25%). Fine particles showcased maximum deposition in the right upper (25%), right lower (27%) and left lower lobes (26%). These findings emphasize the urgent need for extensive and meticulous research on BMI-based, gender-specific impacts on particle deposition and lung health within this critical bodily system.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140601810","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Long term trends in global air pollution potential and its application to ventilation corridors","authors":"Hareef baba shaeb Kannemadugu, Sandelger Dorligjav, Alok Taori, Rajashree Vinod Bothale, Prakash Chauhan","doi":"10.1007/s11869-024-01563-w","DOIUrl":"10.1007/s11869-024-01563-w","url":null,"abstract":"<div><p>Air pollution potential is a measure of the inability of the atmosphere to disperse pollutants away from the source. It depends on Planetary Boundary Layer Height (PBLH) and wind speed. Global air pollution potential Index (APPI) maps have been generated for the first time using 40 years (1980–2019) of PBLH and wind speed data available from ECMWF Reanalysis v5 (ERA5) data. These are useful for identifying ventilation corridors and for sustainable development. The seasonal climatology of APPI is also analyzed. Long-term trends in Ventilation coefficient (VC), PBLH, Wind speed, PM<sub>2.5</sub>, and Aerosol Optical Thickness (AOT) were analyzed globally and in over 30 cities to understand their future impact on climate change scenarios. High APPI is observed in the South Asian regions, giving rise to PM<sub>2.5</sub> and AOT hot spots, and are naturally disadvantageous. Long-term trends in VC and associated trends in PBLH and Wind speed suggest that the PBLH is decreasing at the rate of 1–3 m per year over south Asia, and wind speed is decreasing at the rate of 0.01–0.02 m·s<sup>− 1</sup>per year, resulting in the decrease of VC of about 1–25 m<sup>2</sup>·s<sup>− 1</sup>per year. If this trend continues, South Asia will have more air pollution potential, causing severe stagnation of air pollutants in the coming years and putting health risks to 1.8 billion people. The surface PM<sub>2.5</sub> and AOT are increasing at 0.5–1.5 µg·m<sup>− 3</sup> per year and 0.005–0.01 per year for South Asia cities. Sustainable development goals and climate policies/negotiations should consider global air pollution potential as an essential variable in planning and mitigation.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140601306","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Nuno Canha, Sara Gonçalves, Diogo Sousa, Carla Gamelas, Sergio Mendez, Sandra Cabo Verde, Susana Marta Almeida, Anna Rita de Bartolomeo, Maria Rachele Guascito, Eva Merico, Daniele Contini
{"title":"Pollution sources affecting the oxidative potential of fine aerosols in a Portuguese urban-industrial area - an exploratory study","authors":"Nuno Canha, Sara Gonçalves, Diogo Sousa, Carla Gamelas, Sergio Mendez, Sandra Cabo Verde, Susana Marta Almeida, Anna Rita de Bartolomeo, Maria Rachele Guascito, Eva Merico, Daniele Contini","doi":"10.1007/s11869-024-01556-9","DOIUrl":"10.1007/s11869-024-01556-9","url":null,"abstract":"<div><p>This study targets to determine the oxidative potential (OP) of fine aerosols in an urban-industrial area of the Lisbon Metropolitan Area (Portugal) and, in addition, to identify which pollution sources may have an impact on the OP levels of fine aerosols. For this purpose, thirty samples were selected from a set of 128 samples collected over one year (Dec 2019-Nov 2020), based on the highest load for each source (both mass and %) previously assessed by source apportionment studies (using Positive Matrix Factorisation, a total of 7 different sources were identified: soil, secondary sulphate, fuel-oil combustion, sea, vehicle non-exhaust, vehicle exhaust and industry). The OP associated with the water-soluble components of PM<sub>2.5</sub> was assessed using the dithiothreitol (DTT) method. The samples had a mean DTT activity (normalised to the mass) of 12.9 ± 6.6 pmol min<sup>− 1</sup> µg<sup>− 1</sup>, ranging from 3.5 to 31.8 pmol min<sup>− 1</sup> µg<sup>− 1</sup>. The DTT activity (normalised to the volume, <span>({text{O}text{P}}_{text{V}}^{text{D}text{T}text{T}})</span>) showed to have a significant positive association with PM<sub>2.5</sub> levels (R<sup>2</sup> = 0.714). Considering that the mass contributions of the different sources to the PM<sub>2.5</sub> levels were known, Spearman correlations were assessed and significant correlations were found between <span>({text{O}text{P}}_{text{V}}^{text{D}text{T}text{T}})</span> and three different sources: vehicle exhaust (ρ = 0.647, <i>p</i>-value = 0.001), fuel-oil combustion (ρ = 0.523, <i>p</i>-value = 0.012) and industry (ρ = 0.463, <i>p</i>-value = 0.018). Using a multiple linear regression analysis, these three sources were found to explain 82% of the variability in <span>({text{O}text{P}}_{text{V}}^{text{D}text{T}text{T}})</span>, with vehicle exhaust being the most influential source.