NHC 催化前沿：自由基和位点选择性反应

IF 14 2区化学 Q1 CHEMISTRY, MULTIDISCIPLINARY

Trends in Chemistry Pub Date : 2024-07-09 DOI:10.1016/j.trechm.2024.06.005

Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi

{"title":"NHC 催化前沿：自由基和位点选择性反应","authors":"Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi","doi":"10.1016/j.trechm.2024.06.005","DOIUrl":null,"url":null,"abstract":"<p>Previous work focused on (N-heterocyclic carbene) NHC catalysis has mainly centered on forming new chemical bonds and controlling stereoselectivity through electron-pair transfer processes. While these topics remain interesting and impactful, we envisioned that NHC catalysis can offer unique opportunities in radical chemistry and site-selective reactions of sophisticated molecules bearing multiple functional groups with similar reactivities.</p>","PeriodicalId":48544,"journal":{"name":"Trends in Chemistry","volume":"40 1","pages":""},"PeriodicalIF":14.0000,"publicationDate":"2024-07-09","publicationTypes":"Journal Article","fieldsOfStudy":null,"isOpenAccess":false,"openAccessPdf":"","citationCount":"0","resultStr":"{\"title\":\"Frontiers of NHC catalysis: radical and site-selective reactions\",\"authors\":\"Xiang-Yu Ye, Yongtao Xie, Yonggui Robin Chi\",\"doi\":\"10.1016/j.trechm.2024.06.005\",\"DOIUrl\":null,\"url\":null,\"abstract\":\"<p>Previous work focused on (N-heterocyclic carbene) NHC catalysis has mainly centered on forming new chemical bonds and controlling stereoselectivity through electron-pair transfer processes. While these topics remain interesting and impactful, we envisioned that NHC catalysis can offer unique opportunities in radical chemistry and site-selective reactions of sophisticated molecules bearing multiple functional groups with similar reactivities.</p>\",\"PeriodicalId\":48544,\"journal\":{\"name\":\"Trends in Chemistry\",\"volume\":\"40 1\",\"pages\":\"\"},\"PeriodicalIF\":14.0000,\"publicationDate\":\"2024-07-09\",\"publicationTypes\":\"Journal Article\",\"fieldsOfStudy\":null,\"isOpenAccess\":false,\"openAccessPdf\":\"\",\"citationCount\":\"0\",\"resultStr\":null,\"platform\":\"Semanticscholar\",\"paperid\":null,\"PeriodicalName\":\"Trends in Chemistry\",\"FirstCategoryId\":\"92\",\"ListUrlMain\":\"https://doi.org/10.1016/j.trechm.2024.06.005\",\"RegionNum\":2,\"RegionCategory\":\"化学\",\"ArticlePicture\":[],\"TitleCN\":null,\"AbstractTextCN\":null,\"PMCID\":null,\"EPubDate\":\"\",\"PubModel\":\"\",\"JCR\":\"Q1\",\"JCRName\":\"CHEMISTRY, MULTIDISCIPLINARY\",\"Score\":null,\"Total\":0}","platform":"Semanticscholar","paperid":null,"PeriodicalName":"Trends in Chemistry","FirstCategoryId":"92","ListUrlMain":"https://doi.org/10.1016/j.trechm.2024.06.005","RegionNum":2,"RegionCategory":"化学","ArticlePicture":[],"TitleCN":null,"AbstractTextCN":null,"PMCID":null,"EPubDate":"","PubModel":"","JCR":"Q1","JCRName":"CHEMISTRY, MULTIDISCIPLINARY","Score":null,"Total":0}

引用次数: 0

摘要

以往有关（N-杂环碳烯）NHC 催化的研究主要集中在通过电子对转移过程形成新的化学键和控制立体选择性。尽管这些研究课题仍然很有意义和影响，但我们认为，NHC 催化可以为自由基化学和具有类似反应活性的复杂分子的位点选择性反应提供独特的机会。

本文章由计算机程序翻译，如有差异，请以英文原文为准。

查看原文本刊更多论文

Frontiers of NHC catalysis: radical and site-selective reactions

Previous work focused on (N-heterocyclic carbene) NHC catalysis has mainly centered on forming new chemical bonds and controlling stereoselectivity through electron-pair transfer processes. While these topics remain interesting and impactful, we envisioned that NHC catalysis can offer unique opportunities in radical chemistry and site-selective reactions of sophisticated molecules bearing multiple functional groups with similar reactivities.

求助全文

通过发布文献求助，成功后即可免费获取论文全文。去求助

来源期刊

Trends in Chemistry CHEMISTRY, MULTIDISCIPLINARY-

CiteScore

28.00

自引率

0.60%

发文量

138

期刊介绍： Trends in Chemistry serves as a new global platform for discussing significant and transformative concepts across all areas of chemistry. It recognizes that breakthroughs in chemistry hold the key to addressing major global challenges. The journal offers readable, multidisciplinary articles, including reviews, opinions, and short pieces, designed to keep both students and leading scientists updated on pressing issues in the field. Covering analytical, inorganic, organic, physical, and theoretical chemistry, the journal highlights major themes such as biochemistry, catalysis, environmental chemistry, materials, medicine, polymers, and supramolecular chemistry. It also welcomes articles on chemical education, health and safety, policy and public relations, and ethics and law.