Biomass Conversion and Biorefinery最新文献

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A comprehensive chemical, physical, mechanical, and thermal characterization of novel cellulosic plant extracted from the petiole of Washingtonia robusta fibers 综合化学,物理,机械和热特性的新型纤维素植物提取的叶柄华盛顿罗布斯塔纤维
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-23 DOI: 10.1007/s13399-024-06178-w
Hicham Elmoudnia, Paulina Faria, Rachid Jalal, Mohamed Waqif, Latifa Saâdi
{"title":"A comprehensive chemical, physical, mechanical, and thermal characterization of novel cellulosic plant extracted from the petiole of Washingtonia robusta fibers","authors":"Hicham Elmoudnia,&nbsp;Paulina Faria,&nbsp;Rachid Jalal,&nbsp;Mohamed Waqif,&nbsp;Latifa Saâdi","doi":"10.1007/s13399-024-06178-w","DOIUrl":"10.1007/s13399-024-06178-w","url":null,"abstract":"<div><p>This research aims to extract fibers from <i>Washingtonia robusta</i> petiole waste (<i>WRP</i>) and characterize them to investigate their potential. <i>WRP</i> fibers were treated for 2 h using different concentrations of NaOH solution (1, 3, 5, and 10% by weight) and then soaked for 2 h. The treatments adopted have shown improvements in certain chemical, physical, morphological, thermal, and mechanical properties. This study revealed that the crystallinity index was improved by 40 to 50%. FTIR analysis confirmed the reduction and degradation of hemicellulose for the optimally alkalized fiber. The SEM micrograph results of alkali-treated fibers showed rougher surfaces. The higher thermal stability was achieved when the alkali treatment with 5% NaOH was adopted. Further, fibers treated with 5% NaOH demonstrated interesting tensile properties, clearly superior to those found in the literature: tensile strength, Young’s modulus, and strain to failure of 678 ± 35.24 MPa, 11.2 ± 1.2 GPa, and 22.6% ± 0.75, respectively, with an average diameter of 314 ± 0.02 μm. The characterization results indicate that these treated fibers can be a good alternative natural reinforcement material in lightweight polymer composites or other composites for the building industry.</p></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 10","pages":"14923 - 14939"},"PeriodicalIF":3.5,"publicationDate":"2024-09-23","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144108574","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Assessment of thermochemical, physicochemical, and biochemical properties of purple cabbage powder converted by different drying systems 不同干燥系统转化紫甘蓝粉的热化学、物理化学和生化特性的评价
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-21 DOI: 10.1007/s13399-024-06142-8
Muhammed Taşova, Osman Nuri Öcalan, Samet Kaya Dursun, Onur Saraçoğlu
{"title":"Assessment of thermochemical, physicochemical, and biochemical properties of purple cabbage powder converted by different drying systems","authors":"Muhammed Taşova,&nbsp;Osman Nuri Öcalan,&nbsp;Samet Kaya Dursun,&nbsp;Onur Saraçoğlu","doi":"10.1007/s13399-024-06142-8","DOIUrl":"10.1007/s13399-024-06142-8","url":null,"abstract":"<div><p>In this study, effective diffusion values were determined between 3.26–6.07 × 10<sup>–9</sup> and 1.23–4.02 × 10<sup>–8</sup> m<sup>2</sup>/s. SMER values were calculated between 3–4.1 × 10<sup>–3</sup> and 9 × 10<sup>–3</sup>–1.6 × 10<sup>–2</sup> kg/kWh. SEC values are calculated between 244.99–326.39 and 63.70–111.38 kWh/kg. Evaporating energy values were calculated between 4.83–4.86 and 4.81–4.89 kWh. Carr indexes of the powders were determined between 28.06 and 65.38 and Hausner indexes between 1.77 and 2.90. Minimum color change CD was detected at 70 °C and MTCM at 50 °C drying processes. The total phenolic substance has ranged from 3584.5 to 5774.5 μg GAE g<sup>–1</sup> dw, total flavonoid substance from 499.3 to 1514.1 mg KE L<sup>–1</sup> dw, total monomeric anthocyanin from 162.5 to 955.2 μg cy<sup>–3</sup>-O-glu g<sup>–1</sup> dw, vitamin C from 500 to 820 mg L<sup>–1</sup>, and total antioxidant capacity ranged from 21.37 to 33.78 μmol TE g<sup>–1</sup> dw.</p></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 9","pages":"13831 - 13844"},"PeriodicalIF":3.5,"publicationDate":"2024-09-21","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144091022","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Illumination of biosorption of Allura Red on Rhus coriaria L. (sumac) plant: equilibrium, kinetic, thermodynamic, and density functional theory–based analyses 漆树植物对紫外光的生物吸收:基于平衡、动力学、热力学和密度泛函理论的分析
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-20 DOI: 10.1007/s13399-024-06154-4
Osman Çaylak, Halil İbrahim Çetintaş, Muhammed Safa Çelik, Nurevşan Kaya, Serap Çetinkaya, Mikhail M. Maslov, Savaş Kaya