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11869-024-01556-9.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140601402","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Moss biomonitoring of air quality linked with trace metals pollution around a metallurgical complex in Elbasan, Albania","authors":"Sonila Shehu Kane, Lirim Bekteshi, Shaniko Allajbeu, Pranvera Lazo","doi":"10.1007/s11869-024-01562-x","DOIUrl":"10.1007/s11869-024-01562-x","url":null,"abstract":"<div><p>Anthropogenic pollution impacts human and environmental health, climate change, and air quality. Elbasan, an industrial town about 50 km from the capital city of Tirana, is susceptible to environmental contamination as a result of the outdated technology applied in metal processing and metallurgy. Environmental biomonitoring was conducted to provide a comprehensive view of contamination levels in atmospheric deposition as a result of anthropogenic influences. The aim of this study is to evaluate the distribution of toxic metals in the atmospheric deposits in this area. Concentrations of thirteen trace metals were studied by using the passive method of moss biomonitoring. The ground-growing moss samples, Hypnium cupressiforme, were collected during the dry season of June 2021 from 12 sampling sites evenly distributed over the study area. Statistical analysis was used to assess the spatial distribution, concentration levels, variances, and relationships of the trace metals. The knowledge and the obtained statistical data harmonization made it possible to discuss the most probable sources of contaminants. Very strong and significant inter-element correlations were found between Cr, Ni, Co, and Fe. It looks like an anthropogenic association, which is mostly characteristic of air particles emitted from iron-chromium and iron-smelter plants. Together with cement factories, those are the primary emitters of trace metals in the Elbasan area and the primary sources of the deposition of Cr, Ni, Co, and Fe in this area. Substantial impacts were also found from soil dust emissions.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140600952","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Rishu Agarwal, Shankar G. Aggarwal, Daya Soni, Khem Singh
{"title":"An analytical comparison of two versions (US EPA and BIS) of pararosaniline method used for monitoring of ambient SO2","authors":"Rishu Agarwal, Shankar G. Aggarwal, Daya Soni, Khem Singh","doi":"10.1007/s11869-024-01553-y","DOIUrl":"10.1007/s11869-024-01553-y","url":null,"abstract":"<div><p>The two versions of the reference method of sulphur dioxide (SO<sub>2</sub>) measurement in ambient air (pararosaniline method) available as the Environment Protection Agency (EPA) USA (CFR 40 Part 50, Appendix A) and Bureau of Indian Standards (BIS) India (IS 5182 (Part 2):2001) standard methods were analytically studied. For accuracy and precision of the data obtained, a certain set of specifications should be ascertained before using the method for sample analysis as per the guidelines. On comparing the two methods of operation, the stated set of specifications are fulfilled for the EPA method but not for the BIS method. A different set of specifications were observed for the BIS method (absorbance blank: 0.012 ± 0.001 abs units, slope of calibration curve: 0.014 ± 0.001 abs units/µg SO<sub>2</sub>, intercept of calibration curve: 0.003 ± 0.002, calibration factor:72.0 ± 4.2). The absorption efficiency as well as the method efficiency of both methods were tested using three different concentrations (0.3 ppm, 0.5 ppm, and 0.8 ppm) of standard SO<sub>2</sub> gas. The absorption efficiency of both the methods was found to be 100%. The average method efficiency of the EPA method