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IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-10 DOI: 10.1016/s2589-5974(24)00123-0
{"title":"Subscription and Copyright Information","authors":"","doi":"10.1016/s2589-5974(24)00123-0","DOIUrl":"https://doi.org/10.1016/s2589-5974(24)00123-0","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"34 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141584988","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-10 DOI: 10.1016/s2589-5974(24)00120-5
{"title":"Advisory Board and Contents","authors":"","doi":"10.1016/s2589-5974(24)00120-5","DOIUrl":"https://doi.org/10.1016/s2589-5974(24)00120-5","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"34 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-10","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141584985","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Frontiers of NHC catalysis: radical and site-selective reactions NHC 催化前沿：自由基和位点选择性反应
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-09 DOI: 10.1016/j.trechm.2024.06.005
Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi
{"title":"Frontiers of NHC catalysis: radical and site-selective reactions","authors":"Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi","doi":"10.1016/j.trechm.2024.06.005","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.005","url":null,"abstract":"<p>Previous work focused on (N-heterocyclic carbene) NHC catalysis has mainly centered on forming new chemical bonds and controlling stereoselectivity through electron-pair transfer processes. While these topics remain interesting and impactful, we envisioned that NHC catalysis can offer unique opportunities in radical chemistry and site-selective reactions of sophisticated molecules bearing multiple functional groups with similar reactivities.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"40 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141568379","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Chemical conjugation innovations for protein nanoparticles 蛋白质纳米颗粒的化学共轭创新
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-07-04 DOI: 10.1016/j.trechm.2024.06.004
Mark G. Legendre, Virginia H. Pistilli, Gozde S. Demirer
{"title":"Chemical conjugation innovations for protein nanoparticles","authors":"Mark G. Legendre, Virginia H. Pistilli, Gozde S. Demirer","doi":"10.1016/j.trechm.2024.06.004","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.004","url":null,"abstract":"<p>Protein nanoparticles (PNPs) present versatile platforms for cargo delivery due to their modularity, biocompatibility, and self-assembled structures. PNPs have benefited greatly from developments in bioorthogonal covalent attachment chemistries, which enable efficient post-translational cargo loading. In this paper, we review recent advancements in bioorthogonal strategies for cargo loading onto PNPs, including methods for chemical functionalization of natural scaffolds and the use of established click chemistries. We also discuss how protein engineering strategies, including genetically encoded ligation systems and non-canonical amino acid incorporation, have conferred even greater specificity and control to cargo loading and delivery. We conclude the review with applications and future directions of PNPs in crop and soil sciences, with insights on their translation to industry and agriculture.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"30 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-07-04","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141551671","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Deciphering plasmonic photocatalysis using plasmon-enhanced Raman spectroscopy 利用等离子体增强拉曼光谱解密等离子体光催化技术
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-06-24 DOI: 10.1016/j.trechm.2024.05.006
Hui Wang
{"title":"Deciphering plasmonic photocatalysis using plasmon-enhanced Raman spectroscopy","authors":"Hui Wang","doi":"10.1016/j.trechm.2024.05.006","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.05.006","url":null,"abstract":"<p>Plasmonic photocatalysis, which represents a paradigm-shifting approach to solar-to-chemical energy conversion, has become a rapidly evolving research field full of opportunities, challenges, and open questions. Plasmon-driven photocatalytic reactions are mechanistically complex, dictated not only by multiple interplaying photophysical effects but also by local chemical environments at the catalyst–adsorbate interfaces. This review article highlights the unique value of plasmon-enhanced Raman spectroscopy in mechanistic studies of plasmonic photocatalysis. Using plasmon-driven reductive coupling of nitroarene derivative adsorbates as a model reaction system, this article elaborates on how the rich information extracted from deliberately designed plasmon-enhanced Raman spectroscopic measurements can be carefully analyzed and further rationalized to generate critical insights into the exact roles of hot carriers, photothermal transduction, and catalyst–adsorbate interactions in plasmonic photocatalysis.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"76 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141502752","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Multifunctional COF design addresses Li-S organic electrode limitations 多功能 COF 设计解决了锂-S 有机电极的局限性