{"title":"Illumination of biosorption of Allura Red on Rhus coriaria L. (sumac) plant: equilibrium, kinetic, thermodynamic, and density functional theory–based analyses","authors":"Osman Çaylak,&nbsp;Halil İbrahim Çetintaş,&nbsp;Muhammed Safa Çelik,&nbsp;Nurevşan Kaya,&nbsp;Serap Çetinkaya,&nbsp;Mikhail M. Maslov,&nbsp;Savaş Kaya","doi":"10.1007/s13399-024-06154-4","DOIUrl":"10.1007/s13399-024-06154-4","url":null,"abstract":"<div><p>In the present paper, the biosorption capability of <i>Rhus coriaria L.</i> (sumac) plant for the effective removal of Allura Red (AR) dye from wastewater was tested in the light of theoretical and experimental tools. The reactive functional groups in the structure of the studied biosorbent and the surface morphology of the mentioned biosorbent were highlighted with the help of FTIR spectrophotometer, SEM (scanning electron microscopy), and EDX (energy-dispersive X-ray analysis). The effect of important parameters such as pH, time, adsorbent mass, and temperature on the biosorption process was checked and discussed in detail. pH 2 was determined as the optimum value for the highest biosorption. Maximum effectiveness was reached at a biosorbent mass of 200 mg. The biosorption process adhered to the Langmuir isotherm and PSO kinetic models, and the process was determined to have a spontaneous and exothermic nature. Through the recovery experiments, it was noted that the studied plant retained approximately 30% of its biosorption capacity after three cycles. To prove the power of the interaction between Allura Red dye and dominant components of <i>Rhus coriaria L.</i> (sumac), density functional theory calculations were performed. Theoretically obtained conceptual DFT-based descriptors, the comments made within the framework of popular electronic structure rules, and calculated adsorption energies were in good agreement with the experimentally obtained data. As a result, it was reported that <i>Rhus coriaria L</i>. can be used as an effective and useful biosorbent for the removal of AR from wastewater.</p></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 8","pages":"11701 - 11717"},"PeriodicalIF":3.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144084907","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Facile fractionation of lignocellulosic biomass: a review on promising green technology of deep eutectic solvent for bioethanol production 木质纤维素生物质的快速分馏:深共熔溶剂生产生物乙醇的绿色技术综述
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-20 DOI: 10.1007/s13399-024-06146-4
Fouziya Parveen, Ayush Saxena, Akhtar Hussain, Balendu Shekher Giri, Mohammad Ashfaque
{"title":"Facile fractionation of lignocellulosic biomass: a review on promising green technology of deep eutectic solvent for bioethanol production","authors":"Fouziya Parveen,&nbsp;Ayush Saxena,&nbsp;Akhtar Hussain,&nbsp;Balendu Shekher Giri,&nbsp;Mohammad Ashfaque","doi":"10.1007/s13399-024-06146-4","DOIUrl":"10.1007/s13399-024-06146-4","url":null,"abstract":"<div><p>Sustainable bioethanol production from lignocellulosic biomass to meet the energy demand and generate wealth from waste is the need of the hour. A surplus amount of lignocellulosic biomass is produced worldwide as organic waste which can be utilized for bioethanol production. Pretreatment is a crucial step in biorefinery application, the selection of the best pretreatment technology will reduce the intensive energy requirements, and the operational costs make biofuel production economically feasible and sustainable. Every pretreatment technology has its own drawbacks which needs to be addressed. Among these technologies, deep eutectic solvent (DES) is being investigated as an ideal solvent for the pretreatment of lignocellulosic biomass to improve the enzymatic digestibility, surface area solubility, and lowering lignin content and cellulose crystallinity. DES offers a green way of deconstructing lignocellulosic biomass with minimum environmental hazard. DES is an inexpensive and environment-friendly solvent effective in biomass valorization. This review focuses on the current status and advancements in pretreatment technologies using DES and its future prospects.</p></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 9","pages":"13303 - 13322"},"PeriodicalIF":3.5,"publicationDate":"2024-09-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"144091012","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Innovative strategies to improve the properties of paper with bio-sourced material and its application in food packaging: a review 利用生物源材料改善纸张性能的创新战略及其在食品包装中的应用:综述
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-19 DOI: 10.1007/s13399-024-06066-3