at 0.3 ppm, 0.5 ppm and 0.8 ppm were found to be 81 ± 8%, 81 ± 6% and 87 ± 1% while that of BIS method was observed to be 91 ± 5%, 93 ± 2%, 89 ± 4% at the respective concentrations. An uncertainty estimation study was also performed considering factors involved in sampling and analysis. A combined uncertainty < 9% and < 7% was observed for EPA and BIS method, respectively. This study presents a comprehensive examination of the operational aspects of two versions of pararosaniline method employed for measuring SO<sub>2</sub> in ambient air. The results indicate a need for redefining the specifications outlined in the BIS method. Notably, the BIS method displays greater sensitivity to low blank values compared to the EPA method. Additionally, the study introduces, for the first time, working factors and specifications associated with the BIS method for SO<sub>2</sub> measurement. These findings suggest their potential inclusion in the standard method as a means to enhance data quality and reliability in the assessment of SO<sub>2</sub> levels in ambient air.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-05","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140600985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Integrated assessment of inhalation health risk and economic benefit of improving ambient targeted VOCs in Petrochemical industrial area","authors":"Wissawa Malakan, Sarawut Thepanondh, Jutarat Keawboonchu, Vanitchaya Kultan, Akira Kondo, Hikari Shimadera","doi":"10.1007/s11869-024-01552-z","DOIUrl":"10.1007/s11869-024-01552-z","url":null,"abstract":"<div><p>The Maptaphut industrial area, one of the largest petrochemical complexes in Thailand, is the major cause of the various air pollutants. The larger concern is that a significant volume of air pollution is emitted and that air quality management needs to be improved. This is in part due to a lack of deeper understanding of how anthropogenic emissions are emitted from different sources in this area— especially volatile organic compounds (VOCs). Moreover, it has complicated relationship results of air pollution, disease mechanisms, and health effects. As a result, its available data can only give a rough indication of them. These factors are often assumed to be associated with economic consequences, but assessing the health-related economic losses caused by air pollution remains limited in many ways.</p><p>Four targeted VOCs were analyzed, including benzene, 1,3-butadiene, 1,2-dichloroethane, and vinyl chloride from industrial and non-industrial sources, namely stacks, flares, storage tanks, wastewater treatment plants, transportation and marketing, fugitive losses, slurry/open equipment/vessel, and on-road mobile emissions. Source apportionment can be conducted using emissions inventory (EI) to establish pollution source databases, the dispersion model, and then imported on the risk model by determining receptors. The AERMOD dispersion model coupled with the IRAP-h view model was used to predict the spatial distribution of the ground-level concentration and analyze the inhalation health risk covering cancer and non-cancer risks— as well as the prioritization of pollutants.</p><p>The risk assessment results indicated that the highest risk occurred most from 1,3-butadiene for cancer and chronic non-cancer risks contributed to fugitive sources, about 83% and 94%, and most benzenes for acute non-cancer risk contributed to on-road mobile sources, at about 56%.</p><p>Consequently, the benzene classified as the most important priority depending on its risk results, comprehensive epidemiological studies, and discharge volumes.</p><p>With the economic benefits assessment, BenMAP-CE was further utilized to estimate the health impacts and economic value of multiple scenarios to facilitate decision-making for benzene reduction. Overall, the 10% rollback policy for benzene concentration, monetized value of about 13.13 billion US dollars for all mortalities, gave the best practical scenario for the most economically viable option based on the B/C (benefit/cost) ratio results in Maptaphut. Ultimately, policymakers need to take additional measures to improve air quality and reduce health impacts while also considering economic benefits, especially benzene reduction.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11869-024-01552-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140600980","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