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-06-24 DOI: 10.1016/j.trechm.2024.06.003
Kiana A. Treaster, Ani N. Davis, Megan M. Butala, Austin M. Evans
{"title":"Multifunctional COF design addresses Li-S organic electrode limitations","authors":"Kiana A. Treaster, Ani N. Davis, Megan M. Butala, Austin M. Evans","doi":"10.1016/j.trechm.2024.06.003","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.003","url":null,"abstract":"<p>Lithium-sulfur (Li-S) batteries are restricted by cathode polysulfide shuttling and anode lithium dendrite formation. <span>Jin, Zuo, and coworkers</span><svg aria-label=\"Opens in new window\" focusable=\"false\" height=\"8px\" viewbox=\"0 0 8 8\" width=\"8px\"><path d=\"M1.12949 2.1072V1H7V6.85795H5.89111V2.90281L0.784057 8L0 7.21635L5.11902 2.1072H1.12949Z\"></path></svg> recently showed that Li-S batteries with high capacities and cycling stabilities emerge from intentionally designed covalent organic framework (COF) electrodes. This report highlights how COF design can address fundamental challenges in organic electrode engineering.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"20 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-06-24","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141502753","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Trapped entanglements in polymer networks: formation and characterization 聚合物网络中的捕获纠缠：形成与表征
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-06-22 DOI: 10.1016/j.trechm.2024.05.005
Fu-Sheng Wang, Leah M. Kosovsky, Erin C. Krist, Benjamin J. Kruse, Aleksandr V. Zhukhovitskiy
{"title":"Trapped entanglements in polymer networks: formation and characterization","authors":"Fu-Sheng Wang, Leah M. Kosovsky, Erin C. Krist, Benjamin J. Kruse, Aleksandr V. Zhukhovitskiy","doi":"10.1016/j.trechm.2024.05.005","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.05.005","url":null,"abstract":"<p>The presence of entanglements in polymer networks has been known since the 1940s. These topological crosslinks have been found to strongly affect mechanical properties of the materials, including stiffness, extensibility, and toughness. However, control over the entanglement density and topology remains a challenge. Furthermore, entanglements are invisible to conventional chemical characterization methods, rendering their characterization a challenge in its own right. Recent endeavors in the realm of polymer entanglements have focused on unraveling the nature of entanglements and leveraging this knowledge to enhance the mechanical properties of soft materials. This review covers the latest breakthroughs in controlling and characterizing the formation of trapped entanglements in polymer networks and offers an outlook on the trajectory of this evolving field.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"29 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-06-22","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141528913","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
The ligand: an overlooked element in sustainable catalysis 配体：可持续催化中被忽视的元素
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-06-20 DOI: 10.1016/j.trechm.2024.06.001
Sachin Handa
{"title":"The ligand: an overlooked element in sustainable catalysis","authors":"Sachin Handa","doi":"10.1016/j.trechm.2024.06.001","DOIUrl":"https://doi.org/10.1016/j.trechm.2024.06.001","url":null,"abstract":"<p>Ligands play a pivotal role in catalysis, yet crafting and purifying them often requires toxic reagents and results in solvent waste. Thus, curtailing their sustainability repercussions demands a meticulous synthetic process, robust design leading to minimal usage, and entirely ligand-free methodologies.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"53 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-06-20","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141528914","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
Advisory Board and Contents 咨询委员会和内容
IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-06-12 DOI: 10.1016/s2589-5974(24)00097-2
{"title":"Advisory Board and Contents","authors":"","doi":"10.1016/s2589-5974(24)00097-2","DOIUrl":"https://doi.org/10.1016/s2589-5974(24)00097-2","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"207 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141523847","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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IF 15.7 2区 化学
Trends in Chemistry Pub Date : 2024-06-12 DOI: 10.1016/s2589-5974(24)00100-x
{"title":"Subscription and Copyright Information","authors":"","doi":"10.1016/s2589-5974(24)00100-x","DOIUrl":"https://doi.org/10.1016/s2589-5974(24)00100-x","url":null,"abstract":"No Abstract","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"56 1","pages":""},"PeriodicalIF":15.7,"publicationDate":"2024-06-12","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":null,"resultStr":null,"platform":"Semanticscholar","paperid":"141523848","PeriodicalName":null,"FirstCategoryId":null,"ListUrlMain":null,"RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":"","EPubDate":null,"PubModel":null,"JCR":null,"JCRName":null,"Score":null,"Total":0}
引用次数: 0
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