Pradeep Kumar, Anand Kishore, Shefali Tripathi,  Lavanya, Vinayak Chaudhary, Kirtiraj K. Gaikwad
{"title":"Innovative strategies to improve the properties of paper with bio-sourced material and its application in food packaging: a review","authors":"Pradeep Kumar,&nbsp;Anand Kishore,&nbsp;Shefali Tripathi,&nbsp; Lavanya,&nbsp;Vinayak Chaudhary,&nbsp;Kirtiraj K. Gaikwad","doi":"10.1007/s13399-024-06066-3","DOIUrl":"10.1007/s13399-024-06066-3","url":null,"abstract":"<div><p>The demand for safe and environmentally friendly food packaging is rising, leading to the growing popularity of paper-based biodegradable food packaging materials. Applying biopolymer coatings and reinforcing bioactive compounds into the packaging-grade paper matrix will enhance the physical, mechanical, and barrier properties of paper. Traditional paper coating methods, solution casting, and dip coating methods are improved with innovative spray coating methods, electrospinning, and bar coating methods. Biopolymers starch, cellulose, protein, and wax are widely used for paper coating, enhancing paper properties and showing the potential to replace current synthetic coating materials. Incorporating active materials in paper with innovative coating methods produces active paper-based packaging material that helps protect food from harmful pathogens. This review highlights the innovative strategies to improve the physical and functional properties of paper and their application in food packaging. Also, this article emphasizes paper-based smart packaging material for indicating the quality of food products.</p><h3>Graphical Abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 9","pages":"13037 - 13053"},"PeriodicalIF":3.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257467","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Conversion of lignocellulosic biomass waste into mycoprotein: current status and future directions for sustainable protein production 将木质纤维素生物质废物转化为菌体蛋白:可持续蛋白质生产的现状和未来方向
IF 4 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-19 DOI: 10.1007/s13399-024-06130-y
Zheng Yang Ng, Phei Er Kee, Rosazlin Abdullah, John Chi-Wei Lan, Tau Chuan Ling, Jheng-Jie Jiang, Jun Wei Lim, Kuan Shiong Khoo
{"title":"Conversion of lignocellulosic biomass waste into mycoprotein: current status and future directions for sustainable protein production","authors":"Zheng Yang Ng, Phei Er Kee, Rosazlin Abdullah, John Chi-Wei Lan, Tau Chuan Ling, Jheng-Jie Jiang, Jun Wei Lim, Kuan Shiong Khoo","doi":"10.1007/s13399-024-06130-y","DOIUrl":"https://doi.org/10.1007/s13399-024-06130-y","url":null,"abstract":"<p>Mycoprotein is a nutritious food product derived from fungi that boasts a high protein content, low fat, and substantial fiber, mimicking the texture of meat. It contains essential amino acids (EAA), vitamins, and minerals. Traditionally, it is produced through the fermentation of glucose derived from starch in controlled bioreactors, where pH, temperature, and oxygen levels are optimized to enhance fungal biomass production. Advances in biotechnology have highlighted lignocellulosic biomass waste, such as agricultural residues, forestry waste, and other plant materials, as a sustainable and cost-effective alternative feedstock. This type of biomass, which includes cellulose, hemicellulose, and lignin, can be pretreated and enzymatically broken down to release fermentable sugars, promoting a circular economy by turning waste into valuable bioproducts. This review explores the feasibility of lignocellulosic biomass for producing mycoprotein through advanced pretreatment and fermentation techniques. Techniques like steam explosion and acid hydrolysis effectively break down complex lignocellulosic structures, enhancing the availability of fermentable sugars necessary for efficient mycoprotein synthesis. Furthermore, using lignocellulosic biomass facilitates waste management and supports sustainable agricultural practices. Moreover, this review discusses fungi choices suitable for mycoprotein production, such as <i>Fusarium venenatum</i>, <i>Saccharomyces cerevisiae</i>, <i>Pleurotus</i> sp., <i>Neurospora</i> sp., and <i>Aspergillus</i> sp.. These findings highlight the potential of mycoprotein production from lignocellulosic biomass waste to enhance food sustainability and resource efficiency.</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>\u0000","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"22 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257504","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Mechanical and flammability properties of ultrasonically processed silane-treated areca-banana fiber-reinforced epoxy composites for lightweight applications 用于轻质应用的经超声波处理的硅烷处理山竹纤维增强环氧树脂复合材料的机械性能和可燃性能