{"title":"Impacts of ambient air pollution exposure on child growth in East African countries","authors":"Valérien Baharane, Andrey Borisovich Shatalov","doi":"10.1007/s11869-024-01561-y","DOIUrl":"10.1007/s11869-024-01561-y","url":null,"abstract":"<div><p>Stunting and wasting are important indicators of the child’s physical and cognitive impairments. These indicators are frequently associated with malnutrition and related health care. However, with the increase in air pollution threats, the role of air pollution in impacting children’s growth has been speculated. This study assessed prenatal and postnatal exposure to air pollution and the effects it may have on the child’s growth in five East African countries. The adjusted linear regression model showed that prenatal exposure to PM<sub>2.5</sub> and CO reduced the height-for-age score with an increase of 1 µg/m<sup>3</sup> in PM<sub>2.5</sub> and 1 ppb in CO above the average values resulting in the reduction of the height-for-age score by 0.0106 (Standard Error (SE): 0.0016) and 0.0020 (SE: 0.0005) points, respectively. Moreover, the logistic regression model suggested that postnatal exposure to PM<sub>2.5</sub>, O<sub>3</sub>, and CO respectively contributed by 0.1% (95% Confidence Interval (CI): -0.7%; 0.8%), 3.0% (1.9%; 4.1%) and 1.4% (1.2%; 1.6%) on the stunting prevalence. Furthermore, the same air criteria pollutants showed significant effects on the weight-for-height and weight-for-age related indicators. These results should be useful for policies aiming at the protection of children’s health in the region.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140601322","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
Sung Ho Hwang, Gi Taek Oh, Jeung Yeon Park, Kiyoung Lee, Kyung-Duk Zho, Chungsik Yoon
{"title":"Characteristics of phthalate concentrations in propellant- and trigger-type consumer spray products","authors":"Sung Ho Hwang, Gi Taek Oh, Jeung Yeon Park, Kiyoung Lee, Kyung-Duk Zho, Chungsik Yoon","doi":"10.1007/s11869-024-01560-z","DOIUrl":"10.1007/s11869-024-01560-z","url":null,"abstract":"<div><p>The purposes of this study were to evaluate the bulk sample concentration and airborne concentrations of phthalate in different types of propellent and triggers in consumer spray products and estimate health risk assessment via inhalation. First, the phthalate concentrations were analyzed in the solutions of all products 174 from markets. Then, among 64 products containing phthalates, 10 propellant-type products were selected that contained high phthalate concentrations; airborne concentrations were measured at distances of 1, 3, and 5 m from the spray nozzle in a clean room. Four phthalates were detected in spray products: diisobutyl phthalate (DiBP), di-n-butyl phthalate (DnBP), butyl benzyl phthalate (BBzP), and bis(2-ethylhexyl) phthalate (DEHP). Among propellant-type products, repellents contained the highest mean concentrations (3.90 ppm), whereas sterilized products contained the lowest mean concentrations (0.59 ppm). Among trigger-type products, cleaning products contained the highest mean concentrations (4.54 ppm), whereas coating products contained the lowest mean concentrations (0.73 ppm). In both propellant- and trigger-type products, DnBP and DEHP exceeded the standard set by the Ministry of Food and Drug Safety of South Korea. No significant patterns were observed for the airborne DiBP, DnBP, and DEHP concentrations at 1, 3, and 5 m (p > 0.05). Children were one of the population groups most susceptible to health risks. Overall, phthalates were detected in both product solutions and the air in consumer spray products; some even exceeded safe limits. Therefore, consumer spray products should be used in well-ventilated areas to avoid respiratory exposure.</p></div>","PeriodicalId":49109,"journal":{"name":"Air Quality Atmosphere and Health","volume":null,"pages":null},"PeriodicalIF":2.9,"publicationDate":"2024-04-03","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"https://link.springer.com/content/pdf/10.1007/s11869-024-01560-z.pdf","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"140600956","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"环境科学与生态学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"OA","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}