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-19 DOI: 10.1007/s13399-024-06124-w
Jafrey Daniel James Dhilip, Vijay Raghunathan, Ramesh Mohan, Vinod Ayyappan, Sanjay Mavinkere Rangappa, Suchart Siengchin
{"title":"Mechanical and flammability properties of ultrasonically processed silane-treated areca-banana fiber-reinforced epoxy composites for lightweight applications","authors":"Jafrey Daniel James Dhilip,&nbsp;Vijay Raghunathan,&nbsp;Ramesh Mohan,&nbsp;Vinod Ayyappan,&nbsp;Sanjay Mavinkere Rangappa,&nbsp;Suchart Siengchin","doi":"10.1007/s13399-024-06124-w","DOIUrl":"10.1007/s13399-024-06124-w","url":null,"abstract":"<div><p>Synthetic fiber-based polymers constitute a significant pollution source; however, their elimination is challenging due to their extensive applications. The properties of the natural fibers can be enhanced through chemical treatment. In this study, areca fibers, subjected to ultrasonic modification with silane, were utilized in various stacking sequences, and banana fibers were used without modification. The tri-layer epoxy composites were developed following four stacking sequences using a hand layup process. The mechanical, flammability, and morphological characteristics of the developed composites were analyzed. Fourier transform infrared spectroscopy results indicate the modification of fibers after silane treatment. Morphological investigations using scanning electron microscope revealed an excellent interfacial bond between the chemically treated fibers and the matrix, leading to a 15% improvement in ultimate tensile strength, 20% in hardness, 34% in ultimate flexural strength, and 18% in impact properties. This signifies the impact of surface modification on areca fibers and stacking sequence. The results showed that fiber-matrix interaction played a crucial role in controlling the performance characteristics of the developed composites.</p></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 9","pages":"13693 - 13706"},"PeriodicalIF":3.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257463","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Thermodynamic evaluation on the chemical looping co-gasification performances of Cr-containing tannery sludge and waste surgical mask 含铬制革污泥和废外科口罩化学循环共气化性能的热力学评估
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-19 DOI: 10.1007/s13399-024-06132-w
Congxi Tao, Hao Wang, Jiazhi Yin, Qian Liang, Ming Wang, Qingmei Li, Xudong Wang
{"title":"Thermodynamic evaluation on the chemical looping co-gasification performances of Cr-containing tannery sludge and waste surgical mask","authors":"Congxi Tao,&nbsp;Hao Wang,&nbsp;Jiazhi Yin,&nbsp;Qian Liang,&nbsp;Ming Wang,&nbsp;Qingmei Li,&nbsp;Xudong Wang","doi":"10.1007/s13399-024-06132-w","DOIUrl":"10.1007/s13399-024-06132-w","url":null,"abstract":"<div><p>Clean disposal of Cr-containing tannery sludge (CTS) is a serious environmental issue because the high-content Cr is easily oxidized to toxically hexavalent. To realize the waste to energy, the CTS is used for syngas production via chemical looping co-gasification (CLCG) co-feeding with the waste surgical mask (WSM). The thermodynamic analysis is adopted to analyze the syngas’ quality, the chromium’s fate, and the N-, Cl-, and S-containing gaseous products under different gasification temperatures. Then, the effects of the mass flowrates of the steam, OC, and blending ratio of CTS in the feedstock are investigated. It is found that Cr in CTS can maintain trivalent chromium in the CLCG which is beneficial to the environment. Increasing gasification temperature can increase the <i>Q</i><sub><i>m</i></sub> from 11.44 to 13.43 MJ/kg. More steam in the gasification agent enhances the H<sub>2</sub> production and H<sub>2</sub>/CO ratio in CLCG while increasing OC circulation rate leads to the gasification towards combustion.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 10","pages":"14869 - 14880"},"PeriodicalIF":3.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257466","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Preparation and characterization of activated carbon from medlar seed by chemical activation with phosphoric acid and its application in uranium adsorption 用磷酸化学活化法制备枸杞子活性炭及其在铀吸附中的应用
IF 4 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-19 DOI: 10.1007/s13399-024-06161-5
Messaoud Bennemla, Toufik Semaoune, Meriem Chabane Sari, Fatima Houhoune, Sihem Khemaissia, Mourad Bellaloui, Hamana Adjedar, Yasmina Hammache, Sihem Ouattas
{"title":"Preparation and characterization of activated carbon from medlar seed by chemical activation with phosphoric acid and its application in uranium adsorption","authors":"Messaoud Bennemla, Toufik Semaoune, Meriem Chabane Sari, Fatima Houhoune, Sihem Khemaissia, Mourad Bellaloui, Hamana Adjedar, Yasmina Hammache, Sihem Ouattas","doi":"10.1007/s13399-024-06161-5","DOIUrl":"https://doi.org/10.1007/s13399-024-06161-5","url":null,"abstract":"<p>The aim of this work was to synthesize a high-capacity adsorbent from medlar seeds by chemical activation using phosphoric acid. The confirmation of successful biomass activation was achieved through various characterizations, including SEM–EDS, FTIR, and nitrogen adsorption–desorption. The best parameters were found to be a temperature of 500 °C, a time of 60 min, and an impregnation ratio of 2:1. The specific surface area, average pore diameter, and total pore volume were identified as 1845.32 m<sup>2</sup>/g, 2.88 nm, and 0.896 cm<sup>3</sup>/g, respectively. The performance of the selected activated carbon was evaluated by using it for the sorption of uranium (VI) in a batch system. The maximum adsorption of 52.08 mg/g was obtained under optimum conditions: pH = 3.54, adsorbent dose of 2 g/L, adsorbate concentration of 100 mg/L, particle size between 0.125 and 0.20 mm, and contact time of 90 min. Until the fifth cycle of use, the prepared activated carbon showed excellent regeneration capacity (84.23%). The pseudo-second-order kinetic and the Langmuir isotherm were the best fitted, implying the monolayer chemical adsorption process. The adsorption process could be considered as spontaneous (Δ<i>G</i>° &lt; 0) and exothermic process (− 84.601 kJ/mol).</p><h3 data-test=\"abstract-sub-heading\">Graphical Abstract</h3>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"31 1","pages":""},"PeriodicalIF":4.0,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257465","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Effect of drilling process parameters on agro-waste-based polymer composites reinforced with banana fiber and coconut shell filler 钻孔工艺参数对香蕉纤维和椰壳填料增强的农产废料基聚合物复合材料的影响
IF 3.5 4区 工程技术
Biomass Conversion and Biorefinery Pub Date : 2024-09-19 DOI: 10.1007/s13399-024-06140-w
Gokul Kannan, Rajasekaran Thangaraju, Supakij Suttiruengwong, Vigneshwaran Shanmugam, Sanjay Mavinkere Rangappa, K. R. Sumesh, Rittin Abraham Kurien, Suchart Siengchin
{"title":"Effect of drilling process parameters on agro-waste-based polymer composites reinforced with banana fiber and coconut shell filler","authors":"Gokul Kannan,&nbsp;Rajasekaran Thangaraju,&nbsp;Supakij Suttiruengwong,&nbsp;Vigneshwaran Shanmugam,&nbsp;Sanjay Mavinkere Rangappa,&nbsp;K. R. Sumesh,&nbsp;Rittin Abraham Kurien,&nbsp;Suchart Siengchin","doi":"10.1007/s13399-024-06140-w","DOIUrl":"10.1007/s13399-024-06140-w","url":null,"abstract":"<div><p>The present study effectively employed agro-wastes in the fabrication of novel hybrid polymer composites, incorporating banana fibers (BA) and coconut shell (CS) fillers. The machining performance of the hybrid composites was assessed in relation to the effects of drilling process parameters. CNC drilling was conducted under the following conditions: coconut filler content (1%, 3%, and 5% by volume), feed rates (50, 75, and 100 mm/min), and spindle speeds (1000, 1500, and 2000 rpm). A drilling experiment was carried out using a Taguchi L<sub>27</sub> orthogonal array, and the responses, including thrust force, peel-up delamination, and push-out delamination, were analyzed in detail. The minimum thrust force was achieved with 5 vol.% coconut shell filler, a feed rate of 50 mm/min, and a spindle speed of 2000 rpm. The lowest peel-up delamination was observed with 1 vol.% coconut shell filler, a spindle speed of 1500 rpm, and a feed rate of 100 mm/min, while the minimum push-out delamination occurred under the same filler content, a spindle speed of 1500 rpm, and a feed rate of 75 mm/min. Fiber/matrix debonding, fractured fibers, and matrix cracks were identified as critical failure mechanisms through scanning electron microscopy.</p><h3>Graphical abstract</h3>\u0000<div><figure><div><div><picture><source><img></source></picture></div></div></figure></div></div>","PeriodicalId":488,"journal":{"name":"Biomass Conversion and Biorefinery","volume":"15 9","pages":"13719 - 13732"},"PeriodicalIF":3.5,"publicationDate":"2024-09-19","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"142257464","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":4,"RegionCategory":"工程技术","